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biosynthesized Persicaria odorata-silver nanoparticles supported zeolite Y as biocompatible antibacterial agent against Cutibacterium acnes

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PARTiCUOLOGY 2024年第10期93卷 1-10页

作者： Asraf, Muhammad Hariz Malek, nik Ahmad Nizam nik Radzi, Muhammad Redza Mohd Susanto, Hendra Univ Teknol Malaysia Fac Sci Dept Biosci Skudai 81310 Johor Malaysia Univ Teknol Malaysia Ibnu Sina Inst Sci & Ind Res ISI SIR Ctr Sustainable Nanomat CSNano Utm 81310 Johor Bahru Malaysia Univ Negeri Malang Fac Math & Nat Sci Dept Biol Malang Indonesia

Conventionally synthesized silver nanoparticles (AgNP) imposed an alarming effect on the environment and caused toxicity to humans. However, the use of zeolite (zeoY) as a support system could increase its biocompatibility and reduce its toxicity. Hence, green synthesis of AgNP using Persicaria odorata leaves extract supported on zeolite Y has been prepared by an in situ synthesis technique. The phytochemical compounds in the optimized leaf extract concentration of 1% and volume of 0.9 mL reduced the silver ions to AgNP within the zeolite Y pores. Morphological observation revealed the incorporation of AgNP in the zeolite Y (average size: 18.51 nm). The release of AgNP exhibited antibacterial activity on C. acnes at a concentration lower than 1 g L -1 which is also dependent on the electrolyte. AgNP-zeoY promoted cell proliferation in vitro and it has a non -irritating effect when tested in the in vivo skin irritation model. (c) 2024 Chinese Society of Particuology and institute of Process Engineering, Chinese Academy of Sciences. Published by Elsevier b.V. All rights are reserved, including those for text and data mining, Ai training, and similar technologies.

关键词： Silver nanoparticles biosynthesis Zeolite Antibacterial biocompatible ACiD

Catalytic co-combustion of biomass and brown coal in a fluidized bed:Economic and environmental benefits

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Journal of Environmental Sciences 2024年第6期140卷 24-36页

作者： Yury V.Dubinin nikolay A.Yazykov Petr M.Yeletsky Roman b.Tabakaev Aleksandra i.belyanovskaya Vadim A.Yakovlev Federal Research Center boreskov institute of Catalysis Sb RAS Lavrentiev Ave.5Novosibirsk630090Russia University of Tyumen Volodarskogo str.6Tyumen625003Russia

The work is devoted to the study of combustion of brown coal,pine sawdust,and their mixtures in a fluidized bed of catalyst at 600-750℃.it is shown that an increase in the content of sawdust in a mixture with brown coal leads to an increase in the burnout degree of solid fuel from 94.4%to 99.9%,while the emission of greenhouse gases in the form of CO_(2)CO and NOxis reduced(CO_(2)from the biomass is not included in the balance).The high content of alkaline earth metal oxides(CaO and MgO)in the mineral part of brown coal,sawdust,and their mixtures eliminates the emission of sulfur oxides and the slagging of heat-exchange surfaces during the combustion in a fluidized bed of *** optimal temperature,when the highest burnout degree of the above fuels is achieved in the combustion is 750℃.it is also shown that the increase in temperature and the content of sawdust in the composition of the fuel mixtures has a positive effect on the economic and environmental process indicators.

关键词： Co-combustion Fluidized catalyst bed biomass Coal Economic effect Environmental impact

Microstructure， electrochemical， wear and corrosive wear performance of laser-based powder bed fusion(lpbf) and wrought biomedical Ti-6Al-4V alloys

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Transactions of Nonferrous Metals Society of China 2024年

作者： A.G.Lekatou b.V.Efremenko V.Haoui V.G.Efremenko S.Emmanouilidou V.i.Zurnadzhy i.Petryshynets Yu.G.Chabak i.i.Sili Laboratory of Applied Metallurgy， Department of Materials Science and Engineering， School of Engineering， University of ioannina institute of Materials Science and Computing， University Research Center of ioannina (URCi) Pryazovskyi State Technical University， Department of Physics institute of Materials Research of Slovak Academy of Sciences

Wrought and laser powder bed fusion （LPbF） Ti-6Al-4V specimens were comparatively evaluated， with the objective to determine LPbF Ti-6-4’s suitability for biomedical applications. Testing included nanoindentation， cyclic polarization in simulated body fluid （SbF， 37 ℃ ）， and dry and SbF “ball-on-Plate” sliding. Wrought Ti-6-4 exhibited a lamellar （α+β） microstructure， whereas LPbF displayed a fine-grained α'-martensite microstructure. LPbF Ti-6-4 demonstrated ～3% higher indentation modulus and ～32% higher hardness， while wrought Ti-6-4 showed ～8% higher plasticity. both alloys exhibited low corrosion rates (10–5mA/cm2order) and true passivity (10–4mA/cm2order). No localized corrosion was observed in either alloy， except for occasional metastable pitting in the LPbF alloy. However， LPbF Ti-6-4 presented higher corrosion rate and passive current， ascribed to its martensitic structure. During dry sliding， LPbF Ti-6-4 exhibited ～14% lower volume loss compared to wrought Ti-6-4. Sliding in SbF increased volume losses for both alloys， with wear resistances nearly equalized， as the advantage of LPbF Ti-6-4 decreased due to more intensive wear-accelerated corrosion induced by the stressed martensite. Overall， the results demonstrate the suitability of LPbF Ti-6Al-4V for biomedical uses.

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Antibacterial HA-coatings on bioresorbable Mg alloy

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Journal of Magnesium and Alloys 2024年第5期12卷 1965-1985页

作者： K.V.Nadaraia D.V.Mashtalyar M.A.Piatkova A.i.Pleshkova i.M.imshinetskiy M.S.Gerasimenko E.A.belov V.V.Kumeiko D.N.Kozyrev K.A.Fomenko V.V.Mostovaya b.R.Torpanov A.R.biktimirov i.S.Osmushko S.L.Sinebryukhov S.V.Gnedenkov institute of Chemistry FEb RAS 159 Pr.100-letiya VladivostokaVladivostok 690022Russia Far Eastern Federal University 10 Ajax BayRussky IslandVladivostok 690922Russia A.V.Zhirmunsky National Scientific Center of Marine biology FEb RAS 17 St.PalchevskogoVladivostok 690041Russia Regional Clinical Dermatovenerological Dispensary 18 V St.GamarnikaVladivostok 690033Russia NMiC“Treatment and Rehabilitation Center” 3 Ivankovskoe highwayMoscow 125367Russia

in this study,a calcium-phosphate coating was formed on a Mg-Mn-Ce alloy by the plasma electrolytic oxidation(PEO).The antibiotic vancomycin,widely used in the treatment of infections caused by Staphylococcus aureus(***),was impregnated into the *** with vancomycin showed high bactericidal activity against *** mechanical and electrochemical properties of the formed coatings were studied,as well as in vitro cytotoxicity tests and in vivo tests on mature male rats were *** to SEM,EDS,XRD and XPS data,coatings had a developed morphology and contained hydroxyapatite,which indicates high *** analysis of roughness of coatings without and with vancomycin did not reveal any differences,confirming the high roughness of the *** electrochemical tests,an increase in corrosion resistance by more than two times after the application of PEO coatings was *** to the results of an in vivo study,after 28 days of the implantation of samples with calcium phosphate PEO coating and vancomycin,no signs of inflammation were observed,while an inflammatory reaction developed in the area of implantation of bare alloy,followed by *** release tests from the coatings show a sharp decrease in the concentration of the released antibiotic on day 7 and then a gradual decrease until day *** the experiment,no significant deviations in the condition and behavior of the animals were observed;clinical tests did not reveal a systemic toxic reaction.

关键词： bioactive coatings biocompatibility Mg alloy Plasma electrolytic oxidation Hydroxyapatite Vancomycin

SANC Monte Carlo programs for small-angle bhabha scattering

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Chinese Physics C 2024年第4期48卷 14-19页

作者： A.b.Arbuzov S.G.bondarenko i.R.boyko L.V.Kalinovskaya A.A.Kampf R.R.Sadykov V.L.Yermolchyk bogoliubov Laboratory of Theoretical Physics JINRDubna141980 Russia Dzhelepov Laboratory of Nuclear Problems JINRDubna141980 Russia Dubna State University Dubna141982 Russia

Luminosity monitoring at e^(+)e^(−)colliders was investigated using SANC Monte Carlo event generator ReneSANCe and integrator MCSANC for simulation of bhabha scattering at low *** are presented for center-of-mass energies of the Z boson resonance and at 240 GeV for the conditions of typical luminosity *** is shown that bremsstrahlung events with extremely low electron scattering angles are relevant to match the precision tags of future electron-positron colliders.

关键词： luminosity bhabha scattering QED Monte Carlo simulation

Old-growth mixed dipterocarp forests show variable losses and gains in aboveground biomass and standing carbon over forty years

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Forest Ecosystems 2024年第1期11卷 14-23页

作者： Sisira Ediriweera Champika bandara Tithira Lakkana Shanika Jayasinghe David Woodbury Arun Dayanandan b.M.P.Singhakumara Xiangcheng Mi i.A.U.N.Gunatilleke C.V.S.Gunatilleke Mark SAshton Department of Science and Technology Uva Wellassa UniversityBadullaSri Lanka The Forest School Yale School of the EnvironmentYale UniversityNew HavenCT06511USA Department of Forestry and Environmental Science University of Sri JayewardenepuraNugegodaSri Lanka State Key Laboratory of Vegetation and Environmental Change Institute of BotanyChinese Academy of SciencesBeijing100093China botany Department University of PeradeniyaPeradeniyaSri Lanka

background:No studies have documented long-term trends in aboveground biomass(AGb)for mixed-dipterocarp forests(MDF),the dominant rain forest type in tropical wet equatorial *** our study,we sought to document such trends over forty years across three sites representing lowland to lower montane ***:To do this,we established fifty 100 m×25 m plots in 1978 across three sites sampled along an elevation gradient,identified as mature old-growth *** measured trees for diameter at breast height that we identified to species and *** took wood samples to calculate species wood-specific *** re-measured plots in 1998 and again in ***:We show standing AGb for all sites combined to be 517.52 Mg·ha^(-1)in 1978,but this declined by 17%over 40 years to 430.11 Mg·ha^(-1).No differences exist among sites in AGb primarily because of considerable within site variation;but interactions of time with site show declines across sites were not uniform,one remained about the *** few species represented a high proportion of the AGb with the top five species comprising between 34%and 65%,depending upon site and year *** species,Mesua nagassarium,represented a disproportionately large amount of AGb and decline over time,particularly at the low elevation ***:Our results are directly relevant to estimating AGb and standing carbon sequestered in *** study is the first to demonstrate varying but overall,declining trends in amounts of AGb among forests making predictions of biomass and standing carbon in MDF difficult over wide regions.

关键词： Western ghats Shorea spp. Southeast Asia Sri Lanka Tropical rain forest Wood specific gravity

Effect of Al_(2)O_(3)on the Mechanical Properties of(b_(4)C+Al_(2)O_(3))/Al Neutron Absorbing Materials

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Acta Metallurgica Sinica(English Letters) 2024年第8期37卷 1411-1420页

作者： J.X.Cai b.M.Shi N.Li Y.Liu Z.G.Zhang Y.N.Zan Q.Z.Wang b.L.Xiao Z.Y.Ma Shi‑Changxu innovation Center for Advanced Materials Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China Key Laboratory of Nuclear Materials and Safety Assessment Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China Nuclear Equipment Division Beijing Institute of Nuclear EngineeringChina Nuclear Power Engineering Co.Ltd.Beijing 100840China Department of Materials Science School of Mechanical EngineeringShenyang UniversityShenyang 110044China

b_(4)C/Al composites are widely utilized as neutron absorbing materials for the storage and transportation of spent nuclear *** order to improve the high-temperature mechanical properties of b_(4)C/Al composites,in-situ nano-Al_(2)O_(3)was introduced utilizing oxide on Al powder *** this study,the Al_(2)O_(3)content was adjusted by utilizing spheroid Al powder with varying diameters,thereby investigating the impact of Al_(2)O_(3)content on the tensile properties of(b_(4)C+Al_(2)O_(3))/Al *** was found that the pinning effect of Al_(2)O_(3)on the grain boundaries could hinder the recovery of dislocations and lead to dislocation accumulation at high *** the result,with the increase in Al_(2)O_(3)content and the decrease in grain size,the high-temperature strength of the composites increased *** finest Al powder used in this investigation had a diameter of 1.4μm,whereas the resultant composite exhibited a maximum strength of 251 MPa at room temperature and 133 MPa at 350℃,surpassing that of traditional b_(4)C/Al composites.

关键词： Al matrix composites Neutron absorbing materials (b_(4)C+Al_(2)O_(3))/Al composites High-temperature strength

Measurement of yields and angular distributions ofγ-quanta from the interaction of 14.1 MeV neutrons with oxygen,phosphorus,and sulfur

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Chinese Physics C 2024年第3期48卷 79-92页

作者： D.N.Grozdanov N.A.Fedorov S.b.Dabylova Yu.N.Kopatch i.N.Ruskov V.R.Skoy T.Yu.Tretyakova C.Hramco P.i.Kharlamov G.V.Pampushik P.G.Filonchik A.V.Andreev Joint institute for Nuclear Research(JiNR) DubnaRussia institute for Nuclear Research and Nuclear Energy Bulgarian Academy of SciencesSofiaBulgaria Faculty of Physics Lomonosov Moscow State UniversityMoscowRussia L.N.Gumilyov Eurasian National University AstanaKazakhstan Skobeltsyn institute of Nuclear Physics Moscow State UniversityMoscowRussia institute of Chemistry of Moldova ChisinauRepublic of Moldova Moscow institute of Physics and Technology MoscowRussia

A study of the inelastic scattering of neutrons with an energy of 14.1 MeV on the nuclei of oxygen,phosphorus,and sulfur was performed at the TANGRA facility at JiNR(Dubna).The experiment aimed to refine existing data and obtain new data on the yields and angular distributions ofγ-quanta emitted by the studied nuclei due to neutron-induced nuclear reactions using the tagged neutron *** types of detector systems were used to registerγ-***γ-ray yields were measured using a high-purity germanium(HPGe)*** angular distributions ofγ-rays were obtained using a system of 18 scintillation detectors based on bismuth germanite bi_(4)Ge_(3)O_(12)(bGO)located around the *** performed experiments measured the yields of two transitions for the reaction of tagged neutrons with 16O,nine transitions for the reaction with ^(31)P,and nine transitions for the reaction with ^(32)S for the first *** angular anisotropy of theγ-radiation accompanying the inelastic scattering of neutrons with an energy of 14.1 MeV on ^(31)P nuclei was also measured for the first time.

关键词： tagged neutron method yields of gamma-quanta high-resolution gamma-spectrometry neutron-nuclear reactions neutron scattering

The Adsorption Properties of TEMPO Oxidized Cellulose against the Mixture of Methylene blue and Rhemazol Yellow FG

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Journal of Renewable Materials 2024年第8期12卷 1369-1382页

作者： i.Putu Mahendra Kartika Dinita Program Studi Kimia Fakultas SainsInsitut Teknologi SumateraJalan Terusan RyacuduWay HuwiJati AgungLampung Selatan35365Indonesia

TEMPO/NaOCl/Nabr treatment significantly increased the number of negative charges on the cellulose *** concentrations of NaOCl,5 and 30 mmol/g of cellulose,were used in this *** number of carboxyl groups in the two cellulosic samples oxidized using TEMPO/NaOCl/Nabr was 0.5160 and 1.8461 mmol/g of cellulose,*** oxidized cellulose samples treated with 5 and 30 mmol/g NaOCl exhibited higher crystallinity,at 81.15%and 80.14%,respectively,compared to untreated cellulose,which had a crystallinity of 75.95%.The pH effect indicated that the highest adsorption capacity for methylene blue was achieved under alkaline conditions(pH 9),while the highest adsorption capacity for rhemazol yellow FG was achieved under acidic *** kinetic model of TEMPO-oxidized cellulose for methylene blue and rhemazol yellow FG conformed to the pseudo-second-order *** initial concentration parameter revealed that the isotherm model for the adsorption of methylene blue and rhemazol yellow FG by TEMPO-oxidized cellulose conformed to the Langmuir *** dye removal efficiencies for methylene blue and rhemazol yellow FG using TEMPOoxidized cellulose(30 mmol/g)were approximately 80.17%and 59.52%,*** results demonstrate that TEMPO/NaOCl/Nabr-oxidized samples can effectively separate cationic and anionic dye ***,the use of TEMPO-oxidized cellulose showed good regeneration capability,maintaining more than 95%of its adsorption capacity after 8 cycles.

关键词： Cellulose TEMPO oxidation cationic and anionic dyes dye separation