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Kaoline-based catalyst for a high stability desulfurization of sour heavy naphtha in a three-phase oscillatory baffled reactor

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Particuology 2024年第1期84卷 249-260页

作者： hassan M.Hmood Saba A.Gheni Safaa M.R.Ahmed Mudheher M.Ali Hamid Yonis Saleh mohammed H.mohammed Awad E.mohammed Marwan A.Mahomood Hiba R.mohammed Ahmed A.hassan Adam Harvey North Refineries Company Ministry of OilIraq Chemical Engineering Department Tikrit UniversityIraq Ministry of Oil Iraq AL-Hawija Technical Institute Northern Technical UniversityMoselIraq School of Engineering Newcastle UniversityUK

To meet the rapidly increasing demand for energy and the dramatic depletion of conventional crude oil,it is imperative to utilize sour *** no coke being produced,oxidative desulfurization(ODS)of naphtha lowers its sulfur content and average molecular *** this article,we outline a method for heavy naphtha non-extractive ODS using a very stable *** technique involves the use of a solid catalyst with oxygen gas as the *** necessitated relatively high mixing intensities;hence a three-phase Oscillatory Baffled Reactor(OBR)was *** catalyst was based on the zeolite ZSM-5,prepared from natural kaolin by a series of delamination and activation steps and impregnated with Fe.A TiO2 nanolayer was applied,using the sol-gel method,to prevent rapid *** reactor performance was evaluated to minimize the sulfur content in the naphtha *** to the protective coating,the sulfur conversion stabilized at 90%.The results of this work establish the use of natural clay-based catalysts in a continuous,three-phase ODS,particularly with regard to proving long-term *** also showed that modest ODS can be achieved using an environmentally friendly oxidant,at mild operating conditions,whilst maintaining stability.

关键词： Natural kaoline Desulfurization Three-phase Oscillatory baffled reactor

Gastrointestinal Symptoms—A Rare Complication of Untreated CPA Tumor

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Health 2023年第8期15卷 839-844页

作者： hassan mohammed ismael mohammed Farooq Ahmad Mohamed Abdalrahman Raoof Hagag Ghazy Mohamed Abdelgani Abdlegani Ngwira Joseph Gastroenterology/Medicine Department United Lincolnshire Hospitals NHS Trust Grantham Hospital Grantham UK Internal Medicine Department United Lincolnshire Hospitals NHS Trust Grantham Hospital Grantham UK Acute medicine Department United Lincolnshire Hospitals NHS Trust Grantham Hospital Grantham UK Intensive Care Department Medicine University Hospital Coventry NHS Trust Coventry UK Cardiology Department Scarborough General Hospital Scarborough UK Bank Consultant Internal Medicine Department United Lincolnshire Hospitals NHS Trust Grantham Hospital Grantham UK

Cerebellopontine angle (CPA) lesions account for up to 10% of all intracranial tumors. Most CPA tumors are benign, but can cause nerve damage or compress the surrounding structures if left untreated. The typical presentation is with adult-onset sensorineural hearing loss or non-pulsatile tinnitus. In some patients, this goes unnoticed, and presentation is delayed until the lesion is much larger and presents with symptoms related to mass effect. We present the case study of 63 years old gentleman, who had suspected left CPA lesion on CT head done few years ago for dizziness and left-sided facial numbness. MRI could not be done at that time due to his MRI incompatible pacemaker leading to delay in his management eventually causing loss of patient to the follow up. He later developed progressive difficulty in walking which was initially attributed to as secondary to vasovagal syncope and postural hypotension. He eventually presented to us with intractable nausea and vomiting, worsening headache and ataxia. He had an urgent CT head which showed significant growth in the lesion with compression of the surrounding structures and obstructive hydrocephalus. He was given steroids which improved his nausea and vomiting, followed by undergoing surgery in regional center leading to significant improvement in his gait within few days of surgery. He unfortunately continued to have a degree of ataxia and facial numbness. This case illustrates a rare presentation of CPA tumor with symptoms of nausea and vomiting as a result of mass effect of the growing tumor. In addition, this review also shows the importance of regularly following up the patients with suspected CPA lesions on initial scans which will help with identifying the increase in size of lesion promptly and potentially preventing advanced complications of CPA tumors. We suggest regular monitoring of these patients to timely manage the lesion and avoid the potential life-threatening complications.

关键词： Cerebellopontine Angle (CPA) Vestibulocohlear Nerve (CNV111) Vestibular Schwannoma (VS) Sensorineural Hearing Loss Facial Nerve (CN VII) Vagus Nerve Microsurgery Gamma Knife Surgery (GKS Hydrocephalus)

Analysis of CH_(4) and H_(2) Adsorption on Heterogeneous Shale Surfaces Using aMolecular Dynamics Approach

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Fluid Dynamics & Materials Processing 2024年第1期20卷 31-44页

作者： Surajudeen Sikiru hassan Soleimani Amir Rostami mohammed Falalu Hamza Lukmon Owolabi Afolabi Centre of Subsurface Imaging(CSI) Universiti Teknologi PETRONASTronohPerakMalaysia Department of Geosciences Universiti Teknologi PETRONASBandar Seri IskandarTronohPerakMalaysia Department of Pure&Industrial Chemistry Faculty of Physical SciencesBayero University KanoKanoNigeria Department of Mechanical Engineering Engineering Institute of TechnologyMelbourne Campus VictoriaMelbourneAustralia

Determining the adsorption of shale gas on complex surfaces remains a challenge in molecular simulation *** essentially stem from the need to create a realistic shale structure model in terms of mineral heterogeneityand ***,precise characterization of the competitive adsorption of hydrogen andmethane in shale generally requires the experimental determination of the related adsorptive *** thisstudy,the adsorption of adsorbates,methane(CH_(4)),and hydrogen(H_(2))on heterogeneous shale surface modelsof Kaolinite,Orthoclase,Muscovite,Mica,C_(60),and Butane has been simulated in the frame of a moleculardynamic’s numerical *** results show that these behaviors are influenced by pressure and *** increasing the pressure from 500 to 2000 psi,the sorption effect for CH_(4)significantly increasesbut shows a decline at a certain stage(if compared to H_(2)).The research findings also indicate that raw shalehas a higher capacity to adsorb CH_(4)compared to ***,in shale,this difference is negligible.

关键词： Shale gas adsorption methane hydrogen molecular dynamic sorption

RPL-Based IoT Networks under Decreased Rank Attack:Performance Analysis in Static and Mobile Environments

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Computers, Materials & Continua 2024年第1期78卷 227-247页

作者： Amal Hkiri Mouna Karmani Omar Ben Bahri Ahmed mohammed Murayr Fawaz hassan Alasmari Mohsen Machhout Physic Department Electronics and Micro-Electronics LaboratoryFaculty of Sciences of MonastirMonastir5000Tunisia Department of Science and Technology College of RanyahTaif UniversityP.O.Box 11099Taif21944Saudi Arabia

The RPL(IPv6 Routing Protocol for Low-Power and Lossy Networks)protocol is essential for efficient communi-cation within the Internet of Things(IoT)*** its significance,RPL’s susceptibility to attacks remains a *** paper presents a comprehensive simulation-based analysis of the RPL protocol’s vulnerability to the decreased rank attack in both static andmobilenetwork *** employ the Random Direction Mobility Model(RDM)for mobile scenarios within the Cooja *** systematic evaluation focuses on critical performance metrics,including Packet Delivery Ratio(PDR),Average End to End Delay(AE2ED),throughput,Expected Transmission Count(ETX),and Average Power Consumption(APC).Our findings illuminate the disruptive impact of this attack on the routing hierarchy,resulting in decreased PDR and throughput,increased AE2ED,ETX,and *** results underscore the urgent need for robust security measures to protect RPL-based IoT ***,our study emphasizes the exacerbated impact of the attack in mobile scenarios,highlighting the evolving security requirements of IoT networks.

关键词： RPL decreased rank attacks mobility random direction model

Mechanical performance of cold mix asphalt containing cup lump rubber as a sustainable bio-modifier

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Journal of Traffic and Transportation Engineering(English Edition) 2024年第3期11卷 424-440页

作者： Syed Abdul Ghafar Muhammad Naqiuddin Mohd Warid Norhidayah Abdul hassan Zulfiqar Ali Jattak Ashraf Abdalla mohammed Radwan Faculty of Civil Engineering Universiti Teknologi MalaysiaSkudai 81310Malaysia Department of Civil Engineering Balochistan University of Information TechnologyEngineering&Management SciencesQuettaPakistan Department of Civil Engineering Balochistan University of Engineering and TechnologyKhuzdarPakistan Department of Civil Engineering Faculty of EngineeringUniversity of TripoliTripoliLibya

The road construction industry aims to contribute to the protection of already compromised *** mix asphalt(CMA)is a measure initiated by the road industry to protect the environment and preserve *** having additional benefits,CMA has attracted little attention due to its inferior ***'s performance is enhanced using a sustainable binder bio-modifier,natural cup lump rubber(CLR)is one of *** study evaluated the tensile properties,rutting,moisture susceptibility,and adhesion properties of CLR-modified CMA(CMA-CR).The tensile property was enhanced by 26%due to CLR ***-CR had excellent rutting resistance of less than 2 mm rut depth at 10,000 load cycles,showing 70%improvement compared with conventional *** susceptibility evaluation indicated that CMA-CR had tensile strength ratio(TSR)value of 104%,satisfying the minimum 80%requirement of AASHTO *** also retained more than 96%bitumen *** moisture damage resistance was improved by 12%and 10%in terms of TSR and stripping,*** durability results revealed that the CMA-CR mixture prevented higher mass loss,representing 14%improvement compared with conventional CMA.

关键词： Cup lump rubber Cup lump modified cold mix asphalt Moisture damage Tensile property Rutting Digital imaging

PACK-CXL *** therapy for bacterial,fungal,and mixed infectious keratitis:a prospective randomized phase 3 trial

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Eye and Vision 2024年第1期10卷 10-20页

作者： Farhad Hafezi mohammed Hosny Rohit Shetty Boris Knyazer Shihao Chen Qinmei Wang hassan Hashemi Emilio A.Torres‑Netto 无 Center for Applied Biotechnology and Molecular Medicine(CABMM) University of ZurichZurichSwitzerland ELZA Institute DietikonSwitzerland. Faculty of Medicine University of GenevaGenevaSwitzerland Department of Ophthalmology Medical University of WenzhouWenzhouChina USC Roski Eye Institute University of Southern California Los AngelesLos AngelesUSA Department of Ophthalmology University of CairoCairoEgypt Narayana Nethralaya Eye Hospital and the Postgraduate Institute of Ophthal‑mology BangaloreIndia Department of Ophthalmology Soroka University Medical CenterBen-Gurion University of the NegevBeershebaIsrael Noor Ophthalmology Research Center Noor Eye HospitalTehranIran University Hospital Zurich ZurichSwitzerland. the PACK-CXL Working Group

Background:Infectious keratitis is a major cause of global *** tested whether standalone photoactivated chromophore corneal cross-linking(PACK-CXL)may be an efective frst-line treatment in early to moderate infectious keratitis,compared with standard antimicrobial ***:This is a randomized,controlled,multinational phase 3 clinical *** in fve centers in Egypt,India,Iran,Israel,and China,aged≥18 years,with infectious keratitis of presumed bacterial,fungal,or mixed origin,were randomly assigned(1:1)to PACK-CXL,or antimicrobial *** measures included healing,defned as time to re-epithelialization of the corneal epithelial defect in the absence of infammatory activity in the anterior chamber and clearance of stromal *** success was defned as the complete resolution of signs of ***:Between July 21,2016,and March 4,2020,participants were randomly assigned to receive PACK-CXL(n=18)or antimicrobial therapy per American Academy of Ophthalmology(AAO)guidelines(n=21).No participants were lost to *** eyes were excluded from the epithelialization time analysis due to treatment failure:two in the antimicrobial therapy group,and two in the PACK-CXL *** rates were 88.9%(16/18 patients)in the PACK-CXL group and 90.5%(19/21 patients)in the medication *** was no signifcant diference in time to complete corneal re-epithelialization(P=0.828)between both treatment ***:PACK-CXL may be an alternative to antimicrobial drugs for frst-line and standalone treatment of early to moderate infectious keratitis of bacterial or fungal origin.

关键词： Photoactivated chromophore Corneal cross-linking Infectious keratitis Corneal melting PACK-CXL

Assessing the pomfret stock for setting catch limits in the northern Bay of Bengal,Bangladesh

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Aquaculture and Fisheries 2024年第2期9卷 324-335页

作者： mohammed Shahidul Alam Qun Liu Md Mostafa Monwar Md Enamul Hoque Suman Barua Md Leion hassan Abdullah Munzer College of Fisheries Ocean University of ChinaQingdao266003China Department of Fisheries University of ChittagongChattogram4331Bangladesh Institute of Marine Sciences University of ChittagongChattogram4331Bangladesh Department of Oceanography University of ChittagongChattogram4331Bangladesh Department of Fisheries Ministry of Fisheries and LivestockDhaka1215Bangladesh

Pampus argenteus and Pampus chinensis form the high-value demersal Pomfret fishery of ***,due to a monotonic decline in catches over the last five years,it is essential to explore the current stock status concerning the removal rate to ensure the sustainability of this ***,given the reliability and minimal data requirements,this study employed an extended Bayesian State-Space Surplus Production Model,JABBA(Just Another Bayesian Biomass Assessment),to assess the stock *** results revealed that the stock biomass of the Pomfret fishery in the final year of the time series is significantly lower than BMSY,the biomass required to produce ***,this study recommends a yearly catch limit(TAC)of 10,000 metric tons to prevent further depletion of the stock ***,to avoid growth overfishing by allowing all immature fishes to reproduce at least once before being caught,this study also calculated the optimum length(Lopt)for catch for both species at which biologically maximum yield and revenue can be *** estimated Lopt is 25 cm for *** and 30 cm for ***,and not to capture fishes with lengths lower than these limits,this study further calculated the minimum mesh size limits for gill and set bag nets is 7.5 *** the mesh size regulation was estimated using length-based reference points derived from an empirical equation,this regulation can be used as an associate reference point when TAC is applied to assure the sustainability of this fishery.

关键词： Pomfret fishery Stock assessment JABBA TAC Lower length limits for catches Mesh size regulation

Hematological Alterations in an Eastern Sudanese Chronic Kidney Disease Patient Population

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Open Journal of Urology 2024年第6期14卷 359-367页

作者： mohammed Omer Abaker Gibreel Sundus Kamal Ibrahim Wijdan Abdel Aziz hassan Manar Yahia Mahjoub Leyla mohammed Kheir Hamid Hibatellah Majzoub Abbas Nuha Fouzi mohammed Secretariat of Academic Affairs Port Sudan Ahlia University Port Sudan Sudan Department of Hematology and Immunohematology College of Graduate Studies Port Sudan Ahlia University Port Sudan Sudan

Background: Chronic Kidney Disease (CKD), associated with a slow and progressive loss of kidney function over a period of several years, is an important clinical disaster with an increasing rate of morbidity and mortality especially in the least developed countries. Many hematological parameters are thought to alter dramatically during the course of the disease. These include white blood cells, red blood cells, and platelets. Methods: We tried, retrospectively, to evaluate the peripheral blood hematological alterations in a group of patients undergoing hemodialysis in an eastern Sudan dialysis center to add local medical information. Results: Anemia (Low hemoglobin and hematocrit) was detected in 94% of the patients’ group. Mean Erythrocyte count (3.32vs.4.76 (×109/L)), Hemoglobin concentration (9.4vs.13 (g/dl)), Hematocrit (28.7vs.38.7 (L/L)) and platelet count (296 vs. 238 (×109/L)) were significantly lower in the patients’ group than in the control group (P-values Conclusion: Five out of eight studied parameters (Red cell count, hemoglobin, hematocrit, mean cell hemoglobin concentration, and platelets count) have shown a significant alteration in CKD patients. As the complete blood count (CBC) test is the most utilized test in clinical laboratory practice, these alterations may be considered as early indicators for CKD. Furthermore, all patients with CKD must be routinely checked for these alterations.

关键词： Chronic Kidney Disease Chronic Renal Failure Hematological Alterations CBC Eastern Sudan Hemodialysis

Flood susceptibility mapping using a novel integration of multi-temporal sentinel-1 data and eXtreme deep learning model

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Geoscience Frontiers 2024年第3期15卷 67-84页

作者： Rami Al-Ruzouq Abdallah Shanableh Ratiranjan Jena mohammed Barakat A.Gibril Nezar Atalla Hammouri Fouad Lamghari GIS&Remote Sensing Center Research Institute of Sciences and EngineeringUniversity of SharjahSharjah 27272United Arab Emirates Civil and Environmental Engineering Department University of SharjahSharjah 27272United Arab Emirates Department of Earth and Environmental Sciences Prince El-Hassan bin Talal Faculty for Natural Resources&EnvironmentThe Hashemite UniversityZarqaJordan Fujairah Research Centre Fujairah CityAl Hilal TowerAl Hilal CityFujairahUnited Arab Emirates

Flash floods(FFs)are amongst the most devastating hazards in arid regions in response to climate change and can cause the loss of agricultural land,human lives and *** of the major challenges is the high-intensity rainfall events affecting low-lying areas that are vulnerable to *** works in this field have been conducted using ensemble machine learning models and geohydrological ***,the current advancement of eXtreme deep learning,which is named eXtreme deep factorisation machine(xDeepFM),for FF susceptibility mapping(FSM)is lacking in the *** current study introduces a new model and employs a previously unapplied approach to enhance FSM for capturing the severity of *** proposed approach has three main objectives:(i)During-and after-flood effects are assessed through flood detection techniques using Sentinel-1 data.(ii)Flood inventory is updated using remote sensing-based *** derived flood effects are implemented in the next step.(iii)An FSM map is generated using an xDeepFM ***,this study aims to apply xDeepFM to estimate susceptible areas using 13 factors in the emirates of Fujairah,*** performance metrics show a recall of 0.9488),an F1-score of 0.9107),precision of(0.8756)and an overall accuracy of 90.41%.The accuracy of the applied xDeepFM model is compared with that of traditional machine learning models,specifically the deep neural network(78%),support vector machine(85.4%)and random forest(88.75%).Random forest achieves high accuracy,which is due to its strong performance that depends on factors contribution,dataset size and quality,and available computational ***,the xDeepFM model works efficiently for complicated prediction problems having high non-collinearity and huge *** obtained map denotes that the narrow basins,lowland coastal areas and riverbank areas up to 5 km(Fujairah)are highly prone to FF,whilst the alluvial plains in Al Dhaid and hilly regio

关键词： Flood susceptibility mapping eXtreme Deep Factorisation Machine Sentinel-1 Remote sensing