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Structure stability, electronic property and voltage profile of LiFe_(1-n)NnP_(1-m)M_(m)O_(4) olivine cathode material

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Rare Metals 2021年第12期40卷 3512-3519页

作者： Zhi-hong Cui Xue-Feng Lu Jian-Hua Luo Xin Guo hong-tao Xue Fu-Ling Tang State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metal Department of Materials Science and EngineeringLanzhou University of TechnologyLanzhou 730050China

First-principles computational studies under density functional theory(DFT) framework were used to investigate the structural stability, conductivity and voltage profile of LiFe_(1-n)NnP_(1-m)M_(m)O_(4)(N, M = Si or S) electrode materials. It is found that the Li FeP_(7/8)Si_(1/8)O_(4) system has the most stable structure. After doping, the band gap values of the systems decrease gradually, and LiFe_(7/8)S_(1/8)PO_(4) system has a minimum band gap of 1.553 e V, attributed to the hybridization of the Fe-d and S-p orbital electrons. The Li Fe P7/8 S1/8 O4 system demonstrates the characteristic of n-type semiconductor, and other doping systems have the feature of p-type semiconductor. Charge density difference maps show that the covalent property of Si-O bond is enhanced in the Li FeP_(7/8)Si_(1/8)O_(4) system. The average distance of Li and O atoms in the S doping systems increases from 0.21026 to 0.21486 and 0.21129 nm, respectively,indicating that doping broadens significantly the channel of Li ion de-intercalation in LiFe_(7/8)S_(1/8)PO_(4) and LiFeP_(7/8)S_(1/8)O_(4). Additionally, the results of lithium intercalation potential imply that the voltages of the doping systems fallinto the range of 2.23-2.86 V.

关键词： Energy storage materials First principles Battery cathode LiFePO_(4) Doping Electronic properties

Comparative plastomic analysis and insights into the phylogeny of Salvia (Lamiaceae)

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Plant Diversity 2021年第1期43卷 15-26页

作者： hong Wu Peng-Fei Ma hong-tao Li Guo-Xiong Hu De-Zhu Li Germplasm Bank of Wild Species Kunming Institute of BotanyChinese Academy of SciencesKunmingYunnan650201China University of Chinese Academy of Sciences Beijing100049China College of Life Sciences Guizhou UniversityGuiyangGuizhou550025China

Salvia is the largest genus of Lamiaceae,with almost 1000 species,and has been divided into 11 *** ***,native to East Asia,is particularly important because of its potential medicinal ***,the interspecific relationships of this subgenus have not been resolved and the plastomes of Salvia have rarely been *** the current study,we compared plastid genome structure and organization of 19 species of Salvia(14 newly sequenced and 5 previously published).Our comparative analysis showed that all Salvia plastomes examined have a quadripartite structure typical of most angiosperms and contain an identical set of 114 unique genes(80 protein-coding genes,4 rRNA genes,and 30 tRNA genes).The plastome structure of all Salvia species is highly conserved like other Lamiaceae *** content,gene order,and GC content were highly similar in these *** inverted repeats/single copy region(IR/SC)boundaries of Salvia are highly conserved,and IR contraction only occurred in two species(Salvia mekongensis and ***).In Salvia,sequence divergence was higher in non-coding regions than in coding *** found that using large single copy(LSC)and small single copy regions(SSC)with exclusion of the rapidly evolving sites produced the highest resolution in phylogenetic analysis of Salvia,suggesting that using suitable informative sites to build trees is more conducive in phylogenetic *** study assembled a powerful matrix data set for studying the phylogeny of Salvia,resolving the interspecific relationship of Salvia *** newly sequenced plastid genomes will also enrich the plastome database of Salvia,providing the scientific basis for the development and utilization of germplasm resources of this large and important genus.

关键词： Lamiaceae Salvia subg.Glutinaria Plastome Phylogeny

Preparation, characterization and photocatalytic activity of N-doped TiO_2 nanocrystals

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International Journal of Minerals,Metallurgy and Materials 2009年第6期16卷 701-706页

作者： hong-tao Gao Jing Zhou Dong-mei Dai Guang-jun Liu College of Chemistry and Molecular Engineering Qingdao University of Science ＆ Technology Qingdao 266042 China Department of Chemistry Jining University Jining 273155 China

N-doped TiO2 nanocrystals were prepared using titanium alkoxide as precipitant with different proportional materials. The products were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, and UV-vis diffuse reflectance spectra. It is confirmed experimentally that the photocatalytic activity of N-doped TiO2 is much higher than that of Degussa P25, when used for the degradation of crystal violet. The degradation kinetics follows an apparent first-order reaction, which is consistent with a generally observed Langmuir-Hinshelwood mechanism. The doping of TiO2 with nitrogen significantly increases the absorption in the region of visible light. The energy of the band gap of N-doped TiO2 is 2.92 eV. The better performance of N-doped TiO2 can be explained by the fact that it is also excited with longer-wavelength light.

关键词： pbotocatalyst degradation nitrogen doping TiO2 nanocrystals visible light crystal violet

Fermion-Boson Vertex at Finite Chemical Potential

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Communications in Theoretical Physics 2007年第1期47卷 107-110页

作者： ZONG hong-Shi FENG hong-tao HOU Feng-Yao SUN Wei-Min Department of Physics Nanjing University Nanjing 2100937 China Joint Center for Particle Nuclear Physics and Cosmology Nanjing 210093 China CCAST （World Laboratory） P.O. Box 8730 Beijing 100080 China

Based on the Ward-Takahashi identity at finite chemical potential and Lorentz structure analyms, we generalize the Ball-Chiu vertex to the case of nonzero chemical potential and obtain the general form of the frmionbo... 详细信息

关键词： Ward-Takahashi identity Ball-Chiu vertex finite chemical potential

Application of a neural network model with multimodal fusion for fluorescence spectroscopy

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Nuclear Science and Techniques 2024年第10期35卷 135-148页

作者： Lin Tang Shuang Zhou Kai-Bo Shi hong-tao Shen Lei You College of Electronic Information and Electrical Engineering Chengdu UniversityChengdu 610106China Guangxi Key Laboratory of Nuclear Physics and Nuclear Technology Guangxi Normal UniversityGuilin 541004China National Engineering Research Center for Agro-Ecological Big Data Analysis&Application Anhui UniversityHefei 230039China School of Electrical and Electronic Engineering Nanyang Technological UniversitySingapore 639798Singapore Vanadium and Titanium Resource Comprehensive Utilization Key Laboratory of Sichuan Province Panzhihua UniversityPanzhihua 617000China Key Laboratory of Interior Layout optimization and Security Institutions of Higher Education of Sichuan ProvinceChengdu Normal UniversityChengdu 611130China

In energy-dispersive X-ray fluorescence spectroscopy,the estimation of the pulse amplitude determines the accuracy of the spectrum *** error generated by the amplitude estimation of the pulse output distorted by the measurement system leads to false peaks in the measured *** eliminate these false peaks and achieve an accurate estimation of the distorted pulse amplitude,a composite neural network model is proposed,which embeds long and short-term memory(LSTM)into the UNet *** UNet network realizes the fusion of pulse sequence features and the LSTM model realizes pulse amplitude *** model is trained using simulated pulse datasets with different amplitudes and distortion *** the pulse height estimation,the average relative error of the trained model on the test set was approximately 0.64%,which is 27.37% lower than that of the traditional trapezoidal shaping *** processing of a standard iron source further validated the pulse height estimation performance of the UNet-LSTM *** estimating the amplitude of the distorted pulses using the model,the false peak area was reduced by approximately 91% over the full spectrum and was corrected to the characteristic peak region of interest(ROI).The corrected peak area accounted for approximately 1.32%of the characteristic peak ROI *** results indicate that the model can accurately estimate the height of distorted pulses and has substantial corrective effects on false peaks.

关键词： UNet Long-and short-term memory Pulse distortion Pulse height estimation Fluorescent spectroscopy

Critical Number of Fermion Flavors at Finite Chemical Potential in QED3

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Communications in Theoretical Physics 2005年第6X期44卷 1055-1060页

作者： FENG hong-tao HE Xiang HOU Feng-Yao SUN Wei-Min ZONG hong-Shi Department of Physics Nanjing University Nanjing 210093 China Joint Center for Particle Nuclear Physics and Cosmology Nanjing 210093 China CCAST (World Laboratory) P.O. Box 8730 Beijing 100080 China

We propose a new method for calculating the dressed fermion propagator at finite chemical potential in QED3 under the rainbow approximation of Dyson-Schwinger equation. In the above approximation, we show that the dressed fermion propagator at finite chemical potential # has the form S（p） = iγ.p^-A（p^-2）＋ B（ p^-2） with p^-μ= （p^-1p3 ＋ iμ）. Using this form of fermion propagator at nonzero chemical potential, we investigate the Dyson-Schwinger equation for the dressed fermion propagator at finite chemical potential and study the effects of the chemical potential on the critical number of the fermion flavors.

关键词： DS equation chemical potential critical number of the fermion flavors

A Proposed Batch In vitro Apparatus for Conducting Rumen FermentationExperiment

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Agricultural Sciences in China 2008年第7期7卷 887-894页

作者： ZHANG Guang-qin REN hong-tao College of Animal Science Henan University of Science and Technology Luoyang 471003 P.R. China

This research proposes a batch in vitro rumen apparatus modified from Daisy incubator and procedures of measuring feed digestion by using nylon bag to replace the traditional centrifuging and filtration methods, for the purpose of studying ruminal fermentation. The apparatus consists of 8 sets of airtight reaction vessels which rotated at a speed of 1 r/min and located inside a thermostatic cabin. Optimum procedures was proved to be that the volume of incubation fluid was 400 mL; fineness and size of test feed were 0.125-0.25 mm and 0.4 g, respectively; amount of bags in one vessel was 6; fermentation diet in a single incubation was 4-5 g. Comparing experiments showed that fermentation speed attained with the apparatus was about 15-20% greater than that attained with flask-shaking machine method （revolutionary speed is 100 r/min） and more accurate results could be obtained with the new apparatus. In conclusion, this apparatus could provide an efficient mixing action, and the procedure could allow sensitive detection of differences in ruminal fermentation in a time-saving way.

关键词： in vitro apparatus ruminal fermentation nylon bag

Jasmonic Acid is Induced in a Biphasic Manner in Response of Pea Seedlings to Wounding

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Journal of Integrative Plant Biology 2009年第6期51卷 562-573页

作者： Hao-Ru Yang Ke Tang hong-tao Liu Qiu-hong Pan Wei-Dong Huang College of Food Science and Nutritional Engineering China Agricultural University Beijing 100083 China Institute of Geographic Sciences and Natural Resources Research the Chinese Academy of Sciences Beijing 100101 China

The role of jasmonic acid （JA） in plant wounding response has been demonstrated. However, the source of JA in wound signaling remains unclear. In the present study, pea seedlings were used as material to investigate the systemic induction of JA and the activation of lipoxygenase （LOX）-dependent octadecanoid pathway upon wounding. The results showed that endogenous JA could induce two peaks in the wounded leaves and the stalks, while only one peak in the systemic leaves. LOX activity and its protein amount were also induced and the stimulation mainly occurred in the late phase, while one peak of induction was present after pretreatment with JA. Applied nordihydroguaiaretic acid （NDGA）, an inhibitor of LOX activity, only inhibited the induction of JA in the late phase, and the resistance of pea was impaired. Furthermore, 13（S）- hydroperoxy-9（Z）, 11 （E）-octadecadienoic acid （13（S）-H（P）ODE） was confirmed to be the main product of LOX throughout the experimental time. in addition, immunocytochemical analysis also revealed the occurrence of JA biosynthesis and transport upon wounding. These results demonstrated that wound-induced JA in wounded leaves resulted from its biosynthesis and conversion from its conjugates, while in systemic leaves resulted from its transport and biosynthesis; and proved that the LOX pathway was vital to the wound-induced defense response involved in JA biosynthesis.

关键词： defense response jasmonic acid lipoxygenase pea (Pisum sativum L.).

Bio-electronic bandage: Self-powered performances to accelerate intestinal wound healing

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Chinese Chemical Letters 2024年第12期35卷 29-31页

作者： Saadullah Khattak hong-tao Xu Jianliang Shen The Fifth Affiliated Hospital of Wenzhou Medical University National Engineering Research Center of Ophthalmology and Optometry Eye Hospital Wenzhou Medical University Zhejiang Engineering Research Center for Tissue Repair Materials Wenzhou Institute University of Chinese Academy of Sciences

Intestinal wound healing is complex because of the intestine's intricate structure and the environment, which contains its microbes and digestive modules. Traditional suturing is the utmost standard surgical methodology, which can imply hyperplasia and obstruction, two probable harmful consequences. Thus, patients often face a delayed healing time and constrained healing experiences.

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