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MXene-derived quantum dots based photocatalysts:Synthesis,application,prospects,and challenges

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Chinese Chemical Letters 2024年第6期35卷 123-133页

作者： hao Deng Yuxin Hui Chao Zhang Qi Zhou Qiang Li hao Du Derek hao Guoxiang yang Qi Wang School of Environmental Science and Engineering Zhejiang Gongshang UniversityHangzhou 310018China Instrumental Analysis Center of Zhejiang Gongshang University Hangzhou 310018China Centre for Technology in Water and Wastewater(CTWW) School of Civil and Environmental EngineeringUniversity of Technology Sydney(UTS)UltimoNSW 2007Australia

In recent years,the emerging two-dimensional material-MXenes has attracted widespread attention in the field of photocatalysis due to its high conductivity,suitable Fermi level,tunable elemental composition,and excellent photoelectric *** zero-dimensional quantum dots(MQDs)derived from 2D MXenes not only inherit the characteristics of MXenes but also exhibit better performance due to the quantum size *** on the above excellent physical and chemical properties,MQDs are often used as co-catalysts of photocatalysts,and show excellent co-catalytic *** the same time,compared with other cocatalysts(precious metals,metal oxides,metal sulfides),it has the advantages of low cost and high ***,understanding the status of MQDs in the field of photocatalysis is crucial for their further *** this review,we summarized the synthesis and modification methods of MQDs in recent years,as well as their photocatalytic applications in H_(2) production,CO_(2) reduction,N_(2) fixation,pollutant degradation,and other *** addition,the challenges and prospects faced by MQDs are also proposed,providing theoretical guidance for the further development of MQD-based photocatalysts.

关键词： MXenes Quantum dots Photocatalysis Composites Environment purification

Bimetal MOF-derived NiFe-P nanocomposites coupled with Cu_(3)P nanoparticles to construct tandem electron transfer channels for photocatalytic hydrogen evolution

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Journal of Environmental Sciences 2024年第3期137卷 333-346页

作者： Haiyan Zhang Shitao yang Peng Zhu Senpei Tang ming Li College of Chemistry and Chemical Engineering Jishou UniversityJishou 416000China School of Account Hunan University of Technology and BusinessChangsha 410205China

Finely modulated light-induced charge separation and transfer is a central challenge to achieve efficient *** progress has been made in this field,most of the previous research works focused on the separation or migration of photogenerated carriers but did not build a bridge between the *** to realize the strong driving and precise migration of carriers has become the focus of our *** report an ingeniously designed ternary *** NiFe-MOF as the“parent material”,the FeP_(4)/Ni_(x)P_(y)heterojunction is derived in situ while maintaining the frame structure through gas-solid reaction,and finally the Z-type electron transfer is *** Cu_(3)P anchoring spindle matrix,an electron transport tunnel is opened up in Cu_(3)P/FeP_(4)/Ni_(x)P_(y)ternary heterojunction under the action of p-n heterojunction built-in electric field driving and accurate energy band *** strong driving force of the built-in electric field provides an inexhaustible power for the transmission of electrons,and the fine series of electron transmission channels realizes the precise transmission of *** above fine design makes the perfect fit between the built-in electric field and the electron transfer channel,which not only effectively improves the embarrassing situation of insufficient electron driving force of hydrogen evolution reaction in the previous research,but also makes up for the weakening of semi-conductor reduction ability caused by the construction of traditional p-n *** research work provides a new idea for the construction of multiple heterostructures and the design of fine interface engineering in the future.

关键词： Cu_(3)P/FeP_(4)/Ni_(x)P Built-in electric field Electron transfer channels Photocatalysis

Skin Microbiota and the Skin Barrier

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International Journal of Dermatology and Venereology 2024年第1期7卷 18-26页

作者： ming-yang Wu Xu Yao Department of Allergy and Rheumatology Jiangsu Key Laboratory of Molecular Biology for Skin Diseases and STIsHospital for Skin Diseases(Institute of Dermatology)Chinese Academy of Medical Sciences and Peking Union Medical CollegeNanjingJiangsu 210042China Jiangsu Key Laboratory of Molecular Biology for Skin Diseases and STIs NanjingJiangsu 210042China

The skin constitutes the primary barrier between the human body and the external *** skin microbiome plays an important role in the microecosystem on the skin surface and mediates multiple facets of the skin barrier function,including physical,chemical,microbial,and immune *** this review,we discuss the host-microbiota interactions in barrier maintenance and disruption,implications for skin disorders such as atopic dermatitis,psoriasis,and rosacea,and the latest strategies for targeting the skin microbiota to improve the skin barrier.

关键词： skin barrier microbiota immune atopic dermatitis

Better use of experience from other reservoirs for accurate production forecasting by learn-to-learn method

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Petroleum Science 2024年第1期21卷 716-728页

作者： hao-Chen Wang Kai Zhang Nancy Chen Wen-Sheng Zhou Chen Liu Ji-Fu Wang Li-ming Zhang Zhi-Gang Yu Shi-Ti Cui Mei-Chun yang China University of Petroleum(East China) 66 Changjiang West RoadQingdao West Coast New AreaQingdao266580ShandongChina University of Calgary 2500 University Dr NWCalgaryT2N 1N4AlbertaCanada Qingdao University of Technology Qingdao266071ShandongChina State Key Laboratory of Offshore Oil Exploitation Beijing100028China CNOOC Research Institute Ltd. Beijing100028China CNPC Tarim Oilfield Branch Company Korla841000XinjiangChina National Engineering Laboratory for Exploration and Development of Low-Permeability Oil and Gas Fields Xi'an710000ShaanxiChina Sinopec Matrix Co. LTDQingdao266000ShandongChina

To assess whether a development strategy will be profitable enough,production forecasting is a crucial and difficult step in the *** development history of other reservoirs in the same class tends to be studied to make predictions ***,the permeability field,well patterns,and development regime must all be similar for two reservoirs to be considered in the same *** results in very few available experiences from other reservoirs even though there is a lot of historical information on numerous reservoirs because it is difficult to find such similar *** paper proposes a learn-to-learn method,which can better utilize a vast amount of historical data from various ***,the proposed method first learns how to learn samples before directly learning rules in ***,by utilizing gradients from networks with independent parameters and copied structure in each class of reservoirs,the proposed network obtains the optimal shared initial parameters which are regarded as transferable information across different *** on that,the network is able to predict future production indices for the target reservoir by only training with very limited samples collected from reservoirs in the same *** cases further demonstrate its superiority in accuracy to other widely-used network methods.

关键词： Production forecasting Multiple patterns Few-shot learning Transfer learning

Influences of shale microstructure on mechanical properties and bedding fractures distribution

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Petroleum Science 2024年第3期21卷 1944-1954页

作者： ming-Zhe Gu Mao Sheng Shi-Zhong Cheng Fan-hao Gong Gen-Sheng Li State Key Laboratory of Petroleum Resources and Engineering China University of Petroleum-BeijingBeijing2249China College of Petroleum Engineering China University of Petroleum-BeijingBeijing102249China Shenyang Center of China Geological Survey ShenyangLiaoning110034China

The difference in microstructure leads to the diversity of shale mechanical properties and bedding fractures distribution *** this paper,the microstructure and mechanical properties of Longmaxi marine shale and Qingshankou continental shale were studied by X-ray diffractometer(XRD),field emission scanning electron microscope(FE-SEM)with mineral analysis system,and ***,the typical bedding layers area was properly stratified using Focused Ion Beam(FIB),and the effects of microstructure and mechanical properties on the distribution patterns of bedding fractures were *** results show that the Longmaxi marine shale sample contains more clay mineral grains,while the Qingshankou continental shale sample contains more hard brittle mineral grains such as *** Longmaxi marine shale sample,hard brittle minerals with grain sizes larger than 20μm is18.24%and those with grain sizes smaller than 20μm is 16.22%.For Qingshankou continental shale sample,hard brittle minerals with grain sizes larger than 20μm is 40.7%and those with grain sizes smaller than 20μm is 11.82%.In comparison to the Qingshankou continental shale sample,the Longmaxi marine shale sample has a lower modulus,hardness,and *** shales are formed by alternating coarse-grained and fine-grained layers during *** average single-layer thickness of Longmaxi marine shale sample is greater than Qingshankou continental shale *** two types of shale have similar bedding fractures distribution patterns and fractures tend to occur in the transition zone from coarse-grained to fine-grained *** orientation of the fracture is usually parallel to the bedding plane and detour occurs in the presence of hard brittle *** fracture distribution density of the Longmaxi marine shale sample is lower than that of the Qingshankou continental shale sample due to the strong heterogeneity of the Qingshankou continental *** current resea

关键词： Shale Nanoindentation Microstructure Mechanical property Fracture

P-and SV-wave dispersion and attenuation in saturated microcracked porous rock with aligned penny-shaped fractures

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Petroleum Science 2024年第1期21卷 143-161页

作者： Sheng-Qing Li Wen-hao Wang Yuan-Da Su Jun-Xin Guo Xiao-ming Tang School of Geosciences China University of Petroleum(East China)Qingdao 266580ShandongChina Laoshan National Laboratory Qingdao 266071ShangdongChina Guangdong Provincial Key Laboratory of Geophysical High-resolution Imaging Technology Southern University of Science and TechnologyShenzhen 518055GuangdongChina Department of Earth and Space Sciences Southern University of Science and TechnologyShenzhen 518055GuangdongChina

P-and SV-wave dispersion and attenuation have been extensively investigated in saturated poroelastic media with aligned ***,there are few existing models that incorporate the multiple wave attenuation mechanisms from the microscopic scale to the macroscopic ***,in this work,we developed a unified model to incorporate the wave attenuation mechanisms at different scales,which includes the microscopic squirt flow between the microcracks and pores,the mesoscopic wave-induced fluid flow between fractures and background(FB-WIFF),and the macroscopic Biot's global flow and elastic scattering(ES)from the *** Tang's modified Biot's theory and the mixed-boundary conditions,we derived the exact frequency-dependent solutions of the scattering problem for a single penny-shaped fracture with oblique incident P-and *** then developed theoretical models for a set of aligned fractures and randomly oriented fractures using the Foldy *** results indicated that microcrack squirt flow considerably influences the dispersion and attenuation of P-and SV-wave *** coupling effects of microcrack squirt flow with the FB-WIFF and ES of fractures cause much higher velocity dispersion and attenuation for P waves than for SV *** oriented fractures substantially reduce the attenuation caused by the FB-WIFF and ES,particularly for the ES attenuation of SV *** a comparison with existing models in the limiting cases and previous experimental measurements,we validated our model.

关键词： Aligned fractures P-and SV-wave Dispersion and attenuation Microcracked porous background FB-WIFF Elastic scattering Squirt flow

新中国成立以来基层党组织功能调适的动因、历程与启示

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内蒙古社会科学 2024年第4期45卷 72-81+213页

作者：张浩鲁杜阳明中山大学马克思主义学院

功能调适是政党等政治主体为适应时代变化和实践需要对自身功能进行有针对性的调整。新中国成立以来，基于我国社会主要矛盾的发展转化、不同时期或阶段党的中心任务的现实需求、基层党组织先进性建设的主体自觉以及我国发展历史方位的... 详细信息

功能调适是政党等政治主体为适应时代变化和实践需要对自身功能进行有针对性的调整。新中国成立以来，基于我国社会主要矛盾的发展转化、不同时期或阶段党的中心任务的现实需求、基层党组织先进性建设的主体自觉以及我国发展历史方位的深刻演进等多方面动因，党的基层组织对自身功能进行了深刻调整。新中国成立以来基层党组织功能调适的历程分为三个阶段：社会主义革命和建设时期，基层党组织以实现由新民主主义向社会主义的转变为目的进行功能调适；改革开放和社会主义现代化建设新时期，基层党组织以探索社会主义建设的正确道路和追求社会生产力的稳步增长为目的进行功能调适；中国特色社会主义进入新时代，基层党组织以奋进“两个一百年”奋斗目标为目的进行功能调适。新中国成立以来基层党组织的功能调适历程告诉我们，基层党组织的功能调适要坚持以夯实党的执政根基为根本目的，以厘清基层党组织的角色定位为前提基础，以执行党的政治路线为原则遵循，以调动各方积极性为实践要义，以解决现实问题为方向引领。

关键词：基层党组织功能调适生成动因历史进程现实启示

Generating a nanoscale blade-like optical field in a coupled nanofiber pair

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Photonics Research 2024年第1期12卷 154-162页

作者： YUXIN yang JIAXIN GAO hao WU ZHANKE ZHOU LIU yang XIN GUO PAN WANG LIMIN TONG Interdisciplinary Center for Quantum Information New Cornerstone Science LaboratoryState Key Laboratory of Extreme Photonics and InstrumentationCollege of Optical Science and EngineeringZhejiang UniversityHangzhou 310027China Jiaxing Key Laboratory of Photonic Sensing&Intelligent Imaging Intelligent Optics&Photonics Research CenterJiaxing Research Institute Zhejiang UniversityJiaxing 314000China Collaborative Innovation Center of Extreme Optics Shanxi UniversityTaiyuan 030006China

An optical field with sub-nm confinement is essential for exploring atomic-or molecular-level light-matter *** such fields demonstrated so far have typically point-like cross-sections,an optical field having a higher-dimensional cross-section may offer higher flexibility and/or efficiency in ***,we propose generating a nanoscale blade-like optical field in a coupled nanofiber pair(CNP)with a 1-nm-width central *** on a strong mode coupling-enabled slit waveguide mode,a sub-nm-thickness blade-like optical field can be generated with a cross-section down to~0.28 nm×38 nm at 1550 nm wavelength(i.e.,a thickness of~λ_(0)∕5000)and a peak-to-background intensity ratio(PBR)higher than 20 d *** slit waveguide mode of the CNP can be launched from one of the two nanofibers that are connected to a standard optical fiber via an adiabatical fiber taper,in which a fundamental waveguide mode of the fiber can be converted into a high-purity slit mode with high efficiency(>98%)within a CNP length of less than 10μm at 1550 nm *** wavelengthdependent behaviors and group velocity dispersion in mode converting processes are also investigated,showing that such a CNP-based design is also suitable for broadband and ultrafast pulsed *** results may open up new opportunities for studying light-matter interaction down to the sub-nm scale,as well as for exploring ultra-high-resolution optical technology ranging from super-resolution nanoscopy to chemical bond manipulation.

关键词： fiber waveguide optical

A Stable Copper-based Metal-Azolate Framework for Efficient Electroreduction of CO_(2)to C_(2+)Products

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Chemical Research in Chinese Universities 2024年第4期40卷 664-669页

作者： LIU Yuan-Yuan ZHU hao-Lin LIAO Pei-Qin CHEN Xiao-ming Key Laboratory of Bioinorganic and Synthetic Chemistry Ministry of EducationGBRCE for Functional Molecular EngineeringSchool of ChemistryIGCMESun Yat-sen UniversityGuangzhou510275P.R.China Chemistry and Chemical Engineering Guangdong Laboratory Shantou515031P.R.China

Driven by renewable or excess electrical energy,electrochemical CO_(2)reduction reaction(eCO_(2)RR)represents a promising carbon-neutral approach to generating valuable low-carbon fuels by consuming CO_(2)and H_(2)O.C_(2+)products are one of the most economically valuable products among the reduction species of eCO_(2)RR,but there are still some challenges,such as low selectivity or low current *** this work,we showed that a copper-based metal-azolate framework(MAF),denoted as MAF-203,exhibits the high performance of eCO_(2)RR to yield C_(2+)products with the Faradaic efficiency(C_(2+))of 52.5%and a current density of 660 mA/cm^(2)at-1.2 V *** in a flow cell device under alkaline *** experiment,in situ infrared spectroscopy and the density functional theory(DFT)calculations showed that the electron donating effect of methyl substituents on organic ligands of the copper-based MAF could enhance the ligand field and activation of key intermediates(*CO and*CHO species),thus promoting the coupling of*CO and*CHO for yielding C_(2+)products.

关键词： Metal-organic framework Carbon dioxide Electroreduction C_(2+)product Metal-azolate framework