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Study on the hydrogen absorption properties of a YGdTbDyHo rare-earth high-entropy alloy

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 127-135页

作者： Tongyue Li Ziliang xie Wenjiao Zhou huan Tong Dawen Yang Anjia Zhang Yuan Wu xiping Song State Key Laboratory for Advanced Metals and Materials University of Science and Technology BeijingBeijing 100083China Whole Win(Beijing)Materials Sci.&Tech.Co. Ltd.Beijing 100083China

This study investigated the microstructure and hydrogen absorption properties of a rare-earth high-entropy alloy(HEA),*** indicated that the YGdTbDyHo alloy had a microstructure of equiaxed grains,with the alloy elements distributed *** hydrogen absorption,the phase structure of the HEA changed from a solid solution with an hexagonal-close-packed(HCP)structure to a high-entropy hydride with an faced-centered-cubic(FCC)structure without any secondary phase *** alloy demonstrated a maximum hydrogen storage capacity of 2.33 H/M(hydrogen atom/metal atom)at 723 K,with an enthalpy change(ΔH)of-141.09 kJ·mol^(-1)and an entropy change(ΔS)of-119.14 J·mol^(-1)·K^(-1).The kinetic mechanism of hydrogen absorption was hydride nucleation and growth,with an apparent activation energy(E_(a))of 20.90 kJ·mol^(-1).Without any activation,the YGdTbDyHo alloy could absorb hydrogen quickly(180 s at 923 K)with nearly no incubation period *** reason for the obtained value of 2.33 H/M was that the hydrogen atoms occupied both tetrahedral and octahedral *** results demonstrate the potential application of HEAs as a high-capacity hydrogen storage material with a large H/M ratio,which can be used in the deuterium storage field.

关键词： rare-earth high-entropy alloy hydrogen absorption capacity pressure–composition–temperature curves kinetics

Technological insights:combined impedance manometry for esophageal motility testing-current results and further implications

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World Journal of Gastroenterology 2006年第39期12卷 6266-6273页

作者： huan Nam nguyen Gerson Ricardo Souza Domingues Frank Lammert Department of Internal Medicine University of Technology RWTH-Aachen Germany Department of Internal Medicine Gama Filho Unisverity Rio de Janeiro Brazil Department of Internal Medicine University of Bonn Germany

This review focuses on current aspects of the novel technology of combined impedance manometry for esophageal motility testing. It presents methodological features, summarizes current results and discusses implications for further research. The combined technique assesses simultaneously bolus transport and associated peristalsis, thus allowing detailed analysis of the relationships between bolus transit and esophageal motility. Recent studies demonstrate that combined impedance manometry provides important additional information about esophageal motility as compared to conventional manometry: (1) monitoring of bolus transport patterns, (2) calculation of bolus transit parameters, (3) evaluation of bolus clearance, (4) monitoring of swallow associated events such as air movement and reflux, and (5) investigation of the relationships between bolus transit and LES relaxation. Studies with healthy subjects have identified several useful parameters for comprehensive assessment of eosphageal function. These parameters were found to be pathological in patients with classical achalasia, mild GERD, and ineffective esophageal motility. The technology of combined impedance manometry provides an important new tool for esophageal function testing, advancing both clinical and basic research. However, several important issues remain to be standardized to make the technique suitable for widely clinical use.

关键词： Combined impedance manometry Esophageal function testing Review

Complementary doping of van der Waals materials through controlled intercalation for monolithically integrated electronics

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Nano Research 2020年第5期13卷 1369-1375页

作者： Ming Ke Huu Duy nguyen Hang Fan Man Li huan Wu Yongjie Hu School of Engineering and Applied Science University of CaliforniaLos AngelesCalifornia 90095USA

Doping control has been a key challenge for electronic applications of van der Waals ***,we demonstrate complementary doping of black phosphorus using controlled ionic intercalation to achieve monolithic building *** characterize the anisotropic electrical transport as a function of ion concentrations and report a widely tunable resistivity up to three orders of magnitude with characteristic concentration dependence corresponding to phase transitions during *** a further step,we develop both p-type and n-type field effect transistors as well as electrical diodes with high device stability and *** addition,enhanced charge mobility from 380 to 820 cm^2/(V·s)with the intercalation process is observed and explained as the suppressed neutral impurity scattering based on our ab initio *** study provides a unique approach to atomically control the electrical properties of van der Waals materials,and may open up new opportunities in developing advanced electronics and physics platforms.

关键词： nanoelectronics two-dimensional(2D)materials and heterostructures FET diode tunable properties black phosphorus

Postprandial transduodenal bolus transport is regulated by complex peristaltic sequence

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World Journal of Gastroenterology 2006年第37期12卷 6008-6016页

作者： huan Nam nguyen Ron Winograd Gerson Ricardo Souza Domingues Frank Lammert Department of Medicine Ⅲ Division of Gastroenterology Aachen University (RWTH) Aachen Germany

AIM: To study the relationship between the patterns of postprandial peristalsis and transduodenal bolus transport in healthy subjects. METHODS: Synchronous recording of chyme transport and peristaltic activity was performed during the fasting state and after administration of a test meal using a special catheter device with cascade configuration of impedance electrodes and solid-state pressure transducers. The catheter was placed into the duodenum, where the f irst channel was located in the f irst part of the duodenum and the last channel at the duodenojejunal junction. After identif ication of previously def ined chyme transport patterns the associated peristaltic patterns were analyzed. RESULTS: The interdigestive phase 3 complex was reliably recorded with both techniques. Of 497 analyzed impedance bolus transport events, 110 (22%) were short-spanned propulsive, 307 (62%) long-spanned propulsive, 70 (14%) complex propulsive, and 10 (2%) retrograde transport. Short-spanned chyme transports were predominantly associated with stationary or propagated contractions propagated over short distance. Long-spanned and complex chyme transports were predominantly associated with propulsive peristaltic patterns, which were frequently complex and comprised multiple contractions. Propagated double wave contraction, propagated contraction with a clustered contraction, and propagated cluster of contractions have been identif ied to be an integralted part of a peristaltic sequence in human duodenum. CONCLUSION: Combined impedancometry and manometry improves the analysis of the peristaltic patterns that are associated with postprandial transduodenal chymetransport. Postprandial transduodenal bolus transport is regulated by propulsive peristaltic patterns, which are frequently complex but well organized. This f inding should be taken into consideration in the analysis of intestinal motility studies.

关键词： Transduodenal bolus transport Organization of duodenal peristalsis Combined impedance manometry

A new species of Micryletta(Amphibia:Anura:Microhylidae)from the Langbian Plateau in southern Vietnam

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Zoological Research 2021年第6期42卷 726-733页

作者： Nikolay A.Poyarkov Tan Van nguyen Jian-huan Yang Vladislav AGorin Faculty of Biology Department of Vertebrate ZoologyMoscow State UniversityMoscow119234Russia Laboratory of Tropical Ecology Joint Russian-Vietnamese Tropical Research and Technological CenterHanoiVietnam Department of Species Conservation Save Vietnam’s WildlifeNinh BinhVietnam Kadoorie Conservation China Kadoorie Farm and Botanic GardenTai PoHong Kong SARChina

We report a new species of the genus Micryletta from the montane evergreen forest in the Bidoup-Nui Ba National Park,Lam Dong Province,Langbian Plateau,southern Vietnam,based on molecular and morphological *** new species is diagnosed by a combination of the following morphological characters:body size small(snout-vent length(SVL)22.4 mm,single female);iris uniform black;snout nearly truncate in dorsal view,slightly rounded in profile;tibiotarsal articulation of adpressed limb reaching level of eye;dorsal surface smooth;supratympanic fold present,prominent;outer metatarsal tubercle absent;tips of toes very weakly dilated into small discs;finger webbing absent,toe webbing rudimentary;dorsal surfaces of head and body orange-red with small irregularly shaped dark-brown patches;dorsal surface of limbs pale dark brown with small reddish speckles;body flanks dark brown anteriorly fading to grayish brown posteriorly with brown spots in groin area;lateral sides of head immaculate blackish brown without white patches;coloration of ventral surfaces immaculate dark gray.

关键词： Plateau orange brown

Towards understanding structure–property relations in materials with interpretable deep learning

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npj Computational Materials 2023年第1期9卷 157-168页

作者： Tien-Sinh Vu Minh-Quyet Ha Duong-nguyen nguyen Viet-Cuong nguyen Yukihiro Abe Truyen Tran huan Tran Hiori Kino Takashi Miyake Koji Tsuda Hieu-Chi Dam Japan Advanced Institute of Science and Technology NomiIshikawaJapan HPC SYSTEMS Inc. MinatoTokyoJapan Applied Artificial Intelligence Institute Deakin UniversityGeelongVICAustralia School of Materials Science and Engineering Georgia Institute of TechnologyAtlantaGAUSA Research and Services Division of Materials Data and Integrated System National Institute for Materials ScienceTsukubaIbarakiJapan Research Center for Computational Design of Advanced Functional Materials National Institute of Advanced Industrial Science and TechnologyTsukubaIbarakiJapan Department of Computational Biology and Medical Sciences Graduate School of Frontier SciencesUniversity of TokyoKashiwa-shiChiba-kenJapan International Center for Synchrotron Radiation Innovation Smart(SRIS) Tohoku UniversityAoba-kuSendaiJapan

Deep learning(DL)models currently employed in materials research exhibit certain limitations in delivering meaningful information for interpreting predictions and comprehending the relationships between structure and material *** address these limitations,we propose an interpretable DL architecture that incorporates the attention mechanism to predict material properties and gain insights into their structure–property *** proposed architecture is evaluated using two well-known datasets(the QM9 and the Materials Project datasets),and three in-house-developed computational materials ***–test–split validations confirm that the models derived using the proposed DL architecture exhibit strong predictive capabilities,which are comparable to those of current state-of-the-art ***,comparative validations,based on first-principles calculations,indicate that the degree of attention of the atoms’local structures to the representation of the material structure is critical when interpreting structure–property relationships with respect to physical *** properties encompass molecular orbital energies and the formation energies of *** proposed architecture shows great potential in accelerating material design by predicting material properties and explicitly identifying crucial features within the corresponding structures.

关键词： properties property structure

Plastic Effect on the Sliding Inception Bet ween a Cylinder and a Rigid Flat

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Acta Mechanica Solida Sinica 2019年第1期32卷 1-16页

作者： S.Zhang J.huan H.Song x.Liu Y.G.Wei LNM Institute of MechanicsChinese Academy of SciencesBeijing 100190China Department of Mechanical Engineering Johns Hopkins UniversityBaltimoreMD 21218USA College of Engineering Peking UniversityBeijing 100871China School of Engineering Science University of Chinese Academy of SciencesBeijing 100049China

The effec ts of mat erial plasticity and local slip on the sliding inception of asperity are studied in the present ***,a semi-analytical solution is derived under the full-stick condition to analyze the effect of material plasticity on sliding ***,a friction model with contact stiffness criterion is proposed to study the cases from partial-slip condition to full-stick *** element simulations with the provided model are used to present the friction *** friction coefficient of full-s tick interface converges at a st able value,approxima tely *** saturation appears as the normalized contact interference u*is larger than 3.A transition mechanism from slip-dominated to yield-dominated takes place in the sliding *** simulation results are compared with the semi-analytical solution.

关键词： Mat erial yielding Local slip Contact stiffness criterion Finite element simulation

Corrosion Behavior of a Low-Carbon Steel in Simulated Marine Splash Zone

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Acta Metallurgica Sinica(English Letters) 2017年第6期30卷 585-593页

作者： huan-huan Wang Min Du Key Laboratory of Marine Chemistry Theory and Technology Ministry of EducationCollege of Chemistry and Chemical EngineeringOcean University of ChinaQingdao 266100China

Experiments were designed to simulate the corrosion of a low-carbon steel exposed to a marine splash zone. The composition and morphology of the rust were investigated using Raman spectroscopy, x-ray photoelectron spectroscopy, energy-dispersive spectrometry and scanning electron microscopy. Corrosion resistance of the rust films was demonstrated by the electrochemical impedance spectroscopy. The wettability of the steel surface was calculated from the data conceruing the wetting degree and the conductivity. The results showed that, in the initial stage, the products of the outer rust layer were mainly made up of Fe（Ⅲ） oxyhydroxide, while the main component of the inner rust layer was magnetite. With an increase in the corrosion time, the inner rust layer continuously turned into the outer rust layer. In addition, both rust layers became dense, thus playing a protective role with respect to matrix. The existence of the rust layer significantly prolonged the residence time of the seawater on the sample surface, a result that tends to improve the cathodic protection effect for steel structures exposed to marine splash zones.

关键词： Marine splash zone Low-carbon steel Corrosion behavior Electrochemical impedance spectroscopy (EIS) Wetting degree

Limit behaviors for dependent Bernoulli variables

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Applied Mathematics(A Journal of Chinese Universities) 2020年第4期35卷 399-409页

作者： MIAO Yu MA huan-huan College of Mathematics and Information Science Henan Normal UniversityXinxiang 453007China

In this paper,we consider a class of dependent Bernoulli variables,which has the following form:for k≥m,P(xk+1=1jFk)=Σm i=1θixk+1􀀀i+θ0p,where m is a positive integer,Σmi=0θi=1,Fn=σ{x1,……,xn},0 详细信息

关键词： strong law of large numbers moderate deviation Bernoulli variables martingale