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Pd Pt VO_(x)/CeO_(2)-ZrO_(2):Highly efficient catalysts with good sulfur dioxide-poisoning reversibility for the oxidative removal of ethylbenzene

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Journal of Environmental Sciences 2024年第4期138卷 153-166页

作者： Jia Wang Yuxi Liu Jiguang Deng lin Jing Xiuqing Hao Xing Zhang Xiaohui Yu Hongxing Dai Beijing Key Laboratory for Green Catalysis and Separation Key Laboratory of Beijing on Regional Air Pollution ControlKey Laboratory of Advanced Functional MaterialsEducation Ministry of ChinaLaboratory of Catalysis Chemistry and NanoscienceDepartment of Chemical EngineeringFaculty of Environment and LifeBeijing University of TechnologyBeijing 100124China

The PdPtVO_(x)/CeO_(2)-ZrO_(2)(PdPtVO_(x)/CZO)catalysts were obtained by using different approaches,and their physical and chemical properties were determined by various *** activities of these materials in the presence of H_(2)O or SO_(2)were evaluated for the oxidation of ethylbenzene(EB).The PdPtVO_(x)/CZO sample exhibited high catalytic activity,good hydrothermal stability,and reversible sulfur dioxide-poisoning performance,over which the specific reaction rate at 160℃,turnover frequency at 160℃(TOF_(Pd or Pt)),and apparent activation energy were 72.6 mmol/(g_(Pt)·sec)or 124.2 mmol/(g_(Pd)·sec),14.2 sec^(-1)(TOF_(Pt))or 13.1 sec^(-1)(TOF_(Pd)),and 58 k J/mol,*** large EB adsorption capacity,good reducibility,and strong acidity contributed to the good catalytic performance of PdPtVO_(x)/*** activity of PdPtVO_(x)/CZO decreased when 50 ppm SO_(2)or(1.0 vol.%H_(2)O+50 ppm SO_(2))was added to the feedstock,but was gradually restored to its initial level after the SO_(2)was cut *** good reversible sulfur dioxide-resistant performance of PdPtVO_(x)/CZO was associated with the facts:(i)the introduction of SO_(2)leads to an increase in surface acidity;(ii)V can adsorb and activate SO_(2),thus accelerating formation of the SO_(x)^(2-)(x=3 or 4)species at the V and CZO sites,weakening the adsorption of sulfur species at the PdPt active sites,and hence protecting the PdPt active sites to be not poisoned by SO_(2).EB oxidation over PdPtVO_(x)/CZO might take place via the route of EB→styrene→phenyl methyl ketone→benzaldehyde→benzoic acid→maleic anhydride→CO_(2)and H_(2)O.

关键词： Ceria-zirconia Supported palladium-platinum-vanadium catalyst Volatile organic compound Ethylbenzene oxidation Sulfur dioxide resistance

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Low-frequency bandgap and vibration suppression mechanism of a novel square hierarchical honeycomb metamaterial

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Applied Mathematics and Mechanics(English Edition) 2024年第10期45卷 1841-1856页

作者： Xingjian DONG Shuo WANG Anshuai WANG Liang WANG Zhaozhan ZHANG Yuanhao TiE Qingyu lin Yongtao SUN State Key Laboratory of Mechanical Systems and Vibration Shanghai Jiao Tong UniversityShanghai 200240China Department of Mechanics Tianjin UniversityTianjin 300350China Tianjin Key Laboratory of Nonlinear Dynamics and Control Tianjin UniversityTianjin 300350China School of Mechanical and Automotive Engineering Guangxi University of Science and TechnologyLiuzhou 545006Guangxi Zhuang Autonomous RegionChina

The suppression of low-frequency vibration and noise has always been an important issue in a wide range of engineering *** address this concern,a novel square hierarchical honeycomb metamaterial capable of reducing low-frequency noise has been *** combining Bloch’s theorem with the finite element method,the band structure is *** results indicate that this metamaterial can produce multiple low-frequency bandgaps within 500 Hz,with a bandgap ratio exceeding 50%.The first bandgap spans from 169.57 Hz to 216.42 *** reveal the formation mechanism of the bandgap,a vibrational mode analysis is *** analysis demonstrates that the bandgap is attributed to the suppression of elastic wave propagation by the vibrations of the structure’s two protruding corners and overall expansion ***,detailed parametric analyses are conducted to investigate the effect ofθ,i.e.,the angle between the protruding corner of the structure and the horizontal direction,on the band structures and the total effective bandgap *** is found that reducingθis conducive to obtaining lower frequency *** propagation characteristics of elastic waves in the structure are explored by the group velocity,phase velocity,and wave propagation ***,the transmission characteristics of a finite periodic structure are investigated *** results indicate significant acceleration amplitude attenuation within the bandgap range,confirming the structure’s excellent low-frequency vibration suppression capability.

关键词： wave propagation vibration suppression metamaterial low-frequency bandgap

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Endoplasmic reticulum stress improved chicken tenderness,promoted apoptosis and autophagy during postmortem ageing

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Food Science and Human Wellness 2024年第4期13卷 2141-2151页

作者： Yuwei Chai lin Chen Shuya Xiang linxuan Wu Xuebo Liu Jun Luo Xianchao Feng College of Food Science and Engineering Northwest A&F UniversityYangling 712100China College of Animal Science and Technology Northwest A&F UniversityYangling 712100China

in this study,endoplasmic reticulum(ER)stress inducer tunicamycin(TM)and inhibitor 4-phenylbutyric acid(4-PBA)were used to treat postmortem chicken breast muscle to investigate changes in tenderness and effects on apoptosis and autophagy during 5 days ***-induced ER stress reduced shear force,enhanced myofibril fragmentation index(MFi),disrupted myofibril structure,increased desmin degradation,and activatedμ-calpain and *** addition,TM-induced ER stress increased the expression of Bax,Bim,and cytochrome c,and decreased the expression of Bcl-x ***,TM-induced ER stress improved the conversion of LC3i to LC3ii,raised the expression of Beclin-1,and decreased the expression of p62,Pi3K,and m *** opposite results were observed after 4-PBA *** results suggested that ER stress could improve chicken tenderness,promote apoptosis and autophagy during chicken postmortem ageing.

关键词： Endoplasmic reticulum stress Tenderness Apoptosis Autophagy Chicken

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CRiSPR/Cas9-mediated NlinR2 mutants:Analyses of residual mRNA and truncated proteins

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Journal of integrative Agriculture 2024年第6期23卷 2006-2017页

作者： Jun Lü Jingxiang Chen Yutao Hu lin Chen Shihui Li Yibing Zhang Wenqing Zhang State Key Laboratory of Biocontrol/School of Life Sciences Sun Yat-sen UniversityGuangzhou 510275China Development of Food Science and Engineering Moutai InstituteRenhuai 564507China

CRiSPR/Cas9 technology is a powerful genome manipulation tool in ***,little is known about whether mRNA and protein of a target gene are completely cleared in homozygous *** study generated homozygous mutants of the insulin receptor gene 2(NlinR2)in the brown planthopper(Nilaparvata lugens)using CRiSPR/Cas9 genome *** frameshift mutants,E5_D17 and E6_i7,differentiated towards long wings,but there were differences in wing morphology,with E5_D17 showing wing *** investigations revealed the presence of residual expression of NlinR2 mRNA in both mutants,as well as the occurrence of spliceosomes featuring exon skipping splicing in E5_***,the E5_D17 exhibited the detection of N-terminally truncated NlinR2 *** interference experiments indicated that the knockdown of NlinR2 expression in the E5_D17 mutant line increased the proportion of wing deformities from 11.1 to 65.6%,suggesting that the residual NlinR2 mRNA of the E5_D17 mutant might have retained some genetic *** results imply that systematic characterization of residual protein expression or function in CRiSPR/Cas9-generated mutant lines is necessary for phenotypic interpretation.

关键词： CRiSPR/Cas9 Nilaparvata lugens residual mRNA skipping exon truncated protein

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Litter quality and decomposer complexity co-drive effect of drought on decomposition

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Forest Ecosystems 2024年第3期11卷 329-338页

作者： Shumei Wang Junwei Luan Siyu Li Jinhao Ma lin Chen Yi Wang Shirong Liu Sanya Research Base International Centre for Bamboo and RattanSanya572022China institute of Resources and Environment Key Laboratory of Bamboo and Rattan Science and Technology of National Forestry and Grassland AdministrationInternational Centre for Bamboo and RattanBeijing100102China Key Laboratory of Forest Ecology and Environment of National Forestry and Grassland Administration Ecology and Nature Conservation InstituteChinese Academy of ForestryBeijing100091China Experimental Center of Tropical Forestry Chinese Academy of ForestryPingxiang532600China institute of Qinghai-Tibetan Plateau Southwest Minzu UniversityChengdu610041China

Litter decomposition is key to ecosystem carbon(C)and nutrient cycling,but this process is anticipated to weaken due to projected more extensive and prolonged *** how litter quality and decomposer community complexity regulate decomposition in response to drought is less ***,in a five-year manipulative drought experiment in a Masson pine forest,leaf litter from four subtropical tree species(Quercus griffthii Hook.f.&Thomson ex Miq.,Acacia mangium Willd.,Pinus massoniana Lamb.,Castanopsis hystrix Miq.)representing different qualities was decomposed for 350 d in litterbags of three different mesh sizes(i.e.,0.05,1,and 5 mm),respectively,under natural conditions and a 50%throughfall rain exclusion *** of increasing mesh sizes discriminate decomposer communities(i.e.,microorganisms,microorganisms and mesofauna,microorganisms and meso-and macrofauna)that access the litter and represent an increasing *** amount of litter C and nitrogen(N)loss,and changes in their ratio(C/N_(loss)),as well as small and medium-sized decomposers including microorganisms,nematodes,and arthropods,were *** found that drought did not affect C and N loss but decreased C/N_(loss)(i.e.,decomposer N use efficiency)of leaf litter irrespective of litter quality and decomposer ***,changes in the C/N_(loss)and the drought effect on C loss were both dependent on litter quality,while drought and decomposer complexity interactively affected litter C and N *** decomposer community complexity enhanced litter decomposition and allowing additional access of meso-and macro-fauna to litterbags mitigated the negative drought effect on the microbial-driven ***,both the increased diversity and altered trophic structure of nematode due to drought contributed to the mitigation effects via cascading *** results show that litter quality and soil decomposer community complexity co-drive the effect of

关键词： Arthropod Drought Decomposer community Nutrient cycling Nematode

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A New Species of the Genus Boulenophrys(Anura,Megophryidae)from Eastern Guangdong,China

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Asian Herpetological Research 2024年第1期15卷 12-21页

作者： Zhaochi ZENG Jian WANG Honghui CHEN Weiwen XiAO Binbin ZHAN Yuanhang Li Shishi lin Guangdong Polytechnic of Environmental Protection Engineering Foshan 528216GuangdongChina

A new horned toad species,Boulenophrys elongata ***.,is described from ***,Huidong County,eastern Guangdong,*** new species is phylogenetically closest to ***,which is restricted to the east of the Pearl River Estuary(i.e.,Shenzhen City and Hong Kong SAR).The new species can be distinguished from all recognized congeners by a combination of morphological characters and genetic divergences in the combined mitochondrial 16S,12S and CO1 *** recommend the new species be listed as Data Deficient(DD)in the iUCN categorization,pending further investigation.

关键词： Boulenophrys elongata sp.nov. Lianhua Mountains molecular phylogeny morphology taxonomy

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Global and regional soil organic carbon estimates:Magnitudes and uncertainties

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Pedosphere 2024年第4期34卷 685-698页

作者： Ziqi lin Yongjiu DAi Umakant MiSHRA Guocheng WANG Wei SHANGGUAN Wen ZHANG Zhangcai QiN School of Atmospheric Sciences Guangdong Province Key Laboratory for Climate Change and Natural Disaster StudiesSun Yat-sen UniversityZhuhai 519082China Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai) Zhuhai 519082China Computational Biology&Biophysics Sandia National LaboratoriesLivermore CA 94550USA Faculty of Geographical Science Beijing Normal UniversityBeijing 100875China State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing 100029China

Globally,soil is the largest terrestrial carbon(C)*** quantification of soil organic C(SOC)stocks in existing global observation-based estimates avails accurate predictions in carbon-climate feedbacks and future climate *** investigated the magnitudes and distributions of global and regional SOC estimates(i.e.,density and stocks)based on five widely used global gridded SOC datasets,a regional permafrost dataset developed in 2021(UM2021),and a global-scale soil profile database(World Soil information Service)reporting measurements of a series of physical and chemical edaphic *** five global gridded SOC datasets were the Harmonized World Soil Database(HWSD),World inventory of Soil Emission Potentials at 30 arc-second resolution(WiSE30sec),Global Soil Dataset for Earth System Models(GSDE),Global Gridded Soil information at 250-m resolution(SoilGrids250m),and Global Soil Organic Carbon Map(GSOCmap).Our analyses showed that the magnitude and distribution of SOC varied widely among datasets,with certain datasets showing region-specific *** the global scale,SOC stocks at the top 30 and 100 cm were estimated to be 828(range:577–1171)and 1873(range:1086–2678)Pg C,*** estimates from GSDE,GSOCmap,and WiSE30sec were comparable,and those of SoilGrids250m and HWSD were at the upper and lower *** spatial SOC distribution varied greatly among datasets,especially in the northern circumpolar and Tibetan Plateau permafrost ***,UM2021 and WiSE30sec performed well in the northern circumpolar permafrost regions,and GSDE performed well in *** estimates of SOC by different datasets also showed large variabilities across different soil layers and *** discrepancies were generally smaller for the 0–30 cm soil than the 0–100 cm *** datasets demonstrated relatively higher agreement in grasslands,croplands,and shrublands/savannas than in other biomes(e.g.,wetlands).The users should be mindful of the gaps b

关键词： biome carbon cycle Earth System Models permafrost region soil dataset soil map

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M2-type macrophage membrane-mediated delivery of Carvedilol nanocomplex for acute liver failure treatment and remodeling inflammatory microenvironment

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Nano Research 2024年第7期17卷 6362-6375页

作者： Mingge Shang Yaohui Zhang Junjie Qian Wenchao Wang Xizhi Yu Jiacheng Huang lin Zhou Shusen Zheng Division of Hepatobiliary and Pancreatic Surgery Department of SurgeryThe First Affiliated HospitalZhejiang University School of MedicineHangzhou 310003China NHC Key Laboratory of Combined Multi-organ Transplantation Key Laboratory of Organ TransplantationHangzhou 310003China Key Laboratory of the diagnosis and treatment of organ Transplantation Research Unit of Collaborative Diagnosis and Treatment for Hepatobiliary and Pancreatic CancerChinese Academy of Medical Sciences(2019RU019)Hangzhou 310003China State Key Laboratory for Diagnosis and Treatment of infectious Diseases National Clinical Research Center for Infectious DiseasesHangzhou 310003China Department of Thyroid Surgery The First Affiliated HospitalZhejiang University School of MedicineHangzhou 310003China Shulan(Hangzhou)Hospital Affiliated to Zhejiang Shuren University Shulan international Medical College Hangzhou 310000China

interactions of hepatic macrophages with local inflammatory microenvironment is the key factor promoting the development of acute liver failure(ALF).Hence,reprogramming pro-inflammatory M1 into anti-inflammatory M2 phenotype may offer a promising strategy for treating ALF by targeting *** group found Carvedilol possessed potential anti-inflammatory property previously,which had been scarcely reported in *** present a synergy strategy to induce macrophages into the phenotype M2-type anti-inflammatory macrophages with interleukin-4(iL-4)and iL-10 at *** Carvedilol is loaded on the macrophage membrane-camouflaged biomimetic nano-platform(termed as M2M@CNP)to evade reticuloendothelial system(RES)and afford Carvedilol delivery to the inflammatory environment with overproduced reactive oxygen species(ROS),further prolonging its circulation and *** released Carvedilol produced anti-inflammatory,antioxidant and anti-apoptosis effects,combining local M2-type cell membranes(M2-CM)inhibited pro-inflammatory cytokines and ROS levels,which in turn promoted and amplified M1 to M2 phenotype polarization *** study offers new insights into the rational design of biomimetic nanosystems for safe and effective ALF therapy to accelerate the clinical translation.

关键词： acute liver failure hepatic drug delivery M2 macrophage-camouflaged nanoplatform inflammatory microenvironment macrophage polarization

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Glioma-derived ANXA1 suppresses the immune response to TLR3 ligands by promoting an anti-inflammatory tumor microenvironment

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Cellular & Molecular immunology 2024年第1期21卷 47-59页

作者： Yu Zheng Haihui Jiang Naixue Yang Shaoping Shen Daosheng Huang Lemei Jia Jing ling Longchen Xu Mingxiao Li Kefu Yu Xiaohui Ren Yong Cui Xun Lan Song lin Xin lin institute for immunology and School of Medicine Tsinghua UniversityBeijing100084China Department of Neurosurgery Beijing Tiantan HospitalCapital Medical UniversityChina.National Clinical Research Center for Neurological DiseasesCenter of Brain TumorBeijing Institute for Brain Disorders and Beijing Key Laboratory of Brain TumorBeijing100070China Department of Neurosurgery Peking University Third HospitalPeking UniversityBeijing100191China Tsinghua-Peking Center for Life Sciences Beijing100084China

A highly immunosuppressive tumor microenvironment(TME)and the presence of the blood‒brain barrier are the two major obstacles to eliciting an effective immune response in patients with high-grade glioma(HGG).Here,we tried to enhance the local innate immune response in relapsed HGG by intracranially injecting poly(i:C)to establish a robust antitumor immune response in this registered clinical trial(NCT03392545).During the follow-up,12/27(44.4%)patients who achieved tumor control concomitant with survival benefit were regarded as responders in our *** found that the T-cell receptor(TCR)repertoire in the TME was reshaped after poly(i:C)*** on the RNA-seq analysis of tumor samples,the expression of annexin A1(ANXA1)was significantly upregulated in the tumor cells of nonresponders,which was further validated at the protein *** vitro and in vivo experiments showed that ANXA1 could induce the production of M2-like macrophages and microglia via its surface receptor formyl peptide receptor 1(FPR1)to establish a Treg cell-driven immunosuppressive TME and suppress the antitumor immune response facilitated by poly(i:C).The ANXA1/FPR1 signaling axis can inhibit the innate immune response of glioma patients by promoting an anti-inflammatory and Treg-driven ***,ANXA1 could serve as a reliable predictor of response to poly(i:C),with a notable predictive accuracy rate of 92.3%.in light of these notable findings,this study unveils a new perspective of immunotherapy for gliomas.

关键词： glioma ANXA1 TLR3 poly(i:C) immunotherapy

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Effect of different operation conditions on PCDD/F inhibition by ammonium dihydrogen phosphate:concentrations,distributions and mechanisms

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Waste Disposal and Sustainable Energy 2024年第1期6卷 11-23页

作者： Jiayao Wu Weican Xiang Xiaoxiao Wang Wenlong Song Yuxuan Ying Xiaoqing lin Xiaodong Li State Key Laboratory of Clean Energy Utilization National Engineering Laboratory of Waste Incineration Technology and EquipmentInstitute of Thermal Power Engineering of Zhejiang UniversityHangzhou310027ZhejiangChina

Phosphorus-containing compounds are considered as the potential alternatives of traditional inhibitors for suppressing the formation of polychlorinated dibenzo-p-dioxins and dibenzofurans(PCDD/Fs),but the suppression characteristics are scarcely *** this study,ammonium dihydrogen phosphate(ADP)was selected as the inhibitor to inhibit the PCDD/F formation via de novo synthesis at 350℃.The influence of oxygen content and addition method on PCDD/F inhibition was systematically investigated by means of statistical analysis and morphological *** results showed that oxygen enhanced the formation of PCDD/Fs from 1470 ng g^(−1)(9.78 ng i-TEQ g^(−1))to 2110 ng g^(−1)(14.8 ng i-TEQ g^(−1)).ADP significantly inhibited the PCDD/F formation,with inhibition efficiencies ranging from 82.0%to 97.7%.Herein,a higher oxygen content and the premixed way intensified the suppression ***-p-dioxin(DD)/dibenzofuran(DF)chlorination was proven to be effectively suppressed while chlorophenol(CP)route was not obviously *** the addition of ADP,Cl source was significantly reduced and the formation of organic Cl was effectively ***,it decreased the proportion of C–O/C=N and C=O,revealing the efficient inhibition of carbon ***,the formation of copper phosphate and copper pyrophosphate was observed in XPS(X-ray photoelectron spectroscopy)spectra,indicating that the catalytic metal Cu was chelated and passivated by *** premixed way had a better effect on reducing Cl resources,inhibiting oxidation and chelating metals,due to the direct contact with ***,the separation method could only depend on the decomposed gases,resulting in a lower inhibition efficiency.

关键词： Ammonium dihydrogen phosphate Polychlorinated dibenzo-p-dioxins and dibenzofuran inhibition Oxygen content Adding way Mechanisms

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