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Experimental Study for Effect of Multi-Site Spark Ignition on Dedicated Hybrid Engine Performance under High Dilution Condition

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Journal of Thermal Science 2025年第1期34卷 254-267页

作者： YAN Bowen WATERS Benjamin HAINES Andrew MCGHEE Mike hu Tiegang DENG Wei PU Yongxian MA Tianyu Powertrain Engineering R&D Center Chongqing Changan Automobile Co.Ltd.Chongqing 400000China Changan UK R&D Centre Limited Birmingham B377YGUnited Kingdom

In this study,a triple spark ignition scheme was first designed on a three-cylinder 1.5-L dedicated hybrid engine(DHE).On this basis,the effect of different ignition modes on engine combustion and emission characteristics was studied,especially under high dilution *** results tested at 2000 r/min and 0.8 MPa BMEP(brake mean effective pressure)show that with highly increased in-cylinder flow intensity,using only passive prechamber(PPC)has a lower lean limit than that with single central spark plug(CSP),thereby leading to slightly higher minimum fuel consumption and nitrogen oxides(NO_(x))*** side spark plugs(SSP)based on PPC can result in improved capability of lean limit extension and engine performance than ***,the improvement level is lower than that with triple spark plugs(TSP).As the excess air ratio λ increases,the advantage of PPC and PPC with SSP in improving the combustion phasing compared with CSP gradually ***,the increasing tendency of their ignition delay and combustion duration is more *** added SSP based on PPC can effectively shorten the ignition delay of leaner mixture,but the combustion duration can be only slightly *** a result,under extremely lean condition,the advantage of PPC and PPC with SSP in terms of combustion characteristics over CSP becomes much *** contrast,the TSP ignition can achieve much shorter ignition delay and combustion duration simultaneously under this *** to the highest available dilution level,the TSP ignition achieves the lowest raw NO_(x)***,it can also reduce the raw carbon monoxide(CO)and hydrocarbons(HC)emissions compared to CSP due to a more thorough combustion of the end gas *** on the excellent performance of TSP,the highest engine brake thermal efficiency(BTE)was further *** results show that with normal RON 92 fuel,the engine finally achieved 43.69% and 45.02% BTE under stochiometric mode with exhaus

关键词： dedicated hybrid engine triple spark plug scheme passive prechamber high dilution condition thermal efficiency NO_(x)emissions

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Development of Leisure Sports Industry Clusters in Sichuan Province Based on Resource Competitiveness

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Journal of Resources and Ecology 2025年第1期16卷 245-252页

作者： GUO Jianying WEI Yating hu Shiwei School of Tourism and Geographic Sciences Leshan Normal UniversityLeshanSichuan 614000China College of Tourism Northwest Normal UniversityLanzhou 730070China The Engineering&Technical College Chengdu University of TechnologyLeshanSichuan 614007China

Sichuan Province has abundant leisure sports *** evaluation of the competitiveness of its leisure sports resources can provide a scientific basis for the selection and development of leisure sports industry clusters in Sichuan *** addition,a competitiveness evaluation index system for leisure sports resources was constructed to assess the competitiveness of leisure sports resources for 21 regions in Sichuan *** results showed significant differences among the 21 regions,and they could be divided into three ***,the first level included the seven regions of Chengdu,Leshan,Yibin,Mianyang,Zigong,Aba and Luzhou;the second level included the 11 regions of Ya’an,Guangyuan,Ganzi,Neijiang,Deyang,Guang’an,Liangshan,Nanchong,Panzhihua,Bazhong and dazhou;and the third level included Meishan,Suining and *** view of the resource conditions,environmental conditions,and development conditions,Chengdu,Leshan,Yibin,Mianyang,and Zigong were chosen as the most suitable areas for leisure sports industry clusters in Sichuan ***,suggestions for these five potential leisure sports industry clusters were proposed to promote the high-quality development of the sports industry in Sichuan Province.

关键词： leisure sports resources resource competitiveness leisure sports industry cluster Sichuan

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Recent advances,strategies,and future perspectives of peptide-based drugs in clinical applications

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Chinese Journal of Natural Medicines 2025年第1期23卷 31-42页

作者： Qimeng Yang Zhipeng hu Hongyu Jiang Jialing Wang Han Han Wei Shi Hai Qian Centre of Drug Discovery State Key Laboratory of Natural Medicines China Pharmaceutical University Jiangsu Key Laboratory of Drug Discovery for Metabolic Disease China Pharmaceutical University

Peptide-based therapies have attracted considerable interest in the treatment of cancer, diabetes, bacterial infections, and neurodegenerative diseases due to their promising therapeutic properties and enhanced safety profiles. This review provides a comprehensive overview of the major trends in peptide drug discovery and development, emphasizing preclinical strategies aimed at improving peptide stability, specificity, and pharmacokinetic properties. It assesses the current applications and challenges of peptide-based drugs in these diseases, illustrating the pharmaceutical areas where peptide-based drugs demonstrate significant potential. Furthermore, this review analyzes the obstacles that must be overcome in the future,aiming to provide valuable insights and references for the continued advancement of peptidebased drugs.

关键词： Antimicrobial peptides Diabetes Neurodegenerative diseases Oncology Peptide-based drugs

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Iron-nitrogen-doped porous carbon absorbers constructed from hypercrosslinked ferrocene polymers for efficient electromagnetic wave absorption

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International Journal of Minerals,Metallurgy and Materials 2025年第3期32卷 578-590页

作者： Yi hu Yijia Zhou Lijia Liu Qiang Wang Chunhong Zhang Hao Wei Yudan Wang Key Laboratory of Superlight Materials&Surface Technology of Ministry of Education College of Materials Science and Chemical EngineeringHarbin Engineering UniversityHarbin 150001China Yantai Research Institute of Harbin Engineering University Yantai 264006China Qingdao Innovation and Development Base of Harbin Engineering University Qingdao 266404China

Herein,an external crosslinker facilitated the hypercrosslinking of ferrocene and a nitrogen heterocyclic compound(either melamine or imidazole)through a direct Friedel-Crafts reaction,which led to the formation of nitrogen-containing hypercrosslinked fer-rocene polymer precursors(HCP-FCs).Subsequent carbonization of these precursors results in the production of iron-nitrogen-doped por-ous carbon absorbers(Fe-NPCs).The Fe-NPCs demonstrate a porous structure comprising aggregated nanotubes and *** porosity of this structure can be modulated by adjusting the iron and nitrogen contents to optimize impedance *** uniform dis-tribution of Fe-N_(x)C,N dipoles,andα-Fe within the carbon matrix can be ensured by using hypercrosslinked ferrocenes in constructing porous carbon,providing the absorber with numerous polarization sites and a conductive *** electromagnetic wave absorption performance of the specially designed Fe-NPC-M_(2)absorbers is satisfactory,revealing a minimum reflection loss of-55.3 dB at 2.5 mm and an effective absorption bandwidth of 6.00 GHz at 2.0 *** utilizing hypercrosslinked polymers(HCPs)as precursors,a novel method for developing highly efficient carbon-based absorbing agents is introduced in this research.

关键词： hypercrosslinked polymers porous carbon iron-nitrogen doping annealing

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Regional Storm Surge Forecast Method Based on a Neural Network and the Coupled ADCIRC-SWAN Model

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Advances in Atmospheric Sciences 2025年第1期42卷 129-145页

作者： Yuan SUN Po hu Shuiqing LI Dongxue MO Yijun HOU Laboratory of Ocean Observation and Forecasting and Key Laboratory of Ocean Circulation and Waves Institute of OceanologyChinese Academy of SciencesQingdao 266071China Laboratory for Ocean Dynamics and Climate Qingdao Marine Science and Technology CenterQingdao 266237China University of Chinese Academy of Sciences Beijing 100049China Center for Ocean Mega-Science Chinese Academy of SciencesQingdao 266071China

Timely and accurate forecasting of storm surges can effectively prevent typhoon storm surges from causing large economic losses and casualties in coastal *** present,numerical model forecasting consumes too many resources and takes too long to compute,while neural network forecasting lacks regional data to train regional forecasting *** this study,we used the DUAL wind model to build typhoon wind fields,and constructed a typhoon database of 75 processes in the northern South China Sea using the coupled Advanced Circulation-Simulating Waves Nearshore(ADCIRC-SWAN)***,a neural network with a Res-U-Net structure was trained using the typhoon database to forecast the typhoon processes in the validation dataset,and an excellent storm surge forecasting effect was achieved in the Pearl River Estuary *** storm surge forecasting effect of stronger typhoons was improved by adding a branch structure and transfer learning.

关键词： regional storm surge forecast coupled ADCIRC-SWAN model neural network Res-U-Net structure

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Effects of photo-oxidation and transition metals on the formation of reactive oxygen species from aromatic compounds using spectroscopic method

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Journal of Environmental Sciences 2025年第5期151卷 1-11页

作者： Xiaoyu hu Juanjuan Qin Yuanyuan Qin Tianyi Zhao Yuxuan Cao Qinghe Cai Lijia Zhang Yang Zhang College of Resources and Environment University of Chinese Academy of SciencesBeijing 101408China Beijing Yanshan Earth Critical Zone National Research Station Beijing 101408China Resource and Environmental Branch China National Institute of StandardizationHaidian DistrictBeijing 100191China Binzhou Institute of Technology Binzhou 256606China

Particulate matter(PM)can cause adverse health effects by overproducing reactive oxygen species(ROS).Although the ability of PM to induce ROS generation depends on its composi-tion and environmental *** study explores how photo-oxidation affects ROS gen-eration from aromatic compounds(ACs,including catechol(CAT),phthalic acid(PA),and 4,4-oxydibenzoic acid(4,4-OBA))and their mixtures with transition metals(TMs,includ-ing Fe(II),Mn(II),and Cu(II))using Fourier-transform infrared(FTIR)and Ultraviolet-visible spectroscopy(UV-Vis).Results showed that photo-oxidation facilitated ROS generation from ***-Fe(II)/Cu(II)showed synergistic effects,but 4,4-OBA-Fe(II)/Cu(II)showed antag-onistic ***-Mn(II)and PA-Fe(II)/Cu(II)exhibited synergistic effects first and then showed antagonistic *** different interactions were due to complexation between ACs and *** photo-oxidized ACs-TMs significantly enhanced ROS generation com-pared with *** study suggested the photo-oxidation mechanism involved that the transfer ofπ-electrons from the ground to an excited state in benzene rings and func-tional groups,leading to the breakage and formation of chemical bonds or easierπ-electron transfer from ACs to *** former could generate ROS directly or produce polymers that promoted ROS generation,while the latter promoted ROS generation by transferringπ-electrons to dissolved oxygen *** study revealed that both interactions among components and photo-oxidation significantly influenced ROS *** studies should integrate broader atmospheric factors and PM components to fully assess oxidative potential and health impacts.

关键词： Reactive oxygen species Aromatic compounds Transitional metals Photo-oxidation

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CO_(2)-mediated bicarbonate conversion to concentrated formate in a CEM-based electrolyzer

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Journal of Energy Chemistry 2025年第1期100卷 605-611页

作者： Haocheng Xiong Donghuan Wu Haonan Li Andrew Li Qikun hu Siyao Song Bingjun Xu Qi Lu State Key Laboratory of Chemical Engineering Department of Chemical EngineeringTsinghua UniversityBeijing 100084China College of Chemistry and Molecular Engineering Peking UniversityBeijing 100871China Ordos Laboratory Inner Mongolia 017000China

Renewable energy-driven bicarbonate conversion to valuable chemicals presents an attractive strategy for mitigating CO_(2)emissions,as bicarbonate can be efficiently generated from the capture of atmospheric CO_(2)using alkaline solutions with reactive *** this work,we present a CO_(2)-mediated bicarbonate conversion to pure formate using a cation exchange membrane-based electrolyzer with a 25 cm^(2)electrode *** electrolysis achieved selectivities exceeding 75%for formate at a total current of 2.5 A,achieving formate concentrations up to 1.2 M and yields as high as 95%over extended *** techno-economic assessment confirmed the economic viability of the process,highlighting the potential for bicarbonate electrolysis as a sustainable method for producing valuable chemicals.

关键词： Electrocatalysis Techno-economic assessments Electrochemistry Flow electrolyzer

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Nighttime reactions of a series of unsaturated alcohols with NO_(3)•:Kinetics,products and mechanisms study

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Journal of Environmental Sciences 2025年第5期151卷 331-346页

作者： Yanyong Xu Shengrui Tong Weiran Li Meifang Chen Lin hu Hailiang Zhang Sufan Wang Maofa Ge State Key Laboratory for Structural Chemistry of Unstable and Stable Species Chinese Academy of Sciences Research/Education Center for Excellence in Molecular SciencesInstitute of Chemistry Chinese Academy of SciencesBeijing 100190China University of Chinese Academy of Sciences Beijing 100049China College of Chemistry and Material Science Anhui Normal UniversityWuhu 241000China College of Ecology and Environment Xinjiang UniversityUrumqi 830017China

Unsaturated alcohols are a class of Biogenic volatile organic compounds(BVOCs)emitted in large quantities by plants when damaged or under adverse environmental conditions,and studies on their atmospheric degradation at night are still *** used chamber experiments to study the gas-phase reactions of three unsaturated alcohols,E-2-penten-1-ol,Z-2-hexen-1-ol and Z-3-hepten-1-ol,with NO_(3)radicals(NO_(3)•)during the *** rate constants of these reactions were(11.7±1.76)×10^(−13),(8.55±1.33)×10^(−13)and(6.08±0.47)×10^(−13)cm^(3)/(molecule·s)at 298K and 760 Torr,*** contrast,the reaction rate of similar substances with ozone was about 10^(−18)cm^(3)/(molecule·s),which indicates that the reaction with NO_(3)•is themain oxidation pathway for unsaturated alcohols at *** molecule aldehydes and ketones were the main gas-phase organic products of the reaction of three aldehydes and ketones with NO_(3)•,and the total small molecule aldehydes and ketones yields can reach between 45%-60%.They mainly originate from the breakage of alkoxy radicals,and different breakage sites determine different product *** addition,the SOA yields of the three unsaturated alcohols with NO_(3)•were 7.1%±1.0%,12.5%±1.9%and 30.0%±4.5%,respectively,whichweremuch higher than those of similarly structured substances with O_(3)or OH radicals(•OH).The results of high-resolution mass spectrometry shows that the main components of Secondary organic aerosol(SOA)of the three unsaturated alcohols are dimeric compounds containing several nitrate groups,which are formed through the polymerization of oxyalkyl radicals.

关键词： Unsaturated alcohols Reaction rate Aldehyde and ketone products Secondary organic aerosol components Reaction mechanism

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Bioaccessibility and health risk assessment of hydrophobic organic pollutants in soils from four typical industrial contaminated sites in China

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Journal of Environmental Sciences 2025年第1期147卷 282-293页

作者： Shi-Ping Ou Xiao-Liang Liao Zi-Tao huang Yan-Cong hu Zongwei Cai Zhi-Feng Chen Guangdong Key Laboratory of Environmental Catalysis and Health Risk Control Guangdong-Hong Kong-Macao Joint Laboratory for Contaminants Exposure and HealthSchool of Environmental Science and EngineeringGuangdong University of TechnologyGuangzhou 510006China State Key Laboratory of Environmental and Biological Analysis Department of ChemistryHong Kong Baptist UniversityHong Kong 999077China

There have been reports of potential health risks for people from hydrophobic organic pollutants,such as polycyclic aromatic hydrocarbons(PAHs),polychlorinated hydrocarbons(PCHs),and organophosphate flame retardants(OPFRs).When a contaminated site is used for residential housing or public utility and recreation areas,the soil-bound organic pollutantsmight pose a threat to human *** this study,we investigated the contamination profiles and potential risks to human health of 15 PAHs,6 PCHs,and 12 OPFRs in soils from four contaminated sites in *** used an in vitro method to determine the oral bioaccessibility of soil *** PAHswere found at concentrations ranging from26.4 ng/g to 987 ng/***(0.27-14.3 ng/g)and OPFRs(6.30-310 ng/g)were detected,but at low levels compared to earlier *** levels of PAHs,PCHs,and OPFRs released from contaminated soils into simulated gastrointestinal fluids ranged from 1.74%to 91.0%,2.51%to 39.6%,and 1.37%to 96.9%,*** on both spiked and unspiked samples,we found that the oral bioaccessibility of pollutantswas correlated with their logKow andmolecularweight,and the total organic carbon content and pH of *** in 13 out of 38 contaminated soil samples posed potential high risks to *** considering oral bioaccessibility,nine soils still posed potential risks,while the risks in the remaining soils became *** contribution of this paper is that it corrects the health risk of soil-bound organic pollutants by detecting bioaccessibility in actual soils from different contaminated sites.

关键词： Contaminated soil Hydrophobic organic pollutant Polycyclic aromatic hydrocarbon Oral bioaccessibility Risk assessment

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Stable partial nitrification was achieved for nitrogen removal from municipal wastewater by gel immobilization:A pilot-scale study

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Journal of Environmental Sciences 2025年第5期151卷 529-539页

作者： Xin hu Hong Yang Xiaoyue Fang Xuyan Liu Jiawei Wang Xiaotong Wang Yongsheng Bai Bojun Su Key Laboratory of Beijing for Water Quality Science and Water Environmental Recovery Engineering Faculty of ArchitectureCivil and Transportation EngineeringBeijing University of TechnologyBeijing 100124China Beijing General Municipal Engineering Design&Research Institute Co. Ltd.Beijing 100044China Hebei GEO University Shijiazhuang 050031China Hebei Key Laboratory of Water Quality Engineering and Comprehensive Utilization of Water Resources Hebei University of ArchitectureZhangjiakou 075000China School of Environmental Science and Safety Engineering Tianjin University of TechnologyTianjin 300384China Beijing Drainage Group Co.Ltd. Beijing 100022China

As an energy and carbon saving process for nitrogen removal from wastewater,the partial nitrification and denitrification process(PN/D)has been extensively ***,achieving stable PNinmunicipalwastewater has always been *** this study,a gel immobilized PN/D nitrogen removal process(GI-PN/D)was established.A 94 days pilot-scale experiment was conducted using real municipal wastewater with an ammonia concentration of 43.5±5.3mg N/L at a temperature range of 11.3–28.7◦*** nitrogen removal performance and associated pathways,shifts in the microbial community as well as sludge yield were *** results were as follows:the effluent TN and COD were 0.6±0.4mg/L and 31.1±3.8 mg/L respectively,and the NAR exceeding 95%.GI-PN/D achieved deep nitrogen removal ofmunicipalwastewater through stable PN without taking any *** primary pathways for nitrogen removal were identified as denitrification,simultaneous nitrification-denitrification,and aerobic ***-throughput sequencing analysis revealed that the immobilized fillers facilitated the autonomous enrichment of functional bacteria in each reactor,effectively promoting the dominance and stability of the microbial *** addition,GI-PN/D had the characteristic of low sludge yield,with an average sludge yield of 0.029 kg SS/kg *** study provides an effective technical for nitrogen removal from municipal wastewater through PN.

关键词： Gel immobilization Partial nitrification Deep nitrogen removal Autonomous enrichment Sludge yield

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