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Highly uniform Co-Cu bimetallic sulfides for rechargeable alkaline aqueous zinc batteries

Chinese Chemical Letters 2024年第2期35卷 521-526页

作者： Xiaofang Bai Yuwei Zhao Mangwei Cui Tianshuo Guo Zijie Tang Chuan Li Heng Gao Shuo yang Lingzhi Zhao Chunyi Zhi hongfei Li Department of Materials Science and Engineering Southern University of Science and TechnologyShenzhen 518055China Songshan Lake Materials Laboratory Dongguan 523808China Department of Materials Science and Engineering City University of Hong KongHong KongChina International Centre for Quantum and Molecular Structures Department of PhysicsShanghai UniversityShanghai 200444China Guangdong Provincial Engineering Technology Research Center for Low Carbon and Advanced Energy Materials Institute of Semiconductor Science and TechnologySouth China Normal UniversityGuangzhou 510631China

Rechargeable alkaline aqueous zinc batteries(RAZBs)have attracted increasing attention.However,most RAZBs are hindered by the limited availability of cathode materials.The practical electrochemical performance of most cathode materials is lower than the theoretical value due to their poor electrical conductivity and low utilization capacity.In this work,we develop a facile hydrothermal procedure to prepare highly uniform bimetallic sulfides as novel cathode materials for RAZBs.Copper-cobalt binary metallic oxides materials possess higher conductivity and larger capacity compared with their mono-metal oxides compounds due to bimetallic synergistic effects and multiple oxidation states.Furthermore,bimetallic sulfide compounds have smaller bond energy and longer bond length than their oxides,leading to less structural damage,faster kinetics of electrochemical reactions,and better stability.The as-prepared Co-Cu bimetallic sulfides show enhanced electrochemical performance due to various valences of Co and Cu as well as the existence of S.As a result,aqueous Zn/CuCo_(2)S_(4) battery shows a high specific capacity of 117.4 mAh/g at 4 A/g and a good cycle life of over 8000 cycles.Based on PANa hydrogel electrolytes,a flexible Zn/CuCo_(2)S_(4) battery demonstrates excellent cycling stability.This battery can also meet the requirements of electronic devices with different shapes and performs well in extreme environments,such as freezing,drilling,and hammering.This work opens new avenues to obtain high-rate and long-life cathode materials for RAZBs by utilizing the synergistic effects of bimetallic sulfides and provides a new platform for flexible energy storage devices.

关键词： Aqueous zinc batteries Bimetallic sulfides Cathode materials Rate performance Cycling stability

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Boosting the cycling stability of all-solid-state lithium metal batteries through MOF-based polymeric protective layers

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Journal of Energy Chemistry 2024年第8期95卷 511-518页

作者： hongfei Bao Diancheng Chen Jiaqi Cao Pengfeng Jiang Kaili Li Runtao Liu Yuling Zhao Yichun Zheng Beiqi Liao Yaming Zhang Xia Lu yang Sun School of Materials Shenzhen Campus of Sun Yat-sen University

Solid-state electrolytes（SSEs） play a pivotal role in advancing next-generation lithium metal battery technology.However,they commonly encounter substantial interfacial resistance and poor stability when interfacing with lithium metal,hindering practical applications.Herein,we introduce a flexible metal-organic framework（MOF:NUS-6）-incorporated polymeric layer,denoted as NP,designed to protect the sodium superionic conductor（NASICON）-type Li1.3Al0.3Ti1.7（PO4）3（LATP） electrolyte from Li metal anodes.The NP matrix establishes a soft interface with the LATP surface,effectively reducing voids and gaps that may arise between the LATP electrolyte and Li metal.Moreover,the MOF component in NP enhances ionic conductivity,offers abundant Li+transport sites,and provides hierarchical ion channels,ensuring a homogeneous Li+flow and thus effectively inhibiting Li dendrite formation.Utilizing NP,we fabricate Li symmetrical cells cycled for over 1600 h at 0.2 mA cm-2and all-solid-state LiINP-LATPI LiFePO4batteries,achieving a remarkable 99.3% capacity retention after 200 cycles at 0.2 C.This work outlines a general strategy for designing long-lasting and stable solid-state Li metal batteries.

关键词： All-solid-state Li metal battery Interfacial contact LATP electrolyte stability Li dendrite MOF-based polymeric layer

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Enabling an Inorganic-Rich Interface via Cationic Surfactant for High-Performance Lithium Metal Batteries

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Nano-Micro Letters 2024年第8期16卷 1-17页

作者： Zejun Sun Jinlin yang hongfei Xu Chonglai Jiang Yuxiang Niu Xu Lian Yuan Liu Ruiqi Su Dayu Liu Yu Long Meng Wang Jingyu Mao Haotian yang Baihua Cui Yukun Xiao Ganwen Chen Qi Zhang Zhenxiang Xing Jisheng Pan Gang Wu Wei Chen Department of Chemistry National University of Singapore3 Science Drive 3Singapore 117543Singapore Agency for Science Technology and Research(A*STAR)Institute of High-Performance Computing1 Fusionopolis Way#16‑16 ConnexisSingapore 138632Singapore Department of Physics National University of Singapore2 Science Drive 3Singapore 117542Singapore Joint School of National University of Singapore and Tianjin University International Campus of Tianjin UniversityBinhai New CityFuzhou 350207People’s Republic of China Agency for Science Technologyand Research(A*STAR)Institute of Materials Research and EngineeringInnovis2 Fusionopolis Way#08‑03Singapore 138634Singapore

An anion-rich electric double layer(EDL)region is favorable for fabricating an inorganic-rich solid-electrolyte interphase(SEI)towards stable lithium metal anode in ester electrolyte.Herein,cetyltrimethylammonium bromide(CTAB),a cationic surfactant,is adopted to draw more anions into EDL by ionic interactions that shield the repelling force on anions during lithium plating.In situ electrochemical surface-enhanced Raman spectroscopy results combined with molecular dynamics simulations validate the enrichment of NO_(3)^(−)/FSI−anions in the EDL region due to the positively charged CTA^(+).In-depth analysis of SEI structure by X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectrometry results confirmed the formation of the inorganic-rich SEI,which helps improve the kinetics of Li^(+)transfer,lower the charge transfer activation energy,and homogenize Li deposition.As a result,the Li||Li symmetric cell in the designed electrolyte displays a prolongated cycling time from 500 to 1300 h compared to that in the blank electrolyte at 0.5 mA cm^(-2) with a capacity of 1 mAh cm^(-2).Moreover,Li||LiFePO_(4) and Li||LiCoO_(2) with a high cathode mass loading of>10 mg cm^(-2) can be stably cycled over 180 cycles.

关键词： Cationic surfactant Lithium nitrate additive Solid-electrolyte interphase Electric double layer Lithium metal batteries

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Spatio-temporal dynamics of vegetation and its relationship with climate factors Mongolia, China coverage in Inner

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Journal of Geographical Sciences 2013年第2期23卷 231-246页

作者： MU Shaojie yang hongfei LI Jianlong CHEN Yizhao GANG Chengcheng ZHOU Wei JU Weimin SchoolofLifeScience NamingUniversityNanjing210093China InternationalInstituteforEarth-SystemScience N-anjinguniversityNanjing210093China

The vegetation coverage dynamics and its relationship with climate factors on different spatial and temporal scales in Inner Mongolia during 2001-2010 were analyzed based on MODIS-NDVI data and climate data. The results indicated that vegetation coverage in Inner Mongolia showed obvious longitudinal zonality, increasing from west to east across the region with a change rate of 0.2/10N. During 2001-2010, the mean vegetation coverage was 0.57, 0.4 and 0.16 in forest, grassland and desert biome, respectively, exhibiting evident spatial heterogeneities. Totally, vegetation coverage had a slight increasing trend during the study period. Across Inner Mongolia, the area of which the vegetation coverage showed extremely significant and significant increase accounted for 11.25% and 29.13% of the area of whole region, respectively, while the area of which the vegetation coverage showed extremely significant and significant decrease accounted for 7.65% and 26.61%, respectively. On interannual time scale, precipitation was the dominant driving force of vegetation coverage for the whole region. On inter-monthly scale, the change of vegetation coverage was consistent with both the change of temperature and precipitation, implying that the vegetation growth within a year is more sensitive to the combined effects of water and heat rather than either single climate factor. The vegetation coverage in forest biome was mainly driven by temperature on both inter-annual and inter-monthly scales, while that in desert biome was mainly influenced by precipitation on both the two temporal scales. In grassland biome, the yearly vegetation coverage had a better correlation with precipitation, while the monthly vegetation coverage was influenced by both temperature and precipitation. In grassland bi- ome, the impacts of precipitation on monthly vegetation coverage showed time-delay effects.

关键词： Inner Mongolia vegetation coverage precipitation temperature correlation

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青龙寺煤矿智能矿山研究与实践

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工矿自动化 2022年第S2期48卷 37-41页

作者：杨宏飞国能榆林能源有限责任公司青龙寺煤矿分公司陕西榆林719000

在煤矿智能化建设过程中,青龙寺煤矿以加快推进煤矿智能化建设为目标,加快推荐智能化建设工作。从煤矿的信息化存在孤岛、多系统多平台、采掘环节低效、多人、主运与辅运环节复杂、主运与辅运环节复杂4个方面分析了青龙寺煤矿智能矿山... 详细信息

在煤矿智能化建设过程中,青龙寺煤矿以加快推进煤矿智能化建设为目标,加快推荐智能化建设工作。从煤矿的信息化存在孤岛、多系统多平台、采掘环节低效、多人、主运与辅运环节复杂、主运与辅运环节复杂4个方面分析了青龙寺煤矿智能矿山建设过程中存在的难题。从智能矿山平台实现数据融合、管控一体化、智能采掘关键技术与装备研究、智能主辅运输关键技术与装备研究、智能辅助系统关键技术与装备研究、基于一体化通信及位置服务的智能矿山安全保障关键技术与装备研究5个方面分享了青龙寺煤矿智能矿山的建设经验。从一体化通信及位置服务、智能主运、智能辅运、智能供排水系统、管控平台5个方面对青龙寺智能矿山创新成果进行了展望。

关键词：智能化一体化位置服务数据融合智能平台智能采掘

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Long-Range Electronic Effect-Promoted Ring-Opening Polymerization of Thioctic Acid to Produce Biomimetic Ionic Elastomers for Bioelectronics

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CCS Chemistry 2024年第3期6卷 761-773页

作者： hongfei Huang Huijing Wang Lijie Sun Ruohan Zhang Luzhi Zhang ZekaiWu Yaxuan Zheng yang Wang Wei Fu Youwei Zhang Rasoul Esmaeely Neisiany Zhengwei You State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Materials Science and EngineeringInstitute of Functional MaterialsDonghua UniversityResearch Base of Textile Materials for Flexible Electronics and Biomedical Applications(China Textile Engineering Society)Shanghai Engineering Research Center of Nano-Biomaterials and Regenerative MedicineShanghai 201620 Institute of Pediatric Translational Medicine Shanghai Children’s Medical CenterSchool of MedicineShanghai Jiao Tong UniversityShanghai 200127 Department of Materials and Polymer Engineering Faculty of EngineeringHakim Sabzevari UniversitySabzevar ***

Poly(disulfide)s have been widely used in flexible wearable electronics,smart materials,and drug delivery.The synthesis of poly(disulfide)s usually utilizes external stimuli or toxic initiators to promote the polymerization.Here,we indicated that the long-range electronic effect can significantly alter the reactivity of the disulfide group.Accordingly,we established deprotonation-promoted ring-opening polymerization of thioctic acid(TA)as a highly effective and simple method to synthesize poly(disulfide)s due to the long-range electronic effect and nucleophilic carboxylate.Without external stimuli and initiators,simple mixing of TA and deprotonation reagent,choline bicarbonate,in different ratios at room temperature rapidly produced a series of high molecular weight(up to 772 kDa)ionic liquid crystal poly(disulfide)s elastomers with room temperature self-healing ability,adjustable conductivity(2.39×10^(−2)∼0.28×10^(−2)S m^(−1)),degradability,biocompatibility,antibacterial property,and tissue-like softness(Young’s moduli ranging from 18.2±6.0 to 111.1±36.7 kPa).The experiments and density functional theory calculations also revealed the principle of long-range electronic effect to establish a new synthetic strategy of poly(disulfide)s with superior properties favorable for bioelectronics.

关键词： self-healing elastomers thioctic acid ionic liquid bioelectronics

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Spatial-temporal shifting patterns and in situ conservation of spotted seal(Phoca largha)populations in the Yellow Sea ecoregion

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Integrative Zoology 2024年第2期19卷 307-318页

作者： hongfei ZHUANG Fei SHAO Chao ZHANG Wancai XIA Shouqiang WANG Fangyuan QU Zongling WANG Zhichuang LU Linlin ZHAO Zhaohui ZHANG First Institute of Oceanography Ministry of Natural ResourcesQingdaoChina Department of Natural Resources of Shandong Province Shandong Forestry Protection and Development Service CenterJinanChina National Park(Protected Areas)Development Center National Forestry and Grassland AdministrationBeijingChina College of Life Science China West Normal UniversityNanchongChina Liaoning Ocean and Fisheries Science Research Institute DalianChina

Understanding the habitat shifting pattern is a prerequisite for implementing in situ conservation of migratory species.Spotted seals(Phoca largha)inhabiting the Yellow Sea ecoregion(YSE)comprise a small population with independent genes and represent a charismatic flagship species in this region.However,this population has declined by 80%since the 1940s,and increased support from the countries around the YSE is urgently needed to address the potential local extinction risk.A time-series niche model and life-history weighted systematic conservation planning were designed on the basis of a satellite beacon tracking survey(2010–2020)of the YSE population.The results showed clustering and spreading shifting patterns during the breeding and migratory seasons,respectively.The closed-loop migration route formed in the YSE indicated that this population might be geographically isolated from populations in other breeding areas around the world.The conservation priority area(CPA),with an area of 19632 km^(2)(3.58%of the total YSE area),was the most effective response to the potential in situ risk.However,nearly 80%of the CPA was exposed outside the existing marine protected areas(MPAs).Future establishment of MPAs in China should strategically consider the conservation gap identified herein,and it is recommended for Korea’s closed fishing season to be spatially set in the western Korean Peninsula from May to August.This study also exemplified that the lack of temporal information would lead to the dislocation of niche modeling for migratory species represented by spotted seals.Attention should be paid to protecting small and migratory populations in marine biodiversity conservation planning.

关键词： conservation priority area marine protected area migration seasonal management spotted seal

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Enhanced electrochemical performance of Li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3) solid electrolyte by anion doping

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Nano Research 2024年第3期17卷 1465-1472页

作者： Jingrui Kang Xu Guo Rui Gu Honglei Hao Yi Tang Jiahui Wang Li Jin hongfei Li Xiaoyong Wei Electronic Materials Research Laboratory Key Laboratory of the Ministry of Education&International Center for Dielectric ResearchSchool of Electronic and Information EngineeringXi’an Jiaotong UniversityXi’an 710049China School of Energy and Materials Shanghai Key Laboratory of Engineering Materials Application and EvaluationShanghai Polytechnic UniversityShanghai 201209China

Nowadays,the majority of the studies on the substitution are focused on cations(such as Y^(3+),Ti^(4+),P^(5+),etc.)in Li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3)(LATP),while there are few studies on the substitution of anion O^(2-).In this work,the modified LATP with a series of LiCl(LATPClx,x=0.1,0.2,0.3,0.4)additives is prepared to enhance ionic conductivity.The successful introduction of Cl-makes the length of the c axis decrease from 20.822(2)to 20.792(1)Å,and the bulk conductivity of 2.13×10^(-3) S·cm^(-1) is achieved in LATPCl_(0.3).Moreover,the Al/Ti-O1/Cl1 and Al/Ti-O_(2)/Cl_(2) distance decrease,while the Li1-O_(2)/Cl_(2) distance increases.Lithium ions migrate more easily in the nanochannel of M3-M1-M3.In addition,the LiCl additive increases the relative density and the grain boundary conductivity of LATPClx compounds.Naturally,a higher ionic conductivity of 2.12×10^(–4) S·cm^(-1) and a low activation energy of 0.30 eV are obtained in LATPCl_(0.3).Correspondingly,the symmetric cell exhibits a low overpotential of±50 mV for over 200 h in LATPCl_(0.3).The solid-state Li|LATPCl_(0.3)|NCM811(NCM811=LiNi0.8Co0.1Mn0.1O_(2))battery exhibits high initial capacity 185.1 mAh·g^(-1) with a capacity retention rate of 95.4%after 100 cycles at 0.5 C.This result suggests that LiCl additive is an effective strategy to promote electrochemical properties of LATP solid electrolyte and can be considered for reference to other inorganic solid electrolytes systems.

关键词： Li_(1.3)Al_(0.3)Ti_(1.7)(PO_(4))_(3)(LATP)solid electrolyte anion doping ionic conductivity cyclic performance

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COLOR REPRODUCTION BETWEEN CRT DISPLAYS ＆ USE OF COLOR APPEARANCE MODELS

COLOR REPRODUCTION BETWEEN CRT DISPLAYS ＆ USE OF COLOR APPE...

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26th Session of the CIE

作者： Shi Junsheng Yu hongfei yang Weiping School of Physics & Electronic Information Yunnan Normal University Kunming 650092 China

＜正＞In this paper,color reproduction between CRT displays with different white points in dark entironment using three transforms of color appearance of CIECAM02 and CIELAB,and direct matching of tristimulate values was experimentally investigated.The reproduction performances of three model predictions were compared by theoretical calculation and visual evaluation. Theoretical calculation was for the magnitudes of color difference between original display color and reproduction of the twenty-four color patches of Macbeth ColorChecker in different color formulae CIEDE2000 and ones in color spaces of CIELAB and CIECAM02.Experiemntal results showed that:（1）average color difference of reproduction was 0.46,6.72 and 11.07 in unit of CIECAM02 color difference respectively using three model predictions,which was consistent with one of visual evaluation;（2）color difference formula in CIECAM02 color space had better performance than CIELAB color space and CIEDE2000 for evaluating color difference between different viewing entironments;（3）compared with color difference of the transform of color appearance,one of display characterization was smaller,only 0.90 in unit of CIEDE2000,but display characterization for colors with low luminance is a key in color reproduction between displays.

关键词： Color reproduction CIECAM02 CIELAB CRT display Display characterization

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Dielectric polymer grafted electrodes enhanced aqueous supercapacitors

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Nano Research 2024年第3期17卷 1525-1534页

作者： Shian Dong Kunming Shi Jie Chen Yingke Zhu hongfei Li Weihang Gao Zhenli Xu Qinglei Liu Xingyi Huang Shanghai Key Laboratory of Electrical Insulation and Thermal Aging Department of Polymer Science and EngineeringState Key Laboratory of Metal Matrix CompositesShanghai Jiao Tong UniversityShanghai 200240China School of Mathematical Sciences Institute of Natural Sciences and MOE−LSCShanghai Jiao Tong UniversityShanghai 200240China State Key Laboratory of Metal Matrix Composites Shanghai Jiao Tong UniversityShanghai 200240China

Supercapacitors(SCs)have become increasingly important in electrical energy storage and delivery owing to their high power densities and long lifetimes.Aqueous SCs are promising for large-scale engineering applications because of their low cost and safety.However,the low operating voltage and low energy density of aqueous SCs severely limit their practical applications.In this study,a nanoscale dielectric layer is grafted onto a graphene electrode to achieve both a high operating voltage and enhanced capacitance.Compared with an SC without dielectric grafting,a dielectric-enhanced SC(DESC)shows a higher capacitance by 2200%.The mechanism of the capacitance enhancement can be attributed to three factors:the dielectric polarization,the ions desolvation by the dielectric,and the enhanced quantum capacitance from charge transfer and ion adsorption in the polymer molecules.In addition,a 2.5 V pouch DESC with a 1 M KCl electrolyte is confirmed to cycle up to 50,000 times with a capacitance retention of 87.5%.The DESC presents the optimal electrochemical properties after it is grafted with a 5 nm dielectric layer.This study provides new insights into the design of high-voltage and high-energy-density aqueous SCs.

关键词： supercapacitors dielectric polymer high voltage capacitance enhancement

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