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Facile and controllable preparation of mesoporous TiO2 using poly（ethylene glycol） as structure-directing agent and peroxotitanic acid as precursor

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Frontiers of Materials Science 2016年第4期10卷 405-412页

作者： Dongthanh nguyen Wei WANG Haibo long Hongqiang RU Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education) School of Materials Science and Engineering Northeastern University Shenyang 110819 China

This work demonstrated that mesoporous TiO= （meso-TiO2） with con- trollable mesoporous and crystalline structures can be facilely prepared by using poly （ethylene glycol）（PEG） as structure-directing （SD） agent and peroxotitanic acid （PTA） as precursor. Meso-TiO2 with high specific surface area （157 m2.g-1）, pore volume （0.45 cm3.g-1） and large mesopore size of 13.9 nm can be obtained after calcination at 450℃. Such meso-TiO2 also shows relatively high thermal stability. BET surface area still reaches 114 m2-g-1 after calcination at 550℃. In the synthesis and calcination process, PEG that plays multiple and important roles in delivering thermally stable and tunable mesoporous and crystalline structures shows to be a suitable low-cost SD agent for the controllable preparation of nanocrystalline meso-TiO2. The photocataiytic activity tests show that both high surface area and bi-crystallinity of obtained meso-TiO2 are important in enhancing the performance in photo-decomposing Rhodamine B in water.

关键词： sol-gel preparation mesoporous titania poly(ethylene glycol)

Synthesis, characterization and photoactivity of bi-crystalline mesoporous TiO2

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Frontiers of Materials Science 2016年第1期10卷 23-30页

作者： Dongthanh nguyen Wei WANG Haibo long Hongqiang RU Key Laboratory for Anisotropy and Texture of Materials of Ministry of Education (ATM) Northeastern University Shenyang 110819 China School of Materials and Metallurgy Northeastern University Shenyang 110819 China

Mesoporous titania （meso-TiO2） has received extensive attention owing to its versatile potential applications. This paper reports a low-temperature templating approach for the fabrication of meso-TiO2 using the peroxo titanic acid （PTA） sol as precursor and Pluronic P123 as nonionic template. The TGA, XRD, N2 sorption, FE-SEM and HRTEM were used to characterize the obtained samples. The results showed that meso-TiO2 with high surface area up to 163 m2.g^-1 and large pore volume of 0.65 cm3.^-1 can be obtained. The mesopore sizes can be varied between 13 and 20 nm via this synthesis approach. The amount of P123 and the calcination conditions were found to have great influence on the mesoporous and crystalline structures of meso-TiO2. The photocatalytic activity testing clearly shows that the high surface area and bi-crystallinity phases of meso-TiO2 play important roles in enhancing photocatalytic properties of meso-TiO2 in photo-decomposing Rhodamine B in water.

关键词： surfactant templating mesopore bi-crystallinity titania

Picture-Neutrosophic Trusted Safe Semi-Supervised Fuzzy Clustering for Noisy Data

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Computer Systems Science & Engineering 2023年第8期46卷 1981-1997页

作者： Pham Huy Thong Florentin Smarandache Phung The Huan Tran Manh Tuan Tran Thi Ngan Vu Duc Thai nguyen long Giang Le hoang Son Graduate University of Science and Technology Vietnam Academy of Science and TechnologyHanoi100000Vietnam Institute of Information Technology Vietnam Academy of Science and TechnologyHanoi100000Vietnam VNU Information Technology Institute Vietnam National UniversityHanoi100000Vietnam Department of Mathematics University of New MexicoGallup87301New MexicoUSA University of Information and Communication Technology Thai Nguyen UniversityThai Nguyen250000Vietnam Faculty of Computer Science and Engineering Thuyloi UniversityHanoi100000Vietnam

Clustering is a crucial method for deciphering data structure and producing new *** to its significance in revealing fundamental connections between the human brain and events,it is essential to utilize clustering for cognitive *** with noisy data caused by inaccurate synthesis from several sources or misleading data production processes is one of the most intriguing clustering *** data can lead to incorrect object recognition and *** research aims to innovate a novel clustering approach,named Picture-Neutrosophic Trusted Safe Semi-Supervised Fuzzy Clustering(PNTS3FCM),to solve the clustering problem with noisy data using neutral and refusal degrees in the definition of Picture Fuzzy Set(PFS)and Neutrosophic Set(NS).Our contribution is to propose a new optimization model with four essential components:clustering,outlier removal,safe semi-supervised fuzzy clustering and partitioning with labeled and unlabeled *** effectiveness and flexibility of the proposed technique are estimated and compared with the state-of-art methods,standard Picture fuzzy clustering(FC-PFS)and Confidence-weighted safe semi-supervised clustering(CS3FCM)on benchmark UCI *** experimental results show that our method is better at least 10/15 datasets than the compared methods in terms of clustering quality and computational time.

关键词： Safe semi-supervised fuzzy clustering picture fuzzy set neutrosophic set data partition with noises fuzzy clustering

Building 3D CityGML models of mining industrial structures using integrated UAV and TLS point clouds

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International Journal of Coal Science & Technology 2023年第5期10卷 158-177页

作者： Canh Le Van Cuong Xuan Cao Anh Ngoc nguyen Chung Van Pham long Quoc nguyen Department of Mine Surveying Hanoi University of Mining and GeologyHanoiVietnam Viettel Group Viettel Cyberspace CenterHanoiVietnam

Mining industrial areas with anthropogenic engineering structures are one of the most distinctive features of the real world.3D models of the real world have been increasingly popular with numerous applications,such as digital twins and smart factory *** this study,3D models of mining engineering structures were built based on the CityGML *** collecting spatial data,the two most popular geospatial technologies,namely UAV-SfM and TLS were *** accuracy of the UAV survey was at the centimeter level,and it satisfied the absolute positional accuracy requirement of creat-ing all levels of detail(LoD)according to the CityGML ***,the UAV-SfM point cloud dataset was used to build LoD 2 *** addition,the comparison between the UAV-SfM and TLS sub-clouds of facades and roofs indicates that the UAV-SfM and TLS point clouds of these objects are highly consistent,therefore,point clouds with a higher level of detail and accuracy provided by the integration of UAV-SfM and TLS were used to build LoD 3 *** resulting 3D CityGML models include 39 buildings at LoD 2,and two mine shafts with hoistrooms,headframes,and sheave wheels at LoD3.

关键词： 3D modelling CityGML-Mining industry UAV Terrestrial laser scanning Point cloud

Fly boyz,hybrid artists or cool guys:testing the boundaries of imagination

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Journal of Geriatric Cardiology 2005年第3期2卷 191-192页

作者： Thach nguyen hoang Pham James nguyen Bikash Agarwal St Mary Medical Center Hobart IN long Island College Hospital Brooklyn NY St Anthony Memorial Health Center Michigan City IN

In the early years of coronary interventions,when a single lesion was found,the question then was asked whether it was feasible and safe to dilate right away the lesion with plain old balloon angioplasty (ad hoc POBA) or to call in a senior interventional cardiologist to do POBA on a later *** lesions were found in more than one coronary artery territories,then the interventional cardiologists had to pull his or her hair and asked whether it was feasible and safe to dilate right away the other lesion(s) at the same *** than 20 years later,at this present time,with nearly perfect outcomes due to stent availability and high level of experiences from operators,the question of multiple coronary stenting in one session is neither problematic nor ***,if not all lesions are taken care immediately or in near future sessions,the question would be whether the patient receives standard of care as there is no complete revascularization.

关键词： PCI than

Tuberculosis Diagnosis and Visualization with a Large Vietnamese X-Ray Image Dataset

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Intelligent Automation & Soft Computing 2024年第2期39卷 281-299页

作者： nguyen Trong Vinh Lam Thanh Hien Ha Manh Toan Ngo Duc Vinh Do Nang Toan Faculty of Information Technology Lac Hong UniversityBien HoaDong Nai76120Vietnam Institute of Information Technology Vietnam Academy of Science and TechnologyHanoi10072Vietnam Faculty of Information Technology Hanoi University of IndustryHanoi11915Vietnam

Tuberculosis is a dangerous disease to human life,and we need a lot of attempts to stop and reverse ***,in theCOVID-19 pandemic,access to medical services for tuberculosis has become very *** late detection of tuberculosis could lead to danger to patient health,even *** one of the countries heavily affected by the COVID-19 pandemic,andmany residential areas as well as hospitals have to be isolated for a long *** demands a fast and effective tuberculosis diagnosis solution to deal with the difficulty of accessingmedical services,such as an automatic tuberculosis diagnosis *** our study,aiming to build that system,we were interested in the tuberculosis diagnosis problem from the chest X-ray images of Vietnamese *** chest X-ray image is an important data type to diagnose tuberculosis,and it has also received a lot of attention from deep learning *** paper proposed a novel method for tuberculosis diagnosis and visualization using the deeplearning approach with a large Vietnamese X-ray image *** detail,we designed our custom convolutional neural network for the X-ray image classification task and then analyzed the predicted result to provide visualization as a *** prove the performance of our network model,we conducted several experiments to compare it to another study and also to evaluate it with the dataset of this *** support the implementation,we built a specific annotation system for tuberculosis under the requirements of radiologists in the Vietnam National Lung Hospital.A large experiment dataset was also from this hospital,and most of this data was for training the convolutional neural network *** experiment results were evaluated regarding sensitivity,specificity,and *** achieved high scores with a training accuracy score of 0.99,and the testing specificity and sensitivity scores were over *** on the X-ray image classification result,we visualize pr

关键词： Tuberculosis classification Vietnamese chest X-ray deep learning

One-step hydrothermal synthesis of Sn-doped α-Fe_(2)O_(3) nanoparticles for enhanced photocatalytic degradation of Congo red

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Journal of Semiconductors 2022年第12期43卷 22-31页

作者： Van Nang Lam Thi Bich Vu Quang Dat Do Thi Thanh Xuan Le Tien Dai nguyen T-Thanh-Bao nguyen hoang Tung Do Thi Tu Oanh nguyen Department of Natural Sciences Hoa Lu UniversityNinh NhatNinh Binh CityViet Nam Institute of Theoretical and Applied Research Duy Tan UniversityHanoi 100000Viet Nam Faculty of Natural Sciences Duy Tan UniversityDa Nang 550000Vietnam Institute of Physics Vietnam Academy of Science and Technology10 Dao TanBa DinhHanoiVietnam Institute of Materials Science Vietnam Academy of Science and Technology18 Hoang Quoc VietCaugiayHanoiVietnam

We report on the synthesis of Sn-doped hematite nanoparticles(Sn-α-Fe_(2)O_(3) NPs)by the hydrothermal *** prepared Sn-α-Fe_(2)O_(3) NPs had a highly pure and well crystalline rhombohedral phase with an average particle size of 41.4 *** optical properties of as-synthesizedα-Fe_(2)O_(3) NPs show a higher bandgap energy(2.40-2.57 eV)than that of pure bulkα-Fe_(2)O_(3)(2.1 eV).By doping Sn intoα-Fe_(2)O_(3) NPs,the Sn-doped hematite was observed a redshift toward a long wavelength with in-creasing Sn concentration from 0%to 4.0%.The photocatalytic activity of Sn-dopedα-Fe_(2)O_(3) NPs was evaluated by Congo red(CR)dye *** degradation efficiency of CR dye using Sn-α-Fe_(2)O_(3) NPs catalyst is higher than that of pureα-Fe_(2)O_(3) *** highest degradation efficiency of CR dye was 97.8%using 2.5%Sn-dopedα-Fe_(2)O_(3) NPs catalyst under visible-light *** results suggest that the synthesized Sn-dopedα-Fe_(2)O_(3) nanoparticles might be a suitable approach to develop a photocatalytic degradation of toxic inorganic dye in wastewater.

关键词： α-Fe_(2)O_(3)nanoparticles Sn Congo red photocatalytic properties photodegradation

In vivo real-time monitoring delayed administration of M2 macrophages to enhance healing of tendon by NIR-II fluorescence imaging

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Nano Research 2024年第5期17卷 4379-4390页

作者： Yuzhou Chen Mo Chen Chengxuan Yu Huizhu Li Liman Sai nguyen T.K.Thanh Yueming Wang Yan Wo Jian Zhang Xing Yang Evgenii L.Guryev Andrei V.Zvyagin Hao De Min Tang Shiyi Chen Yunxia Li Yuefeng Hao Sijia Feng Jun Chen Sports Medicine Institute of Fudan University Department of Sports MedicineHuashan HospitalFudan UniversityShanghai 200040China Department of Orthopedic Surgery Xinhua Hospital Affiliated to Shanghai Jiao Tong University School of MedicineShanghai 200092China Department of Bone and Joint Surgery Department of OrthopedicsRenji HospitalSchool of MedicineShanghai Jiao Tong UniversityShanghai 200001China Department of Physics Shanghai Normal UniversityShanghai 200234China Biophysics Group Department of Physics and AstronomyUniversity College LondonLondon WC1E 6BTUK UCL Healthcare Biomagnetic and Nanomaterials Laboratories London W1S 4BSUK Department of Anatomy and Physiology School of MedicineShanghai Jiao Tong UniversityShanghai 200025China Department of Orthopedics Affiliated Suzhou Hospital of Nanjing Medical UniversitySuzhou 215500China Institute of Biology and Biomedicine Lobachevsky State University of Nizhny NovgorodNizhny Novgorod 603950Russia Mathematical Institute University of OxfordOxford OX26GGUK Institute of Natural Sciences School of MathematicsShanghai Jiao Tong UniversityShanghai 200240China

The administration time is a critical but long-neglected point in cell therapy based on macrophages because the incorrect time of macrophage administration could result in diverse outcomes regarding the same macrophage *** this work,the second near-infrared(NIR-II)fluorescence imaging in vivo tracking of M2 macrophages during a pro-healing therapy in the mice model of rotator cuff injury revealed that the behavior of administrated macrophages was influenced by the timing of their *** delayed cell therapy(DCT)group had a longer retention time of injected M2 macrophages in the repairing tissue than that in the immediate cell therapy(ICT)*** Keller-Segel model and histological analysis further demonstrated that DCT altered the chemotaxis of M2 macrophages and improved the healing outcome of the repaired structure in comparison with *** results offer a possible explanation of previous conflicting results on reparative cell therapy and provoke reconsideration of the timing of these therapies.

关键词： macrophage cell therapy NIR-II in vivo imaging delayed therapy tendon healing

Formability improvement and blank shape definition for deep drawing of cylindrical cup with complex curve profile from SPCC sheets using FEM

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Journal of Central South University 2014年第1期21卷 27-34页

作者： Duc-Toan nguyen Duy-Khoe Dinh Hong-Minh Thi nguyen Tien-long Banh Young-Suk Kim School of Mechanical Engineering Hanoi University of Science and Technology1A-Dai Co Viet StreetHai Ba Trung DistrictHanoi CityVietnam Department of Mechanical Engineering Hungyen University of Technology and EducationHungyenVietnam Department of Mechanical Engineering Kyungpook National University1370 SangyeokBuk-kuDaegu 702-701Korea

In the current work, to predict and improve the formability of deep drawing process for steel plate cold rolled commercial grade （SPCC） sheets, three parameters including the blanking force, the die and punch comer radius were considered. The experimental plan according to Taguchi＇s orthogonal array was coupled with the finite element method （FEM） simulations. Firstly, the data from the test of stress-strain and forming limit curves were used as input into ABAQUS/Explicit finite element code to predict the failure occurrence of deep drawing process. The three parameters were then validated to establish their effects on the press formability. The optimum case found via simulation was finally confirmed through an experiment. In order to obtain the complex curve profile of cup shape after deep drawing, the anisotropic behavior of earring phenomenon was modeled and implemented into FEM. After such phenomenon was correctly predicted, an error metric compared with design curve was then measured.

关键词： finite element method SPCC deep-drawing forming limit diagram criterion Taguchi's method earring prediction