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Analogy between adsorption and sorption： An elementary mechanistic approach. I. Monolayer adsorption and sorption without solvent cluster formation

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Chinese Journal of Chemical Engineering 2017年第12期25卷 1740-1749页

作者： Pierre Schaetzel Sébastien Thomas hasna louahlia gualous Laboratoire Universitaire des Sciences Appliquées de Cherbourg Université de Caen IUT de Caen Boulevard Marechal Juin 14032 Caen cedex France Institut de chimie et procédés pour l'énergie l'environnement et la santé Université de Strasbourg 25 rue Becquerel 67087 Strasbourg cedex 2 France

The elementary mechanistic model of adsorption and sorption is based on a simple hypothesis： the adsorption sites are uniformly distnbuted on the surface of the pore walls in the adsorbent, the sorption sites are uniformly distributed in the volume of the polymer. In this first paper we will analyze the simple case where one solute molecule is only allowed to occupy a single adsorption or sorption site. A common elementary occupation law of the free sites is assumed： the differential increase of the number of the adsorbed/sorbed molecules is proportional to the differential increase of the activity of the solute and the concentration of the free （non-occupied） sites in the solid. The proportionality coefficient is called affinity coefficient depending on the solid/solute couple and on the temperature and independent of the concentration of the solute. In adsorption the concentration of the free sites is a surface concentration on the pore walls and in sorption it is expressed by the molarity. The simple monolayer adsorption law of Jovanovic is obtained： n = no（1 - e KP） where n is the number of moles adsorbed when the pressure is P. no is the total number of adsorption sites and K the affinity coefficient for adsorption. The sorption law writes： a = 1/k [Ф/1-Ф] ＋ 1-r/k In [1 ＋ 1/r Ф/1-Ф] where Ф, r and k hold respectively for the volume fraction of the solvent in the polymer, for the ratio of the molar volumes of the solvent to the elementary polymer chain containing one single adsorption site and for the sorption affinity coefficient. The confrontation of these equations to experimental isotherms is satisfactory in comparison with the classical Langmuir and Flory-Huggins equations： the best results are obtained for adsorption of vapors on a 5A zeolite and for all analyzed sorption results.

关键词： Adsorption isotherms Sorption isotherms Flory-Huggins theory Langmuir equation

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Condensation Heat Transfer in Horizontal Non-Circular Microchannels

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Energy and Power Engineering 2013年第9期5卷 577-586页

作者： Hicham El Mghari Mohamed Asbik hasna louahlia-gualous LP2MS URAC08Universite Moulay IsmailFaculte des SciencesMeknesMaroc LUSAC Universite de Caen Basse NormandieSaint LoFrance

This investigation contributes to a better understanding of condensation heat transfer in horizontal non-circular microchannels. For this purpose, the conservation equations of mass, momentum and energy have been numerically solved in both phases (liquid and vapor), and all the more, so the film thickness analytical expression has been established. Numerical results relative to variations of the meniscus curvature radius, the condensate film thickness, the condensation length and heat transfer coefficients, are analyzed in terms of the influencing physical and geometrical quantities. The effect of the microchannel shapes on the average Nusselt number is highlighted by studying condensation of steam insquare, rectangular and equilateral triangular microchannels with the same hydraulic diameter of 250 μm.

关键词： Condensation Microchannel Numerical Simulation Capillary Regime Heat Transfer

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