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Rapid prediction of flow and concentration fields in solid-liquid suspensions of slurry electrolysis tanks

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International Journal of Minerals,Metallurgy and Materials 2024年第9期31卷 2006-2016页

作者： Tingting Lu Kang Li hongliang Zhao Wei Wang Zhenhao Zhou Xiaoyi Cai Fengqin Liu State Key Laboratory of Advanced Metallurgy University of Science and Technology BeijingBeijing 100083China State Key Laboratory of Intelligent Optimized Manufacturing in Mining&Metallurgy Process Beijing 102628China School of Materials Science and Engineering Lanzhou University of TechnologyLanzhou 730050China School of Metallurgical and Ecological Engineering University of Science and Technology BeijingBeijing 100083China

Slurry electrolysis(SE),as a hydrometallurgical process,has the characteristic of a multitank series connection,which leads to various stirring conditions and a complex solid suspension *** computational fluid dynamics(CFD),which requires high computing resources,and a combination with machine learning was proposed to construct a rapid prediction model for the liquid flow and solid concentration fields in a SE *** scientific selection of calculation samples via orthogonal experiments,a comprehensive dataset covering a wide range of conditions was established while effectively reducing the number of simulations and providing reasonable weights for each ***,a prediction model of the SE tank was constructed using the K-nearest neighbor *** results show that with the increase in levels of orthogonal experiments,the prediction accuracy of the model improved *** model established with four factors and nine levels can accurately predict the flow and concentration fields,and the regression coefficients of average velocity and solid concentration were 0.926 and 0.937,*** with traditional CFD,the response time of field information prediction in this model was reduced from 75 h to 20 s,which solves the problem of serious lag in CFD applied alone to actual production and meets real-time production control requirements.

关键词： slurry electrolysis solid-liquid suspension computational fluid dynamics K-nearest neighbor algorithm rapid prediction

P-induced electron transfer interaction for enhanced selective hydrogenation rearrangement of furfural to cyclopentanone

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Journal of Energy Chemistry 2024年第5期92卷 43-51页

作者： Weichen Wang Hongke Zhang Yidan Wang Fangyuan Zhou Zhiyu Xiang Wanbin Zhu hongliang Wang Center of Biomass Engineering College of Agronomy and BiotechnologyChina Agricultural UniversityBeijing 100193China

Optimizing the intrinsic activity of non-noble metal by precisely tailoring electronic structure offers an appealing way to construct cost-effective catalysts for selective biomass ***,we reported a P-doping bifunctional catalyst(Ni-P/mSiO_(2))that achieved 96.6%yield for the hydrogenation rearrangement of furfural to cyclopentanone at mild conditions(1 MPaH_(2),150°C).The turnover frequency of Ni-P/mSiO_(2)was 411.9 h^(-1),which was 3.2-fold than that of Ni/mSiO_(2)(127.2 h^(-1)).Detailed characterizations and differential charge density calculations revealed that the electron-deficient Niδ+species were generated by the electron transfer from Ni to P,which promoted the ring rearrangement *** functional theory calculations illustrated that the presence of P atoms endowed furfural tilted adsorb on the Ni surface by the C=O group and facilitated the desorption of *** work unraveled the connection between the localized electronic structures and the catalytic properties,so as to provide a promising reference for designing advanced catalysts for biomass valorization.

关键词： Furfural Hydrogenation rearrangement P-doping Electron transfer Biomass valorization

Enhanced nitrate removal from groundwater using a conductive spacer in flow-electrode capacitive deionization

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Chinese Chemical Letters 2024年第8期35卷 379-382页

作者： Hongjie Guo Qiang Wei yangyang Wu Wei Qiu hongliang Li Changyong Zhang College of Mining Engineering Taiyuan University of TechnologyTaiyuan 030024China CAS Key Laboratory of Urban Pollutant Conversion Department of Environmental Science and EngineeringUniversity of Science and Technology of ChinaHefei 230026China CAS Key Laboratory of Mechanical Behavior and Design of Materials Department of Modern MechanicsUniversity of Science and Technology of ChinaHefei 230026China

Flow-electrode capacitive deionization(FCDI)represents a promising approach for ion separation from aqueous ***,the optimization of spacer,particularly for nitrate-contaminated groundwa-ter systems,has often been *** research comprehensively investigates the influence of using a conductive(carbon cloth,CC)spacer on nitrate removal performance within FCDI system,comparing it to a non-conductive(nylon net,NN)*** both CC and NN FCDI systems,it is unsurprisingly that nitrate removal efficiency improved notably with the increasing current density and hydraulic retention time(HRT).Interestingly,the specific energy consumption(SEC)for nitrate removal did not show obvious fluctuations when the current density and HRT varied in both *** the auspiciously optimized process parameters,CC-FCDI attained a 20%superior nitrate removal efficiency relative to NN-FCDI,ac-companied by a notably diminished SEC for CC-FCDI,registering at a mere 28%of *** great improvement can be primarily attributed to the decrement in FCDI internal resistance after using con-ductive spacer,which further confirmed by electrochemical tests such as linear sweep voltammetry(LSV)and electrochemical impedance spectroscopy(EIS).Upon prolonged continuous nitrate removal at the optimized conditions,the CC-FCDI system achieved a consistent 90%nitrate removal efficiency with a low SEC of 2.7-7.8 kWh/kg NO_(3)-N,underscoring its steady ***,this study highlights the pivotal importance of careful spacer design and optimization in realizing energy-efficient groundwater treatment via FCDI.

关键词： Flow-electrode capacitive deionization Carbon cloth Nitrate Underground water Ions transport

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论起诉案件中部分不起诉决定监督机制之完善

华东政法大学学报 2009年第2期12卷 81-85页

作者：杨宏亮姜伟上海市宝山区人民检察院研究室主任上海市人民检察院第一分院干部

完善对审查起诉案件中部分不起诉决定的监督制约机制,有利于保障被害人、犯罪嫌疑人的合法权益,防止不起诉权的滥用,提高办案的质量和水平。这种机制有别于就整个案件进行的监督,它坚持内外监督相结合、诉讼经济以及公开、公正的原则。... 详细信息

完善对审查起诉案件中部分不起诉决定的监督制约机制,有利于保障被害人、犯罪嫌疑人的合法权益,防止不起诉权的滥用,提高办案的质量和水平。这种机制有别于就整个案件进行的监督,它坚持内外监督相结合、诉讼经济以及公开、公正的原则。在实际操作中,需完善审查起诉案件的具体要求和起诉案件质量标准,拟作出部分不起诉的应事先征询侦查机关(部门)以及当事人的意见,并设立审查监督评议机制,形成部分不起诉决定文书。

关键词：部分不起诉监督制约机制完善

Work-function effect of Ti_(3)C_(2)/Fe-N-C inducing solid electrolyte interphase evolution for ultra-stable sodium storage

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Nano Research 2024年第8期17卷 7163-7173页

作者： Huicong Xia Lingxing Zan hongliang Dong Yifan Wei Yue Yu Jinfu Shu Jia-Nan Zhang Chong-Xin Shan Key Laboratory of Advanced Energy Catalytic and Functional Material Preparation of Zhengzhou College of Materials Science and EngineeringZhengzhou UniversityZhengzhou 450001China Key Laboratory of Materials Physics of Ministry of Education School of Physics and MicroelectronicsZhengzhou UniversityZhengzhou 450001China Key Laboratory of Chemical Reaction Engineering of Shaanxi Province College of Chemistry and Chemical EngineeringYan’an UniversityYan’an 716000China Center for High Pressure Science and Technology Advanced Research PudongShanghai 201203China Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjin 300071China

In the quest to enhance the efficiency of sodium-ion batteries,the dynamics of solid electrolyte interphase(SEI)formation are of paramount *** SEI layer’s integrity is integral to the charge–discharge efficiency and the overall longevity of the ***,a novel two-dimensional Ti_(3)C_(2) fragments enmeshed on iron-nitrogen-carbon(Fe-N-C)nanosheets(Ti_(3)C_(2)/Fe-NC)has been *** electrode features a matrix which has been shown to expedite SEI layer formation through the facilitation of selective anion adsorption,thus augmenting battery *** functional theory calculation reveals that the SEI evolution energy of NaPF6 at the Ti_(3)C_(2)/Fe-N-C interface is 0.81 eV,significantly lower than the Ti_(3)C_(2)(1.23 eV).This process is driven by the electron transportation from Ti_(3)C_(2) to Fe-N-C substrate,facilitated by their work-function difference,leading to the formation of ferromagnetic Fe species,which possesses Fe 3d d_(xz)d_(z)2 orbitals and undergoes hybridization with theπandσorbitals of NaF,creating a key intermediate during *** process diminishes the antibonding energy and attenuates the orbital interaction with NaF,thus reducing the activation energy and improving the SEI formation reaction ***,it leads to the creation of multi-interface SEI characterized by high-throughput ion transport and an efficient reaction network.

关键词： Ti_(3)C_(2)/Fe-N-C heterostructure work-function electron interaction solid electrolyte interphase sodium storage

High-performance anisotropic SmCo-based magnet with novel microstructure

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Journal of Rare Earths 2024年第8期42卷 1539-1545,I0005页

作者： Yingchang Li Zicao Xing Nengjun Yu Zesong Ren Minxiang Pan Qiong Wu hongliang Ge Minggang Zhu Wei Li College of Materials and Chemistry China jiliang UniversityHangzhou 310018China Division of Functional Materials Research Central Iron and Steel Research InstituteBeijing 100081China

A novel micro structure of magnetically anisotropic Sm Co-based magnet with high-performance is *** magnet consists of SmCo_(7)-H(TbCu_(7)-hexagonal type),Sm_(2)Co_(17)-H(Th_(2)Ni_(17)-hexagonal type)and SmCo_(3)-R(SmCo_(3)-rhombohedral type)*** maximum magnetic energy product of the magnet is 231.69 kj/m^(3),and the intrinsic coercivity is 1005.47 kA/*** outstanding intrinsic coercivity temperature coefficient(β)of-0.125%/K between 298 and 773 K is obtained,which is very close to theβof commercial high-temperature Sm_(2)Co_(17)-based sintered *** initial magnetization curve indicates that the coercivity mechanism is controlled by a domain wall pinning *** SmCo_(3)-R lamellar phase may be a potential pinning center or self-pinning *** microstructure of the magnet is different from that of any previous SmCo-based *** findings provide a new idea for preparing high-performance SmCo-based permanent magnets.

关键词： Rare earths Permanent magnet Composite magnet Melt-spinning Microstructure

Preparation of lithium-ion battery anode materials from graphitized spent carbon cathode derived from aluminum electrolysis

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International Journal of Minerals, Metallurgy and Materials 2024年第11期31卷 2466-2475页

作者： Zheng, Zhihao Xie, Mingzhuang Yu, Guoqing Wu, Zegang Zhong, Jingjing Wang, Yi Zhao, hongliang Liu, Fengqin State Key Laboratory of Advanced Metallurgy University of Science and Technology Beijing Beijing China School of Metallurgical and Ecological Engineering University of Science and Technology Beijing Beijing China

Graphitized spent carbon cathode (SCC) is a hazardous solid waste generated in the aluminum electrolysis process. In this study, a flotation–acid leaching process is proposed for the purification of graphitized SCC, and the use of the purified SCC as an anode material for lithium-ion batteries is explored. The flotation and acid leaching processes were separately optimized through one-way experiments. The maximum SCC carbon content (93wt%) was achieved at a 90% proportion of‒200-mesh flotation particle size, a slurry concentration of 10wt%, a rotation speed of 1600 r/min, and an inflatable capacity of 0.2 m3/h (referred to as FSCC). In the subsequent acid leaching process, the SCC carbon content reached 99.58wt% at a leaching concentration of 5 mol/L, a leaching time of 100 min, a leaching temperature of 85°C, and an HCl/FSCC volume ratio of 5:1. The purified graphitized SCC (referred to as FSCC-CL) was utilized as an anode material, and it exhibited an initial capacity of 348.2 mAh/g at 0.1 C and a reversible capacity of 347.8 mAh/g after 100 cycles. Moreover, compared with commercial graphite, FSCC-CL exhibited better reversibility and cycle stability. Thus, purified SCC is an important candidate for anode material, and the flotation-acid leaching purification method is suitable for the resourceful recycling of SCC.

关键词： graphitized spent carbon cathode hazardous solid waste flotation acid leaching lithium-ion batteries

成形系数及强度组配对焊缝区裂尖力学特性的影响

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中国科技论文 2017年第4期12卷 371-373页

作者：杨宏亮薛河西安科技大学工程训练中心西安710054 西安科技大学机械工程学院西安710054

为了解镍基合金焊接接头焊缝成形系数及强度组配对裂纹尖端力学特性的影响,借助有限元数值模拟手段,分析了焊缝成形系数及不同组配条件下裂纹尖端力学特性。低组配下,裂尖Mises应力、等效塑性应变及J积分均随着成形系数的增大而增大;等... 详细信息

为了解镍基合金焊接接头焊缝成形系数及强度组配对裂纹尖端力学特性的影响,借助有限元数值模拟手段,分析了焊缝成形系数及不同组配条件下裂纹尖端力学特性。低组配下,裂尖Mises应力、等效塑性应变及J积分均随着成形系数的增大而增大;等组配下,裂尖力学特性不变;高组配下,裂尖Mises应力、等效塑性应变及J积分均随着成形系数的增大而减小。随着组配比的增加,裂尖Mises应力随之增加,裂尖等效塑性应变和J积分逐渐减小。研究结果表明,强度组配对裂尖力学特性有较大的影响,焊缝成形系数对裂尖力学特性影响较小。

关键词：应力腐蚀开裂焊缝成形系数强度组配应力应变

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膜致应力促氧化膜破裂行为研究

铸造技术 2017年第6期38卷 1274-1277页

作者：杨宏亮薛河杨帆西安科技大学工程训练中心陕西西安710054 西安科技大学机械工程学院陕西西安710054

在以滑移溶解理论为基础的裂纹扩展速率定量预测模型中,裂纹长度是裂纹扩展速率的重要影响参数之一,针对镍基合金裂尖裂纹长度的扩展规律,研究裂纹长度对镍基合金材料裂纹尖端膜致应力产生的应力应变场的影响,采用ABAQUS软件,在不考虑... 详细信息

在以滑移溶解理论为基础的裂纹扩展速率定量预测模型中,裂纹长度是裂纹扩展速率的重要影响参数之一,针对镍基合金裂尖裂纹长度的扩展规律,研究裂纹长度对镍基合金材料裂纹尖端膜致应力产生的应力应变场的影响,采用ABAQUS软件,在不考虑外载的情况下,分析膜致应力应变场随裂纹扩展长度的改变所导致裂尖力学特性的变化规律。结果表明,裂纹长度不同,裂尖膜致应力产生的应力应变分布不同,膜致应力是裂纹扩展驱动力中不可忽略的主要因素之一。

关键词：应力腐蚀裂纹长度膜致应力氧化膜