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Change in Aggregate Shape of Heat Treated Carbon Nanoparticles

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Journal of Chemistry and Chemical Engineering 2013年第4期7卷 326-333页

作者： Kiminori Ono Mlkl Yanaka Aki Watanabe Yoshiya Matsukawa Yasuhiro Saito hideyuki aoki OkiteruFukuda Takayuki aoki Togo Yamaguchi Department of Chemical Engineering Graduate School of Engineering Tohoku University Sendai 980-8579 Japan ASAHI CARBON Co. Ltd. Niigata 950-0883 Japan

To better understand the fusion mechanism of heated carbon black, heat treatment is conducted for carbon black produced by benzene pyrolysis. The effects of （a） heating time, （b） heating temperature and （c） heating rate on the aggregate shape and mean primary particle diameter of the carbon black are investigated using TEM （transmission electron microscopy）. The mean primary particle diameter does not change significantly when carbon black is heat treated. For short heating times and low heating temperatures, the aggregate shapes become simple when compared with those of non-heated carbon black, and shapes become complex with an increase in the heating time. Also, for low heating rates, the aggregate shapes become significantly simple when compared with those of non-heated carbon black. The results of this study suggest that sintering between primary particles is promoted under relatively low heating temperatures, and Ostwald ripening among aggregates is promoted under relatively high heating temperatures.

关键词： Carbon black soot heat treatment.

A Case Report of Synovial Osteochondromatosis of the Knee Joint with neither Calcification nor a Synovial Lesion on Imaging

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Open Journal of Orthopedics 2016年第12期6卷 351-356页

作者： Taihei Go hideyuki aoki Sou Ikata Yoshiyasu Miyazaki Keiji Hasegawa Takashi Nakamura Kazuaki Tsuchiya Department of Orthopedics Toho University Tokyo Japan

Synovial osteochondromatosis is a rare, benign condition of unknown etiology in which the synovium undergoes metaplasia, leading to cartilaginous nodules that ultimately break free, mineralize, and even ossify. The most commonly involved joint is the knee. Typically, radiographs can be diagnostic and mineralized nodules are pathognomonic. In as many as one-third of cases, however, no calcification or ossification of the cartilage occurs in the early stage of the disease because mineralization is time-dependent. In such cases, gadolinium-enhanced MRI can be useful. Unmineralized nodules are typically peripherally enhanced because they are attached to and derive a vascular supply from the synovium. We experienced an unmineralized case of synovial osteochondromatosis of the right knee joint, in which imaging diagnosis was difficult. Neither calcification nor ossification was observed, but all nodules were released from the synovium as loose bodies and there was no vascular supply. Therefore, MRI did not show a typical appearance. These findings suggest that synovial osteochondromatosis should be considered as a differential diagnosis in a case in which unmineralized loose bodies without a synovial lesion are found in an imaging examination.

关键词： Osteochondromatosis Knee Joint Calcification Synovial Lesion

A Case of Simultaneous Total Knee Arthroplasty in Congenital Dislocation of the Patella

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Open Journal of Orthopedics 2018年第7期8卷 267-272页

作者： Kosei Ishigaki hideyuki aoki Muneki Saito Ryo Takamatsu Hiroshi Takahashi Kazuaki Tsuchiya Takashi Nakamura Department of Orthopedic Surgery Toho University Omori Medical Center Tokyo Japan

The gonarthrosis with congenital dislocation of the patella is rare condition. This paper will report about total knee arthroplasty (TKA) for the valgus knee with bilateral congenital dislocation of the patella. A 52-year-old woman presented to our hospital with progressive pain in bilateral knees. Both knee showed severe valgus deformity and lateral dislocation of the patella. Anteroposterior weight-bearing radiographs showed osteoarthritic changes in the lateral compartment with 7 valgus deformity at the right and 15 at the left. A bilateral TKA with cruciate retained components (NAKASHIMA FINE) was performed. Good tracking of the patella was achieved by using a lateral parapatellar approach and vastus medialis plication. There are no normative guidelines of operative procedure about TKA for osteoarthritis of valgus knee with congenital dislocation of the patella. With some referencing to current literature, strategies to good patella tracking are discussed.

关键词： Total Knee Arthroplasty Congenital Dislocation of the Patella Chronic Patellar Dislocation

Posterior Cruciate Ligament Ganglion: Case Report

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Open Journal of Orthopedics 2016年第5期6卷 109-112页

作者： Kosei Ishigaki hideyuki aoki Yoshiyasu Miyazaki Takashi Saito Taisei Sako Ayaka Kuzuhara Kazuaki Tsuchiya Takashi Nakamura Toho University Tokyo Japan

Intra-articular ganglion of the knee is uncommon and it shows non-specific symptoms. In this report, we present for a treatment of the ganglion arising from the PCL and the mechanism of pain. The case is a 33-year-old male with pain in his left knee. On presentation, he had no history of locking or giving way of the knee, but had pain on standing. At the first medical examination, the range of motion of his knee was full, with no loss of extension, and there was no effusion or swelling, but the terminal knee flexion was painful. McMurray’s test was negative, and the collateral and cruciate ligaments were clinically stable. On MRI, ganglion cysts droved from PCL appear as well-defined cystic multiloculated masses. The patient underwent arthroscopy through the standard anteromedial and anterolateral portals. Consequently, it was diagnosed as a ganglion cyst. The pain disappeared completely after the surgery and neither PCL ganglion nor symptoms recurred up to 9 months post-surgery. The intra-articular ganglion of the knee often is asymptomatic and discovered incidentally. But the reports of ganglion cysts of the knee have been increasing with the increasing availability and use of MRI. We considered that the mechanism of the pain due to ganglion in the cruciate ligament was stimulation of the synovial nerve terminal. One key point for consideration in this study is that arthroscopy should be performed through posterior portal to observe the whole of the PCL and ganglion cysts because it was difficult to observe both the PCL and ganglion cysts with anterior portal. While arthroscopy did not confirm continuity of the ACL and meniscus, it was considered that the ganglion cysts developed in the PCL because of the continuity with the PCL.

关键词： PCL Posterior Cruciate Ligament Ganglion

A Case of Rectus Sheath Hematoma Due to Anticoagulants after Total Knee Arthroplasty

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Open Journal of Orthopedics 2016年第6期6卷 135-138页

作者： Wataru Shishikura hideyuki aoki Takashi Nakamura Yoshiyasu Miyazaki Takashi Saito Ryo Takamatsu Katsunori Fukutake Kazuaki Tsuchiya Department of Orthopedics Toho University Tokyo Japan

Background: Hematoma in the rectus sheath is not common but if happens it will become major bleeding. Sometimes anticoaglation of deep vein thrombosis (DVT) causes the hematoma in the rectus sheath. Case Report: A 74-year-old female patient after total knee arthroplasty (TKA) due to osteoarthritis. Postoperation, residual DVT was noted in the right soleus vein on ultrasonography of the veins of the lower limbs. Anticoaglation was started 7.5 mg/day Arixtra for treatment of DVT. Anticoaglation was administered throughout rehabilitation, and abdominal pain developed on postoperative day 9. Since respiratory distress developed on day 10, then thoracoabdominal contrast CT was performed. Although no PE was observed, a hematoma was detected in the rectus sheath, and it perforated into the abdominal cavity. The hemoglobin level was reduced by about 4 g/dL, and the patient was admitted to the ICU. Surgical treatment was not performed, anticoagulant treatment was discontinued, and conservative treatment was administered. During management in the ICU, a total of 24 units of red blood cells were transfused. Conclusions: Rectus sheath hematoma should be in mind of surgeons during differential diagnosis of acute abdominal pain especially in patients receiving anticoagulants. Early recognition can be of great importance for patients’ recovery, preventing from severe complications. Management is usually supportive although surgical intervention in some patients should be considered.

关键词： Rectus Sheath Hematoma TKA Anticoagulation

A Patient with Malignant Spinal Epidural Lymphoma with Initial Rapidly Aggravating Paraplegia

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Open Journal of Orthopedics 2017年第3期7卷 90-97页

作者： Taihei Go Yasuaki Iida hideyuki aoki Shintaro Tsuge Keiji Hasegawa Yuichiro Yokoyama Akihito Wada Yuri Akishima-Fukasawa Hiroshi Takahashi Department of Orthopedics Toho University Tokyo Japan

We report the case of a 51-year-old female with rapid neurological deterioration as an initial presentation of non-Hodgkin’s lymphoma. Paraplegia occurred suddenly after a 4-day history of weakness and numbness of the lower extremity. MRI revealed a dorsal epidural mass from T10 to T11 that compressed the spinal cord. There was neither bone destruction nor a paravertebral mass. Emergency decompressive laminectomy and tumor resection were performed. Histological analysis of the surgical specimen indicated diffuse large B cell lymphoma. The clinical stage was IV on CT and complete remission was achieved by subsequent chemotherapy. Spinal cord compression occurs in the course of non-Hodgkin’s lymphoma in 0.1% - 6.5% of cases, but this situation usually develops in the late phase with bone destruction and/or a paravertebral mass. Cord compression and especially the severe symptoms such as paraplegia are rare as the initial presentation of lymphoma.

关键词： Malignant Lymphoma Epidural Mass Paraplegia Thoracic Spine

Spinal cord injury regenerative therapy development:integration of design of experiments

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Neural Regeneration Research 2025年第9期20卷 2571-2573页

作者： Yuji Okano hideyuki Okano Yoshitaka Kase Division of CNS Regeneration and Drug Discovery International Center for Brain Science(ICBS)Fujita Health UniversityKutsukake-ChoToyoake-ShiAichiJapan Department of Extended Intelligence for Medicine The Ishii-Ishibashi LaboratoryKeio University School of MedicineShinanomachiShinjuku-KuTokyoJapan Keio University Regenerative Medicine Research Center Kawasaki-kuKawasaki-shiJapan

Spinal cord injury(SCI)can cause motor and sensory paralysis,and autonomic nervous system disorders including malfunction of urination and defecation,thereby significantly impairing the quality of *** continue to explo re new stem cell strategies for the treatment of paralysis by transpla nting human induced pluripotent stem cell-derived neural ste m/progenitor cells(hiPSCNS/PCs)into spinal cord injured tissues.

关键词： Spinal paralysis injury

Mechanophore activation enhanced by hydrogen bonding of diarylurea motifs:An efficient supramolecular force-transducing system

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Aggregate

Aggregate 2021年第3期2卷 9-13页

作者： Jumpei Kida Daisuke aoki hideyuki Otsuka Department of Chemical Science and Engineering Tokyo Institute of TechnologyMeguro-kuTokyoJapan

Macromolecules are efficient as mechanical transducers for mechanically induced chemical bond cleavage *** various classes of polymers have been studied as effective mechanical-force transducers for mechanophores,alternatives to polymer chains,that is,small molecules,have rarely been *** this paper,the role of hydrogen bonding as small-molecule mechanical-force transducers for the activation of mechano-responsive molecular units(mechanophores)in the bulk is *** introduction of diarylurea linkage motifs,which are known as strong hydrogen bonding groups,enhances the mechanochemical activation of the fluorescent mechanophore tetraarylsuccinonitrile(TASN)as effectively as the attachment of a typical macromolecular *** paramagnetic resonance measurements of mechanically activated TASN with diphenyl urea motifs demonstrate its higher carbon–carbon bond dissociation ratio compared to that of TASN without diphenyl urea *** efficient supramolecular-forcetransducing system represents a new concept in the field of mechanochemistry,namely,the enhancement of mechanochemical bond scission by simply changing the substituents of a mechanophore,even in small molecules.

关键词： hydrogen bonding mechanophore radical

Principle for obtaining high joint quality in dissimilar friction welding of Ti-6Al-4V alloy and SUS316L stainless steel

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Journal of Materials Science & Technology 2020年第11期42卷 211-224页

作者： Huihong Liu Yo aoki Yasuhiro aoki Kohsaku Ushioda Hidetoshi Fujii Joining and Welding Research Institute Osaka UniversityIbarakiOsaka 567-0047Japan

Ti-6Al-4V alloy(Ti64)and SUS316 L stainless steel rods were dissimilarly friction *** focusing on the detailed observation of interface microstructural evolution during the friction welding(FW),the relationship between the processing conditions,weld interface microstructure,and mechanical properties of the obtained joints were systematically investigated to elucidate the principle for obtaining a high joint quality in the FW of Ti64 and SUS316L.A higher friction pressure produced a lower welding temperature in the FW,hence suppressing the thick intermetallic compound layer ***,hard and brittle Ti64/SUS316L mechanically mixed layers generally formed especially at the weld interface periphery due to the high temperature increasing rate,high rotation linear velocity and high outward flow velocity of the *** harmful layers tended to induce the cracks/voids formation at the weld interfaces hence deteriorating the joints’mechanical *** rotation speed reduction and liquid CO2 cooling during the entire processing decreased the temperature increasing rate,rotation linear velocity and outward flow velocity of the Ti64 at the weld interface ***,they suppressed the formation of the harmful mechanically mixed layers,facilitated the homogeneous and sound interface microstructure generation,and finally produced a high-quality dissimilar joint in the FW of Ti64 and SUS316L.

关键词： Friction welding Titanium alloy Stainless steel Microstructure formation mechanism Mechanically mixed layers