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Improving benzene catalytic oxidation on Ag/Co_(3)O_(4) by regulating the chemical states of Co and Ag

Journal of Environmental Sciences 2024年第9期143卷 201-212页

作者： Hao Guo Tao Guo Mengqi Zhao Yaxin Zhang Wenfeng Shangguan Yinnian liao State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources Xinjiang UniversityXinjiang 830017China Xinjiang Key Laboratory of Coal Clean Conversion&Chemical Engineering Process Xinjiang UniversityXinjiang 830017China School of Chemical Engineering and Technology Xinjiang UniversityXinjiang 830017China Research Center for Combustion and Environmental Technology Shanghai Jiao Tong UniversityShanghai 200240China School of Applied Chemistry and Materials Zhuhai College of Science and TechnologyGuangdong 519041China

Silver(9 wt.%)was loaded on Co_(3)O_(4)-nanofiber using reduction and impregnation methods,*** to the stronger electronegativity of silver,the ratios of surface Co^(3+)/Co^(2+) on Ag/Co_(3)O_(4) were higher than on Co_(3)O_(4),which further led to more adsorbed oxygen species as a result of the charge ***,the introducing of silver also obviously improved the reducibility of Co_(3)O_(4).Hence the Ag/Co_(3)O_(4) showed better catalytic performance than Co_(3)O_(4) in benzene *** with the Ag/Co_(3)O_(4) synthesized via impregnation method,the one prepared using reduction method(named as Ag Co-R)exhibited higher contents of surface Co^(3+) and adsorbed oxygen species,stronger reducibility,as well as more active surface lattice oxygen ***,Ag Co-R showed lowest T_(90) value of 183℃,admirable catalytic stability,largest normalized reaction rate of1.36×10^(-4)mol/(h·m^(2))(150℃),and lowest apparent activation energy(E_(a))of 63.2 kJ/*** analyzing of in-situ DRIFTS indicated benzene molecules were successively oxidized to phenol,o-benzoquinone,small molecular intermediates,and finally to CO_(2) and water on the surface of Ag *** last,potential reaction pathways including five detailed steps were proposed.

关键词： Reduction method Co_(3)O_(4)-supported Ag catalyst,VOCs Benzene oxidation Reaction mechanism

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Mussel-inspired PTW@PDA composites for developing high-energy gun propellants with reduced erosion and enhanced mechanical strength

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Defence Technology（防务技术） 2024年第2期32卷 675-690页

作者： Xijin Wang Zhitao Liu Pengfei Sun Feiyun Chen Bin Xu Xin liao School of Chemistry and Chemical Engineering Nanjing University of Science and TechnologyNanjing 210094JiangsuChina China North Industries Group Corporation Limited Beijing 100045China

The severe erosion and inadequate mechanical strength are prominent challenges for high-energy gun *** address it,novel PTW@PDA composites was prepared by polydopamine(PDA)-modifying onto potassium titanate whisker(PTW,K_(2)Ti_(6)O_(13)),and after was incorporated into gun propellant as erosion-reducing and mechanical-reinforcing *** interfacial characterizations results indicated that as-prepared PTW@PDA composites exhibits an enhanced surface compatible with propellant matrix,thereby facilitating their dispersion into propellants more effectively than raw PTW *** to original propellants,PTW@PDA-modified propellants exhibited significant less erosion,with a Ti-Kbased protective coating being detected on the eroded *** 0.5 wt%and 1.0 wt%addition of PTW@PDA significantly improved impact,compressive and tensile strength of *** the inevitably reduction in relative force,PTW@PDA slightly increase propellant burning rate while exerting little adverse impact on propellant dynamic *** strategy can provide a promising alternative to develop high-energy gun propellant with less erosion and more mechanical strength.

关键词： High energy gun propellant Potassium titanate whiskers Polydopamine modification Erosion inhibitors Mechanical reinforcing fillers

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Robust Reactive Power Scheduling of Distribution Networks Based on Modified Bootstrap Technique

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Journal of Modern Power Systems and Clean Energy 2024年第1期12卷 154-166页

作者： Wenlong liao Shouxiang Wang Birgitte Bak-Jensen Jayakrishnan Radhakrishna Pillai Zhe Yang the AAU Energy Aalborg UniversityAalborg 9220Denmark the Key Laboratory of Smart Grid Ministry of EducationSchool of Electrical and Information EngineeringTianjin UniversityTianjin 300072China

The uncertainties of the power load,wind power,and photovoltaic power lead to errors between point prediction values and real values,which challenges the safe operation of distribution *** this paper,a robust reactive power scheduling(RRPS)model based on a modified bootstrap technique is proposed to consider the uncertainties of power loads and renewable energy ***,a deterministic reactive power scheduling(DRPS)model and an RRPS model are ***,a modified bootstrap technique is proposed to estimate prediction errors of power loads and renewable energy sources without artificially assuming the probability density function of prediction *** represent all possible scenarios,point prediction values and prediction errors are combined to construct two worst-case scenarios in the RRPS ***,the RRPS model is solved to find a scheduling scheme,which ensures the security of distribution networks for all possible scenarios in *** results show that the worst-case scenarios constructed by the modified bootstrap technique outperform popular ***,the RRPS model based on the modified bootstrap technique balances economics and security well.

关键词： Distribution network worst-case scenario robust programming prediction error bootstrap technique

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Unveiling the performance of a novel alkalizing bacterium Enterobacter ***-2 in immobilization of available Cd

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Journal of Environmental Sciences 2024年第3期137卷 245-257页

作者： Yixin Luo Min liao Xiongxiong Lu Na Xu Xiaomei Xie Weiming Gao College of Environmental and Resource Science Zhejiang UniversityHangzhou 310058China Zhejiang Provincial Key Laboratory of Agricultural Resources and Environment Hangzhou 310058China National Demonstration Center for Experimental Environmental and Resources Education Zhejiang UniversityHangzhou 310058China

A novel alkalizing strain Enterobacter ***-2 that could resist 400 mg/L Cd was isolated from Cd-contaminated soil,which immobilized 96.05%Cd^(2+)from *** distribution analysis demonstrated that more than half of the Cd^(2+)was converted into extracellular precipitated Cd through mobilization of the alkali-producing mechanism by the strain LYX-2,achieving the high immobilization efficiency of Cd^(2+).Biosorption experiments revealed that strain LYX-2 had superior biosorption capacity of 48.28 mg/g for *** experiments with Brassica rapa *** performed with and without strain *** to control,15.92%bioavailable Cd was converted to non-bioavailable Cd and Cd content in aboveground vegetables was decreased by 37.10%with addition of strain *** Cd was mainly immobilized through extracellular precipitation,cell-surface biosorption and intracellular accumulation of strain LYX-2,which was investigated through Cd distribution,Scanning Electron Microscope and Energy-Dispersive X-ray Spectroscopy(SEM-EDS),Fourier Transform Infrared Spectroscopy(FT-IR),X-ray Photoelectron Spectroscopy(XPS)and Transmission Electron Microscopy(TEM)*** addition,the application of strain LYX-2 significantly promoted the growth of vegetables about *** results indicated that highly Cd-resistant alkalizing strain LYX-2,as a novel microbial passivator,had excellent ability and reuse value to achieve the remediation of Cd-contaminated soil coupled with safe production of vegetables simultaneously.

关键词： Cadmium Enterobacter sp.LYX-2 Cd Immobilization Microbial passivator

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Triphenylphosphine-Assisted Exsolution Engineering on Ruddlesden-Popper Perovskites for Promoting Oxygen Evolution

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Energy & Environmental Materials 2024年第4期7卷 433-441页

作者： Juan Bai Jing Shang Jun Mei Dongchen Qi Ting liao Ziqi Sun School of Chemistry and Physics Queensland University of Technology Centre for Materials Science Queensland University of Technology School of Materials Science and Engineering Shaanxi University of Science and Technology School of Mechanical Medical and Process Engineering Queensland University of Technology

Metal exsolution engineering has been regarded as a promising strategy for activating intrinsically inert perovskite oxide catalysts toward efficient oxygen evolution *** metal exsolution processes on perovskites are often achieved by using the reducing hydrogen gas; however,this is not effective for the relatively stable phase,such as Ruddlesden-Popper perovskite oxides.

关键词： exsolution oxygen evolution perovskite reconstruction Ruddlesden–Popper

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Herpetrione, a New Type of PPARα Ligand as a Therapeutic Strategy Against Nonalcoholic Steatohepatitis

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Research 2024年第3期2023卷 513-527页

作者： Lang Linghu Wei Zong Yixuan liao Qianyu Chen Fancheng Meng Guowei Wang Zhihua liao Xiaozhong Lan Min Chen Key Laboratory of Luminescence Analysis and Molecular Sensing(Southwest University) Ministry of EducationCollege of Pharmaceutical SciencesSouthwest UniversityChongqing 400715China Scholof Pharmacy Zunyi Medical UniversityZunyi 563000China School of Life Sciences Integrative Science Center of Germplasm Creation in Western China(CHONGQING)Science City and Southwest University TAAHC SWU Medicinal Plant Joint R&D CentreSouthwest UniversityChongqing 400715China TAAHC-SWU Medicinal Plant R&D Center Tibet Agricultural and Animal Husbandry UniversityNyingchiTibet 860000China.

Non-alcoholic fatty liver disease, especially nonalcoholic steatohepatitis (NASH), is a leading cause of cirrhosis and liver cancer worldwide;nevertheless, there are no Food and Drug Administration-approved drugs for treating NASH until now. Peroxisome proliferator-activated receptor alpha (PPARα) is an interesting therapeutic target for treating metabolic disorders in the clinic, including NASH. Herpetrione, a natural lignan compound isolated from Tibetan medicine Herpetospermum caudigerum, exerts various hepatoprotective effects, but its efficacy and molecular mechanism in treating NASH have not yet been elucidated. Here, we discovered that herpetrione lessened lipid accumulation and inflammation in hepatocytes stimulated with oleic acid and lipopolysaccharide, and effectively alleviated NASH caused by a high-fat diet or methionine-choline-deficient diet by regulating glucolipid metabolism, insulin resistance, and inflammation. Mechanistically, RNA-sequencing analyses further showed that herpetrione activated PPAR signaling, which was validated by protein expression. Furthermore, the analysis of molecular interactions illustrated that herpetrione bound directly to the PPARα protein, with binding sites extending to the Arm III domain. PPARα deficiency also abrogated the protective effects of herpetrione against NASH, suggesting that herpetrione protects against hepatic steatosis and inflammation by activation of PPARα signaling, thereby alleviating NASH. Our findings shed light on the efficacy of a natural product for treating NASH, as well as the broader prospects for NASH treatment by targeting PPARα.

关键词： PPARα protective metabolism

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Experimental Study on the Molten Salt at Micron Scale during the Melting Process

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Journal of Thermal Science 2024年第1期33卷 70-85页

作者： TIAN Ziqian liao Zhirong XU Chao FANG Yongzhe JIANG Kaijun YUAN Mengdi Key Laboratory of Power Station Energy Transfer Conversion and System Ministry of Education of ChinaSchool of Energy Power and Mechanical EngineeringNorth China Electric Power UniversityBeijing 102206China

The investigation of the melting behaviors of the molten salt at micron scale during the melting process is critical for explaining the solid-liquid phase transition *** this paper,a novel experimental system and analysis method were proposed to study the melting process with three heating rates in the range of1-10℃/min of the solar salt at micron *** solid-liquid boundary morphology and phase transition kinetics of molten salt particles were focused ***,the correlations between liquid fraction,temperature and time under different heating rates were *** solid-liquid boundary morphology was depicted by the visualized experimental set-up,and the instantaneous liquid volume fraction during the non-isothermal phase transition was ***,the correlation between temperature and liquid volume fraction was proposed to reveal the evolution of the solid-liquid boundary with temperature at different heating ***,the non-isothermal phase transition kinetic equation was established by introducing a constant parameter(V_(a,b)),and more kinetic parameters such as 1g V_(a,b) and-lg V_(a,b)/b were *** results showed that the exponent b is not sensitive to the heating rate with a range of 3-5 for solar salt ***,the heating rate influences the value of V_(a,b) and presents a positive ***,the non-isothermal phase transition kinetic equations at different heating rates in the range of 1-10℃/min can be quickly predicted by the proposed improved experimental test *** study could fill the research insufficiency and provide significant guidance for future research on the solid-liquid transition mechanism of molten salts at micron scale.

关键词： molten salt non-isothermal phase transition solid-liquid boundary morphology liquid volume fraction micron scale melting process

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Investigation on Strengthening Mechanism of China Low-Activation Ferrite Steel upon Thermo-Mechanical Treatment

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Acta Metallurgica Sinica(English Letters) 2024年第2期37卷 373-387页

作者： Dongtian Yang Liangyin Xiong Hongbin liao Guoping Yang Xiaoyu Wang Shi Liu Institute of Metal Research Chinese Academy of SciencesShenyang110016China School of Materials Science and Engineering University of Science and Technology of ChinaShenyang110016China Center for Fusion Science Southwestern Institute of PhysicsChengdu610041China

The objective of this study was to investigate the influence of strengthening mechanisms on the high-temperature mechanical properties of China low-activation ferrite(CLF-1)steel,which underwent thermodynamic design and thermo-mechanical treatment(TMT).The microstructure characterization in the normalized and tempered condition and the TMT condition was carried out using optical microscopy,X-ray diffractometer,and scanning electron microscopy with electron backscatter ***-resolution transmission electron microscopy was employed to determine the crystallographic structures of precipitated *** results indicated that the addition of Ti led to an increase in the allocation of C in MC phase and an enhancement in the content of MC *** to CLF-P steel in the normalized and tempered condition,a 1.5-fold increase in dislocation density and an order of magnitude improvement in MX phase density were achieved after *** formation of high-density nano-scale MC phases during TMT played a significant role in precipitation strengthening due to their favorable coherent relationship with the matrix and low interfacial free *** excellent high-temperature mechanical properties observed in CLF-P steel after TMT can be attributed to the combined effects of precipitation strengthening,dislocation strengthening,and lath strengthening.

关键词： China low-activation ferrite(CLF-1)steel Thermo-mechanical treatment MC phase Crystallographic structure Strengthening mechanism

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Creep constitutive model considering nonlinear creep degradation of fractured rock

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International Journal of Mining Science and Technology 2024年第1期34卷 105-116页

作者： Wang Chunping Liu Jianfeng Chen Liang Liu Jian Wang Lu liao Yilin Beijing Research Institute of Uranium Geology Beijing 100029China CAEA Innovation Center for Geological Disposal of High-Level Radioactive Waste Beijing 100029China State Key Laboratory of Hydraulics and Mountain River Engineering Sichuan UniversityChengdu 610065China School of Architecture and Civil Engineering Xihua UniversityChengdu 610039China

Stability analysis of underground constructions requires a model study of rock masses’ long-term performance. Creep tests under different stress conditions was conducted on intact granite and granite samples fractured at 30° and 45° angles. The experimental results indicate that the steady creep strain rates of intact and fractured rock present an exponential increase trend with the increase of stress level. A nonlinear creep model is developed based on the experimental results, in which the initial damage caused by fracture together with the damage caused by constant load have been taken into consideration. The fitting analysis results indicated that the model proposed is more accurate at identifying the full creep regions in fractured granite, especially the accelerated stage of creep deformation. The least-square fit error of the proposed creep model is significantly lower than that of Nishihara model by almost an order of magnitude. An analysis of the effects of elastic modulus, viscosity coefficient, and damage factors on fractured rock strain rate and creep strain is conducted. If no consideration is given to the effects of the damage, the proposed nonlinear creep model can degenerate into to the classical Nishihara model.

关键词： Fractured rock Damage Creep Beishan granite Geological disposal

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Opto-fluidically multiplexed assembly and micro-robotics

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Light(Science & Applications) 2024年第3期13卷 544-554页

作者： Elena Erben Weida liao Antonio Minopoli Nicola Maghelli Eric Lauga Moritz Kreysing Max Planck Institute of Molecular Cell Biology and Genetics Dresden 01307Germany Center for Systems Biology Dresden 01307Germany Institute of Biological and Chemical Systems–Biological Information Processing.Karlsruhe Institute of Technology(KIT) Eggenstein-Leopoldshafen 76344Germany Department of Applied Mathematics and Theoretical Physics University of CambridgeCambridge CB30WAUK

Techniques for high-definition micromanipulations,such as optical tweezers,hold substantial interest across a wide range of ***,their applicability remains constrained by material properties and laser *** while microfluidic manipulations have been suggested as an alternative,their inherent capabilities are limited and further hindered by practical challenges of implementation and *** we show that the iterative application of laser-induced,localized flow fields can be used for the relative positioning of multiple micro-particles,irrespectively of their material *** to the standing theoretical proposal,our method keeps particles mobile,and we show that their precision manipulation is non-linearly accelerated via the multiplexing of temperature stimuli below the heat diffusion *** resulting flow fields are topologically rich and mathematically *** represent unprecedented microfluidic control capabilities that are illustrated by the actuation of humanoid micro-robots with up to 30 degrees of freedom,whose motions are sufficiently well-defined to reliably communicate personal characteristics such as gender,happiness and *** results constitute high-definition micro-fluidic manipulations with transformative potential for assembly,micro-manufacturing,the life sciences,robotics and optohydraulically actuated micro-factories.

关键词： manipulation fluid assembly

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