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Crystallization of battery-grade lithium carbonate with high recovery rate via solid-liquid reaction

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Particuology 2024年第9期92卷 95-105页

作者： Chaofan Wu Longjin Jiang Wei Wang Bin Dong Zhidong Chang Daixiang Wei hira Anwar Minghui Zhang Dekun Gao School of Chemistry and Biological Engineering University of Science and Technology BeijingBeijing100083China Anhui Chaoyue Environmental Protection Technology Co. LtdChuzhou239060China State Key Laboratory of Biochemical Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing100190China Anhui Huihong Technology Co. LtdChuzhou239060China

Lithium carbonate(Li_(2)CO_(3))stands as a pivotal raw material within the lithium-ion battery ***,we propose a solid-liquid reaction crystallization method,employing powdered sodium carbonate instead of its solution,which minimizes the water introduction and markedly elevates one-step lithium recovery *** kinetic calculations,the Li_(2)CO_(3)solid-liquid reaction crystallization process conforms by the Avrami equation rather than shrinking core model,which means the dissolution rate of Na_(2)CO_(3)is the most important factor affecting the reaction *** effects of reaction conditions such as temperature and stirring speed on the Li_(2)CO_(3)precipitation behavior were *** results indicated that temperature is a most essential parameter than other reaction conditions or stirring *** exceptional 93%recovery of Li_(2)CO_(3)at 90℃with a remarkable purity of 99.5%was achieved by using 1.2 M ratio of Na_(2)CO_(3)/Li_(2)SO_(4).This method provides a new idea for the efficient preparation of battery-grade Li_(2)CO_(3).

关键词： Lithium recovery Lithium sulfate Reaction crystallization Battery-grade lithium carbonate

Recurrent acute pancreatitis as an initial presentation of primary hyperparathyroidism:A case report

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World Journal of Clinical Cases 2024年第29期12卷 6302-6306页

作者： Masood M Karim hira Raza Om Parkash Department of Medicine The Aga Khan University HospitalKarachi 74800SindhPakistan Department of Surgery Aga Khan University HospitalKarachi 74800SindhPakistan

BACKGROUND With 4.9 to 35 instances per 100000 cases,hyperparathyroidism is one of the rarest causes of acute *** major cause of primary hyperparathyroidism is a parathyroid adenoma,which can manifest clinically in various *** SUMMARY We discuss the unusual case of a 13-year-old boy with recurrent pancreatitis as the initial presentation of primary *** cause of his recurrent pancreatitis remained unknown,and the patient had multiple admissions with acute pancreatitis over 3 *** diagnosis was delayed due to the initial normal levels of parathyroid hormone,which were later reported elevated in a subsequent episode where ultrasound neck and thyroid scintigraphy revealed a parathyroid adenoma as the underlying *** the diagnosis was made,he underwent surgical resection of the *** This case study stresses the importance of considering uncommon causes for recurrent pancreatitis.

关键词： Recurrent pancreatitis Primary hyperparathyroidism Normal serum parathyroid hormone Parathyroid adenoma Case report

Dosage and utilization of dexamethasone in the management of COVID-19: A critical review

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World Journal of Virology 2024年第3期13卷 107-114页

作者： Imran Sethi Asim Shaikh Musa Sethi hira Khalid Chohan Sheraz Younus Syed A Khan Salim Surani Department of Critical Care Medicine Marion General HospitalMarionIN 46952United States Department of Medicine Aga Khan UniversityKarachi 74200SindhPakistan Department of Medicine Eman SchoolFishersIN 46038United States Department of Internal Medicine Dow University of Health ScienceKarachi 74200SindhPakistan Department of Hospital Medicine Franciscan HealthIndianapolisIN 46237United States Department of Critical Care Medicine Mayo Clinic Health SystemMankatoMN 56001United States Department of Medicine and Pharmacology Texas A and M UniversityCollege StationTX 77843United States

BACKGROUND The severe respiratory manifestations observed in severe coronavirus disease 2019(COVID-19)cases are often associated with an excessive inflammatory ***,a synthetic glucocorticoid,exerts its anti-inflammatory effects by inhibiting the transcription of pro-inflammatory genes and suppressing the activity of various immune *** mechanism has implications for mitigating the cytokine storm observed in severe COVID-19 *** on in the pandemic,the Recovery Collaborative working group showed a mortality benefit of using dexamethasone in decreasing mortality in patients with COVID-19 requiring respiratory ***,the optimal dosage of corticosteroids remains *** studies that compare different doses of dexamethasone in COVID-19 exist,but the results are *** To review the latest evidence regarding dosage,safety,and efficacy of dexamethasone in severe *** We followed preferred reporting items for systematic reviews and meta-analysis guidelines.A detailed literature search was conducted across PubMed,Google Scholar,and Medline to include publications up to March *** keywords included“COVID-19”“SARS-CoV-2”“dexamethasone”“corticosteroid”“steroid”and“glucocorticoid”-along with their *** employed the Cochrane Risk of Bias Tool and the Newcastle-Ottawa scale to evaluate the integrity and potential of bias in the included studies.A meta-analysis was conducted using a random-effects model,assessing pooled odds ratios and mean differences,with heterogeneity gauged by the I2 statistic and theχ^(2) *** No statistical differences were found in 28-day all-cause mortality[pooled odds ratio(OR)=1.109,95%CI:0.918-1.340],60-day all-cause mortality(OR=0.873,95%CI:0.744-1.024;I2=47.29%),mean length of hospital stay(mean difference=-0.08 days,95%CI:-0.001 to 0.161)and adverse events(OR=0.877,95%CI:0.707-1.087).CONCLUSION Differing doses of corticosteroids have no clinical implication

关键词： COVID-19 Steroids Corticosteroids Steroid dosage Critical care Corona virus

Embarking on My Chengdu Journey

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Beijing Review 2024年第13期67卷 48-48页

作者： hira Anwar 不详

As a student in Pakistan,it had always been my dream to come to China and immerse myself in its culture and events.I had gleaned knowledge about China's rich history,cultural heritage and economic growth from sources like television and books and,in 2022,my dream finally came true.I arrived in Chengdu,capital of Sichuan Province,to study at the University of Electronic Science and Technology of China(UESTC),renowned as the birthplace of China's electronic technology industry.I was fortunate enough to be enrolled as a *** in the School of Management and Economics.

关键词： dream Chengdu finally

Long-term outcomes of titanium-nitride-oxide coated stents and drug-eluting stents in acute coronary syndrome:A systematic review and meta-analysis

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World Journal of Cardiology 2024年第5期16卷 293-305页

作者： Muhammad Ahmed Ali Fahim Afia Salman hira Anas Khan Syed Muhammad Hasan Muskan FatimaBhojani Sarah Aslam Amna Zia Ul Haq Vishal Reddy Bejugam Beena Muntaha Nasir Wajiha Gul Abdul Moeed Abdelrahman S Abdalla Muhammad Majid Muhammad Sohaib Asghar Md Al Hasibuzzaman Department of Internal Medicine Dow University of Health SciencesKarachi 74200Pakistan Department of Internal Medicine North Central Bronx HospitalBronxNY 10467United States Department of Urology Center for Academic MedicineStanford University School of MedicinePalo AltoCA 33872United States Department of Cardiovascular Imaging Cleveland ClinicClevelandOH 44195United States Division of Nephrology and Hypertension Mayo Clinic RochesterRochesterMN 55905United States Institute of Nutrition and Food Science University of DhakaDhaka 1000Bangladesh

BACKGROUND In severe cases of coronary artery disease,percutaneous coronary intervention provide promising *** stent used could be a drug-eluting stent(DES)or a titanium-nitride-oxide coated stent(TiNOS).AIM To compare the 5-year effectiveness and safety of the two stent *** The following systematic review and meta-analysis was conducted in accordance with the preferred reporting items for systematic reviews and meta-analysis guidelines,and PubMed/MEDLINE,Scopus,and Cochrane Central were searched from inception till August *** outcomes were major adverse cardiac events(MACE),cardiac death,myocardial infarction(MI),cardiac death or MI,and ischemia-driven total lesion revascularization(ID-TLR).RESULTS Four randomized controlled trials(RCT),which analyzed a sum total of 3045 patients with acute coronary syndrome(ACS)after a median follow-up time of 5 years were *** statistically insignificant,an increase in the ID-TLR was observed in patients receiving TiNOSs vs *** addition,MI,cardiac death and MI,and definite stent thrombosis(DST)were significantly decreased in the TiNOS *** analysis revealed no significant results with meta-regression presenting non-ST elevated MI(NSTEMI)as a statistically significant covariate in the outcome of *** TiNOS was found to be superior to DES in terms of MI,cardiac death or MI,and DST outcomes,however,the effect of the two stent types on ID-TLR and MACE was not significant.A greater number of studies are required to establish an accurate comparison of patient outcomes in TiNOS and DES.

关键词： Stents Drug-eluting Major adverse cardiac events All-cause death Meta-analysis

Big Data Analytics in Telecommunications: Literature Review and Architecture Recommendations

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IEEE/CAA Journal of Automatica Sinica 2020年第1期7卷 18-38页

作者： hira Zahid Tariq Mahmood Ahsan Morshed Timos Sellis Faculty of Computer Science Institute of Business AdministrationKarachi 75270Pakistan School of Engineering and Technology CQUniversityMelbourne Victoria 3000Australia University of Technology Hawthorn VIC 3122Australia

This paper focuses on facilitating state-of-the-art applications of big data analytics(BDA) architectures and infrastructures to telecommunications(telecom) industrial *** companies are dealing with terabytes to petabytes of data on a daily basis. Io T applications in telecom are further contributing to this data deluge. Recent advances in BDA have exposed new opportunities to get actionable insights from telecom big data. These benefits and the fast-changing BDA technology landscape make it important to investigate existing BDA applications to telecom sector. For this, we initially determine published research on BDA applications to telecom through a systematic literature review through which we filter 38 articles and categorize them in frameworks, use cases, literature reviews, white papers and experimental validations. We also discuss the benefits and challenges mentioned in these articles. We find that experiments are all proof of concepts(POC) on a severely limited BDA technology stack(as compared to the available technology stack), i.e.,we did not find any work focusing on full-fledged BDA implementation in an operational telecom environment. To facilitate these applications at research-level, we propose a state-of-the-art lambda architecture for BDA pipeline implementation(called Lambda Tel) based completely on open source BDA technologies and the standard Python language, along with relevant *** discovered only one research paper which presented a relatively-limited lambda architecture using the proprietary AWS cloud infrastructure. We believe Lambda Tel presents a clear roadmap for telecom industry practitioners to implement and enhance BDA applications in their enterprises.

关键词： Big data analytics BDA pipeline BDA technology stack lambda architecture python systematic literature review telecommunications

Optimized Hybrid Block Adams Method for Solving First Order Ordinary Differential Equations

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Computers, Materials & Continua 2022年第8期72卷 2947-2961页

作者： hira Soomro Nooraini Zainuddin Hanita Daud Joshua Sunday Department of Fundamental and Applied Sciences Universiti Teknologi PETRONAS32610Seri IskandarPerakMalaysia Department of Mathematics University of Jos930003JosNigeria

Multistep integration methods are being extensively used in the simulations of high dimensional systems due to their lower computational *** block methods were developed with the intent of obtaining numerical results on numerous points at a time and improving computational *** block methods for instance are specifically used in numerical integration of initial value *** this paper,an optimized hybrid block Adams block method is designed for the solutions of linear and nonlinear first-order initial value problems in ordinary differential equations(ODEs).In deriving themethod,the Lagrange interpolation polynomial was employed based on some data points to replace the differential equation function and it was integrated over a specified ***,the convergence properties along with the region of stability of the method were *** was concluded that the newly derived method is convergent,consistent,and *** method was also found to be A-stable implying that it covers the whole of the left/negative half *** the numerical computations of absolute errors carried out using the newly derived method,it was found that the method performed better than the ones with which we compared our results *** also showed its superiority over the existing methods in terms of stability and convergence.

关键词： Initial value problem(IVPs) linear multi-step method block interpolation hybrid Adams-Moulton method

An Access Control Scheme Using Heterogeneous Signcryption for IoT Environments

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Computers, Materials & Continua 2022年第3期70卷 4307-4321页

作者： Insaf Ullah hira Zahid Fahad Algarni Muhammad Asghar Khan Hamdard Institute of Engineering and Technology Islamabad44000Pakistan Department of Information Technology Abbottabad University of Science and TechnologyAbbottabadPakistan College of Computing and Information Technology The University of BishaBishaSaudi Arabia

When the Wireless Sensor Network(WSN)is combined with the Internet of Things(IoT),it can be employed in a wide range of applications,such as agriculture,industry 4.0,health care,smart homes,among *** the big data generated by these applications in Cloud Servers(CSs),requires higher levels of authenticity and confidentiality during communication conducted through the *** is one of the most promising approaches nowadays for overcoming such obstacles,due to its combined nature,i.e.,signature and encryption.A number of researchers have developed schemes to address issues related to access control in the IoT literature,however,the majority of these schemes are based on homogeneous *** will be neither adequate nor practical for heterogeneous IoT *** addition,these schemes are based on bilinear pairing and elliptic curve cryptography,which further requires additional processing time and more communication overheads that is inappropriate for real-time ***,this paper aims to solve the above-discussed issues,we proposed an access control scheme for IoT environments using heterogeneous signcryption scheme with the efficiency and security hardiness of hyperelliptic *** the security services such as replay attack prevention,confidentiality,integrity,unforgeability,non-repudiations,and forward secrecy,the proposed scheme has very low computational and communication costs,when it is compared to existing *** is primarily because of hyperelliptic curve lighter nature of key and other *** AVISPA tool is used to simulate the security requirements of our proposed scheme and the results were under two backbends(Constraint Logic-based Attack Searcher(CL-b-AtSER)and On-the-Fly Model Checker(ON-t-FL-MCR))proved to be SAFE when the presented scheme is coded in HLPSL *** scheme was proven to be capable of preventing a variety of attacks,including confidentiality,integrity,unforge

关键词： Internet of Things(IoT) access control big data heterogeneous signcryption

Recent advances in functional oxides for high energy density sodium-ion batteries

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Materials Reports(Energy) 2021年第2期1卷 3-21页

作者： hira Fatima Yijun Zhong Hongwei Wu Zongping Shao Western Australia School of Mines:Minerals Energy and Chemical Engineering(WASM-MECE)Curtin UniversityPerthWestern Australia6102Australia State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical EngineeringNanjing Tech UniversityNanjing211816PR China

The rapid development of power generation from renewable energy,such as geothermal,wind,and tidal energy,arises the need for efficient and economic electrochemical energy storage systems for integrating electric power smoothly into power *** lithium-ion battery has been successfully utilized for a variety of portable electronic devices but its application in large-scale energy storage has raised concerns about safety,availability of lithium resources,and its increasing ***,sodium-ion battery(SIB)has been in acquisition predominantly,because of the abundant sodium resources over the earth’s crust at low *** high energy density electrode materials is one of the most intensive research *** have been extensively investigated as the cathode and anode materials for high-performance and durable SIBs,owing to their various advantages including facile synthesis,versatile compositions,and easy structural *** this review,we provide an in-time thorough summary of recent advances in oxide materials for cathodes and anodes for high energy density *** energy storage mechanism,challenges,categories,and optimizations of both electrodes are *** research gaps and future perspectives are also *** review is expected to accelerate the research for developing new pathways for tuning the properties of the oxide electrodes based on different sodium storage mechanisms.

关键词： Sodium-ion battery Oxide Cathode Anode High energy density