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Rapid evaluation of arsenic contamination in paddy soils using field portable X-ray fluorescence spectrometry

Journal of Environmental Sciences 2018年第2期30卷 345-351页

作者： Jian-hong Liang pan-pan Liu Zheng Chen Guo-Xin Sun hong Li Key Laboratory of Karst Ecosystem and Treatment of Rocky Desertification Institute of Karst Geology Chinese Academy of Geological Sciences Guilin 541004 China State Key Joint Laboratory of Environment Simulation and Pollution Control School of Environment Tsinghua University Beijing 100084 China State Key Laboratory of Urban and Regional Ecology Research Center for Eco-Environmental Sciences Chinese Academy of Sciences Beijing 100085 China Department of Environmental Science Xi' an Jiaotong-Liverpool University Suzhou 215123 China College of Urban Construction and Environmental Engineering Chongqing University Chongqing 400045 China

Arsenic（As） in paddy fields is deteriorating food security and human health through rice ingestion. Rice is the dominant food source of arsenic exposure to half of the world’s population. Therefore, an in situ effective method for As risk evaluation in paddy soil is strongly needed to avoid As exposure through rice ingestion. Herein, we developed a rapid analytical methodology for determination of As in plant tissues using field portable X-ray fluorescence spectrometry（FP-XRF）. This method was applied to rice roots in order to evaluate the As contamination in paddy soils. The results showed that rice roots with iron plaques were superior to rhizosphere soils for generating FP-XRF signals, especially for field sites with As concentrations lower than the soil detection limit of FP-XRF（30.0 mg/kg）.Moreover, the strong linear relationships of As concentrations between the rice roots and corresponding leaves and grains proved that the rice root, rather than the soil, is a better predictor of As concentrations in rice grains. The research provides an efficient As monitoring method for As contaminated paddy fields by using wetland plant roots with iron plaques and XRF-based analytical techniques.

关键词： XRF Arsenic Risk evaluation Rice roots Rhizosphere soils Iron plaque

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Preparation of a wearable K-pan@CuS composite fabric with excellent photothermal/electrothermal properties

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Frontiers of Materials Science 2023年第4期17卷 65-79页

作者： Jintao Zhang Qi Zhang wei pan Yu Qi Yajie Qin Zebo Wang Jiarui Zhao International Joint Laboratory of New Textile Materials and Textiles of Henan Province Zhongyuan University of TechnologyZhengzhou 450007China Huanghe Science and Technology College Zhengzhou 450006China School of Materials and Chemical Engineering Zhongyuan University of TechnologyZhengzhou 451191China College of Textiles Zhongyuan University of TechnologyZhengzhou 451191China

Electrospun nanofibers with highly efficient photothermal/electrothermal performance are extremely popular because of their great potential in wearable ***,the lack of necessary wearable properties such as high mechanical strength and quick response of electrospun micro/nanofibers seriously affects their practical *** this work,a technical route combining electrospinning and surface modification technology is *** 3-triethoxysilylpropylamine-polyacrylonitrile@copper sulfide(K-pan@CuS)composite fabric was achieved by modifying the original electrospinning pan fiber and subsequently loading CuS *** results show that the break strength of the K-pan@CuS fabric was increased by 10 times compared to that of the original pan@CuS ***,the saturated temperature of the K-pan@CuS fabric heater could reach 116℃within 15 s at a relatively low voltage of 3 V and 120.3℃within 10 s under an infrared therapy lamp(100 W).In addition,due to its excellent conductivity,such a unique structural design enables the fiber to be closely attached to the human skin and helps to monitor human *** K-pan@CuS fabric shows great potential in wearable heaters,hyperthermia,all-weather thermal management,and in vitro physical therapy.

关键词： electrospinning strain sensor electrothermal/photothermal conversion CuS wearable fabric

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Adaptive H_∞ Control for Nonlinear Hamiltonian Systems with Time Delay and Parametric Uncertainties

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International Journal of Automation and computing 2014年第4期11卷 368-376页

作者： pan Wang wei-wei Sun Institute of Automation Qufu Normal University School of Electrical Information and Automation Qufu Normal University

This paper addresses the adaptive H∞ control problem for a class of nonlinear Hamiltonian systems with time delay and parametric uncertainties. The uncertainties under consideration are some small parameter perturbations involved in the structure of the Hamiltonian system. Both delay-independent and delay-dependent criteria are established based on the dissipative structural properties of the Hamiltonian systems and the Lyapunov-Krasovskii functional approach. In order to construct the adaptive H∞controller, the situation that the parameter perturbation is inexistent in the system is also studied and the controller is *** adaptive H∞ control problem is solved under some sufficient conditions which ensure the asymptotic stability and the L2 gain performance of the resulted closed-loop system. Numerical example is given to illustrate the applicability of the theoretical results.

关键词： Nonlinear Hamiltonian systems time delay H∞ control uncertainties Lyapunov-Krasovskii function

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Synthesis of Multiester-appended and Multicarboxylic-appended Imidazolium Ionic Liquids

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Chinese Chemical Letters 2006年第2期17卷 169-172页

作者： wei Guo GENG Xuc Hui LI Le Fu WANG hong Li DUAN wei Ping pan Department of Chemical Engineering School of Chemical and Energy Engineering South China University of Technology Guangzhou 510640

Multiester-appended imidazolium ionic liquids were synthesized in a quatemization reaction between the imidazole derivatives carrying single or double esters and ethyl chloroacetate or bromoethane. Multicarboxylic-appended imidazolium ionic liquids were achieved from the hydrolysis of the corresponding ionic liquids. The influences of multifunctional groups on the transition temperatures and viscosity of these new ionic liquids were investigated.

关键词： Ionic liquid multiester group multicarboxylic group synthesis

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Influencing factors and mechanism of high-temperature oxidation of high-entropy alloys: A review

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International Journal of Minerals,Metallurgy and Materials 2021年第6期28卷 915-930页

作者： Ya wei Yu Fu Zhi-min pan Yi-chong Ma hong-xu Cheng Qian-cheng Zhao hong Luo Xiao-gang Li National Materials Corrosion and Protection Data Center Institute for Advanced Materials and TechnologyUniversity of Science and Technology BeijingBeijing 100083China Key Laboratory for Corrosion and Protection of The Ministry of Education(MOE) Beijing 100083China BRI Southeast Asia Network for Corrosion and Protection(MOE) Shunde Graduate School of University of Science and Technology BeijingFoshan 528000China

High-temperature oxidation is a common failure in high-temperature environments,which widely occur in aircraft engines and aerospace thrusters;as a result,the development of anti-high-temperature oxidation materials has been ***-based alloys are a common high-temperature material;however,they are too ***-entropy alloys are alternatives for the anti-oxidation property at high temperatures because of their special structure and *** recent achievements of high-temperature oxidation are reviewed in this *** high-temperature oxidation environment,temperature,phase structure,alloy elements,and preparation methods of high-entropy alloys are *** reason why high-entropy alloys have anti-oxidation ability at high temperatures is *** research,material selection,and application prospects of high-temperature oxidation are introduced.

关键词： high-entropy alloy high-temperature oxidation influencing factors oxidation mechanism

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Broadband and perfect terahertz absorber based on multilayer metamaterial with cross-ring patterned structures

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Optoelectronics Letters 2025年第1期21卷 1-6页

作者： WEN Jin LIU Zhanzhi WU Zhengwei pan Yu ZHANG Ying School of Science Xi'an Shiyou University Shaanxi Key Laboratory of Measurement and Control Technology for Oil and Gas Wells

Broadband and perfect terahertz absorber based on multilayer metamaterial using cross-ring patterned structures is proposed and investigated. The structure of the absorber is double absorption layers consisting of a chromium cross ring and eight isosceles right triangles. The unique structure of the double absorbing layers excites the electric dipole multimode resonance, giving rise to high absorption performance. Meanwhile, the influence of construal parameters on absorber behavior is also discussed. The numerical results show that the absorption achieves over 90% ranging from 2.45 THz to 6.25 THz and 99% absorption in the range of 3.7—5.3 THz. The realization of broadband and perfect absorber is described using the impedance matching principle. It is obviously found that the absorber is insensitive to the high angle of incidence for both transverse electric(TE) and transverse magnetic(TM) polarizations. Compared with the former reports, this absorber has remarkable improved absorption efficiency and smaller period. The terahertz absorber may be found applications in the fields of energy capture and thermal detection.

关键词： Metamaterials

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Characterization of the Promoter of a Homolog of Maize MADS-Box Gene m18

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Journal of Integrative Agriculture 2014年第11期13卷 2330-2345页

作者： QIN Hui-juan pan hong FAN Xian-wei WU Qiao LI You-zhi Key Laboratory for Microbial and Plant Genetic Engineering Ministry of Education/State Key Laboratory for Conservation and Utilization of Subtropical Agro-Bioresources Ministry of Science and Technology/College of Life Science and Technology Guangxi University

Maize （Zea mays L.） is one of the world’s major food crops, and often suffers from tremendous yield loss caused by abiotic stresses. The MADS-box genes are known to play versatile roles in plants, controlling plant responses to multiple abiotic stresses. However, understanding of regulation of their expressions by the conventional loss-of-function approach is very dififcult. So far, regulation of MADS-box gene expression is little known. The best approach to retrieve expression regulation of this category of genes is to characterize expression of their promoters. In this study, the promoter of a homolog （GenBank accession no. EC864166） of maize MADS-box gene m18 was cloned by way of genome-walking PCR, named Pro66. Predicative analysis indicated that Pro66 contains more than one TATA box and multiple cis-acting environmental conditions-responsive elements （ECREs）. Pro66 could drive expression of theβ-glucuronidase （GUS）-encoding gene in maize, and heterologous expression of GUS in red pepper stressed by water deifcit, salt, copper, iron deifciency, heat, cold, and grown under short and long photoperiods, echoing predicative ECREs. Conclusively, maize MADS-box gene m18 likely plays versatile functions in maize response to multiple abiotic stresses due to the promoter with multiple cis-acting elements. The complex arrangement of multiple cis-acting elements in the promoter features meticulously regulated expression of m18. The results give informative clues for heterologous utilisation of the promoters in monocot and dicot species. The copy of the ECREs and heterologous expression of the promoter in dicot species are also discussed.

关键词： maize MADS-box gene promoter stress transcription

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Highly efficient removal of trace lead(Ⅱ)from wastewater by 1,4-dicarboxybenzene modified Fe/Co metal organic nanosheets

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Journal of Materials Science & Technology 2022年第3期98卷 212-218页

作者： Junmao hong Le Kang Xiaofeng Shi Renbo wei Xianmin Mai Duo pan Nithesh Naik Zhanhu Guo School of Environment and Safety Engineering School of Materials Science and TechnologyInstitute of Advanced Energy Materials and SystemsNorth University of ChinaTaiyuanChina School of Chemical Engineering Northwest UniversityXi’an 710069China School of Urban Planning and Architecture Southwest Minzu UniversityChengdu 610041China Key Laboratory of Materials Processing and Mold(Zhengzhou University) National Engineering Research Center for Advanced Polymer Processing TechnologyMinistry of EducationZhengzhou UniversityZhengzhou 450000China Department of Mechanical&Manufacturing Engineering Manipal Institute of TechnologyManipal Academy of Higher EducationManipalKarnataka 576104India Integrated Composites Laboratory(ICL) Department of Chemical&Biomolecular EngineeringUniversity of TennesseeKnoxvilleTN 37996United States

A novel Fe/Co metal organic complex nanosheet modified by 1,4-dicarboxybenzene(BDC),i.e.,FeCo@BDC,was prepared,and highly efficient removal performance for trace lead(Ⅱ)(Pb^(2+))was demonstrated in the neutral aqueous *** removal rates were higher than 95%and the adsorption was equilibrated in 15 *** isotherms and kinetics for the adsorption Pb^(2+)by the FeCo@BDC adsorbents followed Langmuir model and pseudo-second-order model,*** maximum adsorption capacity was 220.48 mg g^(-1).The FeCo@BDC adsorbents also own a prominent regeneration *** prominent performance of in the removal of trace Pb^(2+)makes FeCo@BDC an ideal candidate as commercial adsorbent materials.

关键词： Metal organic complex Nanosheet Trace level Lead(Ⅱ) Adsorption

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Construction of 3D porous Cu_(1.81)S/nitrogen-doped carbon frameworks for ultrafast and long-cycle life sodium-ion storage

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International Journal of Minerals,Metallurgy and Materials 2025年第1期32卷 191-200页

作者： Chen Chen hongyu Xue Qilin Hu Mengfan Wang pan Shang Ziyan Liu Tao Peng Deyang Zhang Yongsong Luo Key Laboratory of Microelectronics and Energy of Henan Province Henan Joint International Research Laboratory of New Energy Storage TechnologyCollege of Physics and Electronic EngineeringXinyang Normal UniversityXinyang 464000China School of Physics and Electronic Engineering Nanyang Normal UniversityNanyang 473061China

Transition metal sulfides have great potential as anode mterials for sodium-ion batteries(SIBs)due to their high theoretical specific ***,the inferior intrinsic conductivity and large volume variation during sodiation-desodiation processes seriously affect its high-rate and long-cyde performance,unbeneficial for the application as fast-charging and long-cycling SIBs ***,the three-dimensional porous Cu_(1.81)S/nitrogen-doped carbon frameworks(Cu_(1.81)S/NC)are synthesized by the simple and facile sol-gel and annealing processes,which can accommodate the volumetric expansion of Cu_(1.81)S nanoparticles and accelerate the transmission of ions and electrons during Na^(+)insertion/extraction processes,exhibiting the excellent rate capability(250.6 mA·g^(-1)at 20.0 A·g^(-1))and outstanding cycling stability(70% capacity retention for 6000 cycles at 10.0 A·g^(-1))for ***,the Na-ion full cells coupled with Na_(3)V_(2)(PO_(4))_(3)/C cathode also demonstrate the satisfactory reversible specific capacity of 330.5 mAh·g^(-1)at 5.0 A·g^(-1)and long-cycle performance with the 86.9% capacity retention at 2.0 A·g^(-1)after 750 *** work proposes a promising way for the conversionbased metal sulfides for the applications as fast-charging sodium-ion battery anode.

关键词： copper sulfide nanoparticles porous carbon framework fast charging long-cycle performance sodium-ion full batteries

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Design strategies of high-performance lead-free electroceramics for energy storage applications

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Rare Metals 2024年第3期43卷 853-878页

作者： Biao Guo Fei Jin Li Li Zi-Zhao pan Xin-wei Xu hong Wang Department of Materials Science and Engineering College of EngineeringSouthern University of Science and TechnologyShenzhen518055China School of Microelectronics and State Key Laboratory for Mechanical Behavior of Materials Xi’an Jiaotong UniversityXi’an710049China

A greater number of compact and reliable electrostatic capacitors are in demand due to the Internet of Things boom and rapidly growing complex and integrated electronic systems,continuously promoting the development of high-energy-density ceramic-based *** significant successes have been achieved in obtaining high energy densities in lead-based ferroelectric ceramics,the utilization of lead-containing ceramies has been restricted due to environmental and health hazards of ***-free ferroelectric ceramics have garnered tremendous attention and are expected to replace lead-based ceramics in the near ***,the energy density of lead-free ceramics is still lagging behind that of lead-containing ***,severely limiting their *** efforts have been made to enhance the energy storage performance of lead-free ceramics using multi-scale design strategies,and exciting progress has been achieved in the past *** review briefly discusses the energy storage mechanism and fundamental characteristics of a dielectric capacitor,summarizes and compares the state-of-the-art design strategies for high-energy-density lead-free ceramics,and highlights several critical issues and requirements for industrial *** prospects and challenges of lead-free ceramics for energy storage applications are also discussed.

关键词： Dielectric materials Lead-free ceramic Environment friendly Energy storage Design strategy

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