检索结果-南通市图书馆

CaH2-promoted activity of Ni-carbonate interface for CO2 methanation

在线全文

学校读者我要写书评

暂无评论

Journal of Energy Chemistry 2025年第1期100卷 522-532页

作者： Jin-Peng Wang Guo-Cui Mao hui-Lin Jiang bao-Xia Dong Yun-Lei Teng School of Chemistry and Chemical Engineering Yangzhou University

Transition metal-carbonate interfaces often act as active sites in heterogeneous catalytic *** interface between transition metal and metal carbonate exhibits a dynamic equilibrium during the CO2hydrogenation reaction,involving surface carbonate hydrogenation and ***,there have been few reports on engineering the activity of the interface between transition metal and alkaline earth metal carbonate for catalytic *** work demonstrated that the incorporation of CaH2in Ni/CaCO3enhances the CO2methanation activity of the *** CO2conversion for Ni/CaH2-CaCO3reached 68.5%at 400°C,which was much higher than that of the Ni/CaCO3（31.6%） and Ni/CaH2-CaO （42.4%） ***,the Ni/CaH2-CaCO3catalysts remained stable during the stability test for 24 h at 400°C and 8 *** research revealed that CaH2played a crucial role in promoting the activity of the Ni-carbonate interface for ***2could modify the electronic structure of Ni and tune the structural properties of CaCO3to generate medium basic sites （OH groups）,which are favorable for the activation of H2and ***-situ Fourier transform infrared spectroscopy （FTIR） analysis combined with density functional theory calculations demonstrated that CO2activation occurs at the hydroxyl group （OH） on the CaH2-modified Ni-carbonate surface,leading to the formation of CO3H****,our study has confirmed that CO2methanation over the Ni/CaH2-CaCO3catalysts proceeds via the formate pathway.

关键词： Metal hydride Ni catalysts Carbonate Metal-carbonate interface

Circulating MicroRNAs as Potential Biomarkers in the Diagnosis of Neurosyphilis: A Case Control Study

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

International Journal of Dermatology and Venereology 2021年第1期4卷 16-25页

作者： Kai-Qi Wu Su-Fang Zhang chao-hui bao Xin Zou Xin Gu Cui-Ni Wang Wei-Ming Gong Mei Shi Yong-Liang Lou Jian Huang Ping-Yu Zhou Sexually Transmitted Disease Institute Shanghai Skin Disease HospitalShanghai 200050China Key Laboratory of Laboratory Medicine(Ministry of Education) School of Laboratory Medicine and Life SciencesWenzhou Medical UniversityWenzhouZhejiang 325035China Shanghai Skin Disease Hospital Clinical School of Anhui Medical UniversityShanghai 200050China Key Laboratory of Systems Biomedicine(Ministry of Education)and Collaborative Innovation Center of Systems Biomedicine Shanghai Center for Systems BiomedicineShanghai Jiao Tong UniversityShanghai 200240China

Objective:Laboratory diagnosis of neurosyphilis(NS)remains a great *** study was the aimed to identify miRNA candidates as biomarkers to distinguish between NS,non-neurosyphilis,and healthy controls(HCs).Methods:We analyzed miRNA expression profiles in peripheral blood mononuclear cells(PBMCs)from six patients with NS,eight patients with secondary syphilis(SS),and five HCs using microarray *** differentially expressed miRNAs were validated in 33 NS samples,31 SS samples,and 30 HC samples using TaqMan miRNA real-time qPCR(qRT-PCR).Results:Thirty-nine miRNAs were differentially expressed in SS and NS patients compared with *** miRNAs were randomly selected to validate their expression levels in the same samples used in microarray assay by *** miRNAs were upregulated in SS and NS samples compared with ***-PCR analysis of the expression of the 13 miRNAs in a second cohort(76 samples)showed that the average expression levels of nine miRNAs were higher in SS than in NS(SS:0.185,NS:0.136,P=3.8E-10),while the expressions of the other four miRNAs were lower in SS than in NS(SS:0.000757,NS:0.000873,P=0.022).ROC curve analysis of the 13 miRNAs showed the area under the curve value to be 1.00 for distinguishing SS patients from HCs,1.00 for distinguishing NS patients from HCs,1.00 for distinguishing SS and NS patients from HCs,and 0.968 for distinguishing NS from SS ***:The present study is the first one that identified differentially expressed miRNAs in PBMCs from patients with *** results suggest that the 13 candidate miRNAs in PBMCs may be novel noninvasive biomarkers for NS diagnosis.

关键词： diagnosis microRNAs neurosyphilis peripheral blood mononuclear cells syphilis

Role of iron ore in enhancing gasification of iron coke:Structural evolution,influence mechanism and kinetic analysis

在线全文

学校读者我要写书评

暂无评论

International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 58-69页

作者： Jie Wang Wei Wang Xuheng Chen Junfang bao Qiuyue Hao Heng Zheng Runsheng Xu School of Chemistry and Materials Science Hubei Engineering UniversityXiaogan 432000China Key Laboratory for Ferrous Metallurgy and Resources Utilization of Ministry of Education Wuhan University of Science and TechnologyWuhan 430081China Institue of Ironmaking Technology Baosteel Central Research InstituteShanghai 201999China State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China

The utilization of iron coke provides a green pathway for low-carbon *** uncover the influence mechanism of iron ore on the behavior and kinetics of iron coke gasification,the effect of iron ore on the microstructure of iron coke was ***,a comparative study of the gasification reactions between iron coke and coke was conducted through non-isothermal thermogravimetric *** findings indicate that compared to coke,iron coke exhibits an augmentation in micropores and specific surface area,and the micropores further extend and *** provides more adsorption sites for CO_(2) molecules during the gasification process,resulting in a reduction in the initial gasification temperature of iron *** the heating rate in non-isothermal gasification can enhance the reactivity of iron *** metallic iron reduced from iron ore is embedded in the carbon matrix,reducing the orderliness of the carbon structure,which is primarily responsible for the heightened reactivity of the carbon *** kinetic study indicates that the random pore model can effectively represent the gasification process of iron coke due to its rich pore ***,as the proportion of iron ore increases,the activation energy for the carbon gasification gradually decreases,from 246.2 kJ/mol for coke to 192.5 kJ/mol for iron coke 15wt%.

关键词： low-carbon ironmaking iron coke gasification structural evolution kinetic model

Pressure dynamics of asymmetrically fractured wells in an arbitrarily shaped reservoir

在线全文

学校读者我要写书评

暂无评论

Journal of Hydrodynamics 2019年第4期31卷 767-777页

作者： Yu-long Zhao bao-chao Shan Lie-hui Zhang State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Southwest Petroleum University Chengdu 610500 China State Key Laboratory^ of Coal Combustion Huazhong University^ of Science and Technology Wuhan 430074 China

A numerical model is established and with the model, the boundary element method and the coupled boundary/finite element method are used to analyze the pressure dynamics of an asymmetrically fractured well in an arbitrarily shaped reservoir. The equation is solved in the Laplace domain, with different flow regimes with or without considerations of the wellbore storage and skin effects. The parameter sensitivity analyses, including the asymmetry factor, the fracture conductivity, the outer boundary shape, the boundary size and the well location, are conducted. The model is validated by comparing the results with those of analytical solutions of two simplified cases and a field case study. The study can be used for the well testing interpretation and the hydraulic fracturing design.

关键词： Asymmetrically fractured well finite conductivity fracture pressure dynamics numerical method arbitrary drainage area

The Noncommutative Residue about Witten Deformation

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Acta Mathematica Sinica,English Series 2019年第4期35卷 550-568页

作者： Kai Hua bao Ai hui SUN chao DENG School of Mathematics Ineer Mongolia University for Nationnalities College of Mathematics Jilin Normal University School of Mathematics and Statistics Northeast Normal University

In this paper, we compute lower dimensional volumes Vol_4^((1,1)) and Vol_6^((2,2)) about Witten deformation for 4, 6-dimensional spin manifolds with boundary respectively, and get assosiated Kastler–Kalau–Walze type theorems. We also give theoritic explaination of the gravitational action for 4, 6 dimensional manifolds with boundary by these noncommutative residues.

关键词： Lower-dimensional volumes noncommutative residue gravitational action Witten deformation

Boosting Oxygen Evolution Reaction Performance on NiFe‑Based Catalysts Through d‑Orbital Hybridization

在线全文

学校读者我要写书评

暂无评论

Nano-Micro Letters 2025年第1期17卷 281-292页

作者： Xing Wang Wei Pi Sheng Hu Haifeng bao Na Yao Wei Luo State Key Laboratory of New Textile Materials and Advanced Processing Technology Key Laboratory of New Textile Materials and Applications of Hubei ProvinceSchool of Materials Science and EngineeringWuhan Textile UniversityWuhan 430200People’s Republic of China College of Chemistry and Molecular Sciences Wuhan UniversityWuhan 430072People’s Republic of China

Anion-exchange membrane water electrolyzers(AEMWEs)for green hydrogen production have received intensive attention due to their feasibility of using earth-abundant NiFe-based *** introducing a third metal into NiFe-based catalysts to construct asymmetrical M-NiFe units,the d-orbital and electronic structures can be adjusted,which is an important strategy to achieve sufficient oxygen evolution reaction(OER)performance in ***,the ternary NiFeM(M:La,Mo)catalysts featured with distinct M-NiFe units and varying d-orbitals are reported in this *** and theoretical calculation results reveal that the doping of La leads to optimized hybridization between d orbital in NiFeM and 2p in oxygen,resulting in enhanced adsorption strength of oxygen intermediates,and reduced rate-determining step energy barrier,which is responsible for the enhanced OER *** critically,the obtained NiFeLa catalyst only requires 1.58 V to reach 1 A cm^(−2) in an anion exchange membrane electrolyzer and demonstrates excellent long-term stability of up to 600 h.

关键词： NiFe-based catalysts d-orbital coupling Oxygen evolution reaction Anion exchange membrane electrolyzer

Zwitterionic hyaluronic acid derivatives for co-delivery of both chemotherapeutic and nucleic acid drugs in breast cancer treatment

在线全文

学校读者我要写书评

暂无评论

Nano Research 2025年第1期18卷 607-617页

作者： Ruo-Lin Jiang hui-Na Liu Yu-Fan Yang Zhi-Cheng Zhang Qi Dai Xiao-Yan bao Lin-Jie Wu Ya-Xin Qin Xin Tan Xiao-Yan Sun Xu-Fang Ying Zhi-Qing Ben Min Han Institute of Pharmaceutics College of Pharmaceutical SciencesZhejiang UniversityHangzhou 310058China Department of Radiation Oncology Key Laboratory of Cancer Prevention and InterventionThe Second Affiliated HospitalCollege of MedicineZhejiang UniversityHangzhou 310058China Hangzhou Institute of Innovative Medicine Zhejiang UniversityHangzhou 310058China Jinhua Institute of Zhejiang University Jinhua 321299China National Key Laboratory of Advanced Drug Delivery and Release Systems Zhejiang UniversityHangzhou 310058China Polytechnic institute Zhejiang UniversityHangzhou 310015China

Traditionally,hyaluronic acid has been widely used for drug delivery,but the current application bottleneck is that hyaluronic acid is hydrophilic and electronegative,which makes it difficult to carry hydrophobic drugs and small interfering RNA(siRNA)with the same *** on previous studies,we designed and synthesized hyaluronic acid nanocarriers HA-spermine/N,N,N-trimethylcystamine/DOX-TPP(HSTD)for loading siRNA to overcome the problem of siRNA release caused by strong electrostatic ***,N,N,Ntrimethylcystamine in the carrier can be degraded by intracellular glutathione to completely and rapidly release siRNA,thus promoting ***,when codelivered with the chemotherapy drug doxorubicin(DOX),this novel nanocarrier showed promising synergy in inhibiting tumor growth.

关键词： zwitterionic hyaluronic acid N N N-trimethylcystamine small interfering RNA(siRNA) doxorubicin

A new monoterpenoid indole alkaloid from Rauvolfia yunnanensis

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Chemical Letters 2009年第10期20卷 1221-1223页

作者： bao hui Cheng Jian chao Chen Ming Hua Qiu a State Key Laboratory of Phytochemistry and Plant Resources in West China Kunming Institute of Botany Chinese Academy of Sciences Kunming 650204 China Graduate School of Chinese Academy of Sciences Beijing 100039 China

One new monoterpenoid indole alkaloid, l l-methoxyburnamine-17-O-3′,4′,5′-trimethoxybenzoate （1）, was isolated from Rauvolfia yunnanensis Tsiang. Its structure was identified by speclroscopic evidences.

关键词： Rauvolfia yunnanensis Monoterpenoid indole alkaloid Akuammiline-type rnonoterpenoid indole alkaloid

A note on the entropy of mean curvature flow

在线全文

学校读者我要写书评

暂无评论

Science China Mathematics 2015年第12期58卷 2611-2620页

作者： bao chao Key Laboratory of Pure and Applied Mathematics School of Mathematical SciencesPeking University

The entropy of a hypersurface is given by the supremum over all F-functionals with varying centers and scales, and is invariant under rigid motions and dilations. As a consequence of huisken's monotonicity formula, entropy is non-increasing under mean curvature flow. We show here that a compact mean convex hypersurface with some low entropy is diffeomorphic to a round sphere. We also prove that a smooth selfshrinker with low entropy is a hyperplane.

关键词： entropy self-shrinker mean curvature flow sphere