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Science China Chemistry 2024年第10期67卷 3193-3194页

作者： Jingfang Zhang Yi huang Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education School of Chemical Engineering&PharmacyWuhan Institute of TechnologyWuhan 430205China College of Chemistry Central China Normal UniversityWuhan 430079China

Furfural(FF),an important bio-based platform molecule,can be valorized to high-value-added chemicals(e.g.,furfuryl alcohol(FA)or 2-methylfuran(MF))through catalytic hydrogenation[1].The traditional thermocatalytic transformation of FF always requires high-temperature and highpressure conditions[2].Accordingly,electrocatalytic hydrogenation is emerging as a promising approach for the selective reduction of FF to FA or MF under environmentally friendly and benign conditions.

关键词： hydrogenation electrolyte selectivity

Higher-dimensional integrable deformations of the classical Boussinesq-Burgers system

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Communications in Theoretical Physics 2024年第6期76卷 1-12页

作者： Xiaoyu Cheng Qing huang School of Mathematics Northwest UniversityXi'an 710127China

In this paper,the(1+1)-dimensional classical Boussinesq-Burgers(CBB)system is extended to a(4+1)-dimensional CBB system by using its conservation laws and the deformation *** Lax integrability,symmetry integrability and a large number of reduced systems of the new higher-dimensional system are ***,for illustration,an exact solution of a(1+1)-dimensional reduced system is constructed from the viewpoint of Lie symmetry analysis and the power series method.

关键词： classical Boussinesq-Burgers system higher-dimensional system deformation algorithm Lax pair conservation law

A Comprehensive Investigation on Shear Performance of Improved Perfobond Connector

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Structural Durability & Health Monitoring 2024年第3期18卷 299-320页

作者： Caiping huang Zihan huang Wenfeng You School of Civil Engineering Architecture and EnvironmentHubei University of TechnologyWuhan430068China

This paper presents an easily installed improved perfobond connector (PBL) designed to reduce the shearconcentration of PBL. The improvement of PBL lies in changing the straight penetrating rebar to the Z-typepenetrating rebar. To study the shear performance of improved PBL, two PBL test specimens which containstraight penetrating rebar and six improved PBL test specimens which contain Z-type penetrating rebars weredesigned and fabricated, and push-out tests of these eight test specimens were carried out to investigate andcompare the shear behavior of PBL. Additionally, Finite Element Analysis (FEA) models of the PBL specimenswere established and validated against the test results. Through FEA, the effects of concrete grade, perforatedplate’s aperture, Z-type penetrating rebar’s diameter, Z-type penetrating rebar’s bending angle, and bending lengthon shear behaviors were discussed. The results indicate that (1) Compared with PBL specimens with straightpenetrating rebars, Z-type penetrating rebar can significantly improve the shear resistance and shear stiffnessof the specimens. This enhanced performance can be mainly attributed to the increased adhesion of the transverserebar. (2) By comparing the load-slip curve, the slip of PBL test specimens which contain straight penetratingrebar increases rapidly and the bearing capacity decreases rapidly after concrete craking, while the bearingcapacity of Z-type penetrating rebar specimens decreases first and then increases gradually, showing betterductility. (3) The stress of the PBL shear connector with Z-type penetrating rebar is more uniform than thePBL shear connector with straight penetrating rebar, and the overall deformation is more uniform. (4) The higherthe concrete grade, the higher the shear bearing capacity and the better ductility of the new PBL. Increasing theaperture of the perforated plate or the diameter of the rebar has a very limited effect on the improvement of theshear capacity of PBL. Through the system

关键词： PBL penetrating rebar push-out test load-slip curve shear capacity finite element analysis

Evaluation and application of kinetic models for Cu-catalyzed acetylene hydrochlorination

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Chinese Journal of Chemical Engineering 2024年第8期72卷 209-219页

作者： Tianxiao huang Binhang Yan Department of Chemical Engineering Tsinghua UniversityBeijing 100084China

The development of environmentally friendly catalysts has become a top priority for acetylene ***,difficulties remain in systematic studies on the applicability of kinetic models for the industrialization of Cu-based ***,a strategy involving reactor modeling,parameter estimation,and model testing is developed to evaluate the predictive ability of kinetic *** order to search for reliable and widely applicable reaction kinetic models for Cu-based catalysts,a case study is *** possible kinetic models derived from the power law,adsorption mechanism,and reaction path are sifted through collecting and testing activity data from tens of Cu-based *** optimum applicable ranges of these kinetic models are *** to the comparative analysis on their applications in various industrial scenarios,this research suggests that kinetic models derived from reaction path exhibits the best extrapolation ability and has the greatest potential for application in the scale-up design of reactors.

关键词： Acetylene hydrochlorination Cu-based catalysts Reaction kinetics Model Reactors

Readily prepared and processed multifunctional MXene nanocomposite hydrogels for smart electronics

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SmartMat 2024年第2期5卷 103-114页

作者： Jiahui huang Xianwu huang Peiyi Wu State Key Laboratory for Modification of Chemical Fibers and Polymer Materials College of Chemistry and Chemical EngineeringCenter for Advanced Low-Dimension MaterialsDonghua UniversityShanghaiChina State Key Laboratory of Molecular Engineering of Polymers Department of Macromolecular Science and Laboratory of Advanced MaterialsFudan UniversityShanghaiChina

Booming sophisticated robotics and prosthetics put forward high requirements on soft conductive materials that can bridge electronics and biology,those soft conductive materials should imitate the mechanical properties of biological tissues and build information transmission *** now,it remains a great challenge to handle the trade-off among ease of preparation,high conductivity,processability,mechanical adaptability,and external stimuli ***,a kind of readily prepared and processed multifunctional MXene nanocomposite hydrogel is reported,which is prepared via the fast gelation of cationic monomer initiated by delaminated MXene *** gelation time can be adjusted(several seconds to minutes)based on the MXene *** adjusting the MXene ratio,the resulting nanocomposites are ultrastretchable(>5000%),three-dimensional(3D)printable,and show outstanding mechanical and electrical *** expected,the integration of multifunctional systems onto various substrates(e.g.,gloves and masks)is further demonstrated via 3D printing and could achieve diverse sensory capabilities toward strain,pressure,and temperature,showing great prospects as smart flexible electronics.

关键词： 3D printable electronics MXene polymeric hydrogels stretchable and conductive

Challenges and Opportunities of Sub-6 GHz Integrated Sensing and Communications for 5G-Advanced and Beyond

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Chinese Journal of Electronics 2024年第2期33卷 323-325页

作者： Yuhong huang China Mobile Research Institute China Mobile Communications Group Co. Ltd

The integrated sensing and communications(ISAC) technology has been perceived as a key feature of5G-Advanced and beyond mobile communication networks. Compared with sensing in millimeter-wave bands, sensing at sub-6 GHz band is an exceptional incentive to promote the industrialization process of ISAC due to its incomparable advantages in industrial development, especially for intelligent transportation and smart drone networks. This paper elaborates on the top challenges of sub-6 GHz ISAC technologies, as well as the potential solutions to improve the sensing capability.

关键词： Electric potential Millimeter wave technology Transportation Mobile communication Sensors Millimeter wave communication Drones

Enhanced boron neutron capture therapy(BNCT)through controlled drug release via boron-loaded nanofiber mats

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Nano Research 2024年第8期17卷 7479-7492页

作者： Wenyong huang Yongjin Yang Yong Pan Shiwei Jing Yanxin Qi Yubin huang Faculty of Chemistry Northeast Normal UniversityChangchun 130024China Key Laboratory of Sustainable Advanced Functional Materials of Jilin Province Changchun 130024China School of Physics Northeast Normal UniversityChangchun 130024China

Boron neutron capture therapy(BNCT)is a novel binary therapy combining boron targeted drugs and neutron irradiation,which can selectively and effectively kill cancer cells at the cellular *** release of boron drug and its accumulation in tumor sites are the crux of ***,we developed a^(10)B-boric acid(^(10)BA)-loaded nanofiber applying for BNCT by in situ *** nanofibers were obtained by electrospinning technique using polyethylene glycol/polylactide(PEO/PLA)block *** changing the ratio of hydrophilicity to hydrophobicity of the nanofibers,the controlled release and the effective accumulation of boron 10 isotope(^(10)B)were achieved in ***^(10)B content in tumor could reach to 2540μg/g,significantly exceeding the required level of 20–50μg/g for BNCT *** pertinent DNA damage experiments,direct evidence and quantified data of BNCT-induced DNA damage in tumor cells were obtained for the first *** sequencing was employed to predict the molecular mechanisms and potential signaling pathways of BNCT,providing theoretical basis for future combined *** antitumor efficiency of BNCT was demonstrated by establishing mice model of subcutaneous tumor and tumor *** research presents a novel boron-loaded nanofiber mats for BNCT,which enables controlled drug release and holds significant potential in the treatment of unresectable or postoperative residual tumors.

关键词： boron neutron capture therapy nanofibers controlled release in situ administration

Reduced-Order Observer-Based LQR Controller Design for Rotary Inverted Pendulum

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Computer Modeling in Engineering & Sciences 2024年第7期140卷 305-323页

作者： Guogang Gao LeiXu Tianpeng huang Xuliang Zhao Lihua huang College of Engineering China University of Petroleum-Beijing at KaramayKaramay834000China School of Electrical Engineering and Information Southwest Petroleum UniversityChengdu610500China

The Rotary Inverted Pendulum(RIP)is a widely used underactuated mechanical system in various applications such as bipedal robots and skyscraper stabilization where attitude control presents a significant *** the implementation of various control strategies to maintain equilibrium,optimally tuning control gains to effectively mitigate uncertain nonlinearities in system dynamics remains *** methods frequently rely on extensive experimental data or the designer’s expertise,presenting a notable *** paper proposes a novel tracking control approach for RIP,utilizing a Linear Quadratic Regulator(LQR)in combination with a reduced-order ***,the RIP system is mathematically modeled using the Newton-Euler-Lagrange ***,a composite controller is devised that integrates an LQR for generating nominal control signals and a reduced-order observer for reconstructing unmeasured *** approach enhances the controller’s robustness by eliminating differential terms from the observer,thereby attenuating unknown *** numerical simulations and experimental evaluations demonstrate the system’s capability to maintain balance below50Hz and achieve precise tracking below1.4 rad,validating the effectiveness of the proposed control scheme.

关键词： Rotary inverted pendulum(RIP) linear quadratic regulator(LQR) reduced-order observer states estimate

Hybrid HMX multi-level assembled under the constraint of 2D materials with efficiently reduced sensitivity and optimized thermal stability

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Defence Technology（防务技术） 2024年第9期39卷 123-132页

作者： Xiaomin Song Longjin huang Rufang Peng Qi huang Jinjiang Xu Jie Sun Institute of Chemical Materials China Academy of Engineering PhysicsMianyang621900China State Key Laboratory of Environment-friendly Energy Materials School of Materials Science and EngineeringSouthwest University of Science and TechnologyMianyang621010China

The interfacial interaction between HMX molecules and coating materials is the key to the safety performance of explosives and has received extensive ***,screening suitable coating agents to enhance the interfacial effect to obtain high-energy and low-sensitivity explosives has long been a major *** this work,HMX-PEI/rGO/g-C_(3)N_(4)(HPrGC)composites were innovatively prepared by a multi-level coating strategy of two-dimensional graphite rGO and g-C_(3)N_(4).The g-C_(3)N_(4) used for desensitization has a richπ-conjugated system and shows outstanding ability in reducing friction *** hierarchical structure of HPrGC formed by electrostatic self-assembly andπ-πstacking can effectively dissipate energy accumulation under heat and mechanical stimulation through structural evolution,thus exhibiting a prominent synergistic desensitization effect on *** results show that rGO/gC_(3)N_(4) coating has no effect on the crystal structure and chemical structure of *** importantly,the perfect combination of g-C_(3)N_(4) and rGO endows HPrGC with enhanced thermal stability and ideal mechanical sensitivity(IS:21 J,FS:216 N).Obviously,the new fabrication of HPrGC enriches the variety of desensitizer materials and helps to deepen the understanding of the interaction between explosives and coatings.

关键词： HMX-PEI/rGO/g-C_(3)N_(4) Electrostatic self-assembly π-πstacking Synergistic desensitization

Mechanical parameter evolutions and deterioration constitutive model for ductile-brittle failure of surrounding rock in high-stress underground engineering

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Underground Space 2024年第2期15卷 131-152页

作者： Zhi Zheng Ronghua Li Qiang Zhang Xiaohua huang Wei Wang Shuling huang State Key Laboratory of Featured Metal Materials and Life-cycle Safety for Composite Structures Key Laboratory of Disaster Prevention and Structural Safety of Ministry of EducationCollege of Civil Engineering and ArchitectureGuangxi UniversityNanning 530004China Key Laboratory of Ministry of Education on Safe Mining of Deep Metal Mines Northeastern UniversityShenyang 110819China State Key Laboratory of Simulation and Regulation of Water Cycle in River Basin China Institute of Water Resources and Hydropower ResearchBeijing 100038China Key Laboratory of Ministry of Education for Geomechanics and Embankment Engineering Hohai UniversityNanjing 210098China Key Laboratory of Geotechnical Mechanics and Engineering of Ministry of Water Resources Yangtze River Scientific Research InstituteWuhan 430010China

The deep surrounding rock is usually in the true triaxial stress state,and previous constitutive models based on the understanding of uniaxial and conventional triaxial test results have difficulty characterizing the degradation and fracture process of rock ductile–brittle failure under true triaxial stress ***,this study conducted a series of true triaxial tests to obtain the understanding of the ductile–brittle behaviour of rock,and then combined the test results and the Mogi–Coulomb strength criterion,and proposed calculation methods for the elastic modulus E,cohesion c and internal friction angle u and the evolution functions of E,c and u of rock under true triaxial *** the decreasing of the minimum principal stress r3 or increasing of the intermediate principal stress r2,the marble post-peak stress drop rate gradually increases,the ductility gradually weakens,and the brittleness significantly *** calculation method and evolution function of rock E,c and u under true triaxial stress were proposed.E decreased at first and then tended to remain stable with the increasing of equivalent plastic strain increment dep.c and u slowly increased at first and then rapidly *** a method of parameter degradation rate to realize post-peak stress drop rate to reflect the ductile–brittle characteristics,a new three-dimensional ductile–brittle deterioration mechanical model(3DBDM)was *** proposed model can accurately characterize the influence of r2 and r3 on mechanical parameters,the ductile–brittle behaviour of rock under true triaxial stresses,and the asymmetric failure characteristics of surrounding rock after excavation of deep underground *** proposed model can be reduced to elastic–perfectly plastic,elastic–brittle,cohesion weakening friction strengthening(CWFS),Mohr–Coulomb,and Drucker–Prager models.

关键词： True triaxial stress Post-peak characteristics 3D deterioration model Elastic modulus evolution Cohesion and friction angle evolution