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Regulation of solvation structure and the cooperation environment of potassium bonds for wider-temperature adaptive potassium storage

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Rare Metals 2024年第4期43卷 1610-1621页

作者： Bing-Bing Liu Yi-hui Liu You-Bin Zhang Zhen-guo Qi guo-hui Qin State Key Laboratory Base for Eco-Chemical Engineering College of Chemical EngineeringQingdao University of Science and TechnologyQingdao266042China Shandong Synergetic Innovation Center of Ecological and Chemical Engineering Qingdao266042China

Antimony selenide(Sb_(2)Se_(3))is one of the perspective candidates for potassium-ion batteries due to its advanced virtues stem including featured high capacity,fertile reserves and the relative narrow band *** the unique advantages,it is still plagued by the unstable interface compatibility and poor wider-temperature *** optimization of microstructure and the construction of inorganic-organic hybrids with a low desolvation barrier and rapid kinetics behaviors are efficient to address these *** Sb_(2)Se_(3)nanorods enclosed by the S-doped carbon layer(SC),further crosslinked by the poly(N-isopropylacrylamide)(PM)film(PM@Sb_(2)Se_(3)@SC),were artificially fabricated,and it displays the enrichment ion aggregated model as well as contacted ion pair state,the well-tailored cooperation environment of potassium bonds,assuring a homogeneous potassium deposition and an excellent widertemperature *** complicated experimental studies and theoretical calculations authenticate the synergistic effects of geometric conformation and compositional design for the tremendously enhanced potassium ***,the full device over PM@Sb_(2)Se_(3)@SC anode and the potassium Prussian blue cathode manifests impressively durable cycling life and wider-temperature adaptability,verifying the glorious contribution from the finely manipulation in solvation structure and potassium bonds to enhancing the potassium storage behaviors.

关键词： Anode Sb_(2)Se_(3) rods Interface compatibility Inorganic-organic electrode Potassium ion battery

Comparison of nonlinear modeling methods for the composite rubber clamp

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Applied Mathematics and Mechanics(English Edition) 2024年第5期45卷 763-778页

作者： Yiming CAO hui MA Xumin guo Bingfeng ZHAO hui LI Xin WANG Bing WANG School of Mechanical Engineering and Automation Northeastern UniversityShenyang 110819China Key Laboratory of Vibration and Control of Aero-Propulsion Systems of Ministry of Education of China Northeastern UniversityShenyang 110819China AVIC Shenyang Engine Design Institute Shenyang 110013China Dalian Mengyu Machinery Co. Ltd.Dalian 116317Liaoning ProvinceChina

The cubic stiffness force model(CSFM)and Bouc-Wen model(BWM)are introduced and compared *** unknown coefficients of the nonlinear models are identified by the genetic algorithm combined with *** fitting the identified nonlinear coefficients under different excitation amplitudes,the nonlinear vibration responses of the system are *** results show that the accuracy of the BWM is higher than that of the CSFM,especially in the non-resonant ***,the optimization time of the BWM is longer than that of the CSFM.

关键词： pipeline system nonlinear clamp model composite rubber clamp amplitude-dependent characteristic vibration response experiment

In situ anchoring in carbon matrix of Bi2O2CO3 as a high-performance anode material for Li-ion batteries

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Rare Metals 2024年第8期43卷 3634-3646页

作者： Pu-Qiang He Jun guo hui Huang Zhong-Cheng guo Faculty of Metallurgy and Energy Engineering Kunming University of Science and Technology Research Center of Metallurgical Electrode Materials Engineering Technology Kunming Hendera Science and Technology Co. Ltd.

Bismuth-based anode materials have been regarded as promising Li-ion batteries due to their high theoretical ***,their low conductivity and associated volume expansion inhabited their *** this work,Bi2O2CO3@C composites were successfully synthesized by in situ anchoring of flower-like Bi2O2CO3nanosheets on a carbon-based substrate via *** unique composited structure of Bi2O2-CO3@C leads to a stable specific capacity of 547 mAh·g-1after 100 cycles at a current density of 0.1 A·***,it demonstrates excellent rate capability with a specific capacity of 210 mAh·g-1at 5 A·*** 550 cycles at a current density of 0.5 A·g-1,a high reversible capacity of nearly 400 mAh·g-1was ***,in situ X-ray diffraction measurements clearly demonstrate the conversion between Bi and Li3Bi during alloying/dealloying,confirming the good electrochemical reversibility of the materials for Li *** reaction kinetics of Bi2O2CO3@C were further investigated using galvanostatic intermittent titration ***,Bi2O2-CO3@C exhibited excellent long-term stability,maintaining its high reversible capacity for over 200 cycles at a current density of 0.5 A·g-1in a full cell configuration using Li1.20Mn0.54Ni0.13Co0.13O2as the cathode *** result further underscores its promising potential for lithium-ion *** work may provide inspiration for the design of alloy-type negative electrode materials for high-performance rechargeable batteries.

关键词： Bi 2 O 2 CO 3 Composite materials Anode materials Full batteries

Crystalline-amorphous M@MN_x(M=Co,Fe,Ni)encapsulated in nitrogen-doped carbon for enhanced efficient and durable hydrogen evolution reaction

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Rare Metals 2024年第4期43卷 1547-1556页

作者： Yang Yang Xiao-Chuan Duan Shao-hui guo Xian-Ming Zhang College of Materials Science and Engineering College of ChemistryKey Laboratory of Interface Science and Engineering in Advanced MaterialsTaiyuan University of TechnologyYuci030600China

Developing earth-abundant electrocatalysts for hydrogen evolution reaction(HER)is important for the sustainable energy ***,efficient and stable heterocatalysts consisting of crystalline-amorphous M@MN_(x)(M=Co,Fe,Ni)encapsulated in N-doped carbon layers supported with N-doped graphene sheets(denoted as M@MN_(x)@NC-NG)are synthesized by facile hydrothermal reaction and nitridation *** the nitriding process,metal ions in M(tzbc)_2(H_(2)O)_4(tzbc=4-(1H-1,2,4-triazol-1-yl)benzoic acid)complexes are reduced to crystalline M cores,accompanied by the formation of amorphous MN_(x)shells;the tzbc ligands are insitu carbonized to form outermost N-doped carbon(NC)layers that connect with inner MN_(x)via M-N-C motifs inherited from the complex precursors and inhibit the transition of MN_(x)from amorphous to crystalline *** Co@CoN_(x)@NC-NG catalyst exhibits excellent HER activity with small overpotentials of 45 and 64 mV at a cathode current density of 10 mA·cm^(-2)and low Tafel slopes of 40 and 85 mV·dec^(-1)in 0.5 mol·L^(-1)H_(2)SO_4 and1.0 mol·L^(-1)KOH electrolytes,*** Co@CoN_(x)@NC-NG retains 97%of the initial overpotential after 100,000 s in both acidic and alkaline *** outstanding HER performance originates from the crystalline-amorphous Co@CoN_(x)that redistributes electrons around the heterointerfaces,facilitating the conversion process of H^(+)/H_(2)O to hydrogen and thereby promoting HER *** outermost NC layers serve as the armor of Co@CoN_(x),and graphene nanosheets act as carriers of egg-like Co@CoN_(x)@NC and conduction paths for electron shuttles,ensuring stable and continuous electrocatalytic hydrogen production.

关键词： Hydrogen evolution reaction Electrocatalysts Iron group metals Heterojunction Crystalline-amorphous structure

Regio-and Stereoselective Polymerization of Bio-based Ocimene by Rare-Earth Metal Catalysts

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Chinese Journal of Polymer Science 2024年第2期42卷 223-229,I0008页

作者： Qi-Yuan Wang Li-Peng Sang Zhen Zhang Yang Jiang hui Tian Xia Zhao Xiang guo Shi-hui Li State Key Laboratory of Polymer Physics and Chemistry Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun130022China School of Applied Chemistry and Engineering University of Science and Technology of ChinaHefei230026China Science and Technology on Aerospace Chemical Power Laboratory Hubei Institute of Aerospace ChemotechonologyXiangyang441003China Shanxi Coal Chemical Industry Technology Research Institute Xi’an710000China Hubei Institute of Aerospace Chemotechonology Xiangyang441003China

Coordination polymerization of renewable β-ocimene has been investigated using asymmetric diiminophosphinate lutetium complex1, β-diketiminate yttrium complex 2, bis(phosphino)carbazolide yttrium complex 3, half-sandwich benzyl fluorenyl scandium complex 4 and pyridyl-methylene-fluorenyl rare-metal complexes 5a–5c. Complexes 1, 4 and 5a–5c show trans-1,2-regioselectivities and high activities, of which 5c exhibits excellent isoselectivity(mmmm>99%). Conversely, complexes 2 and 3 promote β-ocimene polymerization to produce isotactic cis-1,4-polyocimenes(cis-1,4>99%, mm>95%). Diblock copolymers cis-1,4-PIP-block-cis-1,4-POc and cis-1,4-PBD-block-cis-1,4-POc are obtained in one-pot reactions of β-ocimene with isoprene and butadiene using complex 3. Epoxidation and hydroxylation of polyocimene afford functionalized polyolefins with enhanced T_(g)(from-20 ℃ to 79 ℃ and 74 ℃) and hydrophilicity.

关键词： Biobased monomer Terpenes Ocimene Rare-earths Polymerization Regio/stereoselectivity Elastomer

Stable stripe and vortex solitons in two-dimensional spin-orbit coupled Bose-Einstein condensates

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Communications in Theoretical Physics 2024年第6期76卷 26-33页

作者： Yuan guo Muhammad Idrees Ji Lin hui-jun Li Institute of Nonlinear Physics and Department of Physics Zhejiang Normal UniversityJinhua 321004China Zhejiang Institute of Photoelectronics and Zhejiang Institute for Advanced Light Source Zhejiang Normal UniversityJinhua 321004China

We present a flexible manipulation and control of solitons via Bose-Einstein *** the presence of Rashba spin-orbit coupling and repulsive interactions within a harmonic potential,our investigation reveals the numerical local solutions within the *** manipulating the strength of repulsive interactions and adjusting spin-orbit coupling while maintaining a zero-frequency rotation,diverse soliton structures emerge within the *** include plane-wave solitons,two distinct types of stripe solitons,and odd petal solitons with both single and double *** stability of these solitons is intricately dependent on the varying strength of spin-orbit ***,stripe solitons can maintain a stable existence within regions characterized by enhanced spin-orbit coupling while petal solitons are unable to sustain a stable existence under similar *** rotational frequency is introduced to the system,solitons undergo a transition from stripe solitons to a vortex array characterized by a sustained *** rotational directions of clockwise and counterclockwise are non-equivalent owing to spin-orbit *** a result,the properties of vortex solitons exhibit significant variation and are capable of maintaining a stable existence in the presence of repulsive interactions.

关键词： Bose-Einstein condensate spin-orbit coupling rotation frequency stripe solitons vortex array

Insights into in-situ imbibition behavior of fracturing fluid in propped shale fractures based on nuclear magnetic resonance:A case study from Longmaxi Formation shale,Sichuan Basin,China

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Petroleum Science 2024年第1期21卷 410-429页

作者： Jing-Jing guo Kai-Xiang Di Lie-hui Zhang Yu-Long Zhao hui-Ying Tang Rui-Han Zhang Ye Tian National Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Southwest Petroleum UniversityChengdu610500SichuanChina

Shale gas is an important component of unconventional oil and gas *** the imbibition behavior is helpful to optimize flowback parameters and enhance gas *** imbibition studies have focused on shale matrix,and the pressure conditions discussed were mostly *** initial imbibition behavior begins from propped fractures to matrix,but there are few studies working on explaining the imbibition behavior in propped fractures or the phenomenon of many shale wells exhibit higher productivity after a“soaking”***,propped fracture samples were designed for imbibition and migration *** order to accurately study the mechanism and main influencing factors of fracturing fluid imbibition and migration in propped and unpropped shale fractures under high temperature and high pressure,a series of experiments based on nuclear magnetic resonance(NMR)were carried *** showed that NMR T_(2) spectra of all samples exhibited a bimodal *** final imbibition volume of fracturing fluid was positively related to pressure and fracture *** imbibition effect of fracturing fluid was more evident in matrix pores under high *** the migration during soaking stage,the fracturing fluid gradually migrated from large pores to small pores and gradually displaced the shale gas from the matrix,thus allowing the water blocking in propped fractures to self-unlock to some *** permeability decreased in the imbibition stage,while it recovered in the migration stage to some extent.

关键词： Forced imbibition Migration Soaking NMR T_(2)spectra Propped fracture Permeability recovery

Optical and electrical anisotropy regulation engineering of low-dimensional materials toward polarized detection and imaging applications

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Rare Metals 2024年第7期43卷 2968-2993页

作者： Jian-Bin Zhang Nan Zhou Li-hui Zhang Cong-hui Shang Jia-Xuan Li Yi Zhao guo-hui Jia Ru-Sen Yang Hua Xu Xiao-Bo Li Shaanxi Joint Key Laboratory of Graphene Shaanxi Key Laboratory of High-Orbits-Electron Materials and Protection Technology for AerospaceShaanxi Joint Key Laboratory of GrapheneSchool of Advanced Materials and NanotechnologyXidian University Guangzhou Institute of Technology Xidian University Xi'an Thermal Power Research Institute Co. Ltd Key Laboratory of Applied Surface and Colloid Chemistry Ministry of EducationShaanxi Key Laboratory for Advanced Energy DevicesShaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringShaanxi Normal University

Polarized-sensitive image sensors are a kind of photodetector with great development potential due to their enhanced ability to detect and identify the target objects from the aspect of spatial,spectral and polarized ***,low-dimensional anisotropic materials with inherent anisotropic properties,ultrathin thickness,tunable bandgap and feasible integration with complementary metal oxide semiconductor(CMOS) fabrication processes have attracted great interest for their facilitation of polarized photodetector devices *** the polarized detection performance of low-dimensional materials to satisfy realistic needs stimulates the exploration of modulation of anisotropic *** this review,we comprehensively introduce the latest research progress in modulating the optical and optoelectronic anisotropy characteristics of low-dimensional *** strategy of anisotropy regulation through crystal structure engineering and coupling system is discussed ***,the latest progress in image recognition applications using anisotropic low-dimensional materials is reviewed in ***,we summarize the challenge and propose future opportunities in the practical application of polarized-sensitive imaging photodetectors based on low-dimensional anisotropic materials.

关键词： Anisotropy Polarized detection Image recognition Low-dimensional materials

Progress in the research on organic piezoelectric catalysts for dye decomposition

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International Journal of Minerals,Metallurgy and Materials 2024年第2期31卷 245-260页

作者： Zhaoning Yang Xiaoxin Shu Di guo Jing Wang hui Bian Yanmin Jia School of Science Xi’an University of Posts and TelecommunicationsXi’an 710121China School of Physics and Information Technology Shaanxi Normal UniversityXi’an 710119China

Organic contaminants have posed a direct and substantial risk to human wellness and the *** recent years,piezo-electric catalysis has evolved as a novel and effective method for decomposing these *** piezoelectric materials offer a wide range of options,most related studies thus far have focused on inorganic materials and have paid little attention to organic *** materials have advantages,such as being lightweight,inexpensive,and easy to process,over inorganic ***,this paper provides a comprehensive review of the progress made in the research on piezoelectric catalysis using organic materials,high-lighting their catalytic efficiency in addressing various *** addition,the applications of organic materials in piezoelectric cata-lysis for water decomposition to produce hydrogen,disinfect bacteria,treat tumors,and reduce carbon dioxide are ***,fu-ture developmental trends regarding the piezoelectric catalytic potential of organic materials are explored.

关键词： piezoelectric catalysis piezoelectric material dye decomposition organic materials