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不同添加剂对煤灰烧结特性的影响规律研究

能源科技 2024年第3期22卷 59-63页

作者：谷红伟国能销售集团有限公司北京100011

煤灰的烧结和结渣行为对锅炉的热效率、安全性和使用寿命有重要影响,通过添加一定比例的添加剂能够改善灰渣的烧结特性。以原煤烧结得到的灰渣为原料,采用高温热台显微镜、X射线荧光光谱分析仪及Image J图像处理相结合的方法,研究了原... 详细信息

煤灰的烧结和结渣行为对锅炉的热效率、安全性和使用寿命有重要影响,通过添加一定比例的添加剂能够改善灰渣的烧结特性。以原煤烧结得到的灰渣为原料,采用高温热台显微镜、X射线荧光光谱分析仪及Image J图像处理相结合的方法,研究了原煤灰的烧结特性及不同添加剂的影响规律。实验结果表明:随着温度的升高,原煤灰颗粒之间发生烧结、相互熔融,再到最后全部变为液态。在含酸性氧化物较多(Al2O3+SiO2>75%)的原煤灰中加入适量的CaO和Fe2O3,能够降低原煤灰的烧结温度,且与Fe2O3相比,CaO对降低原煤灰烧结温度的影响更大。一般情况下,煤灰的酸碱比与烧结温度正相关,酸碱比越高,烧结温度越高,但还需要结合煤灰的组成和反应机理判断。

关键词：烧结特性烧结过程添加剂酸碱比煤灰组分

Multiple structural defects in ultrathin NiFe-LDH nanosheets synergistically and remarkably boost water oxidation reaction

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Nano Research 2022年第1期15卷 310-316页

作者： Zhongyin Zhao Qi Shao Jiangyan Xue Bolong Huang Zheng Niu hongwei gu Xiaoqing Huang Jianping Lang College of Chemistry Chemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123China State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghai 200032China Department of Applied Biology and Chemical Technology The Hong Kong Polytechnic UniversityHung HornKowloonHong Kong SARChina

Modifying electrocatalysts nanostructures and tuning their electronic properties through defects-oriented synthetic strategies are:essential to improve the oxygen evolution reaction(OER)performance of *** synthetic strategies *** mainly target the single or double structural defects,while the researches about the synergistic effect of multiple'structural defects are *** this work,the ultrathin NiFe layered double hydroxide nanosheets with a holey structure,oxygen;vacancies and Ni^(3+)defects on nickel foam(NiFe-LDH-NSs/NF)are prepared by employing a simple and green H202-assisted etching 1 *** synergistic effect ofthe above three defects leads to the exposure *** active sites and significant improvement of:the intrinsic *** optimized catalyst exhibits an excellent OER performance with an extraordinarily low overpotential of 170 mV;at to mA·cm^(-2) and a small Tafel slope of 39.3 mV·dec^(-1) in 1 M KOH *** functional theory calculations reveal this OER;performance arises from pseudo re-oxidized metal-stable Ni^(3+)near oxygen vacancies(O_(vac)),which suppresses 3d-e_(g) of Ni-site and!elevates d-band center towards the competitively low *** work provides a new insight to fabricate advanced electrocatalysts for renewable energy conversion technologies.

关键词： layered double hydroxide holey structures oxygen vacancies Ni3+defects oxygen evolution reaction

Accelerating water dissociation at carbon supported nanoscale Ni/NiO heterojunction electrocatalysts for high-efficiency alkaline hydrogen evolution

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Nano Research 2023年第4期16卷 4742-4750页

作者： Cong Li Jiang-Yan Xue Wei Zhang Fei-Long Li hongwei gu Pierre Braunstein Jian-Ping Lang College of Chemistry Chemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123China State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghai 200032China School of Chemistry and Materials Engineering Changshu Institute of TechnologyChangshu 215500China Universitéde Strasbourg-CNRS Institut de Chimie(UMR 7177 CNRS)4 rue Blaise Pascal-CS 90032Strasbourg 67081France

The synergistic catalysis of heterojunction electrocatalysts for the multi-step process in hydrogen evolution reaction(HER)is a promising approach to enhance the kinetics of alkaline ***,we proposed a strategy to form nanoscale Ni/NiO heterojunction porous graphitic carbon composites(Ni/NiO-PGC)by reduction-pyrolysis of the preformed Ni-metal-organic framework(MOF)under H2/N2 *** from low electron transfer resistance,increased number of active sites,and unique hierarchical micro-mesoporous structure,the optimized Ni/NiO-PGC_(10-1-400)exhibited excellent electrocatalytic performance and robust stability for alkaline HER(η10=30 mV,65 h).Density functional theory(DFT)studies revealed that the redistribution of electrons at the Ni/NiO interface enables the NiO phase to easily initiate the dissociation of alkaline H_(2)O,and shifts down the d-band center of Ni and optimizes the H*adsorption-desorption process of Ni,thereby leading to extremely high HER *** work contributes to a further understanding of the synergistic promotion of the multi-step HER processes by heterojunction electrocatalysts.

关键词： water dissociation Ni/NiO heterojunction metal-organic frameworks(MOFs)derivatives hydrogen evolution reaction reduction pyrolysis

Ultralong nitrogen/sulfur Co-doped carbon nano-hollowsphere chains with encapsulated cobalt nanoparticles for highly efficient oxygen electrocatalysis

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Carbon Energy 2023年第8期5卷 15-30页

作者： Wei Zhang Xingmei guo Cong Li Jiang-Yan Xue Wan-Ying Xu Zheng Niu hongwei gu Carl Redshaw Jian-Ping Lang College of Chemistry Chemical Engineering and Materials ScienceSoochow UniversitySuzhouChina State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghaiChina College of Environmental and Chemical Engineering Jiangsu University of Science and TechnologyZhenjiangChina Department of Chemistry University of HullHullUK

The development of simple and effective strategies to prepare electrocatalysts,which possess unique and stable structures comprised of metal/nonmetallic atoms for oxygen reduction reaction(ORR)and oxygen evolution reaction(OER),is currently an urgent ***,an efficient bifunctional electrocatalyst featured by ultralong N,S-doped carbon nano-hollow-sphere chains about 1300 nm with encapsulated Co nanoparticles(Co-CNHSCs)is *** multifunctional catalytic properties of Co together with the heteroatom-induced charge redistribution(i.e.,modulating the electronic structure of the active site)result in superior catalytic activities toward OER and ORR in alkaline *** optimized catalyst Co-CNHSC-3 displays an outstanding electrocatalytic ability for ORR and OER,a high specific capacity of 1023.6 mAh gZn^(-1),and excellent reversibility after 80 h at 10mA cm^(-2)in a Zn-air battery *** work presents a new strategy for the design and synthesis of efficient multifunctional carbon-based catalysts for energy storage and conversion devices.

关键词： Co nanoparticles N S co-doping oxygen electrocatalysts rechargeable Zn-air batteries ultralong carbon nano-hollow-sphere chains

One-pot pyrolysis synthesis of highly active Ru/RuOx nanoclusters for water splitting

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Nano Research 2022年第2期15卷 1020-1026页

作者： Fengyuan Zhu Jiangyan Xue Lingjian Zeng Jingrui Shang Shuanglong Lu Xueqin Cao Brendan F.Abrahams hongwei gu Jianping Lang College of Chemistry Chemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123China School of Chemical and Material Engineering Jiangnan UniversityWuxi 214122China School of Chemistry University of MelbourneVictoria 3010Australia

Using simple methods to obtain efficient catalysts has been a long-standing goal for *** this work,the employment of a one-pot pyrolysis reaction to achieve molecular confinement,has led to the preparation of ruthenium(Ru)-based nanoclusters in a carbon matrix.A unique feature of the synthetic approach employed is that solvent and substrates were calcined *** solvent evaporates,during calcination,the substrates form a dense solid which has the effect of limiting the aggregation of Ru centers during the carbonization *** catalyst prepared in this simple manner showed an impressively high activity with respect to the hydrogen/oxygen evolution reaction(HER/OER).The Ru nanoclusters(Ru NCs),as the hydrogen evolution reaction(HER)catalysts,require ultralow overpotentials of 5 mV and 5.1 mV at-10 mA·cm^(-2) in 1.0 M KOH,and 0.5 M H_(2)SO_(4),***,the catalyst prepared by the one-pot method has higher crystallinity,a higher Ru content and an ultrafine cluster size,which contributes to its exceptional electrochemical ***,the RuO_(x) nanoclusters(RuO_(x) NCs),obtained by oxidizing the aforementioned Ru NCs,exhibited good oxygen evolution reaction(OER)performance with an overpotential of 266 mV at 10 mA·cm^(-2).When applied to overall water splitting,Ru/RuO_(x) nanoclusters as the cathode and anode catalysts can reach 10 mA·cm^(-2) at cell voltages of only 1.49 V in 1 M KOH.

关键词： pyrolysis ruthenium nanoclusters ruthenium dioxide nanoclusters hydrogen evolution reaction oxygen evolution reaction overall water splitting

Anti-explosion performance and dynamic response of an innovative multi-layer composite explosion containment vessel

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Defence Technology（防务技术） 2024年第6期36卷 105-121页

作者： Zhen Wang Heng Chen Qi Yuan Wenbin gu Xingbo Xie hongwei Li College of Field Engineering Army Engineering University of PLANanjing 210007China College of Civil Engineering and Architecture Southwest University of Science and TechnologySichuanMianyang 621010China

An innovative multi-layer composite explosion containment vessel(CECV)utilizing a sliding steel platealuminum honeycomb-fiber cloth sandwich is put forward to improve the anti-explosion capacity of a conventional single-layer explosion containment vessel(SECV).Firstly,a series of experiments and finite element(FE)simulations of internal explosions are implemented to understand the basic anti-explosion characteristics of a SECV and the rationality of the computational models and methods is verified by the comparison between the experimental results and simulation *** on this,the CECV is designed in detail and a variety of FE simulations are carried out to investigate effects of the sandwich structure,the explosive quantity and the laying mode of the fiber cloth on anti-explosion performance and dynamic response of the CECV under internal *** results indicate that the end cover is the critical position for both the SECV and *** maximum pressure of the explosion shock wave and the maximum strain of the CECV can be extremely declined compared to those of the *** a result,the explosive quantity the CECV can sustain is up to 20 times of that the SECV can ***,as the explosive quantity increases,the internal pressure of the CECV keeps growing and the plastic deformation and failure of the sandwich structure become more and more severe,yielding plastic strain of the CECV in addition to elastic *** results also reveal that the laying angles of the fiber cloth's five layers have an impact on the anti-explosion performance of the *** example,the CECV with fiber cloth layered in 0°/45°/90°/45°/0°mode has the optimal anti-capacity,compared to 0°/0°/0°/0°/0°and 0°/30°/60°/30°/0°***,owing to remarkable anti-explosion capacity,this CECV can be regarded as a promising candidate for explosion resistance.

关键词： Explosive container Honeycomb-fiber cloth Anti-explosion Aluminum honeycomb core Composite

A hybrid catalyst for efficient electrochemical N_(2)fixation formed by decorating amorphous MoS_(3)nanosheets with MIL-101(Fe)nanodots

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Science China Chemistry 2022年第5期65卷 885-891页

作者： Wan-Ying Xu Cong Li Fei-Long Li Jiang-Yan Xue Wei Zhang hongwei gu Brendan F.Abrahams Jian-Ping Lang College of Chemistry Chemical Engineering and Materials ScienceSoochow UniversitySuzhou 215123China State Key Laboratory of Organometallic Chemistry Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghai 200032China School of Materials Engineering Changshu Institute of TechnologyChangshu 215500China School of Chemistry University of MelbourneVictoria 3010Australia

Metal-organic frameworks possessing relatively large pores,high surface areas,and unsaturated metal sites are attractive materials for use as electrocatalysts in the reduction of N_(2)to NH_(3).In this work,a MIL-101(Fe)/MoS_(3)hybrid catalyst,prepared by using a precursor-transformation strategy,is shown to be an effective electrocatalyst for the N_(2)reduction reaction(NRR).Under solvothermal conditions,micro-sized octahedral MIL-101(Fe)precursors are converted into ultra-small nanodots,while amorphous MoS_(3)derived from(NH_(4))_(2)MoS_(4)provides a surface suitable for anchoring the MIL-101(Fe)*** asprepared composite exhibits excellent electrocatalytic activity and durability for the NRR with a Faraday efficiency of 36.71%and an NH_(3)yield of 25.7μg h^(-1)mg_(cat)^(-1)at-0.1 V *** in 0.1 M *** results show that the dispersion and adherence of MIL-101(Fe)nanodots on amorphous MoS_(3)improves the exposure of active centers and aids mass transfer,resulting in greatly enhanced catalytic activity and stability.

关键词： nitrogen reduction reaction MIL-101(Fe)nanodots amorphous MoS_(3) precursor-transformation hybrid electrocatalysts

CASS工艺在徐州市三八河污水处理厂三期扩建工程的应用

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绿色科技 2024年第10期26卷 115-121页

作者：顾宏威万蕾丁其海贾伟博阳昆华韩鹏徐州市城区水资源管理处江苏徐州221000 徐州工程学院环境工程学院江苏徐州221018 徐州新水环境科技有限公司江苏徐州221018

徐州市三八河污水处理厂(三期)设计规模为5万t/d,采用CASS生化池为主体工艺,深度处理采用转盘滤池+接触消毒工艺。出水执行《城镇污水处理厂污染物排放标准》(GB18918-2002)水污染物排放一级A标准,恶臭气体进入填充塔式生物脱臭罐进行处... 详细信息

徐州市三八河污水处理厂(三期)设计规模为5万t/d,采用CASS生化池为主体工艺,深度处理采用转盘滤池+接触消毒工艺。出水执行《城镇污水处理厂污染物排放标准》(GB18918-2002)水污染物排放一级A标准,恶臭气体进入填充塔式生物脱臭罐进行处理,全厂异味控制参照执行《城镇污水处理厂污染物排放标准》(GB18918-2002)中关于厂界大气污染物排放最高允许浓度二级标准。污泥脱水含水率降低至80%后外运处置。污水厂实际运行结果表明:出水水质优于设计标准,对有机物的去除效果最好,对TN的去除率相对较低。吨水占地为0.26 m^(2) ,综合处理费用为0.5~0.6元/t水。

关键词：污水处理厂 CASS工艺转盘滤池除臭系统

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Recent development of efficient electrocatalysts derived from porous organic polymers for oxygen reduction reaction

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Science China Chemistry 2017年第8期60卷 999-1006页

作者： Shuanglong Lu Yinghua Jin hongwei gu Wei Zhang Key Laboratory of Organic Synthesis of Jiangsu Province College of ChemistryChemical Engineering and Materials ScienceCollaborative Innovation Center of Suzhou Nano Science and TechnologySoochow UniversitySuzhou 215123China Department of Chemistry and Biochemistry University of ColoradoBoulderCO 80309 USA

Porous organic polymers(POPs) have recently emerged as promising candidates for catalyzing oxygen reduction reaction(ORR).Compared to conventional Pt-based ORR catalysts, these newly developed porous materials, including both non-precious metal based catalysts and metal-free catalysts, are more sustainable and cost-effective. Their porous structures and large surface areas facilitate mass and electron transport and boost the ORR kinetics. This mini-review will give a brief summary of recent development of POPs as electrocatalysts for the ORR. Some design principles, different POP structures, key factors for their ORR catalytic performance, and outlook of POP materials will be discussed.

关键词：氧还原反应多孔材料有机聚合物电催化剂 POPs 多孔结构铂基催化剂金属催化剂