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Black phosphorus quantum dots induce myocardial inflammatory responses and metabolic disorders in mice

Journal of Environmental Sciences 2024年第3期137卷 53-64页

作者： Chao Shen Xiaoyan Ding Jinpeng Ruan Fengkai Ruan Weiping Hu Jiyi huang Chengyong He Yi Yu Zhenghong Zuo Department of Nephrology State Key Laboratory of Cellular Stress BiologySchool of Life SciencesFaculty of Medicine and Life SciencesFujian Clinical Research Center for Chronic Glomerular DiseaseThe First Affiliated Hospital of Xiamen UniversitySchool of MedicineXiamen UniversityXiamen 361102China

As an ultrasmall derivative of black phosphorus(BP)sheets,BP quantum dots(BP-QDs)have been effectively used in many ***,information on the cardiotoxicity induced by BP-QDs remains *** aimed to evaluate BP-QD-induced cardiac toxicity in *** examination of heart tissue sections was *** sequencing,real-time quantitative PCR(RT–qPCR),western blotting,and enzyme-linked immunosorbent assay(ELISA)assays were used to detect the m RNA and/or protein expression of proinfammatory cytokines,nuclear factor kappa B(NF-κB),phosphatidylinositol3 kinase-protein kinase B(PI3K-AKT),peroxisome proliferator-activated receptor gamma(PPARγ),and glucose/lipid metabolism pathway-related *** found that heart weight and heart/body weight index(HBI)were significantly reduced in mice after intragastric administration of 0.1 or 1 mg/kg BP-QDs for 28 *** addition,obvious infammatory cell infiltration and increased cardiomyocyte diameter were observed in the BP-QD-treated *** expression of proinfammatory cytokines and genes related to the NF-κB signaling pathway further confirmed that BP-QD exposure induced infammatory *** addition,BP-QD treatment also affected the PI3K-AKT,PPARγ,thermogenesis,oxidative phosphorylation,and cardiac muscle contraction signaling *** expression of genes related to glucose/lipid metabolism signaling pathways was dramatically affected by BP-QD exposure,and the effect was primarily mediated by the PPAR signaling *** study provides new insights into the toxicity of BP-QDs to human health.

关键词： BP-QDs Cardiac toxicity Infammatory responses NF-κB signaling pathway PPARγsignaling pathway Glucose/lipid metabolism

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Catalytic oxidation of toluene by manganese oxides:Effect of K^(+)doping on oxygen vacancy

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Journal of Environmental Sciences 2024年第8期142卷 43-56页

作者： Zhenzhen huang Haiyang Li Xuejun Zhang Yanli Mao Yinghan Wu Wei Liu Hongrun Gao Mengru Zhang Zhongxian Song Faculty of Environmental and Municipal Engineering Henan Key Laboratory of Water Pollution Control and Rehabilitation TechnologyHenan University of Urban ConstructionPingdingshan 467036China College of Environmental and Safety Engineering Shenyang University of Chemical TechnologyShenyang 110142China

Alkali metal potassium was beneficial to the electronic regulation and structural stability of transition metal ***,K ions were introduced into manganese oxides by different methods to improve the degradation efficiency of *** results of activity experiments indicated that KMnO_(4)-HT(HT:Hydrothermal method)exhibited outstanding low-temperature catalytic activity,and 90%conversion of toluene can be achieved at 243℃,which was 41℃and 43℃lower than that of KNO_(3)-HT and Mn-HT,*** largest specific surface area was observed on KMnO_(4)-HT,facilitating the adsorption of *** formation of cryptomelane structure over KMnO_(4)-HT could contribute to higher content of Mn^(3+)and lattice oxygen(Olatt),excellent low-temperature reducibility,and high oxygen mobility,which could increase the catalytic ***,two distinct degradation pathways were ***Ⅰ(KMnO_(4)-HT):toluene→benzyl→benzoic acid→carbonate→CO_(2)and H2O;PathwayⅡ(Mn-HT):toluene→benzyl alcohol→benzoic acid→phenol→maleic anhydride→CO_(2)and *** intermediates were detected on KMnO_(4)-HT,indicating its stronger oxidation capacity of toluene,which was originated from the doping of K^(+)and the interaction between *** intermediates were observed on Mn-HT,which can be attributed to the weaker oxidation ability of pure *** results indicated that the doping of K^(+)can improve the catalytic oxidation capacity of toluene,resulting in promoted degradation of intermediates during the oxidation of toluene.

关键词： Catalytic oxidation Preparation method Cryptomelane Mn^(3+)and lattice oxygen

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基于子CRC的智能变电站改扩建测试边界技术研究

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青海电力 2022年第S1期41卷 42-49页

作者：胡艳娇黄湘高健武昌工学院智能制造学院湖北武汉430065 国网电力科学研究院武汉南瑞有限责任公司湖北武汉430074

针对智能变电站改扩建工作中继电保护和安全自动装置测试工作繁琐、停电影响范围大,且容易遗漏被测试设备等问题,通过循环冗余校验(CRC)技术得到测试边界给出改扩建工作中需要测试的设备,提取应当测试的智能电子设备(IED),避免非必要的... 详细信息

针对智能变电站改扩建工作中继电保护和安全自动装置测试工作繁琐、停电影响范围大,且容易遗漏被测试设备等问题,通过循环冗余校验(CRC)技术得到测试边界给出改扩建工作中需要测试的设备,提取应当测试的智能电子设备(IED),避免非必要的IED传动测试。通过CRC校验进行IED域划分,然后结合子CRC的校验给出测试边界,并通过最小子CRC一致性校验将单个设备测试范围缩减到最小。现场应用分析表明,本研究可以正确提示应测试的设备,并最大限度缩小改扩建及检修工作中测试范围,从而减少一次设备陪停、二次设备投入退出操作,提高改扩建工作安全性和工作效率。

关键词：智能变电站改扩建检修测试边界子CRC

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一维石墨烯超晶格上的氢吸附

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物理学报 2014年第19期63卷 309-313页

作者：黄向前林陈昉尹秀丽赵汝光王恩哥胡宗海北京大学物理学院人工微结构与介观物理国家重点实验室北京100871 量子物质协同创新中心北京100871 北京大学国际量子材料科学中心北京100871

通过化学气相沉积法在一种典型的高指数面铜(410)-氧上制备出了一维石墨烯超晶格,并利用拉曼光谱(Raman)、低能电子衍射(LEED)、扫描隧道显微术(STM)等方法研究了氢原子在该超晶格上的吸附.实验结果揭示了由于超晶格的调制作用所引起的... 详细信息

通过化学气相沉积法在一种典型的高指数面铜(410)-氧上制备出了一维石墨烯超晶格,并利用拉曼光谱(Raman)、低能电子衍射(LEED)、扫描隧道显微术(STM)等方法研究了氢原子在该超晶格上的吸附.实验结果揭示了由于超晶格的调制作用所引起的无缺陷石墨烯区域的选择性吸附,氢原子优先吸附在石墨烯超晶格一维周期中的相同部位.这一发现为进一步通过一维超晶格调控石墨烯的性质提供了更多可能.在石墨烯上的吸附氢原子除了单个或成对存在之外,实验还首次观察到一种新的三氢原子位型.

关键词：扫描隧道显微镜石墨烯一维超晶格氢吸附

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发电厂蒸发冷却通风空调系统室外空气计算参数的确定

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制冷与空调（四川） 2015年第3期29卷 266-271页

作者：张鑫黄翔董晓杰西安工程大学西安710048

结合发电厂建筑物或房间的功能特点及我国现行暖通设计规范中对室外空气计算参数的规定,确定合理的发电厂蒸发冷却通风空调系统室外空气计算参数。通过对比分析不同的气象数据库,采用典型气象年逐时气象参数统计全国31个主要城市全年不... 详细信息

结合发电厂建筑物或房间的功能特点及我国现行暖通设计规范中对室外空气计算参数的规定,确定合理的发电厂蒸发冷却通风空调系统室外空气计算参数。通过对比分析不同的气象数据库,采用典型气象年逐时气象参数统计全国31个主要城市全年不保证50h的湿球温度与同时刻对应的干球温度平均值。将统计得到的参数与其他四组数据作为蒸发冷却空气热湿处理的初状态点,对五组数据经过直接蒸发冷却处理后的出风温度和温降进行对比分析,得出发电厂蒸发冷却空调系统室外空气计算参数为全年不保证50h的湿球温度与所对应的平均干球温度、发电厂蒸发冷却通风系统室外空气计算参数为夏季通风室外计算温度和相对湿度的规定较为合理。

关键词：发电厂蒸发冷却通风系统蒸发冷却空调系统室外空气计算参数逐时气象参数

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Universal and efficient hybrid modeling and direct slicing method for additive manufacturing processes

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Advances in Manufacturing 2024年第2期12卷 300-316页

作者： Sen-Lin Wang Li-Chao Zhang Chao Cai Ming-Kai Tang Si Chen Jiang huang Yu-Sheng Shi State Key Laboratory of Materials Processing and Die and Mould Technology Huazhong University of Science and TechnologyWuhan430074People’s Republic of China School of Machinery and Automation Wuhan University of Science and TechnologyWuhan430081People’s Republic of China

Model design and slicing contour generation in additive manufacturing(AM)data processing face challenges in terms of efficiency and scalability when stereolithography files generated by complex functionally graded structures have millions of *** paper proposes a hybrid modeling and direct slicing method for AM to efficiently construct and handle complex three-dimensional(3D)*** 3D solids,including conformal multigradient structures,were uniformly described using a small amount of data via signed distance *** hybrid representations were quickly discretized into numerous disordered directed lines using an improved marching squares *** establishing a directional HashMap to construct the topological relationship between lines,a connecting algorithm with linear time complexity is proposed to generate slicing contours for *** method replaces the mesh reconstruction and Boolean operation stages and can efficiently construct complex conformal gradient models of arbitrary topologies through hybrid ***,the time and memory consumption of direct slicing are much lower than those of previous methods when handling hybrid models with hundreds of millions of faces after mesh reconstruction.

关键词： Additive manufacturing(AM) Hybrid modeling Direct slicing Signed distance field

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城市生命线安全工程关键技术研究进展

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武汉大学学报（信息科学版） 2024年第8期49卷 1251-1263页

作者：袁宏永章翔黄丽达潘睿陈杨刘罡清华大学安全科学学院北京100084 清华大学合肥公共安全研究院安徽合肥230601

城市生命线安全工程是保障城市燃气、供水、供电等系统安全运行的国家重大民生工程。当前城市生命线安全工程面临三类难题:机理揭示和实验复现难,风险探测和早期识别难、精准预警和协同防控难。为突破机理揭示和实验复现难题,研发了全... 详细信息

城市生命线安全工程是保障城市燃气、供水、供电等系统安全运行的国家重大民生工程。当前城市生命线安全工程面临三类难题:机理揭示和实验复现难,风险探测和早期识别难、精准预警和协同防控难。为突破机理揭示和实验复现难题,研发了全球首套全尺寸城市生命线多灾种大型科学装置,建立了生命线系15类、169种灾害耦合致灾模型,提出了地下管线与地上承灾体耦合的综合风险动态评估方法;为攻关风险探测和早期识别难题,发明了有源光栅与波长偏置的高灵敏燃气传感激光芯片和探测器,研发了基于惯导、力平衡、声学频谱及北斗的供水管网泄漏定位智能球,突破了桥梁整体模态(指纹)监测技术;为解决精准预警和协同防控难题,攻克了城市生命线安全风险物理启发式人工智能预警技术,研发了具备协同感知、融合监测、靶向预警、联动响应等功能的监测预警系统。系列相关成果带动了安全应急产业发展,为城市生命线风险防控作出了开创性和实质性贡献。

关键词：城市生命线风险评估承灾体致灾机理监测预警系统

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蒸发冷却空调技术的诠释(2)

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制冷与空调 2012年第3期12卷 9-14页

作者：黄翔孙铁柱汪超西安工程大学

分析蒸发冷却空调技术对室外空气可实现的3种基本热湿处理过程:等焓加湿、等湿冷却和减湿冷却过程,以及对室外空气的净化功能,并详细介绍集中式、半集中式和分散式蒸发冷却空调系统及其相应设备。

关键词：蒸发冷却空调技术热湿过程净化空调系统

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Migration and transformation of Pb,Cu,and Zn during co-combustion of high-chlorine-alkaline coal and Si/Al dominated coal

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Journal of Environmental Sciences 2024年第7期141卷 26-39页

作者： Jiangze Luo Qiwei Yang Jianqiao Wang Boxiong Shen Zhuozhi Wang Qiqi Shi Zhong Zhao Chao huang Jie Xu Tianjin Key Laboratory of Clean Energy and Pollution Control School of Energy and Environmental EngineeringHebei University of TechnologyTianjin 300103China School of Chemical Engineering Hebei University of TechnologyTianjin 300103China

Shaerhu(SEH)coal is abundant in Xinjiang,*** utilization of SEH suffers from severe ash deposition,slagging,and fouling problems due to its high-chlorine-alkaline *** co-combustion of high-alkaline coal and other type coals containing high Si/Al oxides has been proven to be a simple and effective method that will alleviate ash-related problems,but the risk of heavy metals(HMs)contamination in this process is ***,the volatilization rates and chemical speciation of Pb,Cu,and Zn in co-combusting SEH and a high Si/Al oxides coal,i.e.,Yuanbaoshan(YBS)coal were investigated in this *** results showed that the addition of SEH increased the volatilization rates of Pb,Cu,and Zn during the co-combustion at 800℃from 23.70%,23.97%,and 34.98%to 82.31%,30.01%,and 44.03%,respectively,and promoted the extractable state of Cu and *** addition,the interaction between SEH and YBS inhibited the formation of the Pb residue ***-EDS mapping results showed that compared to Zn and Cu,the signal intensity of Pb was extremely weak in regions where some of the Si and Al signal distributions *** DFT results indicated that the O atoms of the metakaolin(Al_(2)O_(3)·2SiO_(2))(001)surface were better bound to the Zn and Cu than Pb atoms after adsorption of the chlorinated *** results contribute to a better understanding of the effects of high-alkaline coal blending combustion on Pb,Cu,and Zn migration and transformation.

关键词： Heavy metals High-chlorine-alkaline coal Coal blending combustion Density functional theory

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Core-Shell Semiconductor-Graphene Nanoarchitectures for Efficient Photocatalysis:State of the Art and Perspectives

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Nano-Micro Letters 2024年第12期16卷 553-588页

作者： Jinshen Lan Shanzhi Qu Xiaofang Ye Yifan Zheng Mengwei Ma Shengshi Guo Shengli huang Shuping Li Junyong Kang Engineering Research Center of Micro-Nano Optoelectronic Materials and Devices Ministry of EducationFujian Key Laboratory of Semiconductor Materials and ApplicationsCI Center for OSEDDepartment of PhysicsXiamen UniversityXiamen 361005People’s Republic of China

Semiconductor photocatalysis holds great promise for renewable energy generation and environment remediation,but generally suffers from the serious drawbacks on light absorption,charge generation and transport,and structural stability that limit the *** core-shell semiconductorgraphene(CSSG)nanoarchitectures may address these issues due to their unique structures with exceptional physical and chemical *** review explores recent advances of the CSSG nanoarchitectures in the photocatalytic *** starts with the classification of the CSSG nanoarchitectures by the ***,the construction methods under internal and external driving forces were introduced and compared with each ***,the physicochemical properties and photocatalytic applications of these nanoarchitectures were discussed,with a focus on their role in *** ends with a summary and some perspectives on future development of the CSSG nanoarchitectures toward highly efficient photocatalysts with extensive *** harnessing the synergistic capabilities of the CSSG architectures,we aim to address pressing environmental and energy challenges and drive scientific progress in these fields.

关键词： Core-shell semiconductor-graphene Nanoarchitecture Photocatalysis Driving force Interface

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