检索结果-南通市图书馆

Chinese Chemical Letters 2024年第8期35卷 418-424页

作者： Mei-Chen Liu Qing-Song Liu yi-Zhou Quan Jia-Ling Yu Gang Wu Xiu-Li wang Yu-zhong wang The Collaborative Innovation Center for Eco-Friendly and Fire-Safety Polymeric Materials(MoE) National Engineering Laboratory of Eco-Friendly Polymeric Materials(Sichuan)State Key Laboratory of Polymer Materials EngineeringCollege of ChemistrySichuan UniversityChengdu 610064China

Safety and energy density are significant for lithium-ion batteries(LIBs),and the flammable organic elec-trolyte is one of the most critical causes of the safety problem of *** LiNi0.8 Co 0.1 Mn 0.1 O 2(NCM811)cathode with high capacity can improve the energy density,the interface stability between NCM811 cathode and electrolytes needs to be ***,we report a multifunctional additive,diethyl(2-(triethoxysilyl)ethyl)phosphonate(DETSP),which can suppress the flammability of the elec-trolyte and enhance the cycling stability of NCM811 cathode with a capacity retention of 89.9%after 400 cycles at 1 C,while that of the blank electrolyte is merely 61.3%.In addition,DETSP is compati-ble well with the graphite anode without impairing the electrochemical ***,the performance and safety of NCM811/graphite full cells are also *** and theoretical re-sults demonstrate that DETSP can scavenge acidic byproducts and is beneficial to form a stable cathode-electrolyte interface(CEI).Accordingly,DETSP can potentially be an effective solution to ameliorating the safety of the commercial electrolyte and improving the stability of high-voltage cathodes.

关键词： Electrolyte additive NCM Lithium-ion batteries Safety Cathode-electrolyte interface

A universal polymer-assisted route to fabricate Zr-doped TiO2 nanocomposite: boosting reactive desulfurization

在线全文

学校读者我要写书评

暂无评论

Tungsten 2024年第3期6卷 596-609页

作者： Yue Du Ping Li Zhi-yi zhong Wen-Xue Chen yi-Si Liu Yun-Long Xie Li-Na Zhou Kai wang hubei key Laboratory of Photoelectric Materials and Devices College of Material Science and Engineering Hubei Normal University national Laboratory of Solid State Microstructures Nanjing University College of Urban and Environmental sciences Huangshi Key Laboratory of Prevention and Control of Soil Pollution Hubei Normal University School of Chemistry Chemical Engineering and Biotechnology Nanyang Technological University

A series of transition metal ion-doped TiO2composites were prepared by polyethyleneimine-assisted solvent-free *** to the similar electronegativity and ionic radius of Ti and Zr ions,the introduction of Zr element to TiO2can effectively improve its surface acidity and introduce more defect sites on the ***-fabricated Zr-doped TiO2nanocomposite exhibits the formation of Zr-Ti bond,strong surface acidity,connected mesoporous channels,and relatively high *** remarkable properties contribute to its adsorption-oxidation-desulfurization capacity toward thiophene-type sulfides,which can remove 500 ×10-6dibenzothiophene from the model fuel within 100 min at low reaction *** polymer-induced self-assembly method can reduce organic solvent usage,pollutant emissions,and energy consumption,which provides an efficient and practical way to prepare porous metal oxide-based catalysts in future.

关键词： Oxidative desulfurization Transition metal ion-doped TiO 2 nanocomposite Dibenzothiophene Solvent-free self-assembly method

Enhanced Fenton-like process over Cu/L(+)-ascorbic acid co-doping mesoporous silica for toxicity reduction of emerging contaminants

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Frontiers of Environmental science & Engineering 2024年第4期18卷 49-60页

作者： Yuhang Liu Wenxuan Deng Xiaojun Wu chun hu Lai Lyu key Laboratory for Water Quality and Conservation of the Pearl River Delta(Ministry of Education) Institute of Environmental Research at Greater BayGuangzhou UniversityGuangzhou 510006China

Effective removal of emerging contaminants(ECs)to minimize their impacts on human health and the natural environment is a global *** the removal of ECs in water,we fabricated a seaweed spherical microsphere catalyst with Cu cation-πstructures by in situ doping of Cu species and ascorbic acid in mesoporous silica(Cu-C-MSNs)via a hydrothermal *** results indicate that bisphenol A(BPA)is substantially degraded within 5 min under natural conditions,with its biological toxicity considerably ***,industrial wastewater could also be effectively purified by Cu-C-MSNs/H_(2)O_(2) *** presence of metal sites and the complexation of ECs via cation-πinteraction andπ-πstacking on the catalyst surface were directly responsible for the polarization distribution of electrons,thus activating H_(2)O_(2) and dissolved oxygen(DO).The removal of contaminants could be attributed primarily to 1)the activation of H_(2)O_(2) into ^(·)OH to attack the contaminants and 2)self-cleavage because of the transfer of electrons from the contaminants to the *** study provides an innovative solution for the effective treatment of ECs and has positive implications for easing global environmental crises.

关键词： Cation-πstructures Polarization electric field Fenton-like process Contaminants cleavage

The chance of sodium titanate anode for the practical sodium-ion batteries

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Chinese Journal of Chemical Engineering 2024年第8期72卷 226-244页

作者： Feng Chen Haoyu Li Xianyan Qiao Ruoyang wang Changyan hu Ting Chen yifan Niu Benhe zhong Zhenguo Wu Xiaodong Guo School of Chemical Engineering Sichuan UniversityChengdu 610065China Institute for Advanced Study Chengdu UniversityChengdu 610106China Chengdu No.7 High School Chengdu 6100412China

Supporting sustainable green energy systems,there is a big demand gap for grid energy *** storage,especially sodium-ion batteries(SIBs),have advanced significantly and are now emerging as a feasible alternative to the lithium-ion batteries equivalent in large-scale energy storage due to their natural abundance and prospective inexpensive *** various anode materials of SIBs,beneficial properties,such as outstanding stability,great abundance,and environmental friendliness,make sodium titanates(NTOs),one of the most promising anode materials for the rechargeable ***,there are still enormous challenges in application of NTO,owing to its low intrinsic electronic conductivity and collapse of *** research on NTOs is still in its infancy;there are few conclusive reviews about the specific function of various modification ***,we summarize the typical strategies of optimization and analysis the fine structures and fabrication methods of NTO anodes combined with the application of in situ characterization *** work provides effective guidance for promoting the continuous development,equipping NTOs in safety-critical systems,and lays a foundation for the development of NTO-anode materials in SIBs.

关键词： Sodium titanates Sodium-ion batteries Modification methods Electronic materials Electrochemistry Synthesis

Root cause of corrosion failure of tin coating on wire clamp in marine atmosphere

在线全文

学校读者我要写书评

暂无评论

Journal of Iron and Steel Research International 2024年第4期31卷 998-1014页

作者： Zhen zhong wang-yan Ly Teng-yuan Liu yi Xie Yang Yang Zhen-zhu wang Deng-ke Li Xiao-bo Li Tang-qing Wu School of Materials science and Engineering Xiangtan UniversityXiangtan 411105HunanChina Electric Power Research Institute of Guangdong Power Grid Co. Ltd.Guangzhou 510080GuangdongChina Shenyang national L aboratory for Materials science Institute of Metal ResearchChinese Academy of SciencesShenyang 110016LiaoningChina School of Materials science and Engineering.University of science and Technology of china Shenyang 110016LiaoningChina Electric Power Research Institute State Grid Hunan Electric Power CompanyChangsha 410007HunanChina School of Mechanical Engineering and Mechanics Xiangtan UniversityXiangtan 411105HunanChina School of Information science and Engineering Changsha Normal UniversityChangsha 410199HunanChina

The failure cause of a tinned copper wire clamp in marine atmosphere was studied systematically by X-ray photoelectron spectroscopy,scanning electron microscopy with energy dispersive spectroscopy and electrochemical *** main components of the green rust on the surface of the damaged wire clamp are SnO_(2),CuO,Cu_(2)Cl(OH)_(3) and CuCO(OH)_(2).Much of green rust distributes at the platform edge along the axial direction on the crimp connection,and severe corrosion and corrosion pits occur at the platform edge zone along the axial *** enriching Cl-at the marine atmosphere and the existing O_(2) in air collectively enhance the corrosion process of the tin coating and the copper *** element model results show that the residual stress and strain of the tin coating are the largest at the platform edge along the axial direction on the crimp connection,and the corresponding electrode potential of the tin coating at this zone drops *** above results indicate that the residual strain increases the driving force of the corrosion electrochemical reactions and accelerates the corrosion rate and the pit corrosion of the tin coating at this zone.

关键词： Tin coating Marine atmosphere Residual strain-Chloride ion Corrosion failure

Decolorization and kinetics of photo oxidizing cationic blue X-GRL by UV/H_2O_2 system

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Journal of Environmental sciences 2000年第1期12卷 28-34页

作者： hu chun, wang yi\|zhong (SKLEAC, Research Center for Eco Environmental sciences, Chinese Academy of sciences, Beijing 100085, china) foundation item: national key natural science foundation of china (No. 29637010)

Azo dye cationic blue X GRL, which is non biodegradable toxic organic compound, is decolorized and subsequently mineralized by UV/H 2O 2/N 2 or UV/H 2O 2/air (O 2) system. The effects of initial solution concentration, initial solution pH, and some ions produced during the degradation on the rate of decolorization of cationic blue X GRL were investigated. The photodegradation of cationic blue X GRL approximately follows first order kinetics. The regression curve of the natural logarithm of concentration verus reaction time becomes less linear with initial concentration increasing. Oxygen and appropriate OH\+· generator can accelerate reaction rate. The effect of reaction atmosphere, initial concentration, light intensity on the optimal dosage of H 2O 2 were studied. It was found that the optimal H 2O 2 dosage was determined by UV light intensity. These intermediates of cationic blue X GRL decolorization are biodegradable.

关键词： decolorization cationic blue X GRL kinetics photooxidation ultraviolet hydrogen peroxide CLC number: X703 Document code: A

Robust tantalum tuned perovskite oxygen electrode for reversible protonic ceramic electrochemical cells

在线全文

学校读者我要写书评

暂无评论

Rare Metals 2024年第7期43卷 3055-3065页

作者： Yu-Shi Feng Yu Shen Fang wang Chuan Tian Qin-yi hu Qian Duan Jing-Wei Li Di Bao School of Materials science and Engineering Changchun University of Science and TechnologyChangchun 130022China zhongshan Institute of Changchun University of science and Technology Zhongshan528437China State key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry Chinese Academy of SciencesChangchun 130022China key Laboratory of Preparation and Applications of Environmental Friendly Materials Ministry of EducationJilin Normal UniversityChangchun 130103China

Perovskite oxides with diverse composition and structure have exhibited grand advances in boosting the oxygen reduction and evolution reaction(ORR/OER),which are essential for the reversible protonic ceramic electrochemical cell(R-PCEC)toward the sustainable hydrogen production and ***,enhancement of their activity and stability remains ***,we develop the Ta-regulated BaCo_(0.7)Fe_(0.3)O_(3-δ)perovskite oxygen electrode(Ba(Co_(0.7)Fe_(0.3))_(1-x)Ta_xO_(3-δ))with abundant oxygen defects and achieve the simultaneous enhancement in the electrocatalytic activity and stability toward ORR and ***-fabricated R-PCEC with(Ba(Co_(0.7)Fe_(0.3))_(0.9)Ta_(0.1)O_(3-δ))(BCFT10)oxygen electrode performs high power density of 1.47 W·cm^(-2)at 650℃in fuel cell mode,and the current density is up to-2.11 A·cm^(-2)at 1.4 V at 650℃in electrolysis mode,as well as the good stability in both the fuel cell and electrolysis ***,the cell also demonstrates a stable cycling operation between fuel cell and electrolysis mode,suggesting a great potential of BCFT10 as oxygen electrode material for R-PCECs.

关键词： Reversible protonic ceramic electrochemical cells Perovskite oxide Oxygen electrode Ta element doping Oxygen defects

Research status and perspectives of MXene-based materials for aqueous zinc-ion batteries

在线全文

学校读者我要写书评

暂无评论

Rare Metals 2024年第5期43卷 1867-1885页

作者： Xiao-Yu wang Qi-Hang Yang Xin-Yan Meng Meng-Meng Zhen Zhen-zhong hu Bo-Xiong Shen School of Energy and Environmental Engineering Hebei University of TechnologyTianjin 300071China

Aqueous zinc-ion batteries(AZIBs)as green battery systems have attracted widespread attention in large-scale electrochemical energy storage devices,owing to their high safety,abundant Zn materials,high theoretica specific capacity and low redox *** there are some thorny issues in AZIBs that hinder their practical application,such as low intrinsic electron conductivity,slow ion migration kinetics,zinc dendrites and side ***-based materials with superior conductivity,large polar surface and abundant active sites can simultaneously serve as cathode materials,electrolyte additive and protection layer of anode to regulate redox reactions of *** various materials have been used to improve electrochemical performances of AZIBs there is a lack of in-depth discussion on the regulation mechanism of MXene-based materials for *** this review,we elaborate the research progress of MXenebased materials in AZIBs,including their application in cathode materials and inhibition of zinc *** the future prospects and development directions of MXenebased materials that may improve performance of AZIBs are prospected.

关键词： MXene Aqueous zinc-ion batteries Composite materials Zinc dendrites

Machine learning for carbonate formation drilling: Mud loss prediction using seismic attributes and mud loss records

在线全文

学校读者我要写书评

暂无评论

Petroleum science 2024年第2期21卷 1241-1256页

作者： hui-Wen Pang Han-Qing wang yi-Tian Xiao Yan Jin Yun-hu Lu Yong-Dong Fan Zhen Nie national key Laboratory of Petroleum Resources and Engineering China University of Petroleum(Beijing)Beijing102249China College of science China University of Petroleum-BeijingBeijing102249China Petroleum Exploration and Production Research Institute SINOPECBeijing102206China College of Petroleum Engineering China University of Petroleum-BeijingBeijing102249China Research Institute of Petroleum Exploration and Development CNPCBeijing100083China

Due to the complexity and variability of carbonate formation leakage zones, lost circulation prediction and control is one of the major challenges of carbonate drilling. It raises well-control risks and production expenses. This research utilizes the H oilfield as an example, employs seismic features to analyze mud loss prediction, and produces a complete set of pre-drilling mud loss prediction solutions. Firstly, 16seismic attributes are calculated based on the post-stack seismic data, and the mud loss rate per unit footage is specified. The sample set is constructed by extracting each attribute from the seismic trace surrounding 15 typical wells, with a ratio of 8:2 between the training set and the test set. With the calibration results for mud loss rate per unit footage, the nonlinear mapping relationship between seismic attributes and mud loss rate per unit size is established using the mixed density network ***, the influence of the number of sub-Gausses and the uncertainty coefficient on the model's prediction is evaluated. Finally, the model is used in conjunction with downhole drilling conditions to assess the risk of mud loss in various layers and along the wellbore trajectory. The study demonstrates that the mean relative errors of the model for training data and test data are 6.9% and 7.5%, respectively, and that R2is 90% and 88%, respectively, for training data and test data. The accuracy and efficacy of mud loss prediction may be greatly enhanced by combining 16 seismic attributes with the mud loss rate per unit footage and applying machine learning methods. The mud loss prediction model based on the MDN model can not only predict the mud loss rate but also objectively evaluate the prediction based on the quality of the data and the model.

关键词： Lost circulation Risk prediction Machine learning Seismic attributes Mud loss records

Dual-objective two-photon microscope for volumetric imaging of dense scattering biological samples by bidirectional excitation and collection

在线全文

学校读者我要写书评

暂无评论

Photonics Research 2024年第6期12卷 1351-1361页

作者： MUYUE ZHAI JING YU YANhuI hu HANG YU BEICHEN XIE yi YU DAWEI LI AIMIN wang HEPING CHENG national Biomedical Imaging Center College of Future TechnologyPeking UniversityBeijing 100871China Research Unit of Mitochondria in Brain Diseases Chinese Academy of Medical SciencesPKU-Nanjing Institute of Translational MedicineNanjing 211500China Beijing Transcend Vivoscope Biotech Beijing 100085China College of Engineering Peking UniversityBeijing 100871China Academy for Advanced Interdisciplinary Studies Peking UniversityBeijing 100871China Center for Quantitative Biology Peking UniversityBeijing 100871China School of Electronics Peking UniversityBeijing 100871China State key Laboratory of Advanced Optical Communication System and Networks Peking UniversityBeijing 100871China

Full view observation throughout entire specimens over a prolonged period is crucial when exploring the physiological functions and system-level ***-photon microscopy(MPM)has been widely employed for such purposes owing to its deep penetration ***,the current MPM struggles with balancing the imaging depth and quality while avoiding photodamage for the exponential increasement of excitation power with the imaging ***,we present a dual-objective two-photon microscope(Duo-2P),characterized by bidirectional two-photon excitation and fluorescence collection,for long-duration volumetric imaging of dense scattering ***-2P effectively doubles the imaging depth,reduces the total excitation energy by an order of magnitude for samples with a thickness five times the scattering length,and enhances the signal-to-noise ratio up to 1.4 *** these advantages,we acquired volumetric images of a 380-μm suprachiasmatic nucleus slice for continuous 4-h recording at a rate of 1.67 s/volume,visualized the calcium activities over 4000 neurons,and uncovered their state-switching *** conclude that Duo-2P provides an elegant and powerful means to overcome the fundamental depth limit while mitigating photodamages for deep tissue volumetric imaging.

关键词： excitation overcome exponential