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Multicomponent polymerization of elemental sulfur,difluoromethylene phosphobetaine and aryl silyl ethers toward aromatic poly(O,O′-monothiocarbonate)s

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Science China Chemistry 2025年

作者： Yongjiang Yu Rongrong Hu ben Zhong Tang State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular Aggregates South China University of Technology School of Science and Engineering Shenzhen Institute of Aggregate Science and Technology The Chinese University of Hong Kong AIE Institute

Polythiocarbonates with similar structures to polycarbonates, have emerged as a group of promising sulfur-containing polymers with a range of practical applications, taking advantages of their excellent optical properties, good thermal stability and filmforming ability, and so on. However, the synthesis of polythiocarbonates generally suffered from mixed isomeric structures of repeating units, and hazardous sulfur-containing reagents. In this work, an efficient multicomponent reaction of elemental sulfur,difluoromethylene phosphobetaine（PDFA）, and aryl silyl ethers was designed with the assistance of organic base 7-methyl-1,5,7-triazabicyclo[4.4.0]dec-5-ene（MTBD） to produce 12 kinds of O,O′-monothiocarbonate compounds in up to 93% yields,taking advantages of the unique chemical property of difluorocarbene, and the deprotection of silyl group by F-generated from PDFA. Most importantly, the MTBD-assisted multicomponent polymerization of bis（aryl silyl ether）s, elemental sulfur, and PDFA was developed, affording 12 kinds of poly（O,O′-monothiocarbonate）s with well-defined structures, high Mws of up to16900 g/mol and high yields（up to 99%）. These poly（O,O′-monothiocarbonate）s possessed good film-forming properties and thermal stability, high light refractive indices and transmittance. The facile synthesis of these polymonothiocarbonates might pave the way for the development of promising sulfur-containing polymer materials.

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Unraveling the morphological patterns of a subantarctic eelpout:a geometric morphometric approach

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Integrative Zoology 2023年第2期18卷 372-384页

作者： Fernanda S.ORREGO Mathias HÜNE hugo a.ben.tez Mauricio F.LANDAETA Laboratorio de Ictiología e Interacciones Biofísicas(LABITI) Instituto de BiologíaFacultad de CienciasUniversidad de ValparaísoValparaísoChile Centro de Investigación para la Conservación de los Ecosistemas Australes(ICEA) Punta ArenasChile Laboratorio de Ecología y Morfometría Evolutiva Centro de Investigación de Estudios Avanzados del MauleUniversidad Católica del MauleTalcaChile Centro de Observación Marino para Estudios de Riesgos del Ambiente Costero(COSTA-R) Universidad de ValparaísoViña del MarChile Millennium Nucleus for Ecology and Conservation of Temperate Mesophotic Reef Ecosystems(NUTME) Millennium Institute Biodiversity of Antarctic and Subantarctic Ecosystems(BASE) SantiagoChile

Phenotypic variation in organisms depends on the genotype and the environmental constraints of the habitat that they ***,for marine species inhabiting contrasting aquatic conditions,it is expected toﬁnd covari-ation between the shape and its spatial *** studied the morphology of the head and cephalic sensory canals of the eelpout Austrolycus depressiceps(4.5–22.5 cm TL)across its latitudinal distribution in South Paciﬁc(45°S–55°S).Geometric morphometric analyses show that the shape varied from individuals with larger snout and an extended suborbital canal to individuals with shorter snouts and frontally compressed suborbital *** was size variation across the sampled populations,but that size does not have a clear latitudinal *** 8%of the shape variation relates to this size variation(allometry),represented by a decrease in the relative size of the eye,and a depression of the posterior margin of the *** were spatial differences in the shape of the head,but these differences were probably caused by allometric ***,2 of the canals of the cephalic lateralis pores and the head shape showed modularity in its *** study shows that the morphology of marineﬁsh with a shallow distribution varies across distances of hundreds of kilometers(i.e.,phenotypic modulation).

关键词： Austrolycus depressiceps geometric morphometrics morphology phenotype spatial distribution

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Home range variability,spatial aggregation,and excursions of Akodon azarae and Oligoryzomys flavescens in Pampean agroecosystems

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Integrative Zoology 2020年第5期15卷 401-415页

作者： Irene GOROSITO Ailén benÍtez Maria BUSCH Laboratorio de Ecología de PoblacionesFacultad de Ciencias Exactas y NaturalesUniversidad de Buenos Airesand Instituto de EcologíaGenética y Evolución de Buenos AiresConsejo Nacional de Investigaciones Científicas y TécnicasBuenos AiresArgentina Laboratorio de Ecología de Poblaciones Facultad de Ciencias Exactas y NaturalesUniversidad de Buenos AiresBuenos AiresArgentina Laboratorio de Ecología de Poblaciones Facultad de Ciencias Exactas y NaturalesUniversidad de Buenos Airesand Instituto de EcologíaGenética y Evolución de Buenos AiresConsejo Nacional de Investigaciones Científicas y TécnicasBuenos AiresArgentina

Rodents are reservoirs of various types of hantavirus,some of which are agents of hantavirus pulmonary syndrome in *** hantavirus is associated with a single rodent host species but successive spill-over events may eventually lead to host-switching and new species’becoming host of a given *** study aims to gain an understanding of the spatial ecology of two hantavirus-host species,Akodon azarae,and Oligoryzomys flavescens,by identifying factors modulating their home range sizes and stability,and by evaluating intra-and interspecific spatial aggregation for these species and a third one—Oxymycterus rufus—living in *** this,eleven capture-mark-recapture surveys were carried out,spanning 22 *** found that *** males have larger and more mobile home ranges than females,independently of the ***,males could likely have a more relevant role in the transmission of hantavirus because of their greater exposure both to a higher number of contacts between individuals and viral contamination of the ***,*** individuals showed negligible displacements of their home range through time,which could limit the range of hantavirus spread in host *** *** is host to Lechiguanas hantavirus(pathogenic to humans)this result encompasses epidemiological relevance,for it may imply the existence of local foci of ***,individuals of both species performed excursions outside their home *** events could enable hantavirus spread over distances beyond the normal range of movements and lead to new hantavirus outbreaks in formerly non-infected rodent populations,favoring the persistence of the virus in nature.

关键词： hantavirus home range intra-and interspecific contact rodent spatial ecology

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Conversion of Andean montane forest to exotic forest plantation modifies soil physicochemical properties in the buffer zone of Ecuador's Podocarpus National Park

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Forest Ecosystems 2022年第6期9卷 802-812页

作者： Vinicio Carrion-Paladines Angel benítez Roberto García-Ruíz Departamento de Ciencias Biologicas y Agropecuarias Universidad Tecnica Particular de LojaSan Cayetano Alto s/nC.P.1101608LojaEcuador Departamento de Biología Animal Biología Vegetal y EcologíaSeccion de EcologíaUniversidad de JaenCampus Las LagunillasEdificio Ciencias Experimentales y de la Salud(B3)23071JaenSpain

Background:Andean montane forests(AMF)are biodiversity hotspots that provide fundamental hydrological services as well as carbon storage and *** recent decades,southern Ecuador AMFs have been seriously threatened by increased logging and conversion to forest plantations with exotic *** this context,our main objective was to evaluate the effects of AMF conversion to forest plantations on soil physicochemical properties in the buffer zone(Bz)of the Podocarpus National Park(PNP),in southern *** this purpose,random samples were taken at a depth of 0-10 cm in four plots in each contrast zone and analyzed for bulk density,porosity,textural class,leaf litter depth,soil pH,as well as the contents of organic matter(SOM),soil organic carbon(SOC),total nitrogen,and available phosphorus and ***:The results indicate that the conversion of AMFs produces an increase in bulk density and a decrease in SOM,SOC,and total nitrogen contents,thus modifying soil properties,which could result in a decrease in water regulation capacity and produce an increased risk of soil *** accelerates degradation processes,as well as threatens shortages of the drinking water ***:This study can help decision-makers to implement soil management plans in the Bz of the PNP,based on the implementation of new regulations,where the conservation of AMF is *** addition,it is recommended to apply environmental restoration strategies in the anthropized areas of the AMF,as well as in the areas with exotic eucalyptus and pine plantations.

关键词： Andean montane forests Land use conversion Edaphic properties

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Some additive results on Drazin inverse

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Applied Mathematics(A Journal of Chinese Universities) 2015年第4期30卷 479-490页

作者： LIU Xiao-ji QIN Xiao-lan Julio benítez Faculty of Science Guangxi University for Nationalities Universidad Politécnica de Valencia Instituto de Matemática Multidisciplinar

In this paper, we investigate additive results of the Drazin inverse of elements in a ring R. Under the condition ab = ha, we show that a ＋ b is Drazin invertible if and only if aaD （a ＋ b） is Drazin invertible, where the superscript D means the Drazin inverse. Furthermore we find an expression of （a ＋ b）D. As an application we give some new representations for the Drazin inverse of a 2 × 2 block matrix.

关键词： Drazin inverse ring block matrix.

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Trimetallic mesoporous PdCuRu for efficient formate electrosynthesis from polyethylene terephthalate recycling

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Science China Chemistry 2025年

作者： Yuting Li Huiqin Yao Lizhi Sun Shu Han Xiaoxiang Xu Guangyin Fan ben Liu College of Chemistry and Materials Science Sichuan Normal University Key Laboratory of Green Chemistry and Technology of Ministry of Education College of Chemistry Sichuan University School of Basic Medical Sciences Ningxia Medical University Department of Otorhinolaryngology-Head and Neck Surgery Zhongnan Hospital of Wuhan University

Electrochemical recycling of waste polyethylene terephthalate（PET） plastics represents a green and sustainable route to produce valuable fuels and address serious environmental issues. Despite some encouraged achievements, their progress is still slower because of the lack of highly active and selective electrocatalysts. Here, we reported an efficient PET recycling route with trimetallic PdCuRu mesoporous nanospheres（MSs） as a high-performance electrocatalyst that achieved selective electrosynthesis of valuable formate from PET hydrolysate（PETH） electrooxidation. Penetrated metal mesopores and trimetallic compositions of PdCuRu MSs synergistically optimized electronic structures of Pd sites and changed chemisorption properties of intermediates, which disclosed a high formate Faradic efficiency of 97% and impressive yield rate of 0.49 mmol h-1cm-2in an alkaline solution. Meanwhile, this electrocatalyst held good electrocatalytic stability, retaining high formate Faradic efficiency and yield rate even being performed for 10 cycles, which highlighted its potential applications for practical PET recycling. Our study provides a powerful strategy for designing high-performance electrocatalysts toward selective electro-synthesis of valuable fuels from various waste plastics.

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Specific staining and precise killing of cancer cells through fusion of pharmaceutical chemistry and π-bridge effect design philosophy

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Science China Chemistry 2025年

作者： Qiong Liu Qiyun Deng Changxu Zhu Kongqi Chen Lidan Chen Zhaohui Sun ben Zhong Tang Zhiming Wang AIE Institute Center for Aggregation-Induced Emission State Key Laboratory of Luminescent Materials and Devices Key Laboratory of Luminescence from Molecular Aggregates of Guangdong Province South China University of Technology Department of Laboratory Medicine General Hospital of Southern Theater Command School of Life Sciences The Chinese University of Hong Kong Shenzhen Institute of Aggregate Science and Technology School of Science and Engineering The Chinese University of Hong Kong HKUST-Shenzhen Research Institute

The development of an advanced phototheranostic platform that combines imaging and therapy in a single agent is an appealing yet challenging *** this study,we successfully constructed three novel fluorescent probes by leveraging pharmaceutical chemistry and the design philosophy of theπ-bridge *** a systematic comparative analysis of their fluorescence properties,water solubility,molecular conformation,and electrostatic potential,we revealed the fundamental principles governing the optical behavior and biological selectivity of these ***,the probe TPhIQ-CNTh demonstrated extended fluorescence in the near-infrared region,a significant aggregation-induced emission (AIE) effect,and the ability to distinguish tumor cells from normal ***,it efficiently generated reactive oxygen species (ROS) and specifically labeled lipid droplets,enabling the precise staining and killing of cancer *** study presents a practical strategy for designing precise tumor treatments that integrate efficient imaging-guided photodynamic therapy (PDT) by harnessing the unique properties of AIE materials.

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Length–mass allometries in amphibians

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Integrative Zoology 2018年第1期13卷 36-45页

作者： Luca SANTINI Ana.ben.tez-LÓPEZ Gentile Francesco FICETOLA Mark A.J.HUIJBREGTS Department of Environmental Science Institute for Wetland and Water ResearchFaculty of ScienceRadboud UniversityNijmegenthe Netherlands Department of Bioscience University of MilanMilanItaly Alpine Ecology Laboratory Grenoble Alpes UniversityGrenobleFrance PBL Netherlands Environmental Assessment Agency The Haguethe Netherlands

Body mass is rarely recorded in amphibians,and other body measurements(*** to vent length,SVL)are generally collected ***,length measurements,when used as proxies of body mass in comparative analyses,are problematic if different taxa and morphotypes are *** developed allometric relationships to derive body mass from SVL *** fitted phylogenetic generalized least square models for frogs(Anura)and salamanders(Caudata)and for several families *** tested whether allometric relationships differed between species with different habitat preferences and between morphs in *** were fitted with SVL-mass measurements for 88 frog and 42 salamander *** assessed the predictive performance of the models by ***,the models showed high explained variance and low forecasting *** differed among semi-aquatic,terrestrial and arboreal frogs,and between paedomorphic and non-paedomorphic *** mass estimates derived from our models allow for comparability of studies on multiple taxa and can be used for testing theories built upon evolutionary and ecological processes which are directly related to body mass.

关键词： Anura body size body weight Caudata SVL

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Removal of heavy metals from aqueous solution by sawdust adsorption

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Journal of Environmental Sciences 2007年第2期19卷 160-166页

作者： BULUT Yasemin tez Zeki Faculty of Arts and Sciences Department of Chemistry University of Dicle21280 DiyarbakirTurkey. Faculty of Techniqual Education Department of Textile Marmara UniversityGztepeIstanbulTurkey

The adsorption of lead, cadmium and nicel from aqueous solution by sawdust of walnut was investigated. The effect of contact time, initial metal ion concentration and temperature on metal ions removal has been studied. The equilibrium time was found to be of the order of 60 min. Kinetics fit pseudo first-order, second-order and intraparticle diffusion models, hence adsorption rate constants were calculated. The adsorption data of metal ions at temperatures of 25, 45 and 60~C have been described by the Freundlich and Langmuir isotherm models. The thermodynamic parameters such as energy, entropy and enthalpy changes for the adsorption of heavy metal ions have also been computed and discussed. Ion exchange is probably one of the major adsorption mechanisms for binding divalent metal ions to the walnut sawdust. The selectivity order of the adsorbent is Pb（I1）~Cd（II）〉Ni（I1）. From these results, it can be concluded that the sawdust of walnut could be a good adsorbent for the metal ions from aqueous solutions.

关键词： adsorption heavy metals sawdust kinetic thermodynamic parameters

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Sources,characteristics,toxicity,and control of ultrafine particles:An overview

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Geoscience Frontiers 2022年第1期13卷 512-526页

作者： Andrea L.Moreno-Ríos Lesly P.Tejeda.ben.tez Ciro F.Bustillo-Lecompte Department of Civil and Environmental Universidad de la CostaCUCCalle 58#55–66BarranquillaAtlánticoColombia Research Group in Biomedical Toxicological and Environmental Sciences(Biotoxam)University of CartagenaCampus of ZaragocillaCartagenaColombia School of Occupational and Public Health Ryerson University350 Victoria StreetTorontoON M5B 2K3Canada

Air pollution by particulate matter(PM)is one of the main threats to human health,particularly in large cities where pollution levels are continually *** to their source of emission,geography,and local meteorology,the pollutant particles vary in size and *** particles are conditioned to the aerodynamic diameter and thus classified as coarse(2.5–10μm),fine(0.1–2.5μm),and ultrafine(<0.1μm),where the degree of toxicity becomes greater for smaller *** particles can get into the lungs and translocate into vital organs due to their size,causing significant human health ***,PM pollutants have been linked to respiratory conditions,genotoxic,mutagenic,and carcinogenic activity in human *** paper presents an overview of emission sources,physicochemical characteristics,collection and measurement methodologies,toxicity,and existing control mechanisms for ultrafine particles(UFPs)in the last fifteen years.

关键词： Particulate matter Ultrafine particles Air pollution Toxicity Measurement methodologies

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