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Analysis and comparison of retinal vascular parameters under different glucose metabolic status based on deep learning

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International Journal of Ophthalmology(English edition) 2024年第9期17卷 1581-1591页

作者： Yan Jiang Di Gong Xiao-hong Chen Lin Yang Jing-Jing Xu Qi-Jie wei Bin-Bin Chen Yong-Jiang cai Wen-Qun Xi Zhe Zhang Departments of Laboratory Medicine the Second Affiliated HospitalZhejiang University School of MedicineHangzhou 310009Zhejiang ProvinceChina Shenzhen Eye Hospital Jinan UniversityShenzhen 518040Guangdong ProvinceChina Center of Health Management Peking University Shenzhen HospitalShenzhen 518036Guangdong ProvinceChina Visionary Intelligence Ltd. Beijing 100080China Ophthalmology Center the Second Affiliated HospitalZhejiang University School of MedicineHangzhou 310009Zhejiang ProvinceChina

AIM:To develop a deep learning-based model for automatic retinal vascular segmentation,analyzing and comparing parameters under diverse glucose metabolic status(normal,prediabetes,diabetes)and to assess the potential of artificial intelligence(AI)in image segmentation and retinal vascular parameters for predicting prediabetes and ***:Retinal fundus photos from 200 normal individuals,200 prediabetic patients,and 200 diabetic patients(600 eyes in total)were *** U-Net network served as the foundational architecture for retinal arteryvein *** automatic segmentation and evaluation system for retinal vascular parameters was trained,encompassing 26 ***:Significant differences were found in retinal vascular parameters across normal,prediabetes,and diabetes groups,including artery diameter(P=0.008),fractal dimension(P=0.000),vein curvature(P=0.003),C-zone artery branching vessel count(P=0.049),C-zone vein branching vessel count(P=0.041),artery branching angle(P=0.005),vein branching angle(P=0.001),artery angle asymmetry degree(P=0.003),vessel length density(P=0.000),and vessel area density(P=0.000),totaling 10 ***:The deep learning-based model facilitates retinal vascular parameter identification and quantification,revealing significant *** parameters exhibit potential as biomarkers for prediabetes and diabetes.

关键词： deep learning retinal vascular parameters segmentation model diabetes prediabetes

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Gel-Based Triboelectric Nanogenerators for Flexible Sensing:Principles,Properties,and Applications

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Nano-Micro Letters 2024年第10期16卷 257-303页

作者： Peng Lu Xiaofang Liao Xiaoyao Guo Chenchen cai Yanhua Liu Mingchao Chi Guoli Du Zhiting wei Xiangjiang Meng Shuangxi Nie School of Light Industry and Food Engineering Guangxi UniversityNanning 530004People's Republic of China Beijing Institute of Nanoenergy and Nanosystems Chinese Academy of SciencesBeijing 101400People's Republic of China

The rapid development of the Internet of Things and artificial intelligence technologies has increased the need for wearable,portable,and self-powered flexible sensing *** nanogenerators(TENGs)based on gel materials(with excellent conductivity,mechanical tunability,environmental adaptability,and biocompatibility)are considered an advanced approach for developing a new generation of flexible *** review comprehensively summarizes the recent advances in gel-based TENGs for flexible sensors,covering their principles,properties,and *** on the development requirements for flexible sensors,the working mechanism of gel-based TENGs and the characteristic advantages of gels are *** strategies for the performance optimization of hydrogel-,organogel-,and aerogel-based TENGs are systematically *** addition,the applications of gel-based TENGs in human motion sensing,tactile sensing,health monitoring,environmental monitoring,human-machine interaction,and other related fields are ***,the challenges of gel-based TENGs for flexible sensing are discussed,and feasible strategies are proposed to guide future research.

关键词： Triboelectric nanogenerators Gel materials Triboelectric materials Flexible sensing

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基于5 μm厚向列相液晶的高效圆极化相控阵系统的设计、校准和实验验证

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Engineering 2024年第1期32卷 69-81页

作者： Xin Yu Wu Fengshuo Wan hongyuan Feng Shichao Jin Chong Guo Yu wei Dunge Liu Yuqian Yang Longzhu cai Zhi Hao Jiang wei hong State Key Laboratory of Millimeter Waves School ofInformation Science and Engineering Southeast UniversityNanjing 210096China State Key Laboratory of Space-Ground Integrated Information Technology Beijing Institute of Satellite Information Engineering Beijing 100095China Research Institute of Millimeter-Wave and Terahertz Technology(RIMMATT) Nanjing 211111China

This paper presents a systematic investigation and demonstration of a K-band circularly polarized liquidcrystal-based phased array(LCPA),including the design,over-the-air(OTA)in-array calibration,and experimental *** LCPA contains 16 phase-shifting radiating channels,each consisting of a circularly polarized stacked patch antenna and a liquid-crystal-based phase shifter(LCPS)based on a loaded differential line *** to its slow-wave properties,the LCPS exhibits a maximum phase-shifting range of more than 360°with a figure of merit of 78.3(°)·dB^(-1)based on a liquid crystal layer with a thickness of only 5μ***,an automatic OTA calibration based on a state ergodic method is proposed,which enables the extraction of the phase-voltage curve of every individual LCPA *** proposed LCPA is manufactured and characterized with a total profile of only 1.76 mm,experimentally demonstrating a scanned circularly polarized beam from-40°to+40°with a measured peak gain of 12.5 dBic and a scanning loss of less than 2.5 *** bandwidth of the LCPA,which satisfies the require-ments of port reflection(|S_(11)|)<-15 dB,an axial ratio(AR)<3 dB,beam squinting<3°,and a gain variation<2.2 dB,spans from 25.5 to 26.0 *** total efficiency is about 34%,which represents a new state of the *** use of the demonstrated low-profile LCPA to support circularly polarized scanning beams,along with the systematic design and calibration methodology,holds potential promise for a variety of millimeter-wave applications.

关键词： Circularly polarized Liquid crystal Liquid-crystal based phased array(LCPA) Phase shifter Over-the-air(OTA)calibration

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Two new high-temperature molecular ferroelectrics[1,5-3.2.2-Hdabcn]X(X=ClO_(4)^(-),ReO_(4)^(-))

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Chinese Chemical Letters 2024年第6期35卷 234-238页

作者： Keke Han Wenjun Rao Xiuli You Haina Zhang Xing Ye Zhenhong wei Hu cai School of Chemistry and Chemical Engineering Nanchang UniversityNanchang 330031China Jiangxi Key laboratory of Organic Chemistry Jiangxi Science and Technology Normal UniversityNanchang 330013China

Molecular ferroelectrics have attracted much attention because of their excellent piezoelectricity,mechanical workability,and second harmonic ***,we successfully prepared two molecular ferroelectrics[1,5-3.2.2-Hdabcn]X(X=ClO_(4)^(-),1;ReO_(4)^(-),2)by reactions of a quasi-spherical amine 1,5-diazabicycle[3.2.2]nonane(1.5-3.2.2-dabcn)with HX aqueous *** 1 and 2 undergo hightemperature phase transitions at 381 K(1)and 396 K(2).Before and after the phase transition,they crystallize in the polar point group mm2,and the centrosymmetric point groups mmm and 4/mmm,*** to Aizu rules,these two compounds experience mmm Fmm2 and 4/mmm Fmm2 type ferroelectric phase transitions,*** ferroelectricity of both compounds is well expressed in their polycrystalline film at room temperature with low coercive voltages of 13 V for 1 and 25 V for *** piezoelectric force microscopy(PFM),the 180°anti-parallel ferroelectric domains and the reversible polarization switching can be clearly observed in 1 and *** high-temperature molecular ferroelectric material has great application potential in flexible materials,biomechanics,intelligent wearables and other fields.

关键词： Ferroelectric domains Quasi-spherical amine Phase transition Polarization

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Galvanostatic method assembled ZIFs nanostructure as novel nanozyme for the glucose oxidation and biosensing

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Chinese Chemical Letters 2024年第9期35卷 279-283页

作者： Erzhuo Cheng Yunyi Li wei Yuan wei Gong Yanjun cai Yuan Gu Yong Jiang Yu Chen Jingxi Zhang Guangquan Mo Bin Yang The Fourth Affiliated Hospital of Guangzhou Medical University School of Biomedical EngineeringGuangzhou Medical UniversityGuangzhou 511436China Department of Nephrology First Affiliated Hospital of Jinan UniversityGuangzhou 510630China Department of Oncology Xiangyang Central Hospital of Hubei University of Arts and ScienceXiangyang 441000China

Recently,the composite of soft conductive substrates,such as carbon fiber(CF),with metal-organic frameworks(MOFs)has been employed in a myriad of *** composite material has demonstrated exceptional potential in the realm of electrochemical sensing ***,the rapid growth of MOFs on the surface of CF remains a ***,we propose a simple galvanostatic method as an effective strategy for rapidly growing zeolitic imidazolate frameworks(ZIFs)on CF,and obtain nanocaltrop-like ZIFs modified CF(NC-ZIFs/CF)glucose(Glu)sensor platform with distinctive *** prepared NC-ZIFs/CF demonstrated significant electrocatalytic activity towards the oxidation of Glu in alkaline media,characterized by a pronounced augmentation in oxidation current *** an applied potential of 0.4 V,NC-ZIFs/CF exhibited a remarkably broad detection range(3–30,000μmol/L)and demonstrated outstanding selectivity,repeatability and ***,the NC-ZIFs/CF was efficaciously employed for the detection of blood Glu levels in the serum of both normoglycemic and hyperglycemic patients,obtaining highly reliable *** work demonstrates the feasibility of using galvanostatic method assembly to induce the growth of MOFs on conductive substrates,providing new ideas for electrocatalysis sensors and other electrochemical applications.

关键词： Sensor MOFs Electrocatalytic oxidation Electrochemical assembly Glucose

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Performance enhancement and active sites identification of Cu-Cd bimetallic oxide derived catalysts for electrochemical CO_(2) reduction

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Journal of Energy Chemistry 2024年第4期91卷 50-58页

作者： cai Wang Xin Hu Bairong Chen Houan Ren Xiaoyu Wang Yilin Zhang Xinyu Chen Yuping Liu Qingxin Guan wei Li State Key Laboratory of Elemento-Organic Chemistry Key Laboratory of Adv.Energy Mater.Chemistry(Ministry of Education)College of ChemistryNankai UniversityTianjin 300071China

The development of earth-abundant electrocatalysts with high performance for electrochemical CO_(2)reduction(ECR)is of great ***-based catalysts have been widely investigated for ECR due to their unique ability to generate various carbonaceous products,but directing selectivity toward one certain product and identifying the real active sites during ECR are still full of ***,after the incorporation of CdO into CuO,the Cu_(0.5)Cd_(0.5)-O catalyst achieves a 10.3-fold enhancement for CO selectivity in comparison with CuO,and a CO faradic efficiency nearly 90%with a current density around20 mA cm^(-2)could maintain at least 60 ***,a wide CO/H_(2)ratio(0.07-10)is reached on Cu_(x)Cd_(1-x)-O catalysts by varying the Cu/Cd ratio,demonstrating the potential of syngas production using such *** results of ex situ XRD,XPS,and in situ Raman reveal that the real active sites of Cu_(0.5)Cd_(0.5)-O catalysts for CO production during ECR reaction are the reconstructed mixed phases of CuCd alloy and CdCO_(3).In situ FTIR and theoretical calculations further implicate the presence of Cd related species promotes the CO desorption and inhibits the H_(2)evolution,thus leading to an enhanced CO generation.

关键词： CO_(2)reduction Cu-Cd bimetallic Real active sites CO production

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Nomogram predicting the prognosis of primary liver cancer after radiofrequency ablation combined with transcatheter arterial chemoembolization

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World Journal of Gastrointestinal Surgery 2024年第8期16卷 2630-2639页

作者： Hai-Hua Shen Yu-Rong hong Wen Xu Lei Chen Jun-Min Chen Zhi-Gen Yang cai-hong Chen Department of Ultrasound Hangzhou Linping Hospital of Traditional Chinese MedicineHangzhou 311106Zhejiang ProvinceChina Department of Ultrasound The Second Affiliated HospitalZhejiang University School of MedicineHangzhou 310009Zhejiang ProvinceChina Department of Nursing Hangzhou Linping Hospital of Traditional Chinese MedicineHangzhou 311106Zhejiang ProvinceChina

BACKGROUND The incidence and mortality rates of primary hepatocellular carcinoma(HCC)are high,and the conventional treatment is radiofrequency ablation(RFA)with transcatheter arterial chemoembolization(TACE);however,the 3-year survival rate is still ***,there are no visual methods to effectively predict their *** To explore the factors influencing the prognosis of HCC after RFA and TACE and develop a nomogram prediction *** Clinical and follow-up information of 150 patients with HCC treated using RFA and TACE in the Hangzhou Linping Hospital of Traditional Chinese Medicine from May 2020 to December 2022 was retrospectively collected and *** examined their prognostic factors using multivariate logistic regression and created a nomogram prognosis prediction model using the R software(version 4.1.2).Internal verification was performed using the bootstrapping *** prognostic efficacy of the nomogram prediction model was evaluated using the concordance index(CI),calibration curve,and receiver operating characteristic RESULTS Of the 150 patients treated with RFA and TACE,92(61.33%)developed recurrence and *** regression analysis identified six variables,and a predictive model was *** internal validation results of the model showed a CI of *** correction curve trend of the prognosis prediction model was always near the diagonal,and the mean absolute error before and after internal validation was *** area under the curve of the prediction model after internal verification was 0.882[95%confidence interval(95%CI):0.820-0.945],with a specificity of 0.828 and sensitivity of *** to the Hosmer-Lemeshow test,χ^(2)=3.552 and P=*** predictive model demonstrated a satisfactory calibration,and the decision curve analysis demonstrated its clinical *** The prognosis of patients with HCC after RFA and TACE is affected by several *** developed prediction model ba

关键词： Nomogram Primary liver cancer Radiofrequency ablation Transcatheter arterial chemoembolization Prognosis Influencing factors Decision curve analysis

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Polarized imaging dynamic light scattering for simultaneous measurement of nanoparticle size and morphology

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Particuology 2024年第2期85卷 213-223页

作者： Bingyao Wang Tianyi cai Xiaoshu cai Wu Zhou Zeqi Liu Schoolof Energy and Power Engineering University of Shanghai for Science and TechnologyShanghai200093China Shanghai Key Laboratory of Multiphase Flow and Heat Transfer in Power Engineering Shanghai200093China Jiaxing MeaParTech Instrument Technology Co. LtdZhejiang314000China

The performance of nanoparticles is often affected by particle size and ***,electron microscopy or atomic force microscopy is typically utilized to determine the size and morphology of ***,there are issues such as difficult sample preparation,long processing times,and challenges in quantitative ***,it is of great significance to develop a fast,accu-rate,and statistical method to measure the size and morphology of *** this study,a new method,called polarized imaging dynamic light scattering(PIDLS),is *** nanoparticles are irradiated with a vertical linearly polarized laser beam,and a polarization camera collected the dynamic light scattering images of particles at four different polarization directions(0°,45°,90°,and 135°)at a scattering angle of 90°.The average particle size and distribution are obtained using the imaging dy-namic light scattering method at 0°polarization direction,and the morphology of the particles is ob-tained based on the depolarization patterns of the scattered *** optical sphericityΦis defined based on the degree of linear polarization(DoLP).It is also implemented for the quantitative evaluation of the sphericity of the nanoparticles,including spherical,octahedral,nanoplate,nanorod,and linear *** with the Poincarésphere parameterψ,the morphology of the nanoparticles can be roughly *** addition,PIDLS enables the measurement of particle size and morphology distributions simultaneously for evaluating the uniformity of *** effectiveness of PIDLS is verified by the measurement of five kinds of industrial titanium dioxide as well.

关键词： Imaging dynamic light scattering Polarized light scattering Non-spherical nanoparticles Morphology Online measurement

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MICROPYLAR GUIDANCE1(MG1) is required for micropylar pollen tube guidance during fertilization in Arabidopsis

MICROPYLAR GUIDANCE1(MG1) is required for micropylar pollen ...

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中国遗传学会植物遗传和基因组学专业委员会2009年学术研讨会

作者： hong-Ju Li,and wei-cai Yang~* Institute of Genetics and Developmental Biology,Chinese Academy of Sciences,Beijing 100190

In flowering plant,precise guidance of the pollen tube through the female reproductive tissues to the embryo sac is vital for sexual *** pollen tube guidance (MPTG) by which pollen tube find the entry to the embryo sa... 详细信息

关键词： Arabidopsis MG1 Pollen tube guidance

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Enhancing Photovoltaic Performance of Nonfused-Ring Electron Acceptors via Asymmetric End-Group Engineering and Noncovalently Conformational Locks

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Chinese Journal of Chemistry 2024年第5期42卷 485-490页

作者： Bo Liu Congqi Li Xiaobin Gu Yinghui Han Zhixiang wei Yunhao cai Xin Zhang Hui Huang Yanping Huo School of Chemical Engineering and Light Industry Guangdong University of TechnologyGuangzhouGuangdong510006 China College of Materials Science and Opto-Electronic Technology & Center of Materials Science and Optoelectronics Engineering & CAS Center for Excellence in Topological Quantum Computation & CAS Key Laboratory of Vacuum Physics University of Chinese Academy of SciencesBeijing100049 China College Resources and Environment University of Chinese Academy of SciencesBeijing100049 China Center for Excellence in Nanoscience (CAS) & Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS) National Center for Nanoscience and TechnologyBeijing100190 China

By employing the asymmetric end-group engineering,an asymmetric nonfused-ring electron acceptor(NFREA)was designed and *** with the symmetric analogs(NoCA-17 and NoCA-18),NoCA-19 possesses broader light absorption range,more coplanarπ-conjugated backbone,and appropriate crystallinity according to the experimental and theoretical *** organic solar cells based on J52:NoCA-19 exhibited a power conversion efficiency as high as 12.26%,which is much higher than those of J52:NoCA-17(9.50%)and J52:NoCA-18(11.77%),mainly due to more efficient exciton dissociation,better and balanced charge mobility,suppressed recombination loss,shorter charge extraction time,longer charge carrier lifetimes,and more favorable blend film *** findings demonstrate the great potential of asymmetric end-group engineering in exploring low-cost and high-performance NFREAs.

关键词： Organic solar cells Nonfused-ring electron acceptors Asymmetric end-group engineering Noncovalently conformational locks Low-cost acceptors

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