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Effect of iridium loading on HZSM-5 for isomerization of n-heptane

Journal of Natural Gas Chemistry 2011年第5期20卷 477-482页

作者： herma dina setiabudi Sugeng Triwahyono Aishah Abdul Jalil Nur Hidayatul Nazirah Kamarudin Muhammad Arif Ab Aziz Department of Chemical Engineering Faculty of Chemical Engineering Universiti Teknologi Malaysia Ibnu Sina Institute for Fundamental Science Studies Faculty of Science Universiti Teknologi Malaysia

The effect of iridium loading on the properties and catalytic isomerization of n-heptane over Ir-HZSM-5 is studied. Ir-HZSM-5 was prepared by impregnation method and subjected to isomerization process in the presence of flowing hydrogen gas. XRD and BET studies show that the presence of iridium stabilizes the crystalline structure of HZSM-5, leading to more ordered framework structure and larger surface area. TGA and FTIR results substantiate that iridium species interacts with OH group on the surface of HZSM-5. Pyridine FT-IR study verifies the interaction between iridium and surface OH group slightly increased the Bro¨nsted and Lewis acid sites without changing the lattice structure of HZSM-5. The presence of iridium and the increase of strong Lewis acid sites on HZSM-5 were found to bring an increase about 4.1%, 33.2% and 11.8% in conversion, selectivity and yield of n-heptane isomerization, respectively.

关键词： Ir-HZSM-5 n-heptane isomerization Lewis acid sites protonic acid sites

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Negative effect of Ni on PtHY in n-pentane isomerization evidenced by IR and ESR studies

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Journal of Natural Gas Chemistry 2012年第1期21卷 29-36页

作者： Muhammad Arif Ab Aziz Nur Hidayatul Nazirah Kamarudin herma dina setiabudi Halimaton Hamdan Aishah Abdul Jalil Sugeng Triwahyono Department of Chemical Engineering Faculty of Chemical Engineering Universiti Teknologi Malaysia 81310 UTM Johor Bahru Johor Malaysia Department of Chemistry Faculty of Science Universiti Teknologi Malaysia 81310 UTM Johor Bahru Johor Malaysia Ibnu Sina Institute for Fundamental Science Studies Faculty of Science Universiti Teknologi Malaysia 81310 UTM Johor Bahru Johor Malaysia

Ni/PtHY with different Ni loadings was prepared by impregnating HY with hexachloroplatinic acid solution and Ni2＋/N,N-dimethylformamide solution. An increase in the Ni loading decreased the crystallinity, specific surface area and meso-micropores of the catalysts. Ni interacted with hydroxyl groups to produce IR absorption bands at 3740-3500 cm-1, Increasing Ni loadings resulted in a decrease in the intensities of the broad bands at 3730-3500 cm-1 and the sharp band at 3740 cm-1 with simultaneous development of new absorbance band at 3700 cm-1 that was attributed to （-OH）Ni. The acidity of the samples did not significantly change with Ni loadings up to 1.0 wt%, which indicated that Ni mostly interacts with non-acidic silanol groups （terminal- and structural-defect OH groups）. The presence of Ni decreased the activity of PtHY toward the isomerization of n-pentane because of a decrease in the number of active protonic-acid sites that formed from molecular hydrogen. IR and ESR studies confirmed that Pt facilitated the formation of protonic-acid sites from molecular hydrogen, whereas Ni, even when combined with Pt, didn＇t exhibit such ability. The absence of protonic-acid sites from molecular hydrogen significantly decreased the yield of iso-pentane and markedly increased the cracking products.

关键词： Ni.Ni/PtHY n-pentane isomerization hydrogen protonic acid sites

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