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Green Energy & Environment 2024年第1期9卷 114-125页

作者： Yang Zhou Qiang Zeng hongyan he Kejia Wu Fuqiao Liu Xuehui Li School of Chemistry and Chemical Engineering The Guangdong Provincial Key Laboratory of Green Chemical Product TechnologyState Key Laboratory of Pulp and Paper EngineeringSouth China University of TechnologyGuangzhouGuangdong510640China CAS Key Laboratory of Green Process and Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing100190China

In order to better understand the specific substituent effects on the electrochemical oxidation process of β-O-4 bond, a series of methoxyphenyl type β-O-4 dimer model compounds with different localized methoxyl groups, including 2-(2-methoxyphenoxy)-1-phenylethanone, 2-(2-methoxyphenoxy)-1-phenylethanol, 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)ethanone, 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)ethanol, 2-(2,6-dimethoxyphenoxy)-1-(4-methoxyphenyl)ethanone, 2-(2,6-dimethoxyphenoxy)-1-(4-methoxyphenyl)ethanol have been selected and their electrochemical properties have been studied experimentally by cyclic voltammetry, and FT-IR spectroelectrochemistry. Combining with electrolysis products distribution analysis and density functional theory calculations, oxidation mechanisms of all six model dimers have been explored. In particular, a total effect from substituents of both para-methoxy(on the aryl ring closing to Cα) and Cα-OH on the oxidation mechanisms has been clearly observed, showing a significant selectivity on the Cα-Cβbond cleavage induced by electrochemical oxidations.

关键词： Lignin model compounds β-O-4 dimers Electrochemical oxidation Oxidation mechanisms Substituent effect

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Ionic liquid-trimetallic electrocatalytic system for C–O bond cleavage in lignin model compounds and lignin under ambient conditions

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Nano Research 2024年第4期17卷 2420-2428页

作者： Guangyong Liu Yumiao Lu JunFeng Lu Yanlei Wang Shijing Liang hongyan he Lilong Jiang National Engineering Research Center of Chemical Fertilizer Catalyst Fuzhou UniversityFuzhou 350002China CAS Key Laboratory of Green Process and Engineering State Key Laboratory of Multiphase Complex SystemsBeijing Key Laboratory of Ionic Liquids Clean ProcessInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190China Longzihu New Energy Laboratory Zhengzhou Institute of Emerging Industrial TechnologyZhengzhou 450000China

Electrocatalytic depolymerization of lignin into value-added chemicals offers a promising technique to make biorefining sustainable.herein,we report a robust trimetallic PdNiBi electrocatalyst for reductive C–O bond cleavage of different lignin model dimers and oxidized lignin under mild conditions.The reduction reaction proceeds with complete substrate conversion and excellent yields toward monomers of phenols(80%–99%)and acetophenones(75%–96%)in the presence of an ionic liquid electrolyte with operational stability.Systematic experimental investigations together with density functional theory(DFT)calculations reveal that the outstanding performance of the catalyst results from the synergistic effect of the metal elements,which facilitates the easier formation of a key Cαradical intermediate and the facile desorption of the as-formed products at the electrode.The results open up new opportunities for lignin valorization through the green electrocatalytic approach.

关键词： electrocatalytic depolymerization lignin Ionic liquids density functional theory(DFT)calculation

Recent Advances in Biomass-derived Porous Carbon Materials:Synthesis,Composition and Applications

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Chemical Research in Chinese Universities 2024年第1期40卷 3-19页

作者： ZHAI Ziqi LU Yumiao LIU Guangyong DING Wei-Lu CAO Bobo he hongyan CAS Key Laboratory of Green Process and Engineering State Key Laboratory of Mesoscience and EngineeringBeijing Key Laboratory of Ionic Liquids Clean ProcessInstitute of Process EngineeringChinese Academy of SciencesBeijing 100190P.R.China University of Chinese Academy of Sciences Beijing 100049P.R.China Longzihu New Energy Laboratory Zhengzhou Institute of Emerging Industrial TechnologyZhengzhou 450000P.R.China

Porous carbon materials(PCMs)play a pivotal role in diverse applications,such as energy storage,adsorption,catalysis,environmental remediation,and microwave adsorption.The selection of carbon precursors,in particular,is crucial for tailoring porous structures with specific functionalities.Biomass,with its rich carbon feedstock,abundant availability,renewability,and versatile structures,has emerged as a promising precursor for porous carbon material synthesis.This review comprehensively summarizes the recent advances in biomass-derived porous carbon materials(BPCMs)encompassing synthetic strategy,morphology,structural composition,and multiple applications.We first review synthetic approaches aiming at regulating porosity,followed by morphological and composition features of BPCMs,with a special emphasis on elucidating the dimensional clarification and heteroatom doping effects.The discussion then extends to the wide-ranging applications of BPCMs,covering energy-related applications and CO_(2) adsorption to environmental remediation.Finally,the review outlines the existing challenges and prospects in the field.In summary,this review systematically describes BPCMs and provides valuable guidance for researchers to select and synthesize BPCMs that meet specific functional requirements.

关键词： Biomass Porous carbon Pyrolysis heteroatom-doping Supercapacitor CO_(2)adsorption

Corrigendum to “Increasing the greenness of an organic acid through deep eutectic solvation and further polymerisation” [Green Energy & Environ 7 (4) (August 2022) 840–853]

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Green Energy & Environment 2024年第3期9卷 596-596页

作者： Liteng Li Xiaofang Li Susu Zhang Hongyuan Yan Xiaoqiang Qiao hongyan he Tao Zhu Baokun Tang College of Phamaceutical Science Instiute of Life Science and Green DevelopmentKey Laboratory of Medicinal Chemisty and Malecular Diagnosis of Ministry of EducationHebei UniversityBaoding071002China CAS Key Laboratony of Green Process and Engineering Institute of Prcess EngineeringChinese Academy of SciencesBeijing010190China

The authors regret that the name of the ethic committee that approved the study and the reference number was omitted from the published paper.In this research,all animal experiments were performed in accordance with the Guide for the Care and Use of Laboratory Animals(US National Institutes of healh)and were approved by the Animal Welfare and Ethical Committee of hebei University(No.IACUC-2020XG021,Baoding,China).

关键词： approved committee hebei

Targeting LTA4H facilitates the reshaping of the immune microenvironment mediated by CCL5 and sensitizes ovarian cancer to Cisplatin

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Science China(Life Sciences) 2024年第6期67卷 1226-1241页

作者： Zhengyang Guo Jiaqi Huang Xiao Huo Chen Huang Xiaotong Yu Yan Sun Yanfang Li Tianhui he hongyan Guo Jianling Yang Lixiang Xue Cancer Center of Peking University Third Hospital Beijing 100191China Center of Basic Medical Research Institute of Medical Innovation and ResearchPeking University Third HospitalBeijing 100191China Peking University Third Hospital Cancer Center Department of Radiation OncologyPeking University Third HospitalBeijing 100191China Department of Obstetrics and Gynecology Peking University Third HospitalBeijing 100191China

Ovarian cancer is the most lethal and aggressive gynecological cancer with a high recurrence rate and is often diagnosed late.In ovarian cancer,multiple metabolic enzymes of lipid metabolism are abnormally expressed,resulting in metabolism disorder.As a characteristic pathway in polyunsaturated fatty acid(PUFA)metabolism,arachidonic acid(AA)metabolism is disturbed in ovarian cancer.Therefore,we established a 10-gene signature model to evaluate the prognostic risk of PUFA-related genes.This 10-gene signature has strong robustness and can play a stable predictive role in datasets of various platforms(TCGA,ICGC,and GSE17260).The high association between the risk subgroups and clinical characteristics indicated a good performance of the model.Our data further indicated that the high expression of LTA4H was positively correlated with poor prognosis in ovarian cancer.Deficiency of LTA4H enhanced sensitivity to Cisplatin and modified the characteristics of immune cell infiltration in ovarian cancer.Additionally,our results indicate that CCL5 was involved in the aberrant metabolism of the AA/LTA4H axis,which contributes to the reduction of tumor-infiltrating CD8+T cells and immune escape in ovarian cancer.These findings provide new insights into the prognosis and potential target of LTA4H/CCL5 in treating ovarian cancer.

关键词： ovarian cancer polyunsaturated fatty acids prognostic risk model LTA4H tumor immunity CCL5

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The crucial role of soil moisture in the evolution of forest cover in Asia since the Last Glacial Maximum

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The Innovation 2024年第3期5卷 9-10页

作者： Ying Cheng hongyan Liu School of Geography and Tourism Shaanxi Normal UniversityXi’an 710119China College of Urban and Environmental Sciences and MOE Laboratory for Earth Surface Processes Peking UniversityBeijing 100871China

Forest cover plays a pivotal role in facilitating ecosystem services and climate regulation.In recent decades,much concern has been raised regarding the extent to which forest cover tracks past climate change.Studies at different spatiotemporal scales have revealed significant temporal lags,ranging from decades to millennia,with no consensus reached on this issue.

关键词： forest soil Forest

The clinical characteristics and risk factors for necrotizing soft tissue infection in children

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儿科学研究(英文) 2024年第1期8卷 21-26页

作者： Liu Jing Chen Jigang Wang Yanni Qi hongyan Yu Jing Department of Burn and Plastic Surgery Beijing Children’s Hospital Capital Medical University National Center for Children’s Health Beijing China

Importance: Necrotizing soft tissue infection (NSTI) is a serious infectious disease. However, the early clinical manifestations and indicators of NSTI in children are still unclear.Objective: The purpose of this study was to analyze the clinical characteristics and risk factors of NSTI in pediatric patients.Methods: A total of 127 children with skin and soft tissue infection (SSTI) were treated at our hospital and divided into two groups: the NSTI group and the non-NSTI group, based on their discharge diagnosis from January 2011 to December 2022. Then, we collected and analyzed the clinical characteristics and risk factors of all patients, including sex and age, disease inducement, admission temperature, local skin manifestations, infection site, the presence of sepsis, bacterial culture, and laboratory indicators.Results: In our study, there was a statistical difference in the age distribution and disease inducement between NSTI and non-NSTI groups. The occurrence of local skin manifestations (blisters/bullae and ecchymosis) and the presence of sepsis significantly increased in the NSTI group compared to the non-NSTI group. Additionally, only the platelet count on laboratory tests was statistically different between the NSTI and non-NSTI groups. Finally, the logistic regression analysis suggested that local skin manifestations such as blisters/bullae, and ecchymosis, as well as the presence of sepsis, were identified as risk factors for NSTI.Interpretation: Children with SSTI and skin manifestations such as blisters/bullae, ecchymosis, and the presence of sepsis are at a higher risk of developing NSTI. These symptoms serve as useful indicators for early detection of NSTI.

关键词： Clinical characteristics Risk factors Necrotizing soft tissue infection Skin and soft tissue infection

Improved STNModels and heuristic Rules for Cooperative Scheduling in Automated Container Terminals

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Computer Modeling in Engineering & Sciences 2024年第2期138卷 1637-1661页

作者： hongyan Xia Jin Zhu Institute of Logistics Science and Engineering Shanghai Maritime UniversityShanghai201306China

Improving the cooperative scheduling efficiency of equipment is the key for automated container terminals to copewith the development trend of large-scale ships. In order to improve the solution efficiency of the existing spacetimenetwork (STN) model for the cooperative scheduling problem of yard cranes (YCs) and automated guidedvehicles (AGVs) and extend its application scenarios, two improved STN models are proposed. The flow balanceconstraints in the original model are decomposed, and the trajectory constraints of YCs and AGVs are added toacquire the model STN_A. The coupling constraint in STN_A is updated, and buffer constraints are added toSTN_A so that themodel STN_B is built.As the size of the problem increases, the solution speed of CPLEX becomesthe bottleneck. So a heuristic method containing three groups of heuristic rules is designed to obtain a near-optimalsolution quickly. Experimental results showthat the computation time of STN_A is shortened by 49.47% on averageand the gap is reduced by 1.69% on average compared with the original model. The gap between the solution ofthe heuristic rules and the solution of CPLEX is less than 3.50%, and the solution time of the heuristic rules is onaverage 99.85% less than the solution time of CPLEX. Compared with STN_A, the computation time for solvingSTN_B increases by 58.93% on average.

关键词： Automated container terminal buffer cooperative scheduling heuristic rules space-time network

Dynamics and vibration reduction performance of asymmetric tristable nonlinear energy sink

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Applied Mathematics and Mechanics(English Edition) 2024年第3期45卷 389-406页

作者： hongyan CheN Youcheng ZENG Hu DING Siukai LAI Liqun CheN School of Mechanical Engineering University of Science and Technology BeijingBeijing 100083China Shanghai Key Laboratory of Mechanics in Energy Engineering Shanghai Frontier Science Center of MechanoinformaticsShanghai Institute of Applied Mathematics and MechanicsSchool of Mechanics and Engineering ScienceShanghai UniversityShanghai 200444China Department of Civil and Environmental Engineering The Hong Kong Polytechnic UniversityKowloonHong KongChina

With its complex nonlinear dynamic behavior,the tristable system has shown excellent performance in areas such as energy harvesting and vibration suppression,and has attracted a lot of attention.In this paper,an asymmetric tristable design is proposed to improve the vibration suppression efficiency of nonlinear energy sinks(NESs)for the first time.The proposed asymmetric tristable NES(ATNES)is composed of a pair of oblique springs and a vertical spring.Then,the three stable states,symmetric and asymmetric,can be achieved by the adjustment of the distance and stiffness asymmetry of the oblique springs.The governing equations of a linear oscillator(LO)coupled with the ATNES are derived.The approximate analytical solution to the coupled system is obtained by the harmonic balance method(HBM)and verified numerically.The vibration suppression efficiency of three types of ATNES is compared.The results show that the asymmetric design can improve the efficiency of vibration reduction through comparing the chaotic motion of the NES oscillator between asymmetric steady states.In addition,compared with the symmetrical tristable NES(TNES),the ATNES can effectively control smaller structural vibrations.In other words,the ATNES can effectively solve the threshold problem of TNES failure to weak excitation.Therefore,this paper reveals the vibration reduction mechanism of the ATNES,and provides a pathway to expand the effective excitation amplitude range of the NES.

关键词： asymmetric nonlinear energy sink(NES) tristable vibration control po-tential barrier

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Color Image Compression and Encryption Algorithm Based on 2D Compressed Sensing and Hyperchaotic System

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Computers, Materials & Continua 2024年第2期78卷 1977-1993页

作者： Zhiqing Dong Zhao Zhang hongyan Zhou Xuebo Chen School of Computer Science and Software Engineering University of Science and Technology LiaoningAnshan114051China School of Electronic and Information Engineering University of Science and Technology LiaoningAnshan114051China

With the advent of the information security era,it is necessary to guarantee the privacy,accuracy,and dependable transfer of pictures.This study presents a new approach to the encryption and compression of color images.It is predicated on 2D compressed sensing(CS)and the hyperchaotic system.First,an optimized Arnold scrambling algorithm is applied to the initial color images to ensure strong security.Then,the processed images are con-currently encrypted and compressed using 2D CS.Among them,chaotic sequences replace traditional random measurement matrices to increase the system’s security.Third,the processed images are re-encrypted using a combination of permutation and diffusion algorithms.In addition,the 2D projected gradient with an embedding decryption(2DPG-ED)algorithm is used to reconstruct images.Compared with the traditional reconstruction algorithm,the 2DPG-ED algorithm can improve security and reduce computational complexity.Furthermore,it has better robustness.The experimental outcome and the performance analysis indicate that this algorithm can withstand malicious attacks and prove the method is effective.

关键词： Image encryption image compression hyperchaotic system compressed sensing