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Curing the vulnerable heterointerface via organic-inorganic hybrid hole transporting bilayers for efficient inverted perovskite solar cells

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Chinese Chemical Letters 2024年第6期35卷 254-257页

作者： Kangrong Yan Ziqiu Shen Yanchun Huang Benfang Niu hongzheng chen Chang-Zhi Li State Key Laboratory of Silicon and Advanced Semiconductor Materials Department of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027China

To promote the practices of perovskite photovoltaics,it requires to develop efficient perovskite solar cells(PVSCs)standing long-time operation under the adverse environments.Herein,we demonstrate that the tailor-made conjugated polymers as conductive adhesives stabilized the originally redox-reactive heterointerface between perovskite and metal oxide,facilitating the access of efficient and stable inverted PVSCs.It was revealed that bithiophene and phenyl alternating conjugated polymers with partial glycol chains atop of the metal oxide layer has resulted in effective organic-inorganic hybrid hole transporting bilayers,which allow maintaining efficient hole extraction and transport,meanwhile preventing halide migration to directly contact with the nickel oxide(NiO_(x))layer.As a result,the corresponding inverted PVSCs with the organic-inorganic hole transporting bilayers have achieved an excellent power conversion efficiency of 23.22%,outperforming 20.65% of bare NiO_(x)-based devices.Moreover,the encapsulated PVSCs with organic-inorganic bilayers exhibited the excellent photostability with 91% of the initial efficiency after 1000-h one-sun equivalent illumination in ambient conditions.Overall,this work provides new insights into stabilizing the vulnerable heterointerface for perovskite solar cells.

关键词： Perovskite solar cells Conjugated polymer Hole transporting bilayer Charge extraction Heterointerface degradation

Ion Migration and Accumulation in Halide Perovskite Solar Cells

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Chinese Journal of Chemistry 2023年第7期41卷 861-876页

作者： Lijian Zuo Zexin Li hongzheng chen State Key Laboratory of Silicon Materials MOE Key Laboratory of Macromolecular Synthesis and FunctionalizationDepartment of Polymer Science and EngineeringZhejiang UniversityHangzhouZhejiang310027 China Zhejiang University-Hangzhou Global Scientific and Technological Innovation Center HangzhouZhejiang310014 China

Comprehensive Summary The halide perovskite semiconductors-based solar cells(PVSCs)show great promise as next-generation renewable energy sources,with the merits of low cost,high performance,good flexibility,etc.A major difference distinguishing the perovskite semiconductors from others lies in their ionic feature.This intrinsic property induces“freely-moving”ions to migrate and accumulate in the perovskite films and devices under different external stresses.As a charge carrier,these processes will strongly couple with the electronic process,and dramatically affect the performance and stability of PVSCs.This review summarizes and discusses the recent progresses and fundamental understandings of ion migration and accumulation behaviors in PVSCs.First,the basic principles of the general ion migration are reviewed.Second,following the fundamental understandings,the critical factors,e.g.,ion migration activation energy,ion density,ion diffusion coefficient,etc.,are extracted to understand the ion migration and accumulation in perovskite film.Third,the principles governing ion accumulation behaviors under different external stresses are discussed.Finally,the effect of ion migration and accumulation on band bending,and device performance is presented.Therefore,we hope this review provides a tutorial and insightful perspective regarding the most prominent ionic feature of perovskite semiconductors and their application for photovoltaics.

关键词： Semiconductors Perovskite phases Crystal engineering Defects Photovoltaic

Solid Additive-Assisted Layer-by-Layer Processing for 19%Efficiency Binary Organic Solar Cells

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Nano-Micro Letters 2023年第7期15卷 16-29页

作者： Guanyu Ding Tianyi chen Mengting Wang Xinxin Xia chengliang He Xiangjun Zheng Yaokai Li Di Zhou Xinhui Lu Lijian Zuo Zhikang Xu hongzheng chen State Key Laboratory of Silicon Materials Department of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027People’s Republic of China Department of Physics The Chinese University of Hong KongNew TerritoriesHong Kong 999077People’s Republic of China Zhejiang University-Hangzhou Global Scientific and Technological Innovation Center Hangzhou 310014People’s Republic of China MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027People’s Republic of China Key Laboratory of Adsorption and Separation Materials and Technologies of Zhejiang Province Zhejiang UniversityHangzhou 310027People’s Republic of China

Morphology is of great significance to the performance of organic solar cells(OSCs),since appropriate morphology could not only promote the exciton dissociation,but also reduce the charge recombination.In this work,we have developed a solid additive-assisted layer-by-layer(SAA-LBL)processing to fabricate high-efficiency OSCs.By adding the solid additive of fatty acid(FA)into polymer donor PM6 solution,controllable pre-phase separation forms between PM6 and FA.This intermixed morphology facilitates the diffusion of acceptor Y6 into the donor PM6 during the LBL processing,due to the good miscibility and fast-solvation of the FA with chloroform solution dripping.Interestingly,this results in the desired morphology with refined phase-separated domain and vertical phase-separation structure to better balance the charge transport/collection and exciton dissociation.Consequently,the binary single junction OSCs based on PM6:Y6 blend reach champion power conversion efficiency(PCE)of 18.16%with SAA-LBL processing,which can be generally applicable to diverse systems,e.g.,the PM6:L8-BO-based devices and thick-film devices.The efficacy of SAA-LBL is confirmed in binary OSCs based on PM6:L8-BO,where record PCEs of 19.02%and 16.44%are realized for devices with 100 and 250 nm active layers,respectively.The work provides a simple but effective way to control the morphology for high-efficiency OSCs and demonstrates the SAA-LBL processing a promising methodology for boosting the industrial manufacturing of OSCs.

关键词： Organic solar cells Fatty acid Solid additive Layer-by-layer Vertical phase separation

Polypropylene Glycol-Modified Anode Interface for High-Performance Perovskite Solar Cells

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Chinese Journal of Chemistry 2022年第22期40卷 2694-2700页

作者： Fei Wu Kangrong Yan Haotian Wu Yuanhang Guo Shiqi Shan Tianyi chen Weifei Fu Lijian Zuo hongzheng chen State Key Laboratory of Silicon Materials MOE Key Laboratory of Macromolecular Synthesis and FunctionalizationDepartment of Polymer Scienceand EngineeringZhejiang UniversityHangzhouZhejiang310027China Zhejiang University-Hangzhou Global Scientific and Technological Innovation Center HangzhouZhejiang 310014China

The surface properties and chemical interactions are critical for perovskite solar cells(PVSCs).In this work,we show that the polypropylene glycol(PPG)can simultaneously passivate the NiOx surface and grain boundaries of perovskite films,allowing more efficient charge transfer at the anode interface and reducing the recombination of PVSCs.As a result,the open-circuit voltage(Voc)of MAPbI3 based inverted PVSCs increases from 1.087 V to 1.127 V,and the short-circuit current density(Jsc)is increased from 20.87 mA·cm^(–2) to 22.32 mA·cm^(–2),thereby realizing the improvement of the device power conversion efficiency(PCE)from 18.34%to 20.12%.Moreover,the steady-state output of the PVSCs is remarkably improved by incorporating PPG.Further analysis of surface properties suggests that part of the PPG at the interface can permeate into the precursor solution with the help of DMF solvent and remain in the perovskite layer to form a concentration gradient.The ether bond of PPG and the uncoordinated Pb2+in the perovskite are coordinated to achieve passivation effects and improve device performance.

关键词： Nanoparticles Polymers Interfaces Passivation effects Inverted perovskitesolarcells

Healing the degradable organic–inorganic heterointerface for highly efficient and stable organic solar cells

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InfoMat 2022年第2期4卷 162-170页

作者： Yangdan Tao Haoran Liu Di Wang Feng Zhao Zeng chen Haiming Zhu hongzheng chen Chang-Zhi Li State Key Laboratory of Silicon Materials MOE Key Laboratory of Macromolecular Synthesis and FunctionalizationDepartment of Polymer Science and EngineeringZhejiang UniversityHangzhouChina Department of Chemistry Zhejiang UniversityHangzhouChina

The heterointerface between the contacted organic and inorganic semiconductors critically affects the charge extraction,hence overall performance of organic optoelectronics,especially for organic solar cells(OSCs).Herein,we develop an effective interfacial strategy that simultaneously boosts the chemical,electric,and electronic properties of the organic–inorganic heterointerface of the derived OSCs,through implanting conjugated molecules as selfassemble monolayers(SAMs)to metal oxide nanoparticles(MO NPs).As results,SAM passivated zinc oxide nanoparticles(ZnO NPs)as electron transport layers(ETLs)not only enable the best performed OSCs containing MO ETLs,but also exhibit the most desirable thickness insensitive features(up to 300 nm).In addition,SAM-ZnO ETLs help also substantially improving the photostability of the derived OSCs.Overall,this work can be beneficial to the further development of high-performance and cost-effective OSCs.

关键词： charge extraction organic-inorganic heterointerface organic solar cells photostability

A multifunctional and scalable fullerene electron transporting material for efficient inverted perovskite solar cells and modules

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Science China Chemistry 2023年第6期66卷 1795-1803页

作者： Kangrong Yan Ziqiu Shen Benfang Niu Yanchun Huang Di Wang Emely Gu Buyi Yan Jizhong Yao hongzheng chen Chang-Zhi Li State Key Laboratory of Silicon Materials Department of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027China Hangzhou Microquanta Semiconductor Co.LTD. Innovation ParkHangzhou 310027China

The interfacial properties between charge transporting material and perovskite(PVSK)play critical roles in governing the photovoltaic performances of perovskite solar cells(PVSCs).Herein,we develop a multifunctional fulleropyrrolidine(FMG)as an electron transporting material(ETM),which facilitates the construction of efficient and stable inverted PVSCs and modules.It revealed that the facile and scalable FMG possesses not only excellent electron extraction capabilities,but also multi-groups to simultaneously passivate PVSKs via Lewis acid-base and hydrogen bonding interactions.The coating of FMG onto PVSK interestingly yields a dense and interactive layer with the graded ETM-PVSK heterojunction architecture.As a result,FMGbased PVSCs demonstrate a champion efficiency of 23.8%,outperforming 21.0%of PCBM-based devices.FMG could also be utilized to improve photovoltaic performance of large-scale modules.In addition,FMG has successfully elongated the lifetime of the corresponding PVSCs,maintaining 85%of the initial performance after the continuous 60-day one sun equivalent illumination in ambient.

关键词： fullerene derivative interface electron transporting material perovskite solar cells

Design of Non-fused Ring Acceptors toward High-Performance,Stable,and Low-Cost Organic Photovoltaics

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Accounts of Materials Research 2022年第6期3卷 644-657页

作者： Qing Shen chengliang He Shuixing Li Lijian Zuo Minmin Shi hongzheng chen State Key Laboratory of Silicon Materials MOE Key Laboratory of Macromolecular Synthesis and FunctionalizationInternational Research Center for X PolymersDepartment of Polymer Science and EngineeringZhejiang UniversityHangzhou 310027P.R.China Shanxi-Zheda Institute of Advanced Materials and Chemical Engineering Hangzhou 310027P.R.China

Toward future commercial applications of organic solar cells(OSCs),organic photovoltaic materials that enable high efficiency,excellent stability,and low cost should be developed.Fused-ring electron acceptors(FREAs)have declared that OSCs are capable of showing efficiencies over 19%,whereas stability and cost are not solved yet.As the counterparts of FREAs,non-fused ring electron acceptors(NFREAs)are more flexible in molecular design.They have better stability because of the reduction of intramolecular tension via breaking fused backbone and have more advantages in cost with the reduction of synthetic complexity.However,the challenge for NFREAs is the relatively lower efficiencies(around 15%at current stage),which require better molecular designs for addressing the issues of conformational unicity and effective molecular packing.In this Account,we comprehensively summarize works about NFREAs carried out in our group from three main frameworks,including molecular design and efficiency optimization,material cost,and stability.First,in the part of molecular design and efficiency optimization,the existing rotatable single bond in NFREAs will bring the problem of conformational uncertainty,but it can be solved through proper molecular design,which also regulates the energy levels,light absorption range,and the packing mode of the molecule for obtaining higher performance.Thus,in this part,we discuss the evolution of NFREAs in three aspects,including molecular skeleton optimization,terminal modification,and side chain engineering.Many strategies are used in the design of a molecular skeleton,such as utilizing the quinoid effect,introducing functional groups with the electron push−pulling effect,and using multiple conformational lock.Furthermore,simplifying the skeleton is also the preferred development tendency.As for the terminal,the main modification strategy is adjusting the conjugation length and halogen atoms.What is more,by adjusting the side chain to induce appropriate steric hindrance,we can fix the orientation

关键词： stability fused stability

Electron-deficient core fused-ring based non-fullerene acceptor enables over 15% efficiency in single junction organic solar cells

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Science China Chemistry 2019年第4期62卷 403-404页

作者： hongzheng chen State Key Laboratory of Silicon Materials MOE Key Laboratory of Macromolecular Synthesis and Functionalization Department of Polymer Science and Engineering Zhejiang University

Organic solar cells(OSCs)are promising to access flexible,light weight and semi-transparent photovoltaic devices by low-cost solution fabrication.Recently,the fused-ring nonfullerene acceptors play an important role in promoting the research progress of the OSCs.The power conversion efficiencies(PCEs)have been rapidly boosted to over 14%in single junction OSCs with the development of new nonfullerene acceptors and the related devices[1-3].Although the PCEs of OSCs are still inferior to their inorganic counterparts,further improvement of the PCEs could be expected by the development of new photovoltaic materials.

关键词： Electron-deficient core single junction non-fullerene acceptor

Recent advances in plasmonic organic photovoltaics

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Science China Chemistry 2015年第2期58卷 210-220页

作者： Xi Yang Wenqing Liu hongzheng chen State Key Laboratory of Silicon Materials Key Laboratory of Macromolecular Synthesis and Functionalization Ministry of Education Department of Polymer Science and Engineering Zhejiang University

Light trapping based on the localized surface-plasmon resonance(LSPR)effect of metallic nanostructures is a promising strategy to improve the device performance of organic solar cells(OSCs).We review recent advances in plasmonic-enhanced OPVs with solution-processed metallic nanoparticles(NPs).The different types of metallic NPs(sizes,shapes,and hybrids),incorporation positions,and NPs with tunable resonance wavelengths toward broadband enhancement are systematically summarized to give a guideline for the realization of highly efficient plasmonic photovoltaics.

关键词：表面等离子共振光伏金属纳米粒子金属纳米颗粒有机太阳能电池混合动力车纳米结构器件性能