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Radical Cation Diels-Alder Reactions of Non-Conjugated Alkenes as Dienophiles by Electrocatalysis

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Chinese Journal of Chemistry 2019年第6期37卷 561-564页

作者： Atsushi Ozaki Yusuke yamaguchi Yohei Okada Kazuhiro Chiba Department of Applied Biological Science Tokyo University of Agriculture and Technology3-5-8 Saiwai-choFuchuTokyo 183-8509Japan Department of Chemical Engineering Tokyo University of Agriculture and Technology2-24-16 Naka-choKoganeiTokyo 184-8588Japan

Radical cation Diels-Alder reactions provide a powerful method for the construction of six-membered ring systems between both electron-rich dienes and dienophiles. However, the most recent examples of this class have been limited to β-methylstyrenes as dienophiles;the use of non-conjugated alkenes remains challenging. The present study describes the serendipitous development of novel radical cation Diels-Alder reactions by electrocatalysis that use non-conjugated alkenes as dienophiles. The key to successful transformation involves highly substituted cyclohexenyl radical cations that are stable enough to be reduced by intermolecular single electron transfer.

关键词： radical cation Diels-Alder reaction non-conjugated alkene electrochemistry single electron transfer

Excision of a large abdominal wall lipoma improved bowel passage in a Proteus syndrome patient

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World Journal of Gastroenterology 2009年第26期15卷 3312-3314页

作者： Yoshifumi Nakayama Shinichi Kusuda Naoki Nagata Koji yamaguchi Department of Surgery 1 School of MedicineUniversity of Occupational and Environmental Health Department of Surgery Moji Medical Center Department of Surgery Kitakyushu General Hospital

Proteus syndrome is an extremely rare congenital disorder that produces multifocal overgrowth of tissue. This report presents a surgical case of a large lipoma in the abdominal wall of a patient with Proteus syndrome. She was diagnosed with Proteus syndrome based on certain diagnostic criteria. The neoplasm increased in size gradually, producing hemihypertrophy of her left lower extremity and trunk, and spread to her retroperitoneum and her left abdominal wall. She experienced gradually progressive constipation, nausea, vomiting, and abdominal pain. Computed tomography （CT） of the abdomen demonstrated a large mass in the subcutaneous adipose tissue of the left lower abdominal wall which measured 12 cm×8 cm×6 cm in diameter and encased the left colon. This mass in the abdominal wall was excised. The weight of the excised mass was 1550 g. The histopathological diagnosis of this mass was lipoma. After surgery, the encasement of the left colon was improved, and the patient was able to move her bowels twice per day. The excision of the large lipoma in the abdominal wall contributed to the improved bowel passage in this patient with Proteus syndrome.

关键词： Proteus syndrome Lipoma Bowel obstruction Abdominal wall Bowel passage

Gastric and enteric anisakiasis successfully treated with Gastrografin therapy: A case report

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World Journal of Gastrointestinal Endoscopy 2018年第3期10卷 69-73页

作者： hiroki Fujikawa Toshio Kuwai Toshiki yamaguchi Ryoichi Miura Yuki Sumida Takeshi Takasago Yuki Miyasako Tomoyuki Nishimura Sumio Iio hiroki Imagawa Atsushi yamaguchi Hirotaka Kouno Hiroshi Kohno Department of Gastroenterology National Hospital OrganizationKure Medical Center and Chugoku Cancer Center

We report a case of a 59-year-old woman who was diagnosed with gastric and small intestinal anisakiasis, which was successfully treated with endoscopic extraction and Gastrografin therapy. She was admitted to our hospital with epigastric pain and vomiting one day after eating raw fish. She exhibited tenderness in the epigastrium without obvious rebound tenderness or guarding. Computed tomography (CT) demonstrated segmental edema of the intestinal wall with proximal dilatation and a small number of ascites. Because enteric anisakiasis was suspected based on the patient's history of recent raw fish consumption and abdominal CT, we performed gastroscopy and confirmed that nine Anisakis larvae were attached to the gastric mucosa. All of the Anisakis larvae were extracted via endoscopy, and the patient was diagnosed with gastric and enteric anisakiasis. Additionally, in the hospital, we performed ileography twice using Gastrografin, which led to shortened hospital stay. Based on the clinical results of this case, we suggest that Gastrografin therapy is a safe, convenient, and useful method to extract enteric Anisakis larvae.

关键词： Enteric anisakiasis Gastrografin Ileus Endoscopic extraction Anisakis larvae

Effects of Asian dust events on atmospheric bacterial communities at different distances downwind of the source region

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Journal of Environmental Sciences 2018年第10期30卷 133-139页

作者： Jonguk Park Pin-Fang Li Tomoaki Ichijo Masao Nasu Nobuyasu yamaguchi Graduate School of Pharmaceutical Sciences Osaka University1-6 Yamada-okaSuitaOsaka 565-0871Japan National Institutes of Biomedical Innovation Health and Nutrition7-6-8 Asagi Saito Ibaraki Osaka 567-0085 Japan College of Resources and Environmental Sciences China Agricultural University Beijing100193 China Faculty of Pharmacy Osaka Ohtani University3-11-1 Nishikiori-kita Tondabayashi Osaka 584-8540 Japan Osaka Institute of Public Health 1-3-69 Nakamichi Higashinari Osaka 537-0025 Japan

Aeolian dust particles arising from arid and semiarid zones are known to carry microbes by air currents. The effect of wind-borne bacteria on atmospheric bacterial population at various downwind distances from the dust source regions must be clarified, but has not yet been reported. This study monitored the bacterial abundance and community composition in outdoor aerosol samples in Beijing, China, which is close to the Asian dust source regions, and compared them with the results obtained in a distant region（Osaka, Japan）.The Asian dust collected in Beijing contained（4 ± 3） × 10^4 bacterial cells/m^3, approximately 4 times higher than in Osaka. On 15 April 2015, Beijing experienced severe Asian dust events with a 1000-fold increase in bacterial abundance, relative to non-Asian dust days. Dominant bacterial phyla and classes in Asian dust collected in Beijing were Actinobacteria, Bacilli and Acidobacteria, and the bacterial community composition varied more widely than in *** bacterial community compositions differed between the Beijing and Osaka dusts, even for the same Asian dust events. These results indicated that aerosol bacterial communities nearer the dust source are more affected by eolian dust than their distant counterparts.

关键词： Aeolian dust Amplicon sequencing Asian dust Bacterial community Bioaerosols

Ground-state mass of ^(22)Al and test of state-of-the-art ab initio calculations

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Chinese Physics C 2024年第3期48卷 72-78页

作者：孙铭泽于越王新鹏王猛李健国张玉虎 K.Blaum 陈祖毅陈瑞九邓涵宇付超义葛文文黄文嘉焦红扬李红蕙李宏福罗胤芳廖挺 YuALitvinov 司敏帅鹏史金阳王茜邢元明徐星徐瑚珊许甫荣袁琪 T.yamaguchi 颜鑫亮杨建成原有进周小红周旭张敏曾奇 CAS Key Laboratory of High Precision Nuclear Spectroscopy Institute of Modern PhysicsChinese Academy of SciencesLanzhou 730000China School of Nuclear Science and Technology University of Chinese Academy of SciencesBeijing 100049China Max-Planck-Institut für Kernphysik Saupfercheckweg 169117 HeidelbergGermany GSI Helmholtzzentrum für Schwerionenforschung Planckstraße 164291 DarmstadtGermany Advanced Energy Science and Technology Guangdong Laboratory Huizhou516007China State Key Laboratory of Nuclear Physics and Technology School of PhysicsPeking UniversityBeijing 100871China Department of Physics Saitama UniversitySaitama 338-8570Japan School of Nuclear Science and Engineering East China University of TechnologyNanchang 330013China

The ground-state mass excess of the T_(z)=−2 drip-line nucleus ^(22)Al is measured for the first time as 18103(10)keV using the newly-developed Bρ-defined isochronous mass spectrometry method at the cooler storage ring in *** new mass excess value allowed us to determine the excitation energies of the two low-lying 1+states in ^(22)Al with significantly reduced uncertainties of 51 *** compared to the analogue states in its mirror nucleus ^(22)F,the mirror energy differences of the two 1^(+)states in the ^(22)Al-^(22)F mirror pair are determined to be−625(51)keV and−330(51)*** excitation energies and mirror energy differences are used to test the state-of-the-art ab initio valence-space in-medium similarity renormalization group calculations with four sets of interactions derived from the chiral effective field *** mechanism leading to the large mirror energy differences is investigated and attributed to the occupation of theπs_(1/2) orbital.

关键词： nuclear mass Bρ-defined IMS mirror energy difference ab initio VS-IMSRG calculations chiral interactions

Natural Convection of Temperature-Sensitive Magnetic Fluids in Porous Media

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Advances in Applied Mathematics and Mechanics 2011年第1期3卷 121-130页

作者： Valentin Roussellet Xiaodong Niu Hiroshi yamaguchi Frederic Magoules Applied Mathematics and Systems Laboratory Ecole Centrale Paris92295 Chatenay-MalabryFrance Department of Mechanical Engineering Doshisha UniversityKyoto 610-0321Japan

In this article,natural convection of a temperature-sensitive magnetic fluid in a porous media is studied numerically by using lattice Boltzmann *** show that the heat transfer decreases when the ball numbers *** the magnetic field is increased,the heat transfer is enhanced;however the average wall Nusselt number increases at small ball numbers but decreases at large ball numbers due to the induced flow being more likely confined near the bottom walls with a high number of obstacles.

关键词： Temperature sensitive magnetic fluid natural convection porous media lattice Boltzmann method

Smad3 phospho-isoform signaling in hepatitis C virus-related chronic liver diseases

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World Journal of Gastroenterology 2014年第35期20卷 12381-12390页

作者： Takashi yamaguchi Katsunori Yoshida Miki Murata Koichi Matsuzaki Department of Gastroenterology and Hepatology Kansai Medical University

The risk of hepatocellular carcinoma (HCC) development increases as hepatitis virus C (HCV)-related liver diseases progress, especially in patients with active inflammation. Insight into hepatic carcinogenesis have emerged from recent detailed analyses of transforming growth factor-β and c-Jun-N-terminal kinase signaling processes directed by multiple phosphorylated (phospho)-isoforms of a Smad3 mediator. In the course of HCV-related chronic liver diseases, chronic inflammation and host genetic/epigenetic alterations additively shift the hepatocytic Smad3 phospho-isoform signaling from tumor suppression to carcinogenesis, increasing the risk of HCC. Chronic inflammation represents an early carcinogenic step that provides a nonmutagenic tumor-promoting stimulus. After undergoing successful antiviral therapy, patients with chronic hepatitis C could experience a lower risk of HCC as Smad3 phospho-isoform signaling reverses from potential carcinogenesis to tumor suppression. Even after HCV clearance, however, patients with cirrhosis could still develop HCC because of sustained, intense carcinogenic Smad3 phospho-isoform signaling that is possibly caused by genetic or epigenetic alterations. Smad3 phospho-isoforms should assist with evaluating the effectiveness of interventions aimed at reducing human HCC.

关键词： Chronic inflammation c-Jun N-terminal kinase Hepatitis C virus Hepatocellular carcinoma Smad3 phospho-isoform signaling Transforming growth factor β

Excited-state conformation capture by supramolecular chains towards triplet-involved organic emitters

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Chinese Chemical Letters 2021年第5期32卷 1669-1674页

作者： Hao Liu Naoki Ando Shigehiro yamaguchi Pance Naumov Hongyu Zhang State Key Laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchun 130012China Department of Chemistry Graduate School of Scienceand Integrated Research Consortium on Chemical Sciences(IRCCS)Nagoya UniversityFuro ChikusaNagoya 464-8602Japan Institute of Transformative Bio-Molecules(WPI-ITbM) Nagoya UniversityFuro ChikusaNagoya 464-8602Japan New York University Abu Dhabi PO Box 129188Abu DhabiUnited Arab Emirates

Nowadays,the development of trip let-involved materials becomes a hot research topic in solid-state luminescence ***,the mechanism of trip let-involved emission still remains some mysteries to ***,we proposed a new concept of excited-state confo rmation capture for the const ructio ns of different types of trip let-involved ***,excited-state conformation could be trapped by supramolecular chains in crystal and fo rm a new optimum excited-state structure which is different from that in solution or simple rigid environment,leading to bright thermally activated delayed fluorescence(TADF) *** on excited-state conformation capture methodology,next,we obtained roomtemperature phosphorescence(RTP) by introducing Br atoms for the enhancement of intersystem *** could be concluded from experime ntal results that TADF may originate from aggregate effect while RTP may derive from ***,heavy-atom free RTP and ultra RTP were achieved by eliminating aggregate *** wo rk could not only exte nd the design methodology of triplet-involved materials but also set clear evidences for the mechanism of triplet-involved emissions.

关键词： Room-temperature phosphorescence Supramolecular chains Conformation capture Organic emitters Triplet-involved emission

Early gastric cancer diagnostic ability of ultrathin endoscope loaded with laser light source

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World Journal of Gastroenterology 2019年第11期25卷 1378-1386页

作者： Takuto Suzuki Yoshiyasu Kitagawa Rino Nankinzan Taketo yamaguchi Department of Endoscopy Chiba Cancer Center Department of Gastroenterology Chiba Cancer Center

BACKGROUND Conventionally, the low luminous intensity, low image resolution, and difficulty in operation have been reported with the ultrathin endoscope. However, it has markedly advanced recently. The improvement of the diagnostic ability is *** To compare the early gastric cancer diagnostic ability of an ultrathin endoscope loaded with a laser light source and that of the conventional *** The target subjects were 375 consecutive patients who underwent endoscopy at our hospital for post-endoscopic submucosal dissection follow-up of gastric cancer from January to August 2018. During endoscopy, the ultrathin endoscope was used in 140 patients(37.3%), and the conventional endoscope was used in235 patients(62.7%). Patient background was adjusted using the propensity score matching method, and gastric cancer detection ability was evaluated in the two *** The gastric cancer detection rate was 7.8% in the ultrathin endoscope group and7.0% in the conventional endoscope group, and the mean intragastric observation time was 4.1 ± 1.7 min in the ultrathin endoscope group and 4.1 ± 1.9 min in the conventional endoscope group, showing no significant differences between the groups. Moreover, the biopsy implementation rate was 31.8% in the ultrathin endoscope group and 41.1% in the conventional endoscope group, and the biopsy prediction rate was 17.9% and 13.2%, respectively, showing no significant differences between the *** The gastric cancer diagnostic ability of the ultrathin endoscope loaded with a laser light source was comparable to that of the conventional endoscope. The observation time was also comparable. Thus, endoscopy using the ultrathin endoscope loaded with the laser light source would be the first option in screening examinations of gastric cancer due to its low invasion.

关键词： Conventional endoscope Gastric cancer Laser light source Screening Ultrathin endoscope