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Molybdenum carbide as catalyst in biomass derivatives conversion

Journal of Energy Chemistry 2022年第10期31卷 68-87,I0003页

作者： Xiangze Du Rui Zhang Dan Li Changwei Hu hermenegildo garcia Key Laboratory of Green Chemistry and Technology Ministry of EducationCollege of ChemistrySichuan UniversityChengdu 610064SichuanChina Instituto Universitario de Tecnología Química Consejo Superior de Investigaciones Científicas.-Universitat Politecnica de ValenciaUniversitat Politecnica de ValenciaAv.De los Naranjos s/nValencia 46022Spain Department of Chemistry University of HelsinkiA.I.Virtasen Aukio 1P.O.Box 5500014Finland

The present energy dilemma in conjunction with the adverse environmental impacts caused by fossil fuel combustion motivates researchers to seek for new renewable energy with minimal CO_(2)*** a practice pathway,it is of significance to produce biofuel and platform chemicals from sustainable biomass ***,the research and development of high-efficiency catalysts remain one key scientific *** the catalysts developed,transition metal carbides,especially molybdenum carbide,show promising performances on biomass-based *** efforts have been made in past few decades on tuning the structure and electronic property of molybdenum carbide via controlling particle size and morphology,metal and nonmetal doping and vacancies,*** review summarizes recent developments of molybdenum carbide as catalysts in converting biomass into fuel,mainly focused on the preparation methods,the structure-dependent effects and the electronic *** controllable selective cleavage of C-C,C-O and C-H bonds over modified molybdenum carbides that has been demonstrated in the conversion of biomass feedstocks is then *** addition,the possible deactivation mechanisms of molybdenum carbide are also presented in the *** review provides systematic and fundamental information for the further design and development of molybdenum carbide for the conversion of biomass resources.

关键词： Molybdenum carbide Synthesis Modification Hydrogenation Biomass Selective cleavage

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Nickel phosphonate MOF as efficient water splitting photocatalyst

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Nano Research 2021年第2期14卷 450-457页

作者： Pablo Salcedo-Abraira Sergio M.F.Vilela Artem A.Babaryk Maria Cabrero-Antonino Pedro Gregorio Fabrice Salles Sergio Navalon hermenegildo garcia Patricia Horcajada IMDEA Energy Advanced Porous Materials Unit(APMU)Avda.Ramon de Ia Sagra 3E 28935 MostolesMadridSpain Deparrtamento de Quimica Inorginica I.Fac.CC.Quimicas Universidad Complutense de MadridAvda.Complutense s/n28040 MadridSpain Departamento de Quimica and Instituto de Tecnologia Quimica(CSIC-UPV) Universitat Politecnica de ValenciaC/Camino de Veras/n46022 ValenciaSpain Institut Charles Gerhardt Montpellier UMR 5253 CNRS UM ENSCMUniversite MontpellierPlace E.Bataillon34095 Montpellier Cedex 05France

A novel microporous two-dimensional(2D)Ni-based phosphonate metal-organic framework(MOF;denoted as IEF-13)has been successfully synthesized by a simple and green hydrothermal method and fully characterized using a combination of experimental and computational *** resolution by single-crystal X-ray diffraction reveals that IEF-13 crystallizes in the triclinic space group Pi having bi-octahedra nickel nodes and a photo/electroactive tritopic phosphonate ***,this material exhibits coordinatively unsaturated nickel(II)sites,free-P0_(3)H_(2)and-P0_(3)H acidic groups,a C0_(2)accessible microporosity,and an exceptional thermal and chemical ***,its in-deep optoelectronic characterization evidences a photoresponse suitable for *** this sense,the photocatalytic activity for challenging H_(2)generation and overall water splitting in absence of any co-catalyst using UV-Vis irradiation and simulated sunlight has been evaluated,constituting the first report for a phosphonate-MOF ***-13 is able to produce up to 2,200 fimol of H_(2)per gram using methanol as sacrificial agent,exhibiting stability,maintaining its crystal structure and allowing its *** more,170μmol of H_(2)per gram were produced using IEF-13 as photocatalyst in the absence of any co-catalyst for the overall water splitting,being this reaction limited by the 0_(2)*** present work opens new avenues for further optimization of the photocatalytic activity in this type of multifunctional materials.

关键词： metal-organic framework phosphonates photocatalysis water splitting

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