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Improved Cycle Properties of FeS_2 Cathode Material with Metallic Additives

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材料科学与工程学报 2007年第6期25卷 910-913页

作者： Jae-Won Choi Jae-Kwang Kim Gouri Cheruvally Jou-Hyeon ahn Ki-Won Kim hyo-jun ahn Dong-Kyu Park Department of Chemical & Biological Engineering and Engineering Research Institute Gyeongsang National University900 Gajwa-dongJinju660-701Korea School of Nano and Advanced Materials Engineering and Engineering Research Institute Gyeongsang National University900 Gajwa-dongJinju660-701Korea Kaya Advanced Material Art Inc. Baekrok-Ri 1010-1Yangsan 626-862Korea

Iron disulfide(FeS_2)cathode active material was prepared from iron and sulfur at room temperature by high energy mechanical *** FeS_2 composites containing Co or Ni transition metal powders as additives were also prepared by the same *** cells with these FeS_2 cathodes were studied for charge-discharge properties at room temperature using 0.5M LiTFSI in tetra(ethylene glycol)dimethyl ether(TEGDME)*** voltammetry showed two anodic oxidation peaks at 1.8 and 2.5V and two cathodic reduction peaks at 2.0 and 1.3 V for FeS_2 with metal *** addition of 5wt% Co and 3wt% Ni resulted in an enhancement of the first discharge capacity giving 571 and 844mAh/g respectively at *** cycle performance was also enhanced remarkably by the addition of these electrically conductive transition metals in the active ***_2 with 5wt% Co exhibited a stable cycle performance delivering a reversible capacity of 338mAh/g(37.8% of theoretical capacity)after 20 cycles.

关键词：阴极材料二硫化铁锂离子电池循环性能

Effect of Oxide Assisted Metal Nanoparticles on Microstructure and Morphology of Gallium oxide Nanowires

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材料科学与工程学报 2007年第6期25卷 886-891页

作者： Kyo-Hong CHOI Kwon-Koo CHO Gyu-Bong CHO hyo-jun ahn Ki-Won KIM Yoo-Young KIM School of Nano & Advanced Materials Engineering ERI & i-cube centerGyeongsang National University900 GazwadongJinjuGyeongnam 660-701Korea Dept.of Mechanical Engineering Jinju National UniversityJinjuKorea

Several researches have been reported about the characteristic of β-Ga_2O_3 nanowires which was synthesized on nickel oxide *** indeed,recent researches about synthesis of β-Ga_2O_3 nanowires on oxide-assisted transition metal are limited to nickel or cobalt oxide *** this work,Gallium oxide(β-Ga_2O_3)nanowires were synthesized by a simple thermal evaporation method from gallium powder in the range of 700-1000℃ using the iron,nickel,copper,cobalt and zinc oxide as a catalyst,*** β-Ga_2O_3 nanowires with single crystalline without defects were successfully synthesized at the reaction temperature of 850,900 and 950℃ in all the *** optimum experimental condition in synthesis of nanowires varied with the kind of *** increasing synthesis temperature,the morphology of gallium oxide nanowires changed from nanowires to nanorods,and its diameter *** these results,we could be proposed that the growth mechanism of β-Ga_2O_3 nanowires was changed with synthesis temperature of *** and morphology of Synthesized nanowire was characterized by HR-TEM,FE-SEM,EDX and XRD.

关键词：金属纳米粒子显微结构镓氧化物形态学

Electrochemical Intercalation of Sodium into Silicon Thin Film

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材料科学与工程学报 2008年第1期26卷 141-144页

作者： Dong-Yeon Kim hyo-jun ahn Gyu-Bong Cho Jong-Seon Kim Ho-Suk Ryu Ki-Won Kim Jou-Hyeon ahn Won-Cheol Shin I-cube center nano advanced materials Engineering Gyeongsang National Uhiversity Jinju 660-701 Korea Department of Chemical ＆ Biological Engineering Gyeongsang National University J inju 660-701 Korea INOSTEK Inc Gyeonggi Technopark 1271-11 Sal-dong Sangnok-gu Ansan-si Gyeonggi-do 426-901 Korea

In order to investigate the possibility of Si thin film as an anode for Na battery,we studied the electrochemical intercalation of sodium into the Si *** Si thin film electrode was prepared using DC magnetron *** ion could intercalate into Si thin film upto Na0.52Si,i.e.530mAh·*** first discharge capacity was 80mAh·g-1-Si,which meant reversible amount of sodium *** discharge capacity slightly decreased to 70mAh·g-1-Si after 10 cycles.

关键词：钠插层反应电池硅薄膜电极直流电磁控溅射

Atypical case of bow hunter’s syndrome linked to aberrantly coursing vertebral artery: A case report

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World Journal of Clinical Cases 2023年第35期11卷 8399-8403页

作者： jun hyong ahn hyo Sub jun In Kyeong Kim Choong hyo Kim Seung Jin Lee Department of Neurosurgery Kangwon National University School of MedicineKangwon National University HospitalGangwon-doChuncheon-si 24289South Korea

BACKGROUND In bow hunter’s syndrome(BHS),also known as rotational vertebral artery(VA)syndrome,there is dynamic/rotational compression of the VA producing verte-brobasilar *** occurrences involve atlantoaxial rather than mid-cervical VA compromise,the latter being rarely ***,we detail successful VA decompression at mid-cervical spine,given a departure from its usual *** SUMMARY The patient,a 45-year-old man,presented to our hospital with occipital headache and *** tomography angiography showed anomalous C4 entry of right VA,with compression upon head rotation to that *** cartilage and anterior tubercle of C5 transverse process were visibly at *** opted for sur-gery,using an anterior cervical approach to remove the anterior *** recovery was uneventful and brought resolution of all preoperative *** BHS is an important consideration where aberrant coursing of VA and neurologic symptoms coexist.

关键词： Bow hunter’s syndrome Vertebral artery Vertebrobasilar insufficiency Case report

The Arabidopsis Floral Repressor BFT DelaysFlowering by Competing with FT for FD Bindingunder High Salinity

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Molecular Plant 2014年第2期7卷 377-387页

作者： Jae Yong Ryu hyo-jun Lee Pil Joon Seo Jae-Hoon jung Ji Hoon ahn Chung-Mo Park Department of Chemistry Seoul National University Seoul 151-742 Korea Present address: Department of Chemistry Chonbuk National University Jeonju 561-756 Korea The Sainsbury Laboratory University of Cambridge Cambridge UK Creative Research Initiatives Division of Life Sciences Korea University Seoul 136-701 Korea PGBI Seoul National University Seoul 151-742 Korea

Soil salinity is one of the most serious agricultural problems that significantly reduce crop yields in the aridand semi-arid regions. It influences various phases of plant growth and developmental processes, such as seed germina-tion, leaf and stem growth, and reproductive propagation. Salt stress delays the onset of flowering in many plant spe-cies. We have previously reported that the Arabidopsis BROTHER OF FT AND TFL1 （BFT） acts as a floral repressor undersalt stress. However, the molecular mechanisms underlying the BFT function in the salt regulation of flowering inductionis unknown. In this work, we found that BFT delays flowering under high salinity by competing with FLOWERING LOCUST （FT） for binding to the FD transcription factor. The flowering time of FD-deficient fd-2 mutant was insensitive to highsalinity. BFT interacts with FD in the nucleus via the C-terminal domain of FD, which is also required for the interactionof FD with FT, and interferes with the FT-FD interaction. These observations indicate that BFT constitutes a distinct saltstress signaling pathway that modulates the function of the FT-FD module and possibly provides an adaptation strategythat fine-tunes photoperiodic flowering under high salinity.

关键词： Arabidopsis BFT FD flowering time FT salt stress

Effect of Ni and Mn on the Mechanical Properties of 22Cr Microduplex Stainless Steel

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Acta Metallurgica Sinica(English Letters) 2015年第1期28卷 32-38页

作者： jun-Young Park Yong-Sik ahn Department of Materials Science and Engineering Pukyong National University

The tensile properties of 22Cr–2Ni–4Mn–0.2N micro-duplex stainless steels with different Ni and Mn contents were investigated. Duplex stainless steels were vacuum induction melted and hot rolled, then annealed at 1,000–1,100 °C, at which temperature both the austenite and ferrite phases were stable. The volume fraction of the ferrite phase was markedly affected by the alloying elements of Mn and Ni; 1 wt% of Mn was equivalent to 0.4 wt% of Ni. All of the steels tested at room temperature showed the common strain-hardening behavior, while the steels tested at lower temperatures（-30 or-50 °C）showed a distinct inflection point in their stress–strain curves, which resulted from the transformation of the austenite to straininduced martensite. The onset strain（e0） of the inflection point in the stress–strain curve depended on the Md30 value of the steel. Testing at lower temperatures resulted in smaller e0 and consequently higher strengths and fracture strains（ef）. The tensile behavior was examined from the perspective of austenite stability of the micro-duplex stainless steels with the different Ni and Mn contents.

关键词： Duplex stainless steel Microstructure Mechanical property Alloy composition

Fracture Characteristics of Frit Bonding through In-Situ Nano-Indentation Testing

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Journal of Materials Science & Technology 2016年第11期32卷 1204-1210页

作者： Won Je Jo Hee-jun ahn Jong hyoung Kim Dongil Kwon Department of Materials Science and Engineering Seoul National University

Because frit bonding material is brittle, sudden impacts such as dropping may damage the bonding significantly. Strain-rate-controlled in-situ nano-indentation testing, which can determine localized material properties, was carried out on the frit-bonded specimen, especially on the frit bonding matrix and the filler. The results were compared with the drop-impact fracture behavior to understand the fracture characteristics. Mechanical properties at static condition or low strain rate did not show proper relationship with the fracture tendency of the drop tested result of the frit bonding. From the relationship between fracture toughness and the ratio of modulus/hardness, fracture characteristics at the drop impact situation could be estimated by the values at the high strain rate nano-indentation. The ratio between modulus and hardness on frit matrix showed close relationship with drop impact fracture. Though crack propagation path deflected at filler interface, filler property gave less influence on fracture tendency of drop impact fracture due to its small volume fraction. The properties of frit matrix were crucial to the fracture characteristics of the frit bonding.

关键词： Nanoindentation Bonding Fracture behavior

Increased susceptibility of ethanol-treated gastric mucosa to naproxen and its inhibition by DA-9601, an Artemisia asiatica extract

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World Journal of Gastroenterology 2005年第47期11卷 7450-7456页

作者： Tae Young Oh Gook jun ahn Seul Min Choi Byoung Ok ahn Won Bae Kim Research Laboratories Dong-A Pharm. Co.Ltd.47-5SanggalKiheungYonginKyunggi449-905South Korea

AIM： To examine the effect of DA-9601, a new gastroprotective agent, on the vulnerability of ethanoltreated rat＇s stomach to naproxen （NAP）. METHODS： Male Sprague-Dawley rats were pretreated with 1 mL of 50% ethanol twice a day for 5 d and then NAP （50 mg/kg） was administered. DA-9601 was admin- istered 1 h before NAP. Four hours after NAP, the rats were killed to examine gross injury index （mm2）, histologic change and to determine mucosal levels of malondialdehyde （MDA）, prostaglandin E2 （PGE2）, glutathione （GSH） and myeloperoxidase （MPO）. RESULTS： Pretreatment of ethanol significantly increased NAP-induced gastric lesions, as well as an increase in NDA and MPO. On the contrary, mucosal PGE2 and GSH contents were decreased dramatically by ethanol pretreatment, which were aggravated by NAR DA-9601 significantly reduced NAP-induced gastric injury grossly and microscopically, regardless of pretreatment with ethanol. DA-9601 preserved, or rather, increased mucosal PGE2 and GSH in NAP-treated rats （P〈0.05）, with reduction in mucosal MDA and MPO levels. CONCLUSION： These results suggest that repeated alcohol consumption renders gastric mucosa more susceptible to NSAIDs though, at least in part, reduction of endogenous cytoprotectants including PGE2 and GSH, and increase in MPO activation, and that DA-9601, a new gastroprotectant, can reduce the increased vulnerability of ethanol consumers to NSAIDs-induced gastric damage via the mechanism in which PGE2 and GSH are involved.

关键词： DA-9601 Alcohol Naproxen Gastric damage Malondialdehyde Prostaglandin E2 Glutathione Myeloperoxidase NSAIDS

Defect Engineering in Earth-Abundant Cu_(2)ZnSnSe_(4) Absorber Using Efficient Alkali Doping for Flexible and Tandem Solar Cell Applications

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Energy & Environmental Materials 2024年第2期7卷 249-256页

作者： Muhammad Rehan Ara Cho Inyoung Jeong Kihwan Kim Asmat Ullah jun-Sik Cho Joo Hyung Park Yunae Jo Sung jun Hong Seung Kyu ahn SeJin ahn Jae Ho Yun Jihye Gwak Donghyeop Shin Photovoltaics Research Department Korea Institute of Energy Research(KIER)152-Gajeong-roYuseong-guDaejeon 34129Korea Department of Renewable Energy Engineering University of Science and Technology(UST)217-Gajeong-roYuseong-guDaejeon 34113Korea Korea Institute of Energy Technology(KENTECH) 50772 Ujeong-roNaju Jeonnam 58217Korea

To demonstrate flexible and tandem device applications,a low-temperature Cu_(2)ZnSnSe_(4)(CZTSe)deposition process,combined with efficient alkali doping,was ***,high-quality CZTSe films were grown at 480℃by a single co-evaporation,which is applicable to polyimide(PI)*** of the alkali-free substrate,Na and K alkali doping were systematically studied and optimized to precisely control the alkali distribution in *** bulk defect density was significantly reduced by suppression of deep acceptor states after the(NaF+KF)*** the low-temperature deposition with(NaF+KF)PDTs,the CZTSe device on glass yields the best efficiency of 8.1%with an improved Voc deficit of 646 *** developed deposition technologies have been applied to *** the first time,we report the highest efficiency of 6.92%for flexible CZTSe solar cells on ***,CZTSe devices were utilized as bottom cells to fabricate four-terminal CZTSe/perovskite tandem cells because of a low bandgap of CZTSe(~1.0 eV)so that the tandem cell yielded an efficiency of 20%.The obtained results show that CZTSe solar cells prepared by a low-temperature process with in-situ alkali doping can be utilized for flexible thin-film solar cells as well as tandem device applications.

关键词： alkali doping Earth-abundant Cu_(2)ZnSnSe_(4) flexible solar cells four-terminal tandem cells low-temperature process