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公共化:概念、结果与前景

经济法论丛 2019年第1期33卷 3-31页

作者： hartmut bauer 李剑(译) 德国波茨坦大学德国慕尼黑大学

本文致力于探讨关于'公共化'的概念,该概念尝试以一个统一的术语将(再)市镇化与(再)预算化结合起来,并且为'重返公共性'提供一个适当的分析框架。这一新的用词所针对的是联邦在社会福利方面的现代化,并对目前的法律事实以及法律教义学... 详细信息

本文致力于探讨关于'公共化'的概念,该概念尝试以一个统一的术语将(再)市镇化与(再)预算化结合起来,并且为'重返公共性'提供一个适当的分析框架。这一新的用词所针对的是联邦在社会福利方面的现代化,并对目前的法律事实以及法律教义学领域之基本状况给予理论支持。此外,对公共给付领域可支配手段之'武器库'以及针对忽略合作社作为公共给付之方式进行了必要的补充和调整。

关键词：公民协力公私协力公共化合作社

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新旧保护规范论

财经法学 2019年第1期 97-126页

作者：哈特穆特.鲍尔王世杰德国波茨坦大学法学院中国人民大学法学院

作为现代公权理论的核心,保护规范理论对于主观公权利的证成具有决定性。随着历史的发展,保护规范理论的新旧两种见解得以形成。但保护规范理论立基于存疑的原理:作为保护规范理论基础的利益概念并不明确,公益与私益的区分颇有疑问;法... 详细信息

作为现代公权理论的核心,保护规范理论对于主观公权利的证成具有决定性。随着历史的发展,保护规范理论的新旧两种见解得以形成。但保护规范理论立基于存疑的原理:作为保护规范理论基础的利益概念并不明确,公益与私益的区分颇有疑问;法规范的解释方法与解释规则并不确定;保护规范理论在适用上也存在相当的不确定性。有鉴于此,应当对证成主观公权利进行方向性的调整,转而关注与保护规范理论相异的行政法律关系理论。在证成主观公权利时,法律关系理论依据调整法律关系的所有规范材料,注重行政法与宪法的一体式观察,同时兼顾各规范调整领域的具体事实结构。法律关系理论吸收了保护规范理论的合理见解,排除了其中具有不确定性的内容,从而确保主观公权利的证成具有规范性与可靠性。

关键词：保护规范理论主观公权利法律关系理论

An inverted triplesalen ligand by a convergent synthesis and its influence on trinuclear Fe_3~Ⅲ complexes

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Science China Chemistry 2012年第6期55卷 951-966页

作者： FELDSCHER Bastian KRICKEMEYER Erich MOSELAGE Marc THEIL Hubert HOEKE Veronika KAISER Yvonne STAMMLER Anja BGGE hartmut GLASER Thorsten Lehrstuhl für Anorganische Chemie I Fakultt für Chemie Universitt Bielefeld Universittsstr. 25 D-33615 Bielefeld Germany

The inverted triplesalen ligand H 6 feld Me has been synthesized from 2,4,6-triformyl-phloroglucinol and a ketimine salen half-unit in a convergent synthesis. NMR, IR, and UV-vis spectroscopy reveal that this ligand is not in the O-protonated tautomer but in the N-protonated tautomer with substantial heteroradialene contribution. This ligand and the conventional triplesalen ligand H 6 talen t-Bu 2 have been used to synthesize the trinuclear Fe III complexes [(feld Me )(FeCl) 3 ] and [(talen t-Bu 2 )(FeCl) 3 ], respectively. The molecular structures of these complexes were obtained by single-crystal X-ray diffraction. Two trinuclear Fe III complexes of [(feld Me )(FeCl) 3 ] dimerize via two Fe-phenolate bonds, whereas due to steric hindrance no dimerization is observed for [(talen t-Bu 2 )(FeCl) 3 ]. The structural data also reveal some heteroradialene contribution in the trinuclear complexes. Whereas UV-vis and M bauer spectroscopy are not suitable to distinguish between the two complexes, FT-IR spectra show characteristic features due to the different substitution patterns of the conventional and the inverted triplesalen ligands. Another handle is provided by electrochemistry. Whereas both complexes exhibit an irreversible oxidation wave (0.94 V vs. Fc + /Fc for [(feld Me )(FeCl) 3 ] and 0.84 V vs. Fc + /Fc for [(talen t-Bu 2 )(FeCl) 3 ]), which is assigned to the oxidation of the central backbone, higher potential oxidations are reversible for [(talen t-Bu 2 )(FeCl) 3 ]) but irreversible for [(feld Me )(FeCl) 3 ]. This is attributed to the reversible oxidation of the terminal phenolates in the di-tert-butyl substituted [(talen t-Bu 2 )(FeCl) 3 ] in contrast to the mono-methyl-substituted phenolates in [(feld Me )(FeCl) 3 ]. The magnetic properties of [(talen t-Bu 2 )(FeCl) 3 ] reveal a very small ferromagnetic coupling with significant zero-field splitting of the FeⅢ S = 5/2 ions. In contrast, the dimerization of two trinuclear complexes in [(feld Me )(FeCl) 3 ] r

关键词：三核配合物氯化铁复合物合成收敛反铁磁相互作用单晶X-射线衍射紫外可见光谱

An inverted triplesalen ligand by a convergent synthesis and its influence on trinuclear FeXII3 complexes

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中国科学：化学 2012年第6期42卷 897-900页

作者： Bastian FELDSCHER Erich KRICKEMEYER Marc MOSELAGE Hubert THEIL Veronika HOEKE Yvonne KAISER Anja STAMMLER hartmut BGGE Thorsten GLASER Lehrstuhl f黵 Anorganische Chemie I Fakult鋞 f黵 Chemie Universit鋞 Bielefeld Universit鋞sstr. 25 D-33615 Bielefeld Germany

The inverted triplesalen ligand H6feldMehas been synthesized from 2,4,6-triformyl-phloroglucinol and a ketimine salen half-unit in a convergent synthesis. NMR, IR, and UV-vis spectroscopy reveal that this ligand is not in the O-protonated tautomer but in the N-protonated tautomer with substantial heteroradialene contribution. This ligand and the conventional triplesalen ligand H6talent-Bu2 have been used to synthesize the trinuclear FeⅢcomplexes [(feldMe)(FeCl)3] and [(talent-Bu2)(FeCl)3], respectively. The molecular structures of these complexes were obtained by single-crystal X-ray diffraction. Two trinuclear FeⅢcomplexes of [(feldMe)(FeCl)3] dimerize via two Fe-phenolate bonds, whereas due to steric hindrance no dimerization is observed for [(talent-Bu2)(FeCl)3]. The structural data also reveal some heteroradialene contribution in the trinuclear complexes. Whereas UV-vis and M??bauer spectroscopy are not suitable to distinguish between the two complexes, FT-IR spectra show characteristic features due to the different substitution patterns of the conventional and the inverted triplesalen ligands. Another handle is provided by electrochemistry. Whereas both complexes exhibit an irreversible oxidation wave (0.94 V vs. Fc+/Fc for [(feldMe)(FeCl)3] and 0.84 V vs. Fc+/Fc for [(talent-Bu2)(FeCl)3]), which is assigned to the oxidation of the central backbone, higher potential oxidations are reversible for [(talent-Bu2)(FeCl)3]) but irreversible for [(feldMe)(FeCl)3]. This is attributed to the reversible oxidation of the terminal phenolates in the di-tert-butyl substituted [(talent-Bu2

关键词：三核配合物合成收敛反铁磁相互作用复合物单晶X-射线衍射紫外可见光谱铁配合物