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Understand the Temperature Sensing Behavior of Solid-state Polymerized PEDOT Hybrid Based on X-ray Scattering Studies

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Chinese Journal of Polymer Science 2024年第1期42卷 105-112,I0010页

作者： Zhen-hang he Guang-Feng Liu Ze-Kun Zhou Zhen Liu Yi-Shu Zeng Peng Zhang School of Materials Science and Engineering Key Laboratory for Polymeric Composite and Functional Materials of Ministry of EducationSun Yat-sen UniversityGuangzhou 510275China Shanghai Advanced Research Institute(Zhangjiang Laboratory) Chinese Academy of SciencesShanghai 201204China

Poly(3,4-ethylenedioxythiophene)(PEDOT) is one of the most successful conductive polymers that recently has been used in wearable sensors for human health monitoring. In this work, we prepared a series of PEDOT hybrids consisting of PEDOT, sodium poly(styrene sulfonate)(PSSNa) and polyethylene oxide(PEO), and their preparation could be scaled-up via an adapted solid-state polymerization process. The resistance of the as-prepared PEDOT:PSS/PEO hybrid shows clear temperature response, i.e., it decreases almost linearly with the temperature increase. To understand this phenomenon, the in situ synchrotron radiation wide-and small-angle X-ray scattering(WAXS/SAXS) characterizations were undertaken to study the temperature-dependent microstructure change of the PEDOT:PSS/PEO hybrid. It demonstrated that PEDOT formed conductive paths in the hybrids, which were not destroyed by the PEO crystallization. As temperature increased, the PEO crystals' melting and the accompanying reorganization of PEDOT chains endowed the hybrid sample temperature responsiveness. Based on these fundamental knowledges, the hybrid materials were used to fabricate flexible wearable sensor that showing temperature sensing performance with an accuracy of 1 ℃. These findings shed lights on the scalable manufacturing of wearable sensors for body temperature monitoring.

关键词： Solid-state polymerization PEDOT hybrid Structure-property correlation X-ray scattering

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Bright InP quantum dots by Ga-doping for red emitters

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Nano Research 2024年第7期17卷 6721-6733页

作者： Kai-Zheng Song Xiao-hang he Zhe-Yong Chen Ge Tang Jin-Zhao Huang Feng-Lei Jiang College of Chemistry and Molecular Sciences Wuhan UniversityWuhan 430072China

Environment-friendly indium phosphide(InP)-based quantum dots(QDs)with efficient red-emitting properties are sufficiently needed to satisfy the requirement of burgeoning display and lighting ***,the syntheses of InP QDs using tris(trimethylsilyl)phosphine as the precursor are highly toxic and ***,we successfully introduced gallium(Ga)ions into tris(dimethylamino)phosphine-based red InP cores through thermally-promoted cation exchange,and the obtained Ga-doped InP cores exhibited significantly increased photoluminescence quantum yields(PLQY)of up to 26%.The existence of Ga was directly confirmed by energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy,and the functions of Ga were systematically *** subsequent coating of Ga-doped InP cores with ZnSeS and ZnS shells,the resulting Ga-InP/ZnSeS/ZnS QDs achieved a high PLQY of 62%with an emission maximum at 640 *** contrast,without Ga-doping,the PLQY only attained 36%using the same synthetic *** indicated an approximate 1.7-fold increase in *** enhancement of photoluminescence was related to the Ga^(3+),as it not only passivated surface defects of InP cores but also reduced core–shell interface *** Ga-InP/ZnSeS/ZnS QDs exhibited good stability towards heat treatment and ultraviolet(UV)***,the red light-emitting diode(LED)based on Ga-InP/ZnSeS/ZnS QDs performed well in a wide injected current range of 2 to 200 mA,with a maximum power efficiency of 0.68 lm/*** work showcases Ga-doping through cation exchange as a promising strategy for enhancing the efficiency of InP-based red emitters.

关键词： indium phosphide gallium doping optical properties light emitting diode

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Increased long-distance and homo-trans interactions related to H3K27me3 in Arabidopsis hybrids

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Journal of Integrative Plant Biology 2024年第2期66卷 208-227页

作者： Zhaoxu Gao Yanning Su Le Chang Guanzhong Jiao Yang Ou Mei Yang Chao Xu Pengtao Liu Zejia Wang Zewen Qi Wenwen Liu Linhua Sun Guangming he Xing Wang Deng hang he School of Advanced Agriculture Sciences and School of Life Sciences State Key Laboratory of Protein and Plant Gene ResearchPeking UniversityBeijing 100871China College of Grassland Science Beijing Forestry UniversityBeijing 100083China Peking University Institute of Advanced Agricultural Sciences Shandong Laboratory of Advanced Agricultural Sciences in WeifangWeifang 261325China

In plants,the genome structure of hybrids changes compared with their parents,but the effects of these changes in hybrids remain *** reciprocal crosses between Col×C24 and C24×Col in Arabidopsis using high-throughput chromosome conformation capture assay(Hi-C)analysis,we found that hybrid three-dimensional(3D)chromatin organization had more long-distance interactions relative to parents,and this was mainly located in promoter regions and enriched in genes with heterosis-related *** interactions between euchromatin and heterochromatin were increased,and the compartment strength decreased in *** compartment domain(CD)boundaries,the distal interactions were more in hybrids than their *** the hybrids of CURLY LEAF(clf)mutants clfCol×clfC24and clfC24×clfCol,the heterosis phenotype was damaged,and the long-distance interactions in hybrids were fewer than in their parents with lower ***-seq data revealed higher levels of H3K27me3 in the region adjacent to the CD boundary and the same interactional homo-trans sites in the wild-type(WT)hybrids,which may have led to more long-distance *** addition,the differentially expressed genes(DEGs)located in the boundaries of CDs and loop regions changed obviously in WT,and the functional enrichment for DEGs was different between WT and clf in the longdistance interactions and loop *** findings may therefore propose a new epigenetic explanation of heterosis in the Arabidopsis hybrids and provide new insights into crop breeding and yield increase.

关键词： 3D chromatin organization H3K27me3 homo-trans hybrids long-distanceinteractions

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Comparison of prognosis and postoperative morbidities between standard pancreaticoduodenectomy and the TRIANGLE technique for resectable pancreatic ductal adenocarcinoma

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World Journal of Gastrointestinal Surgery 2024年第3期16卷 689-699页

作者： he-Xing hang Zheng-Hua Cai Yi-Fei Yang Xu Fu Yu-Dong Qiu Hao Cheng Division of Pancreatic Surgery Department of General SurgeryNanjing Drum Tower HospitalThe Affiliated Hospital of Medical SchoolNanjing UniversityNanjing 210008Jiangsu ProvinceChina

BACKGROUND Radical surgery combined with systemic chemotherapy offers the possibility of long-term survival or even cure for patients with pancreatic ductal adenocar-cinoma(PDAC),although tumor recurrence,especially locally,still inhibits the treatment *** TRIANGLE technique was introduced as an extended dissection procedure to improve the R0 resection rate of borderline resectable or locally advanced ***,there was a lack of studies concerning postoperative complications and long-term outcomes of this procedure on patients with resectable *** Patients with resectable PDAC eligible for PD from our hospital between June 2018 and December 2021 were enrolled in this retrospective cohort *** the patients were divided into PDstandard and PDTRIANGLE groups according to the surgical *** characteristics,surgical data,and postoperative morbidities were *** of the patients were followed up,and the date and location of tumor recurrence,and death were *** Kaplan-Meier method and log-rank test were used for the survival *** There were 93 patients included in the study and 37 underwent the TRIANGLE *** of operation was longer in the PDTRIANGLE group compared with the PDstandard group[440(410-480)min vs 320(265-427)min](P=0.001).Intraoperative blood loss[700(500-1200)mL vs 500(300-800)mL](P=0.009)and blood transfusion[975(0-1250)mL vs 400(0-800)mL](P=0.009)were higher in the PDTRIANGLE *** was a higher incidence of surgical site infection(43.2%vs 12.5%)(P=0.001)and postoperative diarrhea(54.1%vs 12.5%)(P=0.001)in the PDTRIANGLE *** rates of R0 resection and local recurrence,overall survival,and disease-free survival did not differ significantly between the two *** The TRIANGLE technique is safe,with acceptable postoperative morbidities compared with standardized PD,but it does not improve prognosis for patients with resectable PDAC.

关键词： Pancreatic ductal adenocarcinoma TRIANGLE technique Pancreaticoduodenectomy Prognosis Postoperative morbidities

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Low Resource Chinese Geological Text Named Entity Recognition Based on Prompt Learning

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Journal of Earth Science 2024年第3期35卷 1035-1043页

作者： hang he Chao Ma Shan Ye Wenqiang Tang Yuxuan Zhou Zhen Yu Jiaxin Yi Li Hou Mingcai Hou State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation Institute of Sedimentary GeologyCollege of Computer Science and Cyber SecurityChengdu University of TechnologyChengdu 610059China Key Laboratory of Deep-Time Geography and Environment Reconstruction and Applications of Ministry of Natural Resources Chengdu University of TechnologyChengdu 610059China School of Information Engineering China University of Geosciences(Beijing)Beijing 100083China

Geological reports are a significant accomplishment for geologists involved in geological investigations and scientific research as they contain rich data and textual *** the rapid development of science and technology,a large number of textual reports have accumulated in the field of ***,many non-hot topics and non-English speaking regions are neglected in mainstream geoscience databases for geological information mining,making it more challenging for some researchers to extract necessary information from these *** Language Processing(NLP)has obvious advantages in processing large amounts of textual *** objective of this paper is to identify geological named entities from Chinese geological texts using NLP *** propose the RoBERTa-Prompt-Tuning-NER method,which leverages the concept of Prompt Learning and requires only a small amount of annotated data to train superior models for recognizing geological named entities in low-resource dataset *** RoBERTa layer captures context-based information and longer-distance dependencies through dynamic word ***,we conducted experiments on the constructed Geological Named Entity Recognition(GNER)*** experimental results show that the proposed model achieves the highest F1 score of 80.64%among the four baseline algorithms,demonstrating the reliability and robustness of using the model for Named Entity Recognition of geological texts.

关键词： Prompt Learning Named Entity Recognition(NER) low resource geological text text information mining big data geology.

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基于人体和场景上下文的多人3D姿态估计

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软件学报 2024年第4期35卷 2039-2054页

作者：何建航孙郡瑤刘琼华南理工大学软件学院广东广州510006

深度歧义是单帧图像多人3D姿态估计面临的重要挑战,提取图像上下文对缓解深度歧义极具潜力.自顶向下方法大多基于人体检测建模关键点关系,人体包围框粒度粗背景噪声占比较大,极易导致关键点偏移或误匹配,还将影响基于人体尺度因子估计... 详细信息

深度歧义是单帧图像多人3D姿态估计面临的重要挑战,提取图像上下文对缓解深度歧义极具潜力.自顶向下方法大多基于人体检测建模关键点关系,人体包围框粒度粗背景噪声占比较大,极易导致关键点偏移或误匹配,还将影响基于人体尺度因子估计绝对深度的可靠性.自底向上的方法直接检出图像中的人体关键点再逐一恢复3D人体姿态.虽然能够显式获取场景上下文,但在相对深度估计方面处于劣势.提出新的双分支网络,自顶向下分支基于关键点区域提议提取人体上下文,自底向上分支基于三维空间提取场景上下文.提出带噪声抑制的人体上下文提取方法,通过建模“关键点区域提议”描述人体目标,建模姿态关联的动态稀疏关键点关系剔除弱连接减少噪声传播.提出从鸟瞰视角提取场景上下文的方法,通过建模图像深度特征并映射鸟瞰平面获得三维空间人体位置布局;设计人体和场景上下文融合网络预测人体绝对深度.在公开数据集MuPoTS-3D和Human3.6M上的实验结果表明:与同类先进模型相比,所提模型HSC-Pose的相对和绝对3D关键点位置精度至少提高2.2%和0.5%;平均根关键点位置误差至少降低4.2 mm.

关键词：多人场景3D姿态估计关键点区域提议人体上下文场景上下文人体绝对深度

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基于等面积圆环和伴星夹角的星图识别算法

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吉林大学学报（工学版） 2024年第3期54卷 821-827页

作者：张刘何金航刘赫章家保吕雪莹吉林大学仪器科学与电气工程学院长春130012

针对于传统径向和环向特征星图识别算法在构建径向特征过程中伴星分布不均匀以及采用环向特征匹配过程中特征值不稳定的问题,提出了一种等面积圆环划分和伴星矢量夹角相结合的星图识别算法。通过选取动态半径使得径向特征下的圆环面积相... 详细信息

针对于传统径向和环向特征星图识别算法在构建径向特征过程中伴星分布不均匀以及采用环向特征匹配过程中特征值不稳定的问题,提出了一种等面积圆环划分和伴星矢量夹角相结合的星图识别算法。通过选取动态半径使得径向特征下的圆环面积相等,保证伴星落在每个圆环的概率相等,有效提高了径向匹配过程的识别率。对于径向匹配后冗余的导航星,采用伴星组成的矢量夹角特征进行筛选,选定匹配特征值最高的为最终识别结果。仿真模拟结果表明:当添加位置噪声为1像素时,星图识别成功率达到95%;当伪星数目为2颗时,识别率达到98%。相较于传统径向和环向识别算法,本文方法在识别率和识别速度上具有明显优势。

关键词：星图识别径向特征环向特征匹配度

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Clinical efficacy of intradermal type Ⅰ collagen injections in treating skin photoaging in patients from high-altitude areas

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World Journal of Clinical Cases 2024年第16期12卷 2713-2721页

作者： Bin Yang Ao he Bin-Bin Bu Gong Zhuo Qing-Zhu Zhou Jia-hang he Liu Liu Wen-Li Huang Xian Zhao Department of Plastic and Cosmetic Surgery The Affiliated Calmette Hospital of Kunming Medical UniversityThe First People's Hospital of KunmingCalmette Hospital KunmingKunming 650224Yunnan ProvinceChina Department of Dermatology The People's Hospital of Chuxiong Yi Autonomous PrefectureChuxiong Yi Autonomous Prefecture 675099Yunnan ProvinceChina

BACKGROUND Photoaging,a result of chronic sun exposure,leads to skin damage and pigmentation *** treatments may have limitations in high-altitude areas like Yunnan *** Col Ⅰ injections stimulate collagen production,potentially improving skin *** study aims to assess the efficacy and safety of this treatment for *** To evaluate the efficacy and safety of intradermal typeΙcollagen(ColΙ)injection for treating *** This prospective,self-controlled study investigated the impact of intradermal injections of ColΙon skin photodamage in 20 patients from the Yunnan *** six treatment sessions were conducted every 4 wk±3 *** and after each treatment,facial skin characteristics were quantified using a VISIA skin *** thickness data were assessed using the ultrasound probes of the Dermalab skin *** Face-Q scale was used for subjective evaluation of the treatment effect by the *** The skin thickness of the right cheek consistently increased after each treatment session compared with *** skin thickness of the left cheek significantly increased after the third through sixth treatment sessions compared with *** skin thickness of the right zygomatic region increased after the second to sixth treatment sessions,whereas that of the left zygomatic region showed a significant increase after the fourth through sixth treatment *** skin thickness of both temporal regions significantly increased after the fifth and sixth treatment sessions compared with baseline(Phese findings were also supported by skin ultrasound *** feature count for the red areas and wrinkle feature count decreased following the treatment(Phe red areas after *** Face-QSatisfaction with Facial Appearance Overall and Face-Q-Satisfaction with Skin scores significantly increased after each treatment ***

关键词： Photoaging TypeΙcollagen Face-Q High-altitude area Skin photodamage Patient satisfaction

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高精度数控机床液压控制系统故障诊断试验研究

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液压气动与密封 2024年第5期44卷 102-106页

作者：朱航科陕西工业职业技术学院机械工程学院陕西咸阳712000

高精度数控机床是一种高度集成的复杂机电液自动化控制系统,部件间的故障极易导致数控机床的失稳。针对高精度数控机床的故障诊断和故障响应问题,在整个机床控制系统结构基础上,对各个子系统进行故障诊断功能系统划分,构建了高精度数控... 详细信息

高精度数控机床是一种高度集成的复杂机电液自动化控制系统,部件间的故障极易导致数控机床的失稳。针对高精度数控机床的故障诊断和故障响应问题,在整个机床控制系统结构基础上,对各个子系统进行故障诊断功能系统划分,构建了高精度数控机床液压控制系统故障监测状态机。采用差异阈值故障监测策略对相关的部件进行故障诊断,对不同的故障严重度事件进行分级故障响应,在搭建的高精度数控机床液压控制系统故障诊断模拟实验环境中验证了故障诊断方法的可行性。实验结果分析后可以看出,该故障诊断方法能够快速有效地监测出整个机床液压控制系统的故障状态。

关键词：数控机床自动化故障诊断故障响应状态机差异阈值

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中小机场运营与补贴之间的互动探究

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科技和产业 2024年第5期24卷 125-129页

作者：何行徐明昊中国民用航空飞行学院经济与管理学院四川广汉618307

基于2013-2021年国内73个中小机场的面板数据,运用DEA(数据包络分析)模型计算机场运营效率,并对面板数据进行回归分析。研究发现,2013-2019年国内中小机场的运营效率呈上升趋势,但2020-2021年受新冠肺炎疫情影响,运营效率显著下降。进... 详细信息

基于2013-2021年国内73个中小机场的面板数据,运用DEA(数据包络分析)模型计算机场运营效率,并对面板数据进行回归分析。研究发现,2013-2019年国内中小机场的运营效率呈上升趋势,但2020-2021年受新冠肺炎疫情影响,运营效率显著下降。进一步研究表明,机场补贴对中小机场的运营效率具有显著正向促进作用。虽然机场效率不能直接影响补贴,但机场业务量对补贴有正向显著影响。因此,提出加强对中小机场的政策支持、注重提高机场业务量、建立应对突发事件的机制等措施,以促进中小机场的可持续发展。

关键词：中小机场 DEA(数据包络分析) 机场运营效率机场补贴

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