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Recrystallization Behavior of the New Ni-Co-Based Superalloy with Fusion Structure Produced by Electron Beam Smelting Layered Solidification Technology

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Acta Metallurgica Sinica(English Letters) 2023年第12期36卷 2013-2030页

作者： hongyang cui Yi Tan Rusheng Bai Lidan Ning Chuanyong cui Xiaogang You Pengting Li School of Materials Science and Engineering Dalian University of TechnologyDalian 116024China Key Laboratory for Energy Beam Metallurgy and Advanced Materials Preparation of Liaoning Province Dalian 116024.China Superalloys Division Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China Zhongyuan Critical Metals Laboratory Zhengzhou UniversityZhengzhou 450001China

The new Ni-Co-based superalloy featuring a"fusion structure"was produced utilizing electron beam smelting layered solidification technology(EBSL).Experimental examination of hot compression deformation with varied settings for EBSL and conventional duplex process melting Ni-Co superalloys was performed.As per the study,EBSL-Ni-Co superalloys exhibited enhanced recrystallization susceptibility during hot deformation.Furthermore,elevating deformation temperature,lowering strain rate,and augmenting strain collectively contribute to enlarging the volume fraction of dynamically recrystallized grains.Aberrant growth of grains occurred when the deformation temperature equaledγ′sub-solvus temperature and the strain rate was slower.Moreover,exceeding theγ′solvus temperature during deformation significantly increases the particle size of dynamic recrystallization(DRX)grains.Theγ′phase can effectively modulate the DRX grain size through the pegging effect.Additionally,it was revealed that the presence of the fusion structure aids in the generation of continuous dynamic recrystallization,discontinuous dynamic recrystallization,and twinning-induced dynamic recrystallization while the alloy undergoes hot deformation.This mechanism promotes DRX granule formation and permits complete recrystallization.Ultimately,the fusion structure was identified as playing a catalytic role in the dynamic recrystallization process of the new Ni-Co superalloy.

关键词： Dynamic recrystallization Hot deformation Electron beam smelting Ni-Co-based superalloy Fusion structure

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Fabrication of a turbine disk alloy by electron beam sheet lamination and investigation on the improved high temperature creep performance

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Journal of Materials Science & Technology 2023年第12期143卷 216-233页

作者： Xiaogang You Yi Tan Masao Takeyama Pengting Li Yi Li Huixing Zhang hongyang cui Chuanyong cui Yinong Wang Jiayan Li Zhijun Zhang Gengyi Dong Wenjia Xiao Key Laboratory of Materials Modification by Laser Ion and Electron Beams(Dalian University of Technology)Ministry of EducationSchool of Materials Science and EngineeringDalian 116024China Department of Materials Science and Engineering School of Materials and Chemical TechnologyTokyo Institute of TechnologyJapan Shi-changxu Innovation Center for Advanced Materials Chinese Academy of SciencesInstitute of Metal ResearchShenyang 110016China Department of Materials Engineering The University of British ColumbiaVancouverCanada School of Mechatronics Engineering and Automation Foshan UniversityFoshan 528225China

A turbine disk alloy was prepared by electron beam sheet lamination(EBSL),giving a refined microstruc-ture and high purity,and the microstructure-property relationship of this alloy has been developed.The alloy showed an outstanding creep life of 1266.3 h at 953 K/500 MPa.Compared with the conventional vacuum induction melted and vacuum arc re-melted alloy,a smaller dendrite arm spacing of less than 23μm was obtained through the EBSL method,which restricted the formation of large inter-dendritic carbides.As a result,the typical intergranular failure mode was observed in the EBSL alloy,whereas the transgranular fracture mode was dominant in the conventional alloy.The inter-dendritic MC carbides formed from the reverse diffusion of Nb are believed to either impede grain boundary sliding or initi-ate cracks,depending on their size and morphology.The tiny grain boundary precipitates of theδphase in the EBSL alloy could reduce the critical stress for microvoid nucleation to 161.07 MPa by decoher-ing the particle/matrix interface,or allowing vacancy condensation near theδinterface,resulting in the formation of grain boundary microcracks.In the conventional alloy,however,the larger-sized MC car-bides which were formed during the solidification process(0.36 vol.%)nucleated the microcracks within the particles,leading to the transgranular fracture.Furthermore,the results indicated that the nanoscaleγ′andγ″precipitates contributed primarily to strengthening and coordinating intragranular deforma-tion during creep,in which the Orowan mechanism and shearing of a/6partial dislocations and a/2doublets were active forγ′andγ″precipitates,respectively.

关键词： Electron beam Superalloy Segregation Deformation Precipitation

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基于计算物流的自动化集装箱码头AGV生产调度

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计算机应用研究 2024年第6期41卷 1704-1713页

作者：李斌崔宏阳福建理工大学机械与汽车工程学院福州350118 福建理工大学福建省大数据挖掘与应用技术重点实验室福州350118 福建理工大学计算机科学与数学学院福州350118

针对自动化集装箱码头自动导引车(AGV)在线实时生产调度约束动态复杂和难以可视化的问题,在计算物流框架下,利用AnyLogic平台创建自动化码头水平运输计算实验模型,并针对平台中已有的经典资源分配策略,面向AGV生产调度提出两方面的改进... 详细信息

针对自动化集装箱码头自动导引车(AGV)在线实时生产调度约束动态复杂和难以可视化的问题,在计算物流框架下,利用AnyLogic平台创建自动化码头水平运输计算实验模型,并针对平台中已有的经典资源分配策略,面向AGV生产调度提出两方面的改进:将运筹规划商业求解器与计算实验平台结合来求解动态复杂组合优化问题;基于计算物流的思想方法,迁移和定制出五种面向问题探索的自定义AGV在线调度算法。由于商业求解器的局限性,模型和实验数据是基于自动化码头进口箱作业部分。实验表明,两种改进策略能够弥补商业求解器和计算实验平台的部分不足,尤其是自定义策略相较于经典资源分配策略能够面向特定装卸船需求更好地实现AGV生产调度,实现自动化码头水平运输的高效作业。

关键词：自动化集装箱码头计算物流 AnyLogic仿真 AGV调度策略 CPLEX求解自定义策略

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Chemical characteristics of fine particulate matter emitted from commercial cooking

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Frontiers of Environmental Science & Engineering 2016年第3期10卷 559-568页

作者： Bing PEI hongyang cui Huan LIU Naiqiang YAN School of Environmental Science and Engineering Shanghai Jiao Tong University Shanghai 200040 China Shanghai Environmental Monitoring Center Shanghai 200030 China Ministry of Education Key Laboratory for Earth System Modeling Center for Earth System Science Tsinghua University Beijing 100084 China School of Environment State Key Joint Laboratory of Environment Simulation and Pollution Control (SKLESPC) Tsinghua University Beijing 100084 China

The chemical characteristics of fine particulate matter （PM2.5） emitted from commercial cooking were explored in this study. Three typical commercial restau- rants in Shanghai, i.e., a Shanghai-style one （SHS）, a Sichuan-style one （SCS） and an Italian-style one （ITS）, were selected to conduct PM2.5 sampling. Particulate organic matter （POM） was found to be the predominant contributor to cooking-related PM2.5 mass in all the tested restaurants, with a proportion of 69.1% to 77.1%. Specifically, 80 trace organic compounds were identified and quantified by gas chromatography/mass spectrometry （GC/MS）, which accounted for 3.8%-6.5% of the total PM2.5 mass. Among the quantified organic compounds, unsaturated fatty acids had the highest concentration, followed by saturated fatty acids. Comparatively, the impacts of other kinds of organic compounds were much smaller. Oleic acid was the most abundant single species in both SCS and ITS. However, in the case of SHS, linoleic acid was the richest one. ITS produced a much larger mass fraction of most organic species in POM than the two Chinese cooking styles except for monosaccharide anhy-drides and sterols. The results of this study could be utilized to explore the contribution of cooking emissions to PM2.5 pollution and to develop the emission inventory of PM2.5 from cooking, which could then help the policymakers design efficient treatment measures and control strategies on cooking emissions in the future.

关键词： commercial cooking PM2.5 chemical char- acteristics organic matter

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Vehicular volatile organic compounds losses due to refueling and diurnal process in China: 2010–2050

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Journal of Environmental Sciences 2015年第7期27卷 88-96页

作者： Xiaofan Yang Huan Liu hongyang cui Hanyang Man Mingliang Fu Jiming Hao Kebin He School of Environment State Key Joint Laboratory of Environment Simulation and Pollution Control Tsinghua University State Environmental Protection Key Laboratory of Sources and Control of Air Pollution Complex Collaborative Innovation Center for Regional Environmental Quality

Volatile organic compounds（VOCs） are crucial to control air pollution in major Chinese cities since VOCs are the dominant factor influencing ambient ozone level, and also an important precursor of secondary organic aerosols. Vehicular evaporative emissions have become a major and growing source of VOC emissions in China. This study consists of lab tests, technology evaluation, emissions modeling, policy projections and cost-benefit analysis to draw a roadmap for China for controlling vehicular evaporative emissions. The analysis suggests that evaporative VOC emissions from China＇s light-duty gasoline vehicles were approximately 185,000 ton in 2010 and would peak at 1,200,000 ton in 2040 without control. The current control strategy implemented in China, as shown in business as usual（BAU） scenario, will barely reduce the long-term growth in emissions. Even if Stage II gasoline station vapor control policies were extended national wide（BAU ＋ extended Stage II）, there would still be over 400,000 ton fuel loss in 2050. In contrast, the implementation of on-board refueling vapor recovery（ORVR） on new cars could reduce 97.5% of evaporative VOCs by 2050（BAU ＋ ORVR/BAU ＋ delayed ORVR）. According to the results, a combined Stage II and ORVR program is a comprehensive solution that provides both short-term and long-term benefits. The net cost to achieve the optimal total evaporative VOC control is approximately 62 billion CNY in 2025 and 149 billion CNY in 2050.

关键词： Evaporative VOC emissions China roadmap Vehicle Refueling emission control

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Anthropogenic emission inventories in China:a review

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National Science Review 2017年第6期4卷 834-866页

作者： Meng Li Huan Liu Guannan Geng Chaopeng Hong Fei Liu Yu Song Dan Tong Bo Zheng hongyang cui Hanyang Man Qiang Zhang Kebin He Ministry of Education Key Laboratory for Earth System Modeling Department for Earth System Science Tsinghua University now at Max-Planck Institute for Chemistry State Key Joint Laboratory of Environment Simulation and Pollution Control School of Environment Tsinghua University StateKey Joint Laboratory of Environmental Simulation and Pollution Control Department of Environmental SciencePeking University

The development of reliable anthropogenic emission inventories is essential for both understanding the sources of air pollution and designing effective air-pollution-control measures in China. However, it is challenging to quantify emissions in China accurately, given the variety of contributing sources, the complexity of the technology mix and the lack of reliable measurements. Over the last two decades,tremendous efforts have been made to improve the accuracy of emission inventories, and significant improvements have been realized. More reliable statistics and survey-based data have been used to reduce the uncertainties in activity rates and technology distributions. Local emission factors and source profiles covering various sources have been measured and reported. Based on these local databases, improved emission inventory models have been developed for power plants, large industrial plants and the residential,transportation and agricultural sectors. In this paper, we review the progress that has been made in developing inventories of anthropogenic emissions in China. We first highlight the major updates that have been made to emission inventory models and the underlying data by source category. We then summarize the sector-based estimates of emissions of different species contained in current inventories. The progress that has been made in the development of model-ready emissions is also presented. Finally, we suggest future directions for further improving the accuracy of emission inventories in China.

关键词： emission inventory atmospheric chemistry China chemical transport model air pollution

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Diverse functions of sox9 in liver development and homeostasis and hepatobiliary diseases

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Genes & Diseases 2024年第4期11卷 170-187页

作者： Taiyu Shang Tianyi Jiang Xiaowen cui Yufei Pan Xiaofan Feng Liwei Dong hongyang Wang School of Life Sciences Institute of Metabolism and Integrative BiologyFudan UniversityShanghai 200438China National Center for Liver Cancer The Naval Medical UniversityShanghai 201805China International Cooperation Laboratory on Signal Transduction Eastern Hepatobiliary Surgery InstituteThe Second Military Medical UniversityShanghai 200438China Laboratory of Signaling Regulation and Targeting Therapy of Liver Cancer Second Military Medical University&Ministryof EducationShanghai 200438China

The liver is the central organ for digestion and detoxification and has unique metabolic and regenerative capacities.The hepatobiliary system originates from the foregut endoderm,in which cells undergo multiple events of cell proliferation,migration,and differentiation to form the liver parenchyma and ductal system under the hierarchical regulation of transcription factors.Studies on liver development and diseases have revealed that SRY-related high-mobility group box 9(SOx9)plays an important role in liver embryogenesis and the progression of hepatobiliary diseases.sox9 is not only a master regulator of cell fate determination and tissue morphogenesis,but also regulates various biological features of cancer,including cancer stemness,invasion,and drug resistance,making Sox9 a potential biomarker for tumor prognosis and progression.This review systematically summarizes the latest findings of sox9 in hepatobiliary development,homeostasis,and disease.We also highlight the value of sox9 as a novel biomarker and potential target for the clinical treatment of major liverdiseases.

关键词： Biliary system Cancer Homeostasis Liver diseases SOX9

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Corrigendum to Anthropogenic emission inventories in China: a review

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National Science Review 2018年第4期5卷 603-603页

作者： Meng Li Huan Liu Guannan Geng Chaopeng Hong Fei Liu Yu Song Dan Tong Bo Zheng hongyang cui Hanyang Man Qiang Zhang Kebin He Ministry of Education Key Laboratory for Earth System Modeling Department for Earth System Science Tsinghua University Max-Planck Institute for Chemistry State Key Joint Laboratory of Environment Simulation and Pollution Control School of Environment Tsinghua University State Key Joint Laboratory of Environmental Simulation and Pollution Control Department of Environmental Science Peking University

In the Figure 4 of‘Anthropogenic emission inventories in China:a review’(National Science Review,Volume 4,Issue 6,2017,Pages 834–866,doi:10.1093/nsr/nwx150),the data for the MEIC v1.2 was incorrectly plotted.The co... 详细信息

关键词： a review Figure Corrigendum to Anthropogenic emission inventories in China

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电子束熔炼新型Ni-Co基高温合金过程中合金元素的挥发行为及熔池温度计算

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材料导报 2023年第1期37卷 172-177页

作者：王以霖谭毅崔传勇游小刚赵龙海崔弘阳李鹏廷李晓娜大连理工大学材料科学与工程学院辽宁大连116024 辽宁省载能束冶金及先进材料制备重点实验室辽宁大连116024 中国科学院金属研究所高温合金部沈阳110016 大连理工大学三束材料改性教育部重点实验室辽宁大连116024

本工作采用电子束熔炼方法制备了新型Ni-Co基高温合金,对熔炼后铸锭的显微组织、成分、合金元素挥发行为以及熔池表面温度分布进行了研究。结果表明,随着熔炼功率的增加,铸锭的显微组织越来越细,质量损失越来越大。熔炼后Cr和Al的质量... 详细信息

本工作采用电子束熔炼方法制备了新型Ni-Co基高温合金,对熔炼后铸锭的显微组织、成分、合金元素挥发行为以及熔池表面温度分布进行了研究。结果表明,随着熔炼功率的增加,铸锭的显微组织越来越细,质量损失越来越大。熔炼后Cr和Al的质量分数下降,其余元素质量分数上升。在相同温度下,纯元素Al的饱和蒸气压最大,W的饱和蒸汽压最小。将熔体系统简化为Ni-Cr-Co三元合金模型来研究其挥发行为,合金元素的活度系数和活度可采用Miedema模型预测,Ti、Mo、W元素的理论挥发速率很小,挥发损失基本可以忽略不计。Al元素的挥发速率通过引入活度系数补偿因子计算。熔炼功率为10 kW、12 kW、14 kW时熔池的平均温度分别为1863.6 K、1890.6 K和1904.3 K,对应的熔池最高温度分别为2368.1 K、2402.4 K、2419.8 K。

关键词：高温合金电子束熔炼元素挥发温度分布

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新型Ni-Co基高温合金的显微组织特点和析出相热力学计算

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机械工程材料 2023年第1期47卷 111-118页

作者：庄辛鹏谭毅赵龙海崔传勇崔弘阳游小刚李鹏廷大连理工大学材料科学与工程学院大连116024 大连理工大学辽宁省载能束冶金及先进材料制备重点实验室大连116024 中国科学院金属研究所沈阳110016

利用光学显微镜和扫描电镜观察新型Ni-Co基高温合金的铸态组织,采用JMatPro软件在平衡和非平衡凝固条件下对该合金进行热力学计算,研究了合金的相析出特点。结果表明:试验合金呈现枝晶形貌,偏析严重,主要组织为γ'相、η相、γ/γ'共晶... 详细信息

利用光学显微镜和扫描电镜观察新型Ni-Co基高温合金的铸态组织,采用JMatPro软件在平衡和非平衡凝固条件下对该合金进行热力学计算,研究了合金的相析出特点。结果表明:试验合金呈现枝晶形貌,偏析严重,主要组织为γ'相、η相、γ/γ'共晶组织以及MC碳化物。平衡凝固条件下,试验合金的主要析出相为γ'、η、μ、σ、碳化物以及硼化物;钛和铝含量增加导致γ'相析出量增加,析出温度升高;η相析出温度和析出量随钛含量增加呈线性增加。在非平衡凝固过程中,钛、钼元素富集在液相中,而铝、铬、钴和钨元素在液相中贫乏。

关键词：新型Ni-Co基高温合金热力学计算平衡析出相析出温度

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