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Thermodynamic and Economic Analysis of a Conceptual System Combining Sludge Gasification,SOFC,Supercritical CO2 Cycle,and Organic Rankine Cycle

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Journal of Thermal Science 2024年第4期33卷 1491-1508页

作者： LV Jiayang WANG Chizhong CHEN heng pan Peiyuan XU Gang ZHANG Guoqiang School of Energy Power and Mechanical EngineeringNorth China Electric Power University

In order to reduce the environmental impact of conventional sludge treatment methods and to utilize the energy in sludge more effectively,a coupled system based on sewage sludge gasifier（SSG）,solid oxide fuel cells（SOFC）,supercritical CO2cycle（S-CO2）,and organic Rankine cycle（ORC） is proposed.The clean syngas obtained from sludge gasification is mixed with CH4 and then first utilized by the fuel cell.The exhaust gas from the fuel cell is fully combusted in the afterburning chamber and then enters the bottom cycle system consisting of S-CO2& ORC to generate electricity.To understand the performance of the system,thermodynamic and economic analyses were conducted to examine the project's performance.The thermodynamics as well as the economics of the coupled system were analyzed to arrive at the following conclusions,the power production of the system is 37.34 MW;the exergy efficiency is 55.62%,and the net electrical efficiency is 61.48%.The main exergy destruction is the gasifier and SOFC,accounting for 62.45% of the total exergy destruction.It takes only6.13 years to repay the construction investment in the novel system,and the project obtains a NPV of 17 723 820USD during 20 years lifetime.The above findings indicate that the new coupled system has a better performance in terms of energy utilization and economy.

关键词： sewage sludge gasifier SOFC supercritical CO 2 cycle organic Rankine cycle multi-system coupling

High-entropy rare earth stannate ceramics:Acid corrosion resistant radiative cooling materials with high atmospheric transparency window emissivity and high near-infrared solar reflectivity

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Journal of Advanced Ceramics 2024年第5期13卷 630-640页

作者： Tao Chen Yanyan He Yanyu pan Kaixian Wang Minzhong Huang Liyan Xue Yazhu Li Fan Yang Yanchun Zhou heng Chen Fujian Institute of Research on the Structure of Matter Chinese Academy of SciencesFuzhou 350002China College of Chemistry and Materials Science Fujian Normal UniversityFuzhou 350117China Xiamen Institute of Rare Earth Materials Haixi InstitutesChinese Academy of SciencesXiamen 361021China Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China Fuzhou 350108China Xiamen Key Laboratory of Rare Earth Photoelectric Functional Materials Xiamen Institute of Rare Earth MaterialsHaixi InstitutesChinese Academy of SciencesXiamen 361021China Key Laboratory of Rare Earths Ganjiang Innovation AcademyChinese Academy of SciencesGanzhou 341000China School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001China

In response to the development of the concepts of“carbon neutrality”and“carbon peak”,it is critical to developing materials with high near-infrared(NIR)solar reflectivity and high emissivity in the atmospheric transparency window(ATW;8–13μm)to advance zero energy consumption radiative cooling technology.To regulate emission and reflection properties,a series of high-entropy rare earth stannate ceramics(HE-RE_(2)Sn_(2)O_(7):(Y_(0.2)La_(0.2)Nd_(0.2)Eu_(0.2)Gd_(0.2))_(2)Sn_(2)O_(7),(Y_(0.2)La_(0.2)Sm_(0.2)Eu_(0.2)Lu_(0.2))_(2)Sn_(2)O_(7),and(Y_(0.2)La_(0.2)Gd_(0.2)Yb_(0.2)Lu_(0.2))_(2)Sn_(2)O_(7))with severe lattice distortion were prepared using a solid phase reaction followed by a pressureless sintering method for the first time.Lattice distortion is accomplished by introducing rare earth elements with different cation radii and mass.The as-synthesized HE-RE_(2)Sn_(2)O_(7)ceramics possess high ATW emissivity(91.38%–95.41%),high NIR solar reflectivity(92.74%–97.62%),low thermal conductivity(1.080–1.619 W·m^(−1)·K^(−1)),and excellent chemical stability.On the one hand,the lattice distortion intensifies the asymmetry of the structural unit to cause a notable alteration in the electric dipole moment,ultimately enlarging the ATW emissivity.On the other hand,by selecting difficult excitation elements,HE-RE_(2)Sn_(2)O_(7),which has a wide band gap(Eg),exhibits high NIR solar reflectivity.Hence,the multi-component design can effectively enhance radiative cooling ability of HE-RE_(2)Sn_(2)O_(7)and provide a novel strategy for developing radiative cooling materials.

关键词： radiative cooling materials high-entropy ceramics(HECs) rare earth stannate(RE_(2)Sn_(2)O_(7)) high atmospheric transparency window emissivity high near-infrared(NIR)solar reflectivity

ⅢA-ⅡB multicomponent perovskite rare earth ferrites with promising electromagnetic wave absorption properties

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Journal of Rare Earths 2024年第6期42卷 1118-1127,I0005页

作者： Yanyan He Tao Chen Yanyu pan Minzhong Huang Kaixian Wang Liyan Xue Yazhu Li Fengzhi Tan Fan Yang Tongkuan Xu heng Chen School of Light Industry and Chemical Engineering Dalian Polytechnic UniversityDalian116034China Xiamen Institute of Rare EarthMaterials Haixi InstitutesChinese Academy of SciencesXiamen36021China Fujian Institute of Research on the Structure of Matter Chinese Academyof SciencesFuzhou350002China Fujian Science&Technology Innovation Laboratory for Optoelectronic Information of China Fuzhou350108China Xiamen Key-Laboratoryof Rare Earth Photoelectric Functional Materials Xiamen Institute of Rare Earth MaterialsHaixi InstituteChinese Academy of SciencesXiamen361021China Key Laboratory of Rare Earths Ganjiang Innovation AcademyChinese Academy of SciencesGanzhou3410ooChina

Perovskite-type rare-earth ferrites(REFeO_(3))are promising materials for absorbing electromagnetic(EM)wave pollution.However,insufficient dielectric loss and poor impedance matching are key factors that limit the broader implementation of REFeO_(3).Herein,a series of multicomponent perovskite-type ferrites with strong EM wave absorption capabilities was prepared.Through the synergistic effect of chemical constitution regulation and entropy regulation,optimization of the dielectric loss and impedance matching is achieved by strengthening the structural defect mechanism,thus further adjusting the EM wave absorption performance.Compared with(LaGdSmNdBa)FeO_(3)(HE-1)and(LaGdPrSmNdBa)FeO_(3)(HE-2),(LaGdBa)FeO_(3)(ME-1)and(LaGdSmBa)FeO_(3)(ME-2)exhibit favorable performance,with optimal minimum reflection loss(RL_(min))of-56.35 dB(at 11.12 GHz)and-63.25 dB(at 7.22 GHz)and effective absorption bandwidth(EAB)of 4.46 and 4.72 GHz,respectively.This multicomponent design provides a new strategy for the development of EM wave absorption materials.

关键词： Rare earths Multicomponent design Rare earth ferrites Entropy regulation Electromagnetic wave absorption

Significantly enhanced superconductivity in monolayer FeSe films on SrTiO3（001） via metallic δ-doping

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National Science Review 2024年第3期11卷 119-127页

作者： Xiaotong Jiao Wenfeng Dong Mingxia Shi heng Wang Cui Ding Zhongxu Wei Guanming Gong Yanan Li Yuanzhao Li Binjie Zuo Jian Wang Ding Zhang Minghu pan Lili Wang Qi-Kun Xue State Key Laboratory of Low-Dimensional Quantum Physics Department of Physics Tsinghua University School of Physics&Information Technology Shaanxi Normal University Beijing Academy of Quantum Information Sciences Department of Physics Southern University of Science and Technology International Center for Quantum Materials School of Physics Peking University Department of Physics The Pennsylvania State University Collaborative Innovation Center of Quantum Matter Hefei National Laboratory

Superconductivity transition temperature（Tc） marks the inception of a macroscopic quantum phase-coherent paired state in fermionic systems. For 2D superconductivity, the paired electrons condense into a coherent superfluid state at Tc, which is usually lower than the pairing temperature, between which intrinsic physics including Berezinskii–Kosterlitz–Thouless transition and pseudogap state are hotly debated. In the case of monolayer FeSe superconducting films on SrTiO3（001）, although the pairing temperature（Tp） is revealed to be 65–83 K by using spectroscopy characterization, the measured zero-resistance temperature（Tc0） is limited to 20 K. Here, we report significantly enhanced superconductivity in monolayer FeSe films by δ-doping of Eu or Al on SrTiO3（001） surface, in which Tc0is enhanced by 12 K with a narrowed transition width ΔTc～8 K, compared with non-doped samples. Using scanning tunneling microscopy/spectroscopy measurements, we demonstrate lowered work function of the δ-doped SrTiO3（001） surface and enlarged superconducting gaps in the monolayer FeSe with improved morphology/electronic homogeneity. Our work provides a practical route to enhance 2D superconductivity by using interface engineering.

关键词： monolayer FeSe interface superconductivity δ-doping zero-resistance temperature superconductivity transition temperature

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一种信标辅助的北斗伪卫星CPD定位方法

西安电子科技大学学报 2024年第2期51卷 107-115页

作者：张衡蔚保国潘树国东南大学仪器科学与工程学院江苏南京210096 中国电子科技集团公司第五十四研究所河北石家庄050081 卫星导航系统与装备技术国家重点实验室河北石家庄050081

针对北斗伪卫星信号引入室内并在小尺度空间下提供高精度定位的难题,如何在顾及网络建设成本的基础上提升小尺度空间的定位时效性和定位精度是未来室内定位技术中需要解决的重要一环。此处充分结合室内环境下小尺度空间的空间特征,提出... 详细信息

针对北斗伪卫星信号引入室内并在小尺度空间下提供高精度定位的难题,如何在顾及网络建设成本的基础上提升小尺度空间的定位时效性和定位精度是未来室内定位技术中需要解决的重要一环。此处充分结合室内环境下小尺度空间的空间特征,提出一种室内节点信标辅助的北斗伪卫星载波相位差定位方法。该方法首先将传统的大范围指纹构建问题转化为指纹节点的方式,在指纹图谱的基础上提出室内节点信标的概念,通过信标节点实现小尺度空间与周围空间的连接,并对以载噪比和载波相位为基础的信标特征谱构建与处理进行了分析;然后以室内节点信标为基础给出了基于载波相位差的位置估计过程,最后结合粒子群寻优算法提出一种顾及行人特征的位置与速度空间约束下的位置搜索算法。在真实环境下的试验结果表明,通过室内节点信标的辅助在室内环境可以实现动态定位精度优于30 cm、暂停态下的定位精度优于25 cm的定位效果。正常步速运动下算法与惯性导航定位精度相当,同时相比于惯性导航方式具有更宽松的运动姿态条件。在小尺度空间下算法具有更优的适用性。

关键词：北斗伪卫星小尺度空间载波相位室内节点信标高精度定位

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High‑Speed Sirospun Conductive Yarn for Stretchable Embedded Knitted Circuit and Self‑Powered Wearable Device

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Advanced Fiber Materials 2023年第1期5卷 154-167页

作者： Li Niu Jin Wang Kai Wang heng pan Gaoming Jiang Chaoyu Chen Pibo Ma Engineering Research Center of Knitting Technology Ministry of EducationCollege of Textile Science and EngineeringJiangnan UniversityWuxi 214122China State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430200China

In the intelligent era,the textile technique is a high efficiency,mature and simple manufacturing solution capable of fabricat-ing fully flexible wearable devices.However,the external circuit with its integration and comfort limitations cannot satisfy the requirements of intelligent wearable and portable devices.This study presents an industrialized production method to fabricate core–shell structure conductive yarn for direct textile use,prepared by the high-speed sirospun technique.Both integration and flexibility are significantly improved over previous works.Combining sirospun conductive yarn(SSCY)and the intarsia technique can provide the SSCY seamless and convenient embedded knitted circuit(SSCY-EKC)to form a full textile electrical element as the channel of power and signals transmission,allowing for a stable resistance change and wide strain range for meeting practical applications.SSCY based on the triboelectric nanogenerator(SSCY-TENG)can be designed as a caution carpet with attractive design and good washability for a self-powered sensor that recognizes human motions.Furthermore,intrinsic textile properties such as washability,softness,and comfort remained.With benefits such as excellent extension,fitting,and stretchability,the SSCY-EKC used herein can realize a fully flexible electrical textile with a high potential for physical detection,body gesture recognition,apparel fashion,and decoration.

关键词： Sirospun technique Embedded knitted circuit Intarsia technique Stretchable Wearable devices

Audit Scheme of University Scientific Research Funds Based on Consortium Blockchain

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国际计算机前沿大会会议论文集 2022年第2期 351-375页

作者： Pengfan Yue heng pan Zhongyuan University of Technology Zhengzhou 450007HenanChina Henan International Joint Laboratory of Blockchain Data Sharing Zhengzhou 450007HenanChina

In the current process of university scientific research funding audits,the auditors do not obtain audit evidence in a timely manner,resulting in a lag in audit time;at the same time,there is the possibility that the audit evidence may be tampered with,and the sensitive expenditure cannot be effectively protected.Based on this,this paper proposes an audit scheme for university scientific research funds based on a consortium chain.The scheme saves relevant audit evidence through blockchain and IPFS,which changes the storage method of traditional audit evidence and effectively ensures the integrity,auditability of audit evidence and verifiability,and facilitates real-time auditing.We use Pedersen Commitment and Zero-Knowledge Range Proof to ensure the auditability of sensitive data;use smart contracts to automate auditing to further ensure that auditors can find relevant audit issues in a timely manner;and separate different departments and construct an audit tree through multi-channel technology to ensure the integrity and reliability of data and improve audit efficiency and accuracy.Finally,functional comparison analysis and security analysis show that the scheme in this paper has certain feasibility and robustness.

关键词： Blockchain Real-time audit Pedersen Commitment Zero-knowledge range proof Audit tree

预制拼接槽型UHPC柱偏心受压性能试验研究

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湖南大学学报（自然科学版） 2024年第1期51卷 55-66页

作者：周云周易李剑潘恒杜宗湖南大学土木工程学院湖南长沙410082 工程结构损伤诊断湖南省重点实验室(湖南大学) 湖南长沙410082 中建三局第一建设工程有限责任公司湖北武汉430040

为研究预制拼接槽型UHPC柱在受压条件下的力学性能及其影响因素,开展2根整浇UHPC柱及14根预制拼接槽型UHPC柱在不同拼接形式、不同偏心受压方向及不同偏心距下的轴心或偏心受压试验研究.通过考察试件的极限承载力、破坏形态、轴向及侧... 详细信息

为研究预制拼接槽型UHPC柱在受压条件下的力学性能及其影响因素,开展2根整浇UHPC柱及14根预制拼接槽型UHPC柱在不同拼接形式、不同偏心受压方向及不同偏心距下的轴心或偏心受压试验研究.通过考察试件的极限承载力、破坏形态、轴向及侧向变形性能,研究了拼接方式、偏压方向和偏心距对其静力性能的影响.试验结果表明:钢纤维延缓了UHPC的开裂,增强了试件的变形能力,但预制拼接槽型UHPC柱在轴压和小偏压荷载下仍表现出明显脆性破坏特征;在该试验中,偏压柱的破坏形态主要为小偏心受压破坏及大偏心受拉破坏;在相同偏心距下,不同拼接形式、不同偏心受压方向的柱体破坏形态及承载能力表现趋于一致;在相同尺寸与配筋下,预制拼接槽型UHPC柱承载力随偏心距的增加而减小.最后,通过对比试件承载力试验值和我国现行规范理论计算值,定性地指出了现行规范的局限性.本文试验数据可为预制拼接槽型UHPC柱设计提供参考.

关键词：预制拼接槽型UHPC柱轴心受压偏心受压受压试验极限承载力

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复合酵素的贮藏稳定性及货架期研究

食品与发酵工业 2024年第1期50卷 59-66页

作者：刘恒范柳萍张涛潘牧江南大学食品学院江苏无锡214122 贵州省农业科学院生物技术研究所贵州贵阳550006

该研究采用克鲁弗毕赤酵母菌(Pichia kluyveri)和植物乳植杆菌(Lactiplantibacillus plantarum)共发酵制备复合酵素,旨在研究其产品经巴氏杀菌处理后的贮藏稳定性,并建立一个可靠的货架期预测模型。该实验将杀菌后的复合酵素分别放置在4... 详细信息

该研究采用克鲁弗毕赤酵母菌(Pichia kluyveri)和植物乳植杆菌(Lactiplantibacillus plantarum)共发酵制备复合酵素,旨在研究其产品经巴氏杀菌处理后的贮藏稳定性,并建立一个可靠的货架期预测模型。该实验将杀菌后的复合酵素分别放置在4、25、37℃恒温贮藏,测定了复合酵素的感官品质、理化性质和活性成分在贮藏期间的变化。此外,根据Arrhenius方程和零级动力学反应建立了该复合酵素的货架期模型,通过此模型对复合酵素的货架期进行预测并通过实验进行验证。实验结果表明,4℃贮藏的复合酵素pH和总酸变化幅度最小,表现出最高的稳定性,且贮藏56 d后pH值为3.41。抗坏血酸在贮藏过程中分别降低了33.10%、52.11%和77.93%,超氧化物歧化酶活力也呈现不同程度的下降趋势,且抗坏血酸对其具有一定的保护作用。色差ΔE和感官评分在4℃劣变速度最慢。根据建立的货架期模型,预测该复合酵素在常温下的货架期为184 d。在不同温度下(10、20、25℃)对该货架期模型进行验证,相对误差均在5%以下。因此,此货架期模型较为可靠。

关键词：复合酵素贮藏感官品质理化性质活性成分货架期模型