检索结果-南通市图书馆

Mechanistic insight into Cr(Ⅵ)retention by Si-containing ferrihydrite

Journal of Environmental Sciences 2024年第5期139卷 217-225页

作者： Ying Hu Qiang Xue honghan chen Huaming Guo Kenneth C.Carroll Song Wang MOE Key Laboratory of Groundwater Circulation and Environmental Evolution School of Water Resources and EnvironmentChina University of Geosciences(Beijing)Beijing 100083China Beijing Key Laboratory of Water Resources and Environmental Engineering School of Water Resources and EnvironmentChina University of GeosciencesBeijing 100083China State Key Laboratory of Biogeology and Environmental Geology China University of GeosciencesBeijing 100083China Plant&Environmental Science New Mexico State UniversityNM 88003USA Institute of Theoretical Chemistry College of ChemistryJilin UniversityChangchun 130023China

Hexavalent chromium[Cr(Ⅵ)]causes serious harm to the environment due to its high toxicity,solubility,and mobility.Ferrihydrites(Fh)are the main adsorbent and trapping agent of Cr(Ⅵ)in soils and aquifers,and they usually coexist with silicate(Si),forming Si-containing ferrihydrite(Si-Fh)mixtures.However,the mechanism of Cr(Ⅵ)retention by Si-Fh mixtures is poorly understood.In this study,the behaviors and mechanisms of Cr(Ⅵ)adsorption onto Si-Fh with different Si/Fe molar ratios was investigated.Transmission electron microscope,Fourier transform infrared spectroscopy,X-ray diffraction,X-ray photoelectron spectroscopy,and other techniques were used to characterize Si-Fh and Cr(Ⅵ)-loading of Si-Fh.The results show that specific surface area of Si-Fh increases gradually with increasing Si/Fe ratios,but Cr(Ⅵ)adsorption on Si-Fh decreases with increasing Si/Fe ratios.This is because with an increase in Si/Fe molar ratio,the point of zero charge of Si-Fh gradually decreases and electrostatic repulsion between Si-Fh and Cr(Ⅵ)increases.However,the complexation of Cr(Ⅵ)is enhanced due to the increase in adsorbed hydroxyl(A-OH-)on Si-Fh with increasing Si/Fe molar ratio,which partly counteracts the effect of the electrostatic repulsion.Overall,the increase in the electrostatic repulsion has a greater impact on adsorption than the additional complexation with Si-Fh.Density functional theory calculation further supports this observation,showing the increases in electron variation of bonding atoms and reaction energies of inner spherical complexes with the increase in Si/Fe ratio.

关键词： Hexavalent chromium Ferrihydrite Si/Fe ratio Cr(Ⅵ)Adsorption

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Customization of FeNi alloy nanosheet arrays inserted with biomass-derived carbon templates for boosted electromagnetic wave absorption

引用

International Journal of Minerals,Metallurgy and Materials 2024年第4期31卷 812-824页

作者： Xuanqi Yang honghan Wang Jing chen Qingda An Zuoyi Xiao Jingai Hao Shangru Zhai Junye Sheng Liaoning Key Lab of Lignocellulose Chemistry and BioMaterials Liaoning Collaborative Innovation Center for Lignocellulosic BiorefineryCollege of Light Industry and Chemical EngineeringDalian Polytechnic UniversityDalian 116034China Qingdao Medical College Qingdao UniversityQingdao 266071China

Electromagnetic wave(EMW)-absorbing materials have considerable capacity in the military field and the prevention of EMW radiation from harming human health.However,obtaining lightweight,high-performance,and broadband EMW-absorbing material remains an overwhelming challenge.Creating dielectric/magnetic composites with customized structures is a strategy with great promise for the development of high-performance EMW-absorbing materials.Using layered double hydroxides as the precursors of bimetallic alloys and combining them with porous biomass-derived carbon materials is a potential way for constructing multi-interface heterostructures as efficient EMW-absorbing materials because they have synergistic losses,low costs,abundant resources,and light weights.Here,FeNi alloy nanosheet array/Lycopodium spore-derived carbon(FeNi/LSC)was prepared through a simple hydrothermal and carbonization method.FeNi/LSC presents ideal EMW-absorbing performance by benefiting from the FeNi alloy nanosheet array,sponge-like structure,capability for impedance matching,and improved dielectric/magnetic losses.As expected,FeNi/LSC exhibited the minimum reflection loss of-58.3 dB at 1.5 mm with 20wt%filler content and a widely effective absorption bandwidth of 4.92 GHz.FeNi/LSC composites with effective EMW-absorbing performance provide new insights into the customization of biomass-derived composites as high-performance and lightweight broadband EMW-absorbing materials.

关键词： spore-derived carbon FeNi alloy nanosheet array multi-interface heterostructures synergistic effect efficient electromagnet-ic wave absorption

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Yuzaoea gen. nov., a new biraphid diatom(Bacillariophyceae)genus and its phylogenetic significance

引用

Acta Oceanologica Sinica 2024年第2期43卷 130-136页

作者： honghan Liu chenhong Li Lang Li Xuesong Li Lin Sun Junrong Liang Jun Zhang Yahui Gao Changping chen Key Laboratory of Ministry of Education for Coastal and Wetland Ecosystems and School of Life Sciences Xiamen UniversityXiamen 361102China State Key Laboratory of Marine Environmental Science Xiamen UniversityXiamen 361102China Guangxi Key Laboratory of Marine Environmental Science Guangxi Academy of Marine SciencesGuangxi Academy of SciencesNanning 530007China Beibu Gulf Marine Industry Research Institute Fangchenggang 538000China

The flexed frustules in pennate diatoms are usually associated with monoraphid diatoms. Interestingly, we found a biraphid diatom species with flexed frustules in an offshore intertidal beach environment on Weizhou Island,Beihai City, Guangxi Zhuang Autonomous Region, China. Therefore, based on morphological characteristics, we described a new genus of diatoms Yuzaoea sinensis gen. et sp. nov. CH Li, HH Liu, YH Gao & CP chen. The frustule of this genus is characterized by heterogeneous frustule with one concave valve and one convex valve,complete raphe on both valves, straight and moderately eccentric raphe, uniseriate striae and girdle bands with a single row of areolae. The most identifying feature of this genus was the flexed frustule, which is rare in biraphid diatoms and common in monoraphid diatoms. We compared the morphometric characteristics of genus Yuzaoea with genus Rhoikoneis and several genera within the family Rhoicospheniaceae, including Rhoicosphenia,Campylopyxis, and Cuneolus. Phylogenetic analyses based on SSU rRNA and rbc L showed that the genus Yuzaoea was the sister group to the clade of Rhoicosphenia with a high support value(bootstrap values = 100%), and the clade “Yuzaoea+Rhoicosphenia” was sister to the clade of monoraphid diatoms, in which the genera Achnanthidium, Planothidium and some Cocconeis with high support values(bootstrap = 100%).Morphologically, the genus Yuzaoea shares many morphological features with monoraphid diatoms like genera Achnanthidium and Planothidium and the members within the Rhoicospheniaceae. Therefore, based on a combined morphological studies and phylogenetic results we suggested that this branch may represented the evolution of one kind monoraphid diatoms, from biraphid diatoms(e.g. genus Yuzaoea), to incompleted biraphid diatoms(e.g. genera Rhoicosphenia, Campylopyxis), to monoraphid diatoms(e.g. genera Achnanthidium and Planothidium).

关键词： biraphid diatom marine new genus Rhoicospheniaceae taxonomy Yuzaoea

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Overpressure Evolution Recorded in Fluid Inclusions in the Dongpu Depression,Bohai Bay Basin,North China

引用

Journal of Earth Science 2022年第4期33卷 916-932页

作者： Xiuyan Liu honghan chen Xuewei Xiao Hongan Zhang Yuwei Wang Tianwu Xu Pei Shang Lingtao Kong Key Laboratory of Tectonics and Petroleum Resources of Ministry of Education China University of GeosciencesWuhan 430074China Zhongyuan Oilfield Company SINOPECPuyang 457001China Xianhe Production Factory Shengli Oilfield CompanySINOPECDongying 257086China State Key Laboratory of Nuclear Resources and Environment East China University of TechnologyNanchang 330013China

The Dongpu depression,like other depressions in the Bohai Bay Basin,is characterized by overpressure,however,the published studies have not clearly given the overpressure formation mechanism and paleo-pressure evolution history in the Dongpu depression.In addition,the current researches are mainly focused on the northern Dongpu depression,while rare investigation has been conducted in the southern part.In this context,it is urgent to explore the comprehensive overpressure evolution and formation mechanism in the Dongpu depression in academic and industrial fields.This paper provided a systematic analysis of fluid inclusions,including fluid inclusion petrography,microthermometry,vapor phase filling degree measurement and PVT-x modeling.By using homogenization temperature-burial history projection,the trapping time of the oil inclusions are determined.Four pressure evolution stages are identified in both the northern and the southern Dongpu depression.The results indicate that the pressure accumulation stage is derived by disequilibrium compaction and hydrocarbon generation in the northern part because of the salt rock distribution,while the stage is only derived by hydrocarbon generation in the southern part because of no salt rock distribution.The pressure release stages are mainly caused by the tectonic uplifting movements at the end of Dongying and Minghuazhen Formation.The overpressure in most areas in the northern part has been preserved till now,which is considered as a result of the good plasticity and sealing ability of salt rock that prevent the pressure leakage by smearing on the fault.Areas without salt rock distribution show normal pressure,which means the salt rock is an important factor that contributes to the overpressure preservation.However,there are exceptions that in Baimiao and Qiaokou,the overpressure still exists even without salt rock distribution,which is due to fault closure.

关键词： PVT-x modeling burial history Shahejie Formation Paleogene fluid inclusion

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

SeHed,a novel gene expression system with stress-evoked hydrogen peroxide elimination property and anti-aging effect

引用

Signal Transduction and Targeted Therapy 2022年第8期7卷 2698-2700页

作者： Ning Huang honghan chen Hui Gong Haoran Tai Xiaojuan Han Xiaobo Wang Chuhui Gong Tingting Zhao Yu Yang Hengyi Xiao The Lab for Aging Research National Clinical Research Center for GeriatricsState Key Laboratory of BiotherapyWest China HospitalSichuan University1 Keyuan 4 RoadGaopeng AvenueChengdu 610041China Development and Regeneration Key Lab of Sichuan Province Department of Anatomy and Histology and EmbryologyChengdu Medical CollegeChengduChina Shaanxi Key Laboratory of Brain Disorders and Institute of Basic and Translational Medicine Xi’an Medical UniversityXi’an 710049China School of Basic Medicine Dali UniversityDaliYunnan 671000China

Dear Editor,The moderate level of reactive oxygen species(ROS)contributes to cellular functions such as proliferation,differentiation,and infection resistance,but the excessive level of ROS causes oxidative damage which underlies the basic mechanism for aging and geriatric diseases.1 Therefore,precisely managing cellular ROS levels,meaning to keep redox homeostasis properly,stands as an aim for health and longevity.Actually,this aim is challenging,as it asks not only to restrain excessive ROS accumulation at the right time and right place but also to guarantee proper ROS levels for fitting physiological requirements.Traditional ways for eliminating ROS put more attention on the efficiency and identified a variety of drugs and enzymes with antioxidant properties,known as enzymatic and non-enzymatic ROS scavengers,respectively.However,how to accurately manage the integrative effect of ROS scavengers in vivo remains a problem.Actually,the effectiveness of non-enzymatic antioxidants in vivo is controversial,explained mostly by the uncertainty to reach a given organ with the appropriate concentration or to work there persistently.2 As to enzymatic ROS scavengers,although their overexpression in a given place can be achieved,this mode is often unwieldy or harmful to intrinsic physiologic functions in cases.3 For this reason,we attempt to develop new ways for in vivo antioxidation,for establishing a high-quality balance between efficiency and safety.As the consequence,we innovated a gene expression system that can limit the excessive ROS accumulation but keep the physiological level of ROS.

关键词： evoked aging effect

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Soil-Air Partitioning of Polychlorinated Biphenyls and Total Dichloro-Diphenyl-Trichloroethanes

引用

Journal of Earth Science 2014年第4期25卷 741-748页

作者： Yaping Zhang Erping Bi honghan chen School of Water Resources and Environment China University of Geosciences (Beijing) Beijing Key Laboratory of Water Resources and Environment Engineering China University of Geosciences (Beijing)

Soil-air partitioning is an important diffusive process that affects the environmental fate of organic compounds and human health. In this review, factors affecting the soil-air partitioning of polychlorinated biphenyls （PCBs） and total dichloro-diphenyl-trichloroethanes （p,p＇- and o,p＇- isomers of DDT, DDD, and DDE） are discussed. Hydrophobicity is an important factor that influences soil-air partition coefficients （KsA）, and its effect can be explained through enthalpy of phase change for soil-air partitioning transfer （AHsA）. For more hydrophobic compounds, a sharp increase in the KSA of PCBs and organochlorines can be seen in the early aging period. During the aging period, the temperature has a significant effect on the more hydrophobic organic compounds. The content and properties of soil or- ganic matter influence the KSA of the target compounds. Generally, KSA decreases with increasing rela- tive humidity in soils. The linear trend between KSA and temperature （T） changes at 0 ~C. Freezing the air or soil in experiments would change the research results. On the basis of factors influencing soil-air partitioning, a multipleparameter （T, organic carbon fraction （foe）, and octanol-air partition coefficient （KoA）） model is put forward to predict the KSA values for PCBs and total DDTs.

关键词： soil-air interface partition sorption polychlorinated biphenyl （PCB） dichloro-diphenyltrichloroethanes （DDT）.

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

miR-146a impedes the anti-aging effect of AMPK via NAMPT suppression and NAD^(+)/SIRT inactivation

引用

Signal Transduction and Targeted Therapy 2022年第4期7卷 1181-1193页

作者： Hui Gong honghan chen Peng Xiao Ning Huang Xiaojuan Han Jian Zhang Yu Yang Tiepeng Li Tingting Zhao Haoran Tai Weitong Xu Gongchang Zhang Chuhui Gong Ming Yang Xiaoqiang Tang Hengyi Xiao The Lab of Aging Research National Clinical Research Center for GeriatricsState Key Laboratory of BiotherapyWest China HospitalSichuan University1 Keyuan 4 RoadGaopeng AvenueChengdu 610093China Key Laboratory of Birth Defects and Related Diseases of Women and Children of MOE State Key Laboratory of BiotherapyWest China Second University HospitalSichuan UniversityChengdu 610041China

Nicotinamide adenine dinucleotide(NAD^(+))is indispensable for the anti-aging activity of the sirtuin(SIRT)family enzymes.AMPactivated protein kinase(AMPK)upregulates NAD^(+)synthesis and SIRT activity in a nicotinamide phosphoribosyltransferase(NAMPT)-dependent manner.However,the molecular mechanisms that affect AMPK-driven NAMPT expression and NAD^(+)/SIRT activation remain unclear.In this study,we tried to identify senescence-associated microRNAs(miRNAs)that negatively regulate the cascade linking AMPK and NAMPT expression.miRNA-screening experiments showed that the expression of miR-146a increased in senescent cells but decreased following AMPK activation.Additionally,miR-146a overexpression weakened the metforminmediated upregulation of NAMPT expression,NAD^(+)synthesis,SIRT activity,and senescence protection,whereas treatment with the miR-146a inhibitor reversed this effect.Importantly,these findings were observed both in vitro and in vivo.Mechanistically,miR146a directly targeted the 3′-UTR of Nampt mRNA to reduce the expression of NAMPT.AMPK activators metformin and 5-aminoimidazole-4-carboxamide(AICAR)hindered miR-146a expression at the transcriptional level by promoting IκB kinase(IKK)phosphorylation to attenuate nuclear factor-kappaB(NF-κB)activity.These findings identified a novel cascade that negatively regulates the NAD^(+)/SIRT pathway by suppressing miR-146a-mediated NAMPT downregulation.Furthermore,our results showed that miR-146a impedes the anti-aging effect of AMPK.This mutual inhibitory relationship between miR-146a and AMPK enriches our understanding of the molecular connections between AMPK and SIRT and provides new insight into miRNA-mediated NAD^(+)/SIRT regulation and an intervention point for the prevention of aging and age-related diseases.

关键词： miR NAMPT prevention

来源：

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Mixing Characteristics of Oil Inclusions with Different Thermal Maturities in the Wenliu Uplift,Dongpu Depression,Bohai Bay Basin,North China

引用

Journal of Earth Science 2020年第6期31卷 1251-1258页

作者： Xiuyan Liu honghan chen Xuewei Xiao Hongan Zhang Tianwu Xu Key Laboratory of Tectonics and Petroleum Resources of Ministry of Education China University of GeosciencesWuhan 430074China Zhongyuan Oilfield Company SINOPECPuyang 457001China

Multiple types of oil inclusions with different fluorescence colors have been detected in the northern Dongpu depression.Recent evidences show that these inclusions may have been trapped simultaneously or during a very short period.Therefore,whether these oils were mixed before trapping is unknown.In this study,we analyzed the petrography and fluorescence spectral characteristics of oil inclusions in the Wenliu uplift in the northern Dongpu depression,and assessed the data with the oil mixing ratio curve obtained in the previous experiment.The results show that there are three types of oil inclusions(type I,type II and type III)with yellow,green and blue fluorescence colors,corresponding to low-mature,medium-mature and high-mature oil,respectively.The"pure"oil inclusions,do exist in type II and type III group of oil inclusions,showing the medium-mature oil was generated from the source rock rather than being formed by the mixture of high-mature and low-mature end oils.Most of the oil inclusions are mixtures of high-mature and medium-mature end oils from the sub-sags to the Wenliu uplift,the mixing degree increases to close to 50%.The oil between the Qianliyuan sub-sag and the Wenliu uplift was mainly mixed by medium mature oils,whereas the oil between the Liutun sub-sag and the Wenliu uplift was mainly mixed by high mature oil.

关键词： petroleum geology fluorescence spectra oil mixing ratio oil mixing experiment

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

Evolution Characteristics and Influence Factors of Deep Groundwater Depression Cone in North China Plain,China——A Case Studyin Cangzhou Region

引用

Journal of Earth Science 2014年第6期25卷 1051-1058页

作者： Yasong Li Fawang Zhang Zhantao Han Ping Wang honghan chen Zhaoji Zhang School of Water Resources & Environment China University of Geosciences Institute of Hydrogeology and Environmental Geology Chinese Academy of Geological Sciences Institute of Karst Geology Chinese Academy of Geological Sciences

The North China Plain（NCP） is one of the global hotspots of groundwater depletion, groundwater is almost the only source of water for agricultural, industrial and drinking water in this region. After long-term＇s over-exploitation of deep groundwater, there appeared several deep groundwater depression cones, such as Cangzhou cone, Dezhou cone, Hengshui cone, Tianjin cone, etc., in which the Cangzhou cone is one of the typical cones for its special geography and hydrogeology conditions. In this study, the authors intended to analyze the evolution characteristics and influence factors of deep groundwater depression cone in Cangzhou region, especially the No. III aquifer depression cone, which is the main exploitation zone in this region. Analysis of the evolution of the groundwater depression cone of the No. III aquifer group in Cangzhou region showed that this process can be divided into four stages, namely, development, stable development, rapid expansion, and gradual recovery. The shape and evolution characteristics of the depression cone at different stages are described by analyzing the evolution of the-30,-40, and-50 contours of the groundwater table, for example the closed area of water table contour of-50 m has been enlarged from 95 km2 in 1985 to 6 528.5 km2 in 2005. The dominant factors that affect the evolution characteristics at different stages are proposed. The results showed that relatively long dry periods with less precipitation, special geological and hydrogeological conditions, and sharply increased water consumption for industrial and agricultural development are the main factors that cause the formation of deep groundwater depression cones. Meanwhile, an environmental response against groundwater exploitation is presented, and rational solutions are suggested to avert water crisis.

关键词： depression cone,water table contour,groundwater consumption,dynamic monitoring,North China Plain

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

鄂尔多斯盆地南缘泾河油田长7段烃源岩生、排烃期与油气成藏期对比

引用

地质科技通报 2024年第1期43卷 108-121页

作者：张新乐平宏伟杨鑫陈红汉李纯泉何发岐齐荣中国地质大学(武汉)构造与油气资源教育部重点实验室武汉430074 中国石化华北油气分公司郑州450006

泾河油田位于鄂尔多斯盆地西南部,目前已发现的油气主要位于研究区东北部,前人研究表明原油主要来自延长组长7段油页岩,然而原油到底来自研究区还是其东北部盆地中心的烃源岩还未有定论,从而制约了泾河油田的下一步勘探。利用盆地模拟方... 详细信息

泾河油田位于鄂尔多斯盆地西南部,目前已发现的油气主要位于研究区东北部,前人研究表明原油主要来自延长组长7段油页岩,然而原油到底来自研究区还是其东北部盆地中心的烃源岩还未有定论,从而制约了泾河油田的下一步勘探。利用盆地模拟方法,模拟了研究区和盆地中心长7段烃源岩生、排烃史,确定了泾河油田不同构造部位长7段烃源岩的生、排烃时间,并结合流体包裹体技术厘定了延长组储层原油成藏期次。烃源岩生、排烃时间和储层原油成藏时间以及生、排烃量的计算结果显示,泾河油田长7段烃源岩对本区油气成藏贡献有限,而盆地中心烃源岩生、排烃时间与研究区油气成藏时间具有很好的对应关系,并且本区油气明显具有由东北部向西南部运移的特点。因此与普遍认为的延长组储层以近源短距离垂向运移为主的成藏特征不同,本区已发现油藏可能主要来源于其东北部盆地中心优势生、排烃区,沿走滑断裂带经历了一定距离的侧向运移后聚集成藏。研究结果可为下一步研究区有利运聚方向及成藏区带预测提供重要参考。

关键词：盆地模拟流体包裹体热史埋藏史油气运移烃源岩

来源：

维普期刊数据库

同方期刊数据库评论

在线全文

学校读者我要写书评

暂无评论

欢迎您,

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案：

请选择收藏分类：

通借通还

欢迎您,

建议与咨询 留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

时间限定

文献类型

馆藏选择

核心期刊

语言

文献类型

帮助

文字说明：

检索规则说明：

检索范例：

分类表

所选分类

限定检索结果

文献类型

馆藏范围

日期分布

学科分类号

主题

机构

作者

语言

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

在线全文

请选择保存的检索档案： 新增检索档案 确定 取消

请选择收藏分类： 新增自定义分类 确定 取消

通借通还

建议与咨询留下您的常用邮箱和电话号码，以便我们向您反馈解决方案和替代方法

请选择保存的检索档案：

请选择收藏分类：