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Chinese Journal of structural Chemistry 2022年第6期41卷 23-30页

作者： Tao Yang Pengke Deng Lele Wang Jie hu Qinqin Liu hua Tang school of Materials science&Engineering Jiangsu UniversityZhenjiang 212013China school of Environmental science and Engineering Qingdao UniversityQingdao 266071China

The low separation/migration efficiency is a major obstacle that limits the practical application of semiconductor-photocatalysts. Constructing s-scheme heterojunction is an ideal strategy for providing high photocatalytic activity via accelerating charge separation. Herein, an AgPO/Cncomposite was s.nthesized by coupling AgPOparticle with Cnhollow spheres in-situ via a precipitation method. The s-scheme hete-rojunction between AgPOand Cncould accelerate the charge separation and retain high photoredox ability, which s.nchronously realized high photocatalytic oxygen production and hexavalent chromium reduction. The optimized Ag3PO4/Cncomposite shows a high oxygen production rate up to 803.31 μmol·g·hand a high conversion(87.9%) of Cr(Ⅵ) to Cr(Ⅲ). In addition, Cnhollow spheres affords higher reaction efficiency than that of Cntube, Cnbulk and Cnsheet, which indicates that the hollow sphere structure can provide more active sites and adsorption sites in the photocatalytic process. This work offers an effective way in developing a dual-function s-scheme heterojunction for clean energy production and environmental protection.

关键词： s-scheme charge transfer route Ag_(3)PO_(4)/C_(3)n_(4) Cr(Ⅵ)reduction O_(2)production photocatalysis

Hierarchical mesoporous s.n-codoped carbon nanostructures composed of Co/Co-Cu-s/carbon nanoplate arrays on carbon nanofibers as a self-supported air cathode for long-lasting rechargeable Zn-air batteries

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science China(Technological sciences) 2022年第3期65卷 693-703页

作者： XU ZhuYing YAn Lei sHEn JunLing YAnG XiaoJing nInG JiQiang ZHOnG YiJun hu Yong Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Department of ChemistryZhejiang Normal UniversityJinhua 321004China Department of Optical science and Engineering Fudan UniversityShanghai 200438China Hangzhou Institute of Advanced studies Zhejiang Normal UniversityHangzhou 311231China

One of the primary roadblocks to widespread applications of rechargeable Zn-air batteries is the durability issue with oxygen reduction and evolution processes(ORR/Oer)bifunctional *** herein report the construction of a selfsupported air cathode for Zn-air batteries made of s.n-codoped porous complex carbon nanostructures of Co/Co-Cu-s/carbon nanoplate arrays and carbon nanofibers(denoted as Co/Co-Cu-s@snPCP-CFs).The hierarchical heteroatom-doped mesoporous carbon nanohybrids with multiple active species.not only provide a high surface-to-volume ratio,expos.ng more catalytic sites and accelerating the charge and mass transfer,but also boost the activity and *** Co/Co-Cu-s@snPCP-CFs catalyst reveals a small potential gap(ΔE=0.67 V)between the half-wave potential of ORR and Oer potential at 10 m A ccm^(-2),demonstrating outstanding bifunctional ***,the rechargeable Zn-air battery made with the as-obtained electrocatalyst exhibits a high-power density of 220 m W cm^(-2)and a long cycling time of over 800 h at 10 m A ccm^(-2),and the flexible solid-state rechargeable Zn-air battery based on Co/Co-Cu-s@snPCP-CFs self-supporting air cathode also displays a long duration time of over 60 h.

关键词： Co Co-Cu-s carbon bifunctional electrocatalyst rechargeable Zn-air batteries

Tuning the selectivity of natural oils and fatty acids/esters deoxygenation to biofuels and fatty alcohols:A review

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Green Energy & Environment 2023年第3期8卷 722-743页

作者： Yingdong Zhou Javier Remon Zhicheng Jiang Avtar s.Matharu Changwei hu Key Laboratory of Green Chemistry and Technology Ministry of EducationCollege of ChemistrySichuan UniversityChengduSichuan 610064China Instituto de Carboquímica CSICZaragoza50018Spain Department of Biomass science and Engineering Sichuan UniversityChengdu610064China national Engineering Research Center of Clean Technology in Leather Industry Sichuan UniversityChengdu610064China Green Chemistry Centre of Excellence Department of ChemistryUniversity of YorkHeslingtonYorkYO105DDUK

The chemical transformation of natural oils provides alternatives to limited fossil fuels and produces compounds with added value for the chemical *** selective deoxygenation of natural oils to diesel-ranged hydrocarbons,bio-jet fuels,or fatty alcohols with controllable selectivity is especially attractive in natural oil feedstock *** review pres.nts recent progress in catalytic deoxygenation of natural oils or related model compounds(e.g.,fatty acids)to renewable liquid fuels(green diesel and bio-jet fuels)and valuable fatty alcohols(unsaturated and saturated fatty alcohols).Besides,it discusses and compares the existing and potential strategies to control the product selectivity over heterogeneous *** research conducted and reviewed has only addressed the production of one category;therefore,a new integrative vision exploring how to direct the process toward fuel and/or chemicals is urgently ***,work conducted to date address.ng the development of new catalysts and studying the influence of the reaction parameters(e.g.,temperature,time and hydrogen pressure)is summarized and critically discussed from a green and sustainable perspective us.ng efficiency indicators(e.g.,yields,selectivity,turnover frequencies and catalysts lifetime).special attention has been given to the chemical transformations occurring to identify key descriptors to tune the selectivity toward target products by manipulating the reaction conditions and the structures of the ***,the challenges and future research goals to develop novel and holistic natural oil biorefineries are *** a result,this critical review provides the readership with appropriate information to selectively control the transformation of natural oils into either biofuels and/or value-added *** new flexible vision can help pave the wave to suit the pres.nt and future market needs.

关键词： natural oil Deoxygenation Controllable selectivity Biofuels Fatty alcohols

Growth behavior and electronic regulation of Pt on various Mo-based supports for hydrogen evolution electrocatalysis

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science China Chemistry 2025年

作者： Lulu Chen Yichao huang Jiajun Wang Meihong Liao Zhiyuan Liu Meiqi Liu Hanqing Cai Lin Wang Lidong Gao Dawei hu Lianming Zhao ning Pu Zhuangjun Fan state Key Laboratory of Chemical safety School of Materials Science and Engineering China University of Petroleum (East China) school of Mechanical and Electronic Engineering Qingdao Binhai University Qingdao Chuangqi new Energy Catalysis Technology Co.Ltd. s.nopec Research Institute of Petroleum Process.ng Co.Ltd. Institute of Energy Hefei Comprehensive National Science Center

Insight into the growth behavior and electronic regulation of platinum （Pt） on various transition metal supports is paramount in developing high-performing electrocatalysts for hydrogen evolution reactions （Her）.Herein,we studied the influence of molybdenum-based supports （MoX,X=C,n,P,and s） on the growth behavior and electronic regulation of *** found that the formation energy variations between Pt s.ngle atom and clusters on MoX supports play a pivotal role in the growth behavior of ***,the electronic regulation of Pt induced by metal-support interaction may reflect the valence changes of Pt in Pt-MoX/*** Pt-MoC/C catalyst with a moderate valence state of Pt exhibits the best Her activity with an overpotential of 12.0 mV at 10 mA cm-2and a mass activity of 27.1 A mgPt-1,12.3 times as high as that of commercial 20 wt% Pt/*** work provides constructive guidance for the design of high-performance Her catalysts.

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Dendritic spine degeneration:a primary mechanism in the aging process

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neural Regeneration Research 2025年第6期20卷 1696-1698页

作者： Gonzalo Flores Leonardo Aguilar-Hernández Fernado García-Dolores humberto nicolini Andrea Judith Vázquez-Hernández Hiram Tendilla-Beltrán Instituto de Fisiología Benemérita Universidad Autónoma de Puebla(BUAP)PueblaMexico Instituto de Ciencias Forenses(InCIFO) Tribunal Superior de Justicia de la Ciudad de México(TSJCDMX).Mexico CityMexico Instituto nacional de Medicina Genómica(InMEGEn) Mexico CityMexico

Recent reports suggest that aging is.not solely a physiological process in living beings;instead, it should be considered a pathological process or disease(Amorim et al., 2022). Consequently, this process involves a wide range of factors, spanning from genetic to environmental factors, and even includes the gut microbiome(GM)(Mayer et al., 2022). All these processes coincide at some point in the inflammatory process, oxidative stress, and apoptosis, at different degrees in various organs and systems that constitute a living organism(Mayer et al., 2022;AguilarHernández et al., 2023).

关键词： aging process stress

Predicting Maximum Lifespan Limits at Mean Menopausal Age

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Journal of Mathematical Research with Applications 2025年第1期 133-142页

作者： M.sUMATHI s.AnTOnY CARLA Department of Mathematics N.M.S.S.Vellaichamy Nadar College Research scholar (Part-time) Madurai Kamaraj University

The age at which a woman enters.natural menopause has also been associated to death from any cause. Menopause is a natural component of aging that happens between the ages of 45 and 55, with the average menopausal age being 51. Previous research has revealed the age at which women reach menopause, but there is.no evidence to support the link between menopause and longevity. We made a study in assess.ng the limits of maximum lifespan at menopausal age in our previous article. In this paper, we aim to predict the maximum lifespan of women at mean menopausal age.

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nano-Enhanced Dairy scum Biodiesel Blends:Unleashing the Power of Aluminium Oxide for sustainable and Efficient Engine Performance

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Journal of Thermal science 2025年第1期34卷 283-302页

作者： Veeranna MODI Prasad B.RAMPURE s.nil Kumar sHETTY Madeva nAGARAL Channa Keshava nAIK n Johar MGM Muhammad Irsyad ABDULLAH Abdullah I.AL-MAnsOUR shamshad ALAM KLE College of Engineering and Technology ChikodiVisvesvaraya Technological University nitte (Deemed to be University) NMAM Institute of Technology (NMAMIT)Department of Mechanical Engineering Aircraft Research and Design Centre HAL Department of Mechanical Engineering BGS College of Engineering and TechnologyBengaluruAffiliated to Visvesvaraya Technological University Management and science University Department of Civil Engineering College of EngineeringKing Saud University

This study investigates the effect of aluminium oxide nanoparticlesaddition to biodiesel blends made from dairy milk scum on performance and combustion characteristics of the diesel *** dispersion of Al2O3nanoparticles in B20 blends at different concentrations was done with the help of *** number of blends were prepared for the *** Machine learning algorithms(Random Forest（RF）and CatBoost) was used for the *** results show that in comparis.n to biodiesel blends without nanoparticles,the kinematic viscosity and density is higher for fuel blends with *** these Fuel blends have higher calorific *** blends exhibited reduced Brake specific Fuel Consumption（BsFC） of2.85% than the blends without nano particles(Dairy scum Methyl Ester Biodiesel 20%+neat Diesel 80%（in volume）,DsMEB20),57.14% less CO,40.8% less hydrocarbon,and increased nOxemissions compared to conventional diesel,contributing to the development of environmentally friendly and renewable biofuel blends with *** B20nP30 is the optimal blend for performance and emission *** study concludes with findings on enhanced Brake Thermal Efficiency（BTE） of 26.29% in 3×10-5（in volume） Al2O3nanoparticle-blended DsME B20 and other DsME B20 fuel blends,emphasizing the importance of optimal nanoparticle *** correlation matrix shows how engine load,efficiency measures（BTE,BsFC）,and emissions（CO,CO2,nOx,smoke） are connected in complex *** results help us understand the complicated dynamics of engine performance and emission characteristics ***'s diagram for BTE and BsFC shows that CatBoost-based BTE models perform superior to RF-based models during the training as well as testing *** results were obtained for CO and CO2emission results.

关键词： Al2O3 concentration CI engine Dairy scum Methyl Ester Biodiesel

Fe doped g-C_(3)n_(4) composited ZnIn_(2)s_(4) promoting Cr(Ⅵ) photoreduction

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Chinese Chemical Letters 2023年第4期34卷 430-435页

作者： Zhuoga Cirena Yu nie Yanfang Li huilin hu Xiang huang Xin Tan Tao Yu school of Environmental science and Engineering Tianjin UniversityTianjin 300350China school of Chemical Engineering and Technology Tianjin UniversityTianjin 300350China school of Materials science and Engineering Tianjin UniversityTianjin 300350China school of science Tibet UniversityLhasa 850000Chin

30% Fe Cn/ZIs(30% Fe doped g-C_(3)n_(4)composited ZnIn_(2)s_(4)) was s.nthesized by a simple water bath method, via in-situ growth of abundant well-dispersed ZnIn_(2)s_(4)nanosheets on the Fe doped g-C_(3)n_(4)surface. Experimental results showed the optimized 30% Fe Cn/ZIs achieved the best photoreduction of Cr(VI)performance within a wide p H range, which was 9.5 times and 700 times higher than that of pure ZnIn_(2)s_(4)and 30% Fe Cn(Fe doped g-C_(3)n_(4)). This is due to the intense s.nergy between the Fe-nxbond and close interface contact produces a high-speed charge transfer channel, thus significantly improving the efficiency of optical carrier separation and migration. Meanwhile, UV-vis diffuse reflection spectra and photoluminescence spectroscopy showed that iron doping significantly narrowed the bandgap of gC_(3)n_(4), preventing electron-hole pair recombination. Further, the microstructures and charge separation properties were analyzed by scanning electron microscope, Photoluminescence spectroscopy and timeresolved photoluminescence, which revealed the structure-activity relationship of composite structure and the s.nergistic mechanism of each functional component. This research should provide a viable technique for creating composites with high photocatalytic activity for the treatment of chromium-containing wastewater.

关键词： Hexavalent chromium 30%FeCn/ZIs composites Interfacial interaction s.nergistic effect

Designed preparation of Cos/Co/MoC nanoparticles incorporated in n and s dual-doped porous carbon nanofibers for high-performance Zn-air batteries

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Chinese Chemical Letters 2021年第7期32卷 2243-2248页

作者： Yanrong Ren Haiyan Wang Tianyu Zhang Luankexin Ma Pengcheng Ye Yijun Zhong Yong hu Key Laboratory of the Ministry of Education for Advanced Catalysis Materials Department of ChemistryZhejiang Normal UniversityJinhua 321004China school of Biological and Medical Engineering School of Food Science and EngineeringHefei University of TechnologyHefei 230009China Queen Mary University of London Engineering school NPU/Material Science and EngineeringNorthwestern Polytechnical UniversityXi'an 710000China

The development of low-cost and highly efficient bifunctional electrocatalysts toward oxygen reduction reaction(ORR)and oxygen evolution reaction(Oer)is of critical importance for clean energy devices such as fuel cells and metal-air ***,a sophisticated na nostructure composed of Cos,Co and MoC nanoparticles incorporated in n and s dual-doped porous carbon nanofibers(Cos/Co/MoC-n,sPCnFs)as a high-efficiency bifunctional electrocatalyst is designed and s.nthesized via an efficient multistep *** as-prepared Cos/Co/MoC-n,s-PCnFs exhibit a positive half-wave potential(E1/2)of0.871 V for ORR and a low overpotential of 289 mV at 10 mA/cm^(2) for Oer,outperforming the non-noble metal-based catalysts ***,the assembled Zn-air battery based on Cos/Co/MoC-n,sPCnFs delivers an excellent power density(169.1 mW/cm^(2)),a large specific capacity(819.3 mAh/g)and robust durability,demonstrating the great potential of the as-developed bifunctional electrocatalyst in practical *** work is expected to inspire the design of advanced bifunctional nonprecious metal-based electrocatalysts for energy storage.

关键词： Cos Co MoC Porous carbon nanofibers Zn-air batteries

A comparative study of four 20-membered n_2s_4-crown ethers as ionophores for polymeric membrane silver selective electrodes

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Chinese Chemical Letters 2010年第4期21卷 464-467页

作者： Zhang, Jun Yu, shun Yang Yin, Tan Ji hu, Xue Feng Qin, Wei Chinese Acad sci Yantai Inst Coastal Zone Res Key Lab Coastal Environm Proc Yantai 264003 Peoples R China Chinese Acad sci Inst Oceanol Qingdao 266071 Peoples R China Chinese Acad sci Grad Univ Beijing 100049 Peoples R China

Four 20-membered n_2s_4-monoazathiacrown ethers have been s.nthesized and explored as.neutral ionophores for Ag^+-selective *** responses reveal that the flexibility of the ligands has great effect on the selectivity and s.nsitivity to Ag^+ *** electrode based on ionophore 9,10,20,25-tetrahydro-5H,12H-tribenzo[b,n,r][1,7,10,16,4,13]tetrathiadiaza cycloicos.ne 6,13-(7H,14H)-dione(C) with 2-nitrophenyl octyl ether(o-nPOE) as solvent in a poly(vinyl chloride)(PVC) membrane matrix sho...

关键词： Ion-selective electrodes silver Ionophore Azathiacrown ether