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Journal of Materials Science & Technology 2023年第20期151卷 66-72页

作者： Xu-Ye Xin Jun Ma hong-Quan Liu Yi-Jie Gu Yan-Fang Wang hong-zhi cui College of Materials Science and Engineering Shandong University of Science and TechnologyQingdao 266590China School of Mechanical-electronic and Vehicle Engineering Weifang UniversityWeifang 261061China School of Materials Science and Engineering China University of Petroleum HuadongQingdao 266580China

The intensification of energy crises and environmental pollution inspire researchers’attention to environment-friendly SnTe thermoelectric materials.In this work,we achieved a lower lattice thermal conductivity and optimized the power factor via the synergistic optimization of bonding characteristic,VSn,and resonant level for the SnTe system,respectively.Pb-introduction produces weak bonding strength,mass fluctuation,and stress distortion,which result in lower thermal conductivity.The lowest lattice thermal conductivity achieves 0.66 W m^(–1) K^(–1) at 773 K.Further introduced VSn relieves loss of electrical conductivity caused by Pb-introduction,and it also makes the bigger g(E)and up-shift of resonance level.The VSn,enhanced g(E),and resonant level make electrical conductivity and Seebeck coefficient enhance simultaneously.Finally,the further optimization of thermal and electronic transport performance contributes to a higher ZT value of∼0.86 at 773 K in the Sn_(0.685)Pb_(0.285)In_(0.015)Te_(0.7)Se_(0.3) sample.The strategy of bonding characteristic,VSn,and resonant level synergistic engineering will be widely applicable to various TE systems for achieving better thermoelectric performance.

关键词： SnTe-based material Low thermal conductivity Projected crystal orbital hamiltonian populations VSn Resonant level

Atmospheric Corrosion of AZ31B Magnesium Alloy in the Antarctic Low-Temperature Environment

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金属学报:英文版 2023年第9期36卷 1421-1432页

作者： Xi-Zhao Shi Zhong-Yu cui Jie Li Bing-Chen Hu Yi-Qiang An Xin Wang hong-zhi cui School of Materials Science and Engineering Ocean University of ChinaQingdao266100China Polar Research Institute of China Shanghai200136China

In this work,the outdoor corrosion behavior of AZ31B magnesium alloy in the Antarctic atmospheric environment was investigated.The surface corrosion state of the specimens exposed to the Antarctic atmosphere for 1 month and 24 months differ significantly.The corrosion rate after 1 month during the summer season was 19.82 g/m^(2)·year and it decreased to 13.87 g/m^(2)·year after two years’exposure.Corrosion is initiated with pitting corrosion and then evolved to uniform corrosion with prolonging exposure time.The skyward surface exhibited a much severe corrosion than that of the groundward surface,attributed to the long-term existence of the adsorbed electrolyte layer.The corrosion products formed on the alloy exposed in Antarctica environment were MgCO_(3)·3H_(2)O,MgCO_(3)·5H_(2)O and Mg_(2)CO_(3)(OH)_(2)·0.5H_(2)O,with the MgCO_(3)·3H_(2)O as the dominant phase in the initial stage and the Mg_(2)CO_(3)(OH)_(2)·0.5H_(2)O as the dominant phase after long-term exposure.

关键词： Magnesium alloy Corrosion products Antarctica Low temperature

Strengthening CoCrFeNi high-entropy alloy by Laves and boride phases

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China Foundry 2022年第6期19卷 457-463页

作者： Xiu-gang Chen Gang Qin Xue-feng Gao Rui-run Chen Qiang Song hong-zhi cui School of Materials Science and Engineering Shandong University of Science and TechnologyQingdao 266500China School of Materials Science and Engineering Harbin Institute of TechnologyHarbin 150001China

To strengthen the face-centered-cubic(FCC)type CoCrFeNi high-entropy alloy(HEA)by in-situ reinforced phase,(CoCrFeNi)_(100-x)(NbB_(2))_(x)(x=0,2,4,6,8,at.%)alloys were prepared.Phase constitution,microstructure,tensile mechanical properties of the alloys were studied,and the mechanisms were discussed.Results show that the microstructure of all the reinforced alloys consists of the matrix FCC phase,Laves phase,and(Cr_(3)Fe)B_(x) phase.The eutectic structure and(Cr_(3)Fe)B_(x) phases are formed in the interdendritic region,and the eutectic structure is composed of Laves and FCC phases.When x increases from 0 to 8,i.e.,with increase of Nb and B elements,the volume fraction of Laves and(Cr_(3)Fe)B_(x) phases increases gradually from 0 to 5.84%and 8.3%,respectively.Tensile testing results show that the ultimate strength of the alloys increases gradually from 409 MPa to 658 MPa,while the fracture strain decreases from 75%to 1.6%.Fracture analysis shows that the crack originates from the(Cr_(3)Fe)B_(x) phase.The CoCrFeNi alloys are mainly strengthened by the second phase(Laves phase and boride phase).

关键词： high-entropy alloy boride eutectic structure mechanical properties

Wear and corrosion resistance of CoCrNi composite coatings by laser cladding

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China Foundry 2022年第6期19卷 535-543页

作者： Di Jiang hong-zhi cui Xiao-jie Song Xiao-juan Lian Xiao-feng Zhao Hao Chen Guo-liang Ma School of Materials Science and Engineering Shandong University of Science and TechnologyQingdao 266590China School of Materials Science and Engineering Ocean University of ChinaQingdao 266100China

Two kinds of CoCrNi composite coatings,CoCrNiMo and CoCrNiMoBC,were prepared by laser cladding on the base metal of 304 stainless steel.The wear and corrosion properties of the coatings were studied by wear tests and electrochemical tests.Results show that the addition of B_(4)C promotes the generation of the ceramic phase,and therefore improving the microhardness of the coating and enhancing its wear resistance,while simutaneously keeps its excellent corrosion resistance.Energy dispersive X-ray spectrometry analysis shows that the chromium distribution in the two coatings is relatively uniform,which is beneficial for corrosion resistance.Scanning Kelvin probe microscopy results reveal that the potential difference between dendrites and interdendrites is only 20 mV,which leads to a relatively low driving force for galvanic corrosion.Observation through the atomic-scale high-resolution transmission electron microscopy shows that the fundamental reason for the high wear and corrosion resistance of the coating is the excellent coherent interface between the two phases,which reduces the interface energy and potential difference and thus improving its corrosion resistance.

关键词： wear corrosion laser cladding coherent boundary 304 stainless steel

NiO nanoparticles-decorated ZnO hierarchical structures for isopropanol gas sensing

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Rare Metals 2022年第3期41卷 960-971页

作者： Shi-Chao Wang Xiao-Hu Wang Gao-Qun Qiao Xiao-Yan Chen Xin-Zhen Wang Nan-Nan Wu Jian Tian hong-zhi cui School of Materials Science and Engineering Shandong University of Science and TechnologyQingdao 266590China

In this paper,a three-dimensional(3D)hierar-chical ZnO structure consisting of nanosheets modified with ultrafine NiO particles was synthesized via a facile two-step chemical precipitate method.Various techniques characterized the as-synthesized ZnO/NiO composites and pure ZnO.The p-NiO/n-ZnO junctions formed between adjacent ZnO and NiO nanoparticles,improving the gas sensing performance.The ZnO/NiO composite with the Ni:Zn atomic ratio of 7.42:100 exhibited the best iso-propanol sensing properties.Compared to pure ZnO,it showed high selectivity and sensitivity(R_(a)/R_(g)=221.3 toward 400×10^(-6)isopropanol),fast response rate(less than 10 s),short recovery time,and simultaneously low operating temperature.Also,the ZnO/NiO composite exhibited a wide sensing range(1×10^(-6)-1000×10^(-6))to isopropanol and processed good long-term stability.The experimental results suggested the potential application in fabricating efficient isopropanol sensors using this ZnO/NiO composite.The enhanced isopropanol sensing mech-anism is also discussed in charge transfer between heterojunctions,surface area,and surface defects.

关键词： ZnO NiO Hierarchical structure Gas sensor Isopropanol

Corrosion Resistance of Superhydrophobic Mg-Al Layered Double Hydroxide Coatings on Aluminum Alloys

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Acta Metallurgica Sinica(English Letters) 2015年第11期28卷 1373-1381页

作者： Fen Zhang Chang-Lei Zhang Liang Song Rong-Chang Zeng Lan-Yue cui hong-zhi cui College of Materials Science and Engineering Shandong University of Science and Technology State Key Laboratory of Mining Disaster Prevention and Control Co-founded by Shandong Province and the Ministry of Science and Technology Shandong University of Science and Technology Qingdao Institute of Bioenergy and Bioprocess Technology Chinese Academy of Sciences

A superhydrophobic surface was successfully constructed to modify the layered double hydroxide （LDH） coatings on aluminum alloy using stearic acid. The characteristics of the coatings were investigated using SEM, XRD, FT- IR and XPS. The corrosion resistance of the prepared coatings was studied using potentiodynamic polarization and electrochemical impedance spectrum. The results revealed that the superhydrophobic surface considerably improved the corrosion-resistant performance of the LDH coatings on the aluminum alloy substrate. The formation mechanism of the superhydrophobic surface was proposed.

关键词： Aluminum alloy Layered double hydroxide Superhydrophobic Stearic acid Corrosion

Fabrication,Pore Structures and Mechanical Properties of (TiB_2–Al_2O_3)/NiAl Porous Composites

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Acta Metallurgica Sinica(English Letters) 2017年第12期30卷 1145-1154页

作者： Jie Wu Zhao-Tai Yang hong-zhi cui Na Wei Xiao-Jie Song School of Materials Science and Engineering Shandong University of Science and Technology Qingdao 266590 China

Open-celled porous （TiB2-Al2O3）/NiAl composites were successfully fabricated by using spherical carbamide as space holders via self-propagating high-temperature synthesis （SHS）. Effects of 10Al-3B2O3-3TiO2 contents （0-20 wt%） on the pore structures and the quasi-static compressive behaviors of the resultant materials were investigated. The porous （TiBE-Al2O3）/NiAl composites exhibit composite pore structure consisting of homogeneously distributed and interconnected millimeter pores and micropores. The millimeter pores virtually inherit the shape and size of carbamide particles, while the pore size of micropores increases with increasing the 10Al-3BEO3-3TiO2 content. Depending on the volume fraction of the carbamide, the porosity of the porous materials can be easily controlled in a range of 55%-85%. When the porosity is about 72%, the compressive strengths of porous NiAl and porous （TiBE-Al203）/NiAl composite with 15% 10Al-3B2O3-3TiO2 in green compact are 19 and 32 MPa, and the corresponding strains are 2.9% and 5.7%, respectively. Furthermore, the quasi-static compressive behavior of porous （TiB2-AlEO3）/NiAl composites can be estimated by Gibson-Ashby model.

关键词： Self-propagating high-temperature synthesis （SHS） Pore structure Compressive properties Porous （TiB2-Al2O3）/NiAI

Effects of Forming Conditions and TiC–TiB_2 Contents on the Microstructures of Self-Propagating High-Temperature Synthesized NiAl–TiC–TiB_2 Composites

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Acta Metallurgica Sinica(English Letters) 2015年第1期28卷 39-47页

作者： Na Wei hong-zhi cui Jie Wu Jun Wang Guan-Long Wang Chen Jiang School of Materials Science and Engineering Shandong University of Science and Technology

The NiAl–TiC–TiB2 composites were processed by self-propagating high-temperature synthesis（SHS） method using raw powders of Ni, Al, Ti, B4 C, TiC, and TiB2, and their microstructure and micro-hardness were investigated. The TiC–TiB2 in NiAl matrix, with contents from 10 to 30 wt%, emerged with the use of two methods： in situ formed and externally added. The results show that all final products are composed of three phases of NiAl, TiC, and TiB2. The microstructures of NiAl–TiC–TiB2 composites with in situ-formed TiC and TiB2 are fine, and all the three phases are distributed uniformly. The grains of NiAl matrix in the composites have been greatly refined, and the micro-hardness of NiAl increases from 381 HV100 to 779 HV100. However, the microstructures of NiAl–TiC–TiB2 composites with externally added TiC and TiB2 are coarse and inhomogeneous, with severe agglomeration of TiC and TiB2 particles. The samples containing externally added 30 wt% TiC–TiB2attain the micro-hardness of 485 HV100. The microstructure evolution and fracture mode of the two kinds of NiAl–TiC–TiB2 composites are different.

关键词： NiAl–TiC–TiB2 composite Self-propagating high-temperature synthesis（SHS） Forming condition TiC–TiB2 content Microstructure

Synthetic Effect of Cr and Mo Elements on Microstructure and Properties of Laser Cladding NiCrxMoy Alloy Coatings

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Acta Metallurgica Sinica(English Letters) 2020年第10期33卷 1331-1345页

作者： Wen-Ya Zhang Can-Ming Wang Jing-Xin Ji Xiao-Li Feng hong-zhi cui Qiang Song Chun-zhi Zhang College of Materials Science and Engineering Shandong University of Science and TechnologyQingdao 266590China

NiCrxMoy(x=1,1.5;y=0,0.1,0.3)alloy coatings were prepared on the Q235 substrate by laser cladding under the protection of argon.The phase composition,microstructure,corrosion behavior,and mechanical properties of the NiCrxMoy alloy coatings were investigated using X-ray diffraction,scanning electron microscopy,transmission electron microscopy,electrochemical tests,X-ray photoelectron spectroscopy,microhardness,and nanoindentation tests.As the Cr content increased,the phase composition of the coatings changed from a single face-centered cubic(FCC)structure to a dual-phase structure coexisting with body-centered cubic(BCC)and FCC structures,while the addition of Mo promoted the precipitation ofσphase.The appearance of a homogeneous dual-phase structure and some amount ofσphase played a positive role in the corrosion resistance of NiCrxMoy coatings.Cr^3+ ions and Mo^6+ ions in the passive film enhanced the stability of the coatings.The nanoindentation tests showed that the nanohardness(6.71 GPa)and elastic modulus(184.40 GPa)of BCC phase were higher than those of the FCC phase(5.19 GPa and 155.26 GPa,respectively).Overall,the BCC phase andσphase improved the mechanical properties of the coatings.

关键词： NiCrMo coating Laser cladding Corrosion behavior Mechanical properties Q235 substrate

Enhanced thermoelectric properties of Co_(1-x-y)Ni_(x+y)Sb_(3-x)Sn_x materials

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International Journal of Minerals,Metallurgy and Materials 2012年第3期19卷 240-244页

作者： hong-quan Liu Sheng-nan Zhang Tie-jun Zhu Xin-bing Zhao Yi-jie Gu hong-zhi cui College of Materials Science and Engineering Shandong University of Science and Technology Qingdao 266510 China State Key Laboratory of Silicon Materials Development of Materials Science and Engineering Zhejiang University Hangzhou 310027 China

Co1-x-yNix＋ySb3-xSnx polycrystals were fabricated by vacuum melting combined with hot-press sintering. The effect of alloying on the thermoelectric properties of unfilled skutterudite CO1-xNixSb3-xSnx was investigated. A leap of electrical conductivity from the Co0.93Ni0.07Sb2.93Sn0.07 sample to the Co0.88Ni0.12Sb288Sn0.12 sample occurs during the measurement of electrical conductivity, indicating the adjustment of band structure by proper alloying. The results show that alloying enhances the power factor of the materials. On the basis of alloying, the thermoelectric properties of Coo.88Nio.12Sb2.ssSno.12 are improved by Ni-doping. The thermal conductivities of Ni-doping samples have no reduction, but their power factors have obvious enhancement. The power factor of Co0.81Ni0.09Sb2.88Sn0.12 reaches 3.0 mW-m-1·K-2 by Ni doping. The dimensionless thermoelectric figure of merit reaches 0.55 at 773 K for the unfilled Co0.81Ni0.19 Sb2.88Sn0.12,

关键词： thermoelectric material polycrystals skuttemdites alloying thermoelectric properties clopping