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An intrinsically self-healing and anti-freezing molecular chains induced polyacrylamide-based hydrogel electrolytes for zinc manganese dioxide batteries

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Journal of Energy Chemistry 2024年第2期89卷 565-578,I0013页

作者： haiyang liao Wenzhao Zhong Chen Li Jieling Han Xiao Sun Xinhui Xia Ting Li Abolhassan Noori Mir F.Mousavi Xin Liu Yongqi Zhang Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 611731SichuanChina School of Mechanical Engineering Hunan University of TechnologyZhuzhou 412007HunanChina School of Materials Science and Engineering Zhejiang University of TechnologyHangzhou 310014ZhejiangChina Department of Chemistry Faculty of Basic SciencesTarbiat Modares UniversityTehran 14117-13116Iran State Key Laboratory of New Textile Materials and Advanced Processing Technologies Wuhan Textile UniversityWuhan 430200HubeiChina

The anti-freezing strategy of hydrogels and their self-healing structure are often contradictory,it is vital to break through the molecular structure to design and construct hydrogels with intrinsic anti-freezing/self-healing for meeting the rapid development of flexible and wearable devices in diverse service conditions.Herein,we design a new hydrogel electrolyte(AF/SH-Hydrogel)with intrinsic anti-freezing/self-healing capabilities by introducing ethylene glycol molecules,dynamic chemical bonding(disulfide bond),and supramolecular interaction(multi-hydrogen bond)into the polyacrylamide molecular chain.Thanks to the exceptional freeze resistance(84%capacity retention at-20℃)and intrinsic self-healing capabilities(95%capacity retention after 5 cutting/self-healing cycles),the obtained AF/SH-Hydrogel makes the zinc||manganese dioxide cell an economically feasible battery for the state-of-the-art applications.The Zn||AF/SH-Hydrogel||MnO_(2)device offers a near-theoretical specific capacity of 285 m A h g^(-1)at 0.1 A g^(-1)(Coulombic efficiency≈100%),as well as good self-healing capability and mechanical flexibility in an ice bath.This work provides insight that can be utilized to develop multifunctional hydrogel electrolytes for application in next generation of self-healable and freeze-resistance smart aqueous energy storage devices.

关键词： Flexible aqueous battery Hydrogel electrolyte Anti-freezing Self-healing Dual-dynamic reversible bond

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Bifunctional electrolyte regulation towards low-temperature and high-stability Zn-ion hybrid capacitor

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Journal of Energy Chemistry 2023年第4期79卷 495-504页

作者： Shuo Yang Kui Xue haiyang liao Yuning Guo Liujiang Zhou Yongqi Zhang Institute of Fundamental and Frontier Sciences University of Electronic Science and Technology of ChinaChengdu 611731SichuanChina School of Physics University of Electronic Science and Technology of ChinaChengdu 611731SichuanChina School of Mechanical Engineering Hunan University of TechnologyZhuzhou 412007HunanChina Yangtze Delta Region Institute(Huzhou)University of Electronic Science and Technology of China Huzhou 313002ZhejiangChina State Key Lab of Silicon Materials Zhejiang UniversityHangzhou 310027ZhejiangChina

Aqueous Zinc-based energy storage devices are considered as one of the potential candidates in future power technologies.Nevertheless,poor low temperature performance and uncontrollable Zn dendrite growth lead to the limited energy storage capability.Herein,an anti-hydrolysis,cold-resistant,economical,safe,and environmentally friendly electrolyte is developed by utilizing water,ethylene glycol(EG),and ZnCl_(2)with high ionic conductivity(7.9 mS cm^(-1)in glass fiber membrane at-20℃).The spectra data and DFT calculations show the competitive coordination of EG and Cl-to induce a unique solvation configuration of Zn^(2+),conducive to effectively inhibiting the hydrolysis of Zn^(2+),suppressing the dendrite growth,and broadening the working voltage range and temperature range of ZnCl_(2)electrolyte.The isotope tracing data confirm that Cl^(-)could effectively destroy the ZnO passivation film,promoting the formation of Zn nuclei and improving its reaction activity.Compared to the corresponding ZnSO4electrolyte,the Cu/Zn half-cell with the ZnCl_(2)electrolyte exhibits a stable cycle life of more than 1600 h at-20℃,even at the current density of 5 mA cm^(-2).The assembled Zn-ion hybrid capacitor possesses an average capacity of 42.68 m A h g^(-1)under-20℃at a current density of 5 A g^(-1),3.5 times than that of the modified ZnSO4electrolyte.Our work proposes a new approach for optimizing aqueous electrolytes to meet low temperature energy storage applications.

关键词： Hybrid electrolyte Zn-ion capacitor Anti-hydrolysis Low temperature Dendrite-free

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Transient synthesis of carbon-supported high-entropy alloy sulfide nanoparticles via flash Joule heating for efficient electrocatalytic hydrogen evolution

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Nano Research 2024年第4期17卷 3379-3389页

作者： Yuntian liao Rongtao Zhu Wenjun Zhang haiyang Zhu Yang Sun Jiale Chen Zhenhua Dong Ronghuan Lv School of Chemical Engineering and Technology China University of Mining and TechnologyXuzhou 221116China

High entropy alloys(HEA)are frequently employed as catalysts in electrocatalytic hydrogen evolution.However,the traditional high entropy alloy synthesis methods are time-consuming,energy-intensive,and environmentally polluting,which limits their application in the hydrogen evolution reaction(HER).This study leveraged the capabilities of flash Joule heating(FJH)to synthesize carbon-supported high-entropy alloy sulfide nanoparticles(CC-S-HEA)on carbon cloth(CC)with good self-standing properties within 300 ms.The carbon thermal shock generated by the Joule heating could pyrolyze the sulfur source into gas,resulting in numerous pore structures and defects on CC,forming an S-doped carbon substrate(CC-S).Then the S atoms were used to stably anchor the metal atoms on CC-S to form high-density uniformly dispersed HEA particles.The electrochemical test results demonstrated that CC-S-HEA prepared at 60 V flash voltage had HER performance comparable to Pt/C.The density functional theory(DFT)calculation indicated that the S atoms on CC-S accelerated the electron transfer between the carbon substrate and HEA particles.Moreover,the unique electronic structure of CC-S-HEA was beneficial to H*adsorption and promoted catalytic kinetics.The simplicity and versatility of FJH synthesis are of great significance for optimizing the synthesis of HEA and improving the quality of HEA products,which provides a broad application prospect for the synthesis of nanocatalysts with efficient HER performance.

关键词： high entropy alloy flash Joule heating carbon thermal shock hydrogen evolution reaction density functional theory

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A numerical survey of parameters to reach ignition condition for axial compression of a large-sized field reversed configuration

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Plasma Science and Technology 2024年第5期26卷 47-55页

作者：李宜霖廖晖周海洋孙玄 Department of Plasma Physics and Fusion Engineering School of Nuclear Science and TechnologyUniversity of Science and Technology of ChinaHefei 230026People’s Republic of China

Field reversed configuration(FRC)is widely considered as an ideal target plasma for magnetoinertial fusion.However,its confinement and stability,both proportional to the radius,will deteriorate inevitably during radial compression.Hence,we propose a new fusion approach based on axial compression of a large-sized FRC.The axial compression can be made by plasma jets or plasmoids converging onto the axial ends of the FRC.The parameter space that can reach the ignition condition while preserving the FRC's overall quality is studied using a numerical model based on different FRC confinement scalings.It is found that ignition is possible for a large FRC that can be achieved with the current FRC formation techniques if compression ratio is greater than 50.A more realistic compression is to combine axial with moderate radial compression,which is also presented and calculated in this work.

关键词： field reversed configuration magnetized target fusion axial compression

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Neutralization of SARS-CoV-2 infection by antibodies targeting diverse epitopes

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Genes & Diseases 2024年第4期11卷 134-137页

作者： Shusheng Wang Yunji liao Kaiyong Yang Hang Ma Zhangyi Song Haiqiu Huang Li Zhang Ailing Wang Lei Han Jiawei Zhang Hui Chen haiyang Yin Yantin Bian Hua Jiang Xiaodong Xiao Yueqing Xie Yunsheng Yuan Jianwei Zhu Engineering Research Center of Cell and Therapeutic Antibody Ministry of EducationSchool of PharmacyShanghai Jiao Tong UniversityShanghai 200240China Jecho Laboratories Inc.FrederickMD 21704USA Jecho Institute Co. Ltd.Shanghai 200240China

The CoVID-19 pandemic that started in late 2019 is sweeping through the world,posing historic challenges to global health,and disrupting social and economic lives.Previous and recent studies indicate that monoclonal antibodies can be efficacious in preventing and treating SARSCoV-1 and SARS-CoV-2 infections.Using a phage display platform,we have identified dozens of monoclonal antibodies that bind to diverse epitope groups on the SARS-CoV-2 spike protein.Many of them bound to the receptor binding domain(RBD)and inhibited ACE2-RBD interaction.

关键词： antibodies inhibited monoclonal

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A green cross-linking method for the preparation of renewable threedimensional graphene sponges for efficient adsorption of Congo red dye

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Chinese Journal of Chemical Engineering 2024年第2期66卷 84-93页

作者： Zhuang Liu Bo Gao Haoyuan Han Yuling Li haiyang Fu Donghui Wei Key Laboratory for Ecological Metallurgy of Multimetallic Mineral(Ministry of Education) Northeastern UniversityShenyang 110819China

Graphene-based materials possess significant potential for the treatment of dye wastewater due to their exceptional adsorption properties toward stubborn pollutants.However,their utilization is hindered by high preparation costs,low yields,environmental pollution during synthesis,and challenges in regenerating the adsorbent.This study proposes a novel approach to address these limitations by developing nitrogen-doped three-dimensional(3D)polyvinyl alcohol(PVA)crosslinked graphene sponges(N-PGA)using a cross-linking method with ammonium carbonate.This method offers a relatively mild,environmentally friendly approach.Ammonium carbonate serves as both a reducing and modifying agent,facilitating the formation of the intrinsic structure of N-PGA and acting as a nitrogen source.Meanwhile,PVA is utilized as the cross-linking agent.The results demonstrate that N-PGA exhibits a favorable internal 3D hierarchical porous structure and possesses robust mechanical properties.The measured specific surface area(BET)of N-PGA was as high as406.538 m^(2)·g^(-1),which was favorable for its efficient adsorption of Congo red(CR)dye molecules.At an initial concentration of 50 mg·L^(-1),N-PGA achieved an impressive removal rate of 89.6%and an adsorption capacity of 112 mg·g^(-1)for CR dye.Furthermore,it retained 79%of its initial adsorption capacity after 10 cycles,demonstrating excellent regeneration performance.In summary,the synthesized N-PGA displays remarkable efficacy in the adsorption of CR dye in wastewater,opening up new possibilities for utilizing 3D porous graphene nanomaterials as efficient adsorbents in wastewater treatment.

关键词： Green chemistry Graphene sponge Adsorbents Adsorption Congo red Regeneration

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Co含量对Ni/Co合金拉伸性能影响的分子动力学分析

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材料科学与工程学报 2023年第6期41卷 903-911页

作者：周枫林刘浪张展展廖海洋廖翠姣曾鑫湖南工业大学机械工程学院湖南株洲412000

基于分子动力学方法研究了不同Co含量的Ni/Co的拉伸力学性能。首先,模拟了在100 K、应变率为5×10^(9)/s的条件下,Co含量对Ni/Co拉伸力学性能的影响,其中着重研究了Ni单晶与含Co的体积分数为20%的Ni/Co的微观组织变化趋势。结果表明:相... 详细信息

基于分子动力学方法研究了不同Co含量的Ni/Co的拉伸力学性能。首先,模拟了在100 K、应变率为5×10^(9)/s的条件下,Co含量对Ni/Co拉伸力学性能的影响,其中着重研究了Ni单晶与含Co的体积分数为20%的Ni/Co的微观组织变化趋势。结果表明:相比于单晶Ni,Co原子阻碍了Ni/Co中位错的产生,从而提高了抗拉强度,在缺陷越少的情况下,材料的强度越接近其理论上的强度,Co原子对位错的阻碍作用使得Ni/Co的抗拉强度越接近其理论强度。其次,研究了温度对Ni/Co拉伸力学性能的影响,结果发现Ni/20Co(体积分数为20%,下同)的抗拉强度随着温度的升高呈现下降趋势。这是因为随着温度的升高,原子因剧烈运动导致原子间结合力减弱,fcc结构逐渐转变为other无序原子排列结构,结构越趋于非晶化,从而降低了抗拉强度。最后,研究了应变率对Ni/10Co的拉伸力学性能的影响。结果表明:应变率越大,Ni/10Co抗拉强度越高,高应变率对材料具有强化作用。这是因为高应变率使得位错在材料中的生长和扩展过程受阻,从而达到了强化材料的作用。

关键词：分子动力学镍基单晶高温合金镍钴

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基于塑性弦线法的深水爆炸下加筋锥柱壳变形模型

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兵工学报 2024年第3期45卷 705-719页

作者：汪海洋龙仁荣张庆明刘博文廖晨北京理工大学机电学院爆炸科学与技术国家重点实验室北京100081 江南工业集团军品技术研究所湖南长沙410000

为探究凸型加筋锥柱壳在静水压与深水爆炸载荷联合作用下的动态响应,在塑性弦线模型基础上考虑静水压载荷、锥角因素,将问题简化为求解拥有初边界值的波动方程,利用特征值展开将肋间板壳径向位移表示为无穷级数的形式,并对每个特征值计... 详细信息

为探究凸型加筋锥柱壳在静水压与深水爆炸载荷联合作用下的动态响应,在塑性弦线模型基础上考虑静水压载荷、锥角因素,将问题简化为求解拥有初边界值的波动方程,利用特征值展开将肋间板壳径向位移表示为无穷级数的形式,并对每个特征值计算相应的卸载时间,以此显示冲击波载荷的衰减特性。使用有限元程序Abaqus对半锥角为20°的凸型加筋锥柱壳开展最大深度500 m、最大冲击因子0.79 kg 0.5/m的水下爆炸数值模拟研究,对邻近结合处的柱段、锥段肋间板壳的理论模型计算结果进行验证对比和讨论。研究结果表明:与不计静水压相比,静水压使得肋间板壳刚度减小——最大位移出现时刻延滞,最终径向位移随水深而增大;在不同冲击因子下,理论模型与数值模拟最终径向位移误差最大为21.7%(锥段),最小为2.0%(柱段);由于锥角的存在,肋间板壳位移不再关于中心点对称分布,中心点最终位移较柱段减小40%以上。

关键词：加筋锥柱壳塑性弦线深水爆炸特征值卸载

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ITRF2014框架下顾及降雨量与水文负载的CMONOC坐标时间序列关系分析

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武汉大学学报（信息科学版） 2024年第6期49卷 960-969页

作者：何月帆聂桂根武曙光李海洋廖密郭雨武汉大学卫星导航定位技术研究中心湖北武汉430079 地球空间信息技术协同创新中心湖北武汉430079 湖北珞珈实验室湖北武汉430072

水文负载对中国大陆构造环境监测网络(crustal movement observation network of China,CMONOC)测站坐标时间序列具有重要的影响,而降雨量直接影响了水文负载的量级大小。利用ITRF2014(international terrestrial reference frame 2014)参考框架下CMONOC坐标时间序列、MERRA2(modern-era retrospective analysis for research and applications, version 2)水文负载模型以及中国区域降雨量数据来分析三者之间的关系。结果表明,水文负载对CMONOC测站的影响主要体现在垂直方向上,尤其在珠江流域、长江流域以南、西南以及东南诸河流域,水文负载对测站位移的影响尤为显著,水文负载序列的均方根最大可达5.47 mm。水文负载和降雨量都呈现出较为明显的纬度相关性,纬度越高,其量级越小,二者与纬度的线性拟合优度分别为0.63和0.55;同时,降雨量与水文负载也呈现明显的线性关系,拟合优度为0.49,且随着年均降雨量的增加,水文负载的量级会随之增大。对于周期性信号,降雨量、水文负载以及CMONOC坐标时间序列具有一致性,水文负载的周年振幅和CMONOC坐标时间序列的周年振幅与年均降雨量的拟合优度分别为0.64和0.37。在研究水文负载对GNSS坐标时间序列的影响时,除了土壤湿度、积雪以及冠层水,降雨量也是不可忽略的因素。

关键词：水文负载降雨量 CMONOC坐标时间序列拟合优度周年振幅

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三组分低共熔溶剂制备黄麻纳米纤维素的研究

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棉纺织技术 2023年第5期51卷 42-47页

作者：廖海洋毕雪蓉李佳蔚郁崇文张斌东华大学上海201620 产业用纺织品教育部工程研究中心上海201620

为了实现黄麻落麻的高价值回收利用,将5种金属氯化物分别与氯化胆碱、二水合草酸复配形成三组分低共熔溶剂(3c-DES)制备黄麻落麻纳米纤维素,探究了不同金属氯化物的加入对制备纳米纤维素性能的影响。结果表明:加入ZnCl_(2)的3c-DES不适... 详细信息

为了实现黄麻落麻的高价值回收利用,将5种金属氯化物分别与氯化胆碱、二水合草酸复配形成三组分低共熔溶剂(3c-DES)制备黄麻落麻纳米纤维素,探究了不同金属氯化物的加入对制备纳米纤维素性能的影响。结果表明:加入ZnCl_(2)的3c-DES不适宜制备纳米纤维素,加入LiCl、FeCl_(3)·6H_(2)O、MgCl_(2)·6H_(2)O、AlCl_(3)·6H_(2)O形成的3c-DES可以制备出短棒状的纳米纤维素晶体;加入LiCl的3c-DES制备出纳米纤维素的尺寸相对较小,分布最为集中;加入FeCl_(3)·6H_(2)O的3c-DES制备纳米纤维素的热稳定性最好;加入AlCl_(3)·6H_(2)O的3c-DES制备纳米纤维素的结晶度最高,为81.61%;加入LiCl的3c-DES制备纳米纤维素产率最高,为70%。认为:加入不同金属氯化物形成的3c-DES会影响纳米纤维素的性能,其中加入LiCl、FeCl_(3)·6H_(2)O、AlCl_(3)·6H_(2)O制备纳米纤维素效果较好。

关键词：三组分低共熔溶剂纳米纤维素金属氯化物黄麻落麻热稳定性

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