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China Foundry 2018年第6期15卷 422-427页

作者： Wei-zhao Sun Rui Yan Xiong Wan hong-biao dong Tao Jing Key Laboratory for Advanced Materials Processing Technolog Ministry of EducationSchool of Materials Science and EngineeringTsinghua UniversityBeijing 100084China Department of Engineering University of LeicesterLE1 7RHUK

Fluid flow can significantly change the evolution of microstructural morphology. However, relatively little is known how the fluid flow, concentration and microstructure affect each other quantitatively, which is essential to optimize processing parameters. A quantitative simulation study of Al-Cu solidified equiaxed dendrite evolution under forced flow based on phase field-lattice Boltzmann method(PF-LBM) is carried out. Results obtained are validated by Gibbs-Thomson relation at the dendrite tip. Compared with the equiaxed dendrite evolution without flow, the upstream dendrite arm is enhanced while the downstream arm is inhibited. Besides, as the inlet flow rate increases, the secondary arms attached onto the upstream primary arm and the upstream side of the primary arm normal to the inflow velocity has been well developed. Results show that sidewise instabilities of the primary dendrite arm and onset of secondary arm is caused by the local concentration perturbation and will be enhanced or inhabited by the flow. It is believed that the coupled PF-LBM method is able to handle dendrite evolution under forced flow quantitatively, which helps in investigating the solidified dendrite morphology evolution.

关键词： phase field lattice Boltzmann method forced flow instability

Grain selection and growth orientation of prior-β phase for Ti-6-4 during additive manufacturing:insights from a modeling perspective

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China Foundry 2021年第2期18卷 83-93页

作者： Wei-zhao Sun Fei-hu Shan Nan-fu Zong hong-biao dong Tao Jing Key Laboratory for Advanced Materials Processing Technology Ministry of EducationSchool of Materials Science and EngineeringTsinghua UniversityBeijing 100084China Science and Technology on Power Beam Processes Laboratory AVIC Beijing Aeronautical Manufacturing Technology Research InstituteBeijing 100024China School of Engineering University of LeicesterLEI 7RHUK

The microstructure of Ti-6-4 components produced by additive manufacturing suffers from the coarse and elongated prior-β grain,which leads to a decrease of the tensile behavior and the occurrence of *** understand and control the grain evolution,a multiscale simulation is applied to investigate the relationship between the grain selection,growth orientation,and the molten pool morphology with the different deposition layer numbers and processing *** accuracy of the simulation is validated by experiments in both qualitative and quantitative *** show that when the grain with unfavorable orientation loses the competitive growth with its neighbors,there will be a great chance that the blocked grain is eliminated in the following layer-and-layer deposition,which leads to the increase of the grain *** size of the molten pool increases remarkably as the layer number increases,which lays a heavy burden on the stability of the molten *** analytical relationship between the molten pool morphology and the grain growth orientation is also *** flat molten pool causes the grains with the direction close to the building direction to have greater survival ***,decreasing the line power energy shows little effect on the stability of the molten pool and the grain growth orientation,especially when the deposited layer number is *** revealing mechanisms will help in understanding and further controlling the grain evolution.

关键词： additive manufacturing Ti-6-4 simulation grain selection grain growth

Effect of electropulsing on austenite to ferrite transformation in low-carbon steel

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Journal of Iron and Steel Research International 2021年第4期28卷 437-444页

作者： Zheng-hai Zhu Li Zhou Fei He Xiao-fang Shi Li-zhong Chang Hai-jun Wang hong-biao dong School of Metallurgic Engineering Anhui University of TechnologyMaanshan 243002AnhuiChina School of Engineering University of LeicesterLeicester LE17RHUK

We explore the application of electropulsing for the control of phase transformation in a low-carbon *** effect of electropulsing on the transformation from austenite to ferrite in continuous casting low-carbon steel slab has been studied through experimental and thermodynamic *** results reveal that electropulsing promotes the precipitation of ferrite within austenite grain in the low-carbon *** the electropulsing intensity increases,the precipitation of ferrite increases within austenite grains,and ferrite omentum precipitates become thinner along the austenite grain *** results provide a basis for controlling the austenite to ferrite transformation in low-carbon steel.

关键词： Electropulsing Austenite Ferrite Transformation Nucleation Low-carbon steel

Effect of Electromagnetic Stirring on Molten Steel Flow and Solidification in Bloom Mold

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Journal of Iron and Steel Research International 2014年第12期21卷 1095-1103页

作者： Zhen-guo YANG Bao WANG Xiao-feng ZHANG Ya-tao WANG hong-biao dong Qing LIU State Key Laboratory of Advanced Metallurgy University of Science and Technology Beijing Special Steel Plant Laiwu Iron and Steel Co.Ltd. Department of Engineering University of Leicester

The effect of electromagnetic stirring on molten steel flow and heat transfer in a 260 mm× 300 mm bloom mold was investigated by using a method combining both finite element method and finite volume method. The simu lation results related to magnetic fields were consistent with the onsite measured data. The magnetic flux density in creased with increasing the current intensity but decreased with increasing the current frequency. Electromagnetic stirring caused molten steel to flow with rotation on a horizontal section and two sets of recirculation regions with opposite fellow directions in a longitudinal section formed. The maximum tangential velocity increased with increasing the current intensity and frequency. Furthermore, the superheat degree of the molten steel on the outlet cross section of the mold decreased with increasing the current intensity. growth zone of solidified shell in the effective stirring zone. bearing steel, the appropriate values of current intensity and to be 300 A and 3 Hz, respectively. Electromagnetic stirring caused the emergence of a zero For the 260 mm N 300 mm bloom continuous caster of current frequency of electromagnetic stirring were found

关键词： bloom mold electromagnetic stirring flow heat transfer numerical simulation bearing steel

A Flexible Smart Healthcare Platform Conjugated with Artificial Epidermis Assembled by Three‑Dimensionally Conductive MOF Network for Gas and Pressure Sensing

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Nano-Micro Letters 2025年第2期17卷 601-620页

作者： Qingqing Zhou Qihang Ding Zixun Geng Chencheng Hu Long Yang Zitong Kan biao dong Miae Won hongwei Song Lin Xu Jong Seung Kim State Key Laboratory of Integrated Optoelectronics College of Electronic Science and EngineeringJilin UniversityChangchun 130012People’s Republic of China Department of Chemistry Korea UniversitySeoul 02841Republic of Korea TheranoChem Incorporation Seoul 02856Republic of Korea

The rising flexible and intelligent electronics greatly facilitate the noninvasive and timely tracking of physiological information in telemedicine *** building bionic-sensitive moieties is vital for designing efficient electronic skin with advanced cognitive functionalities to pluralistically capture external ***,realistic mimesis,both in the skin’s three-dimensional interlocked hierarchical structures and synchronous encoding multistimuli information capacities,remains a challenging yet vital need for simplifying the design of flexible logic ***,we construct an artificial epidermal device by in situ growing Cu_(3)(HHTP)_(2) particles onto the hollow spherical Ti_(3)C_(2)T_(x) surface,aiming to concurrently emulate the spinous and granular layers of the skin’s *** bionic Ti_(3)C_(2)T_(x)@Cu_(3)(HHTP)_(2) exhibits independent NO_(2) and pressure response,as well as novel functionalities such as acoustic signature perception and Morse code-encrypted message ***,a wearable alarming system with a mobile application terminal is self-developed by integrating the bimodular senor into flexible printed *** system can assess risk factors related with asthmatic,such as stimulation of external NO_(2) gas,abnormal expiratory behavior and exertion degrees of fingers,achieving a recognition accuracy of 97.6%as assisted by a machine learning *** work provides a feasible routine to develop intelligent multifunctional healthcare equipment for burgeoning transformative telemedicine diagnosis.

关键词： Ti_(3)C_(2)T_(x)@Cu_(3)(HHTP)_(2)composites NO_(2)/pressure flexible sensors Health-monitoring Machine learning

An NIR-Ⅱ-emissive Ru(Ⅱ) metallacycle for efficient and safe immunotherapy

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Science China Chemistry 2025年第1期 5-7页

作者： Chonglu Li Jianbo Zhan biao dong Institute of Health Inspection and Testing Hubei Provincial Center for Disease Control and Prevention State Key Laboratory on Integrated Optoelectronics College of Electronic Science and Engineering Jilin University

Immunotherapy, as a groundbreaking cancer treatment, has gained considerable attention for its utilization of the body’s immune system to combat tumors [1]. This therapy induces tumor cell apoptosis, triggering a sustained anti-tumor immune response and effectively preventing tumor recurrence and metastasis [2]. The fundamental principle lies in inducing tumor cell death through specific treatment modalities, leading to the release of a cascade of signaling molecules and antigens, thereby mobilizing the immune system to actively identify and attack tumor cells [3].

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Enhanced solid-electrolyte interface efficiency for practically viable hydrogen-air fuel cell systems

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Journal of Energy Chemistry 2025年第1期100卷 356-368页

作者： Venkitesan Sakthivel dong Jin Yoo Graduate School Department of Energy Storage/Conversion Engineering (BK21 FOUR) Hydrogen and Fuel Cell Research Center Jeonbuk National University Jeonju Department of Life Science Jeonbuk National University

Proton exchange membrane fuel cells （PEMFCs） provide an appealing sustainable energy system,with the solid-electrolyte membrane playing a crucial role in its overall ***,sulfonated poly（1,4-phenylene ether-ether sulfone）(SPEES),an aromatic hydrocarbon polymer,has garnered considerable attention as an alternative to Nafion ***,the long-term durability and stability of SPEES present a significant *** this context,we introduce a potential solution in the form of an additive,specifically a core–shell-based amine-functionalized iron titanate （A–Fe2TiO5）,which holds promise for improving the lifetime,proton conductivity,and power density of SPEES in *** modified SPEES/A–Fe2TiO5composite membranes exhibited notable characteristics,including high water uptake,enhanced thermomechanical stability,and oxidative ***,the SPEES membrane loaded with 1.2 wt%of A–Fe2TiO5demonstrates a maximum proton conductivity of 155 mS cm-1,a twofold increase compared to the SPEES membrane,at 80°C under 100%relative humidity （RH）.Furthermore,the 1.2 wt%of A–Fe2TiO5/SPEES composite membranes exhibited a maximum power density of 397.37 mW cm-2and a current density of 1148 mA cm-2at 60°C under 100%RH,with an opencircuit voltage decay of 0.05 m V/h during 103 h of continuous *** study offers significant insights into the development and understanding of innovative SPEES nanocomposite membranes for PEMFC applications.

关键词： Acid-base Hybrid membrane Proton conductivity Polymer electrolyte fuel cell Single-cell performance

Effect of lamellarization on the microstructure and mechanical properties of marine 10Ni5CrMoV steel

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 402-413页

作者： Tao Zou Yanwu dong Zhouhua Jiang Shuyang Du Yushuo Li School of Metallurgy Northeastern UniversityShenyang 110819China Key Laboratory of Rolling and Automation Northeastern UniversityShenyang 110819China Key Laboratory for Ecological Metallurgy of Multimetallic Ores(Ministry of Education) Northeastern UniversityShenyang 110819China

Multistage heat treatment involving quenching(Q),lamellarizing(L),and tempering(T)is applied to marine 10Ni5CrMoV *** microstructure and mechanical properties were studied by multiscale characterizations,and the kinetics of reverse austenite transformation,strain hardening behavior,and toughening mechanism were further *** lamellarized specimens possess low yield strength but high toughness,especially cryogenic *** leads to the development of film-like reversed austenite at the martensite block and lath boundaries,refining the martensite structure and lowering the equivalent grain *** analysis of austenite reversion based on the JMAK model shows that the isothermal transformation is dominated by the growth of reversed austenite,and the maximum transformation of reversed austenite is reached at the peak temperature(750℃).The strain hardening behavior based on the modified Crussard-Jaoul analysis indicates that the reversed austenite obtained from lamellarization reduces the proportion of martensite,significantly hindering crack propagation via martensitic transformation during the *** a consequence,the QLT specimens exhibit high machinability and low yield *** with the QT specimen,the ductile-brittle transition temperature of the QLT specimens decreases from-116 to-130℃due to the low equivalent grain size and reversed austenite,which increases the cleavage force required for crack propagation and absorbs the energy of external load,*** work provides an idea to improve the cryogenic toughness of marine 10Ni5CrMoV steel and lays a theoretical foundation for its industrial application and comprehensive performance improvement.

关键词： 10Ni5CrMoV steel lamellarizing reversed austenite cryogenic toughness ductile-brittle transition temperature

Low-temperature chlorination roasting technology for the simultaneous recovery of valuable metals from spent LiCoO_(2)cathode material

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 80-91页

作者： Junjie Shi Changle Hou Jingjing dong dong Chen Jianzhong Li Key Laboratory for Ecological Metallurgy of Multimetallic Mineral(Ministry of Education) Northeastern UniversityShenyang 110819China School of Metallurgy Northeastern UniversityShenyang 110819China

With the continuous increase in the disposal volume of spent lithium-ion batteries(LIBs),properly recycling spent LIBs has become essential for the advancement of the circular *** study presents a systematic analysis of the chlorination roasting kinetics and proposes a new two-step chlorination roasting process that integrates thermodynamics for the recycling of LIB cathode *** activation energy for the chloride reaction was 88.41 kJ/mol according to thermogravimetric analysis–derivative thermogravimetry data obtained by using model-free,model-fitting,and Z(α)function(αis conversion rate).Results indicated that the reaction was dominated by the first-order(F1)model when the conversion rate was less than or equal to 0.5 and shifted to the second-order(F2)model when the conversion rate exceeded *** conditions were determined by thoroughly investigating the effects of roasting temperature,roasting time,and the mass ratio of NH_(4)Cl to LiCoO_(2).Under the optimal conditions,namely 400℃,20 min,and NH_(4)Cl/LiCoO_(2)mass ratio of 3:1,the leaching efficiency of Li and Co reached 99.43% and 99.05%,*** of the roasted products revealed that valuable metals in LiCoO_(2)transformed into CoCl_(2) and ***,the reaction mechanism was elucidated,providing insights for the establishment of a novel low-temperature chlorination roasting technology based on a crystal structure *** technology can guide the development of LIB recycling processes with low energy consumption,low secondary pollution,high recovery efficiency,and high added value.

关键词： spent lithium-ion battery thermodynamics chlorination roasting kinetics circular economy

Microstructural evolution during the progressive transformation-induced plasticity effect in a Fe-0.1C-5Mnmedium manganese steel

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International Journal of Minerals,Metallurgy and Materials 2025年第2期32卷 369-379页

作者： Mei Zhang Wenhao Li Yangfei Chen Yang Jiang Xiaofei Guo Han dong School of Materials Science and Engineering Shanghai UniversityShanghai 200444China State Key Laboratory of Advanced Special Steel Shanghai UniversityShanghai 200444China

The microstructural evolution of a cold-rolled and intercritical annealed medium-Mn steel(Fe-0.10C-5Mn)was investigated during uniaxial tensile ***-situ observations under scanning electron microscopy,transmission electron microscopy,and X-ray diffraction analysis were conducted to characterize the progressive transformation-induced plasticity process and associated fracture initiation *** findings were discussed with the local strain measurements via digital image *** results indicated that Lüders band formation in the steel was limited to 1.5%strain,which was mainly due to the early-stage martensitic phase transformation of a very small amount of the less stable large-sized retained austenite(RA),which led to localized stress concentrations and strain hardening and further retardation of *** small-sized RA exhibited high stability and progressively transformed into martensite and contributed to a stably extended Portevin-Le Chatelier *** volume fraction of RA gradually decreased from 26.8%to 8.2%prior to *** the late deformation stage,fracture initiation primarily occurred at the austenite/martensite and ferrite/martensite interfaces and the ferrite phase.

关键词： medium-Mn steel retained austenite progressive transformation-induced plasticity effect local strain fracture initiation