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Enhancing visible-light-driven NO oxidation through molecular‐level insights of dye-loaded sea sands

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Rare Metals 2024年第2期43卷 543-554页

作者： Yu-han Li Bang-Fu Chen Sónia A.C.Carabineiro You-Yu Duan Ping Tan Wing-Kei Ho Fan Dong Engineering Research Center for Waste Oil Recovery Technology and Equipment Ministry of EducationChongqing Key Laboratory of Catalysis and New Environmental MaterialsChongqing Technology and Business UniversityChongqing400067China Nanchang Institute of Technology Nanchang33044China LAQV-REQUIMTE Department of ChemistryNOVA School of Science and TechnologyUniversidade NOVA de Lisboa2829-516CaparicaPortugal College of Physics and Center of Quantum Materials and Devices Chongqing UniversityChongqing401331China Department of Science and Environmental Studies The Education University of Hong KongHong Kong999077China

Natural minerals,abundant and easily obtained through simple physical processing,offer a cost-effective and environmentally friendly solution for dyeing wastewater disposal and air pollution *** study investigates the photocatalytic removal of NO using natural different types of dyes,loaded on natural sand,under visible light *** examining various coating concentrations of dyes and sand weights,we discovered that sand loaded with Rhodamine B(RhB)exhibits high activity for the photo-oxidation of NO.A combination results of X-ray diffraction(XRD),X-ray photoelectron spectroscopy(XPS),Fourier transform infrared spectroscopy(FTIR)and thermogravimetric(TG)analyses confirm the presence of SiO_(2),CaCO_(3),Al_(2)O_(3)and iron oxides as the main components of the ***,studying RhB-loaded individual components reveals that CaCO_(3)plays a crucial role in enhancing the NO removal *** results and theoretical calculations demonstrate the establishment of a directional charge transfer channel from CaCO_(3)to RhB,facilitating the adsorption and activation of molecular NO and O_(2).This work not only promotes the utilization of natural mineral resources but also enriches the fields of environmental photochemistry and semiconductor photocatalysis.

关键词： Sand dyes Rhodamine B Photo-oxidation of NO Visible light illumination

Experimental evaluation of factors affecting performance of concentrating photovoltaic/thermal system integrated with phase‐change materials(PV/T‐CPCM)

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Energy Storage and Saving 2024年第1期3卷 30-41页

作者： Zhaoyang Luan Lanlan Zhang Xiangfei Kong han Li Man Fan School of Energy and Environmental Engineering Hebei University of TechnologyTianjin300401China School of Mechanical Engineering Beijing Institute of TechnologyBeijing100081China

The photovoltaic/thermal(PV/T)system is a promising option for countering energy *** improve the performance of PV/T systems,compound parabolic concentrators(CPCs)and phase-change materials(PCMs)were jointly applied to construct a concentrating photovoltaic/thermal system integrated with phase-change materials(PV/T-CPCM).An open-air environment is used to analyze the effects of different parameters and the intermittent operation strategy on the system *** results indicate that the short-circuit current and open-circuit voltage are positively correlated with the solar irradiance,but the open-circuit voltage is negatively correlated with the temperature of the PV *** the solar irradiance is 500 W⋅m^(−2) and the temperature of the PV modules is 27.5℃,the short-circuit current and open-circuit voltage are 1.0 A and 44.5 V,*** solar irradiance results in higher thermal power,whereas the thermal efficiency is under lower solar irradiance(136.2-167.1 W⋅m^(−2) is twice under higher solar irradiance(272.3-455.7 W⋅m^(−2))).In addition,a higher mass flow rate corresponds to a better cooling effect and greater pump energy *** the mass flow rate increases from 0.01 to 0.02 kg⋅s^(-1),the temperature difference between the inlet and outlet decreases by 1.8℃,and the primary energy-saving efficiency decreases by 0.53%.The intermittent operation of a water pump can reduce the energy consumption of the system,and the combination of liquid cooling with PCMs provides better thermal regulation and energy-saving effects under various conditions.

关键词： Compound parabolic concentrator Factor analysis Open-air experiment Phase-change materials Photovoltaic/thermal system

Theoretical probe into universal tetrad effect for complexation discrepancy between lanthanide elements and organophosphoric extractant diethyl phosphoric acid

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Journal of Rare Earths 2024年第6期42卷 1142-1148,I0006页

作者： Haifeng Zheng Yanling Li Xuyi Zhang Jinglu han Songsong Li Guolong Wu Qingshi Liu Xiaojuan Liu Wuping Liao State Key Laboratory of Rare Earth Resources Utilization Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun130022China University of Science and Technology of China Hefei230026China School of Chemistry and Chemical Engineering Nanchang UniversityNanchang330031China Ganjiang Innovation Academy Chinese Academy of SciencesGanzhou341000China

The deep understanding of 4f-correlated electron motion behavior is experimentally limited due to similar physicochemical properties of rare earth elements(REEs).While the solvent extraction behavior originating from the continuous occupation of 4f electrons along the lanthanide family provides a particular platform to probe the 4f electrons motion behavior and its correlations to their versatile ***,the complexation between REEs and the prototypical extractant of diethyl phosphoric acid(DEP)was substantially studied based on quantum mechanical *** results firstly show that the average bond lengths between Ln and six coordinated oxygen atoms are consistent with lanthanide contraction phenomenon,and gadolinium break effect is also obviously ***,the"tetrad effect"is figured out based on the subtle discrepancy of 4f electrons occupation,namely La-Nd,Sm-Eu,Gd-Dy and ***,the main composition is 4f5d6p for La-Nd,while the discrepancy is due to the increasing electrons in the 5d shell,while it is 4f5d for *** Gd-Dy,their 4f orbitals accept little electrons and the donating electrons flow into 6s5d subshells due to the half-filled stability and the enhancement of shielding *** electrons donate into 5d6p subshells due to multiply electrons occupation of 4f orbitals for *** detailed analyses obviously clarify the"tetrad effect"along the lanthanide family due to the different variation of 4f orbital *** is expected that these microscopic understandings provide important guidance for the separation of REEs and the design of new extractants.

关键词： Theoretical calculation Rare earths 4f electron Tetrad effect Gadolinium break

The Observed Near-Surface Energy Exchange Processes over Arctic Glacier in Summer

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Journal of Meteorological Research 2024年第3期38卷 600-607页

作者： Libo ZHOU Jinhuan ZHU Linlin KONG Peng LI Shupo MA Fei LI han ZOU Meigen ZhanG Irina REPINA Department of Lower Atmospheric Observation and Research Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing100029China State Key Laboratory of Atmospheric Boundary Layer Physics and Atmospheric Chemistry Institute of Atmospheric PhysicsChinese Academy of SciencesBeijing100029China Department of Weather Forecast Aviation Meteorological Centre of Air Traffic Management BureauCivil Aviation Administration of ChinaBeijing100015China A.M.Obukhov Institute of Atmospheric Physics Russian Academy of Sciences(RAS)Moscow119017Russian Federation

Under Arctic warming,near-surface energy transfers have significantly changed,but few studies have focused on energy exchange over Arctic glacier due to limitations in available *** this study,the atmospheric energy exchange processes over the Arctic glacier surface were analyzed by using observational data obtained in summer 2019 in comparison with those over the Arctic tundra *** energy budget over the glacier greatly differed from that over the tundra,characterized by less net shortwave radiation and downward sensible heat flux,due to the high albedo and icy *** of the incoming solar radiation was injected into the glacier in summer,leading to snow ice *** the observation period,strong daily variations in near-surface heat transfer occurred over the Arctic glacier,with the maximum downward and upward heat fluxes occurring on 2 and 6 July 2019,*** analyses suggested that the maximum downward heat flux is mainly caused by the strong local thermal contrast above the glacier surface,while the maximum upward heat transfer cannot be explained by the classical turbulent heat transfer theory,possibly caused by countergradient heat *** results indicated that the near-surface energy exchange processes over Arctic glacier may be strongly related to local forcings,but a more in-depth investigation will be needed in the future when more observational data become available.

关键词： Arctic glacier tundra energy exchange processes

A new insight into LPSO phase transformation and mechanical properties uniformity of large-scale Mg-Gd-Y-Zn-Zr alloy prepared by multi-pass friction stir processing

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Journal of Magnesium and Alloys 2024年第5期12卷 2041-2056页

作者： Xiaohu Guan Wen Wang Ting Zhang Pai Peng Qiang Liu Peng han Ke Qiao Jun Cai Liqiang Wang Kuaishe Wang School of Metallurgical Engineering National and Local Joint Engineering Research Center for Functional Materials ProcessingXi’an University of Architecture and TechnologyNo.13 Yanta RoadXi’anShaanxi 710055China Xi’an Rare Metal Materials Institute Co.Ltd Xi’an 710016China State Key Laboratory of Metal Matrix Composites School of Material Science and EngineeringShanghai Jiao Tong UniversityNo.800 Dongchuan RoadShanghai 200240China

A large-scale fine-grained Mg-Gd-Y-Zn-Zr alloy plate with high strength and ductility was successfully prepared by multi-pass friction stir processing(MFSP)technology in this *** structure of grains and long period stacking ordered(LPSO)phase were characterized,and the mechanical properties uniformity was ***,a quantitative relationship between the microstructure and tensile yield strength was *** results showed that the grains in the processed zone(PZ)and interfacial zone(IZ)were refined from 50μm to 3μm and 4μm,respectively,and numerous original LPSO phases were *** IZ,some block-shaped 18R LPSO phases were transformed into needle-like 14H LPSO phases due to stacking faults and the short-range diffusion of solute *** severe shear deformation in the form of kinetic energy caused profuse stacking fault to be generated and move rapidly,greatly increasing the transformation rate of LPSO *** MFSP,the ultimate tensile strength,yield strength and elongation to failure of the large-scale plate were 367 MPa,305 MPa and 18.0% *** refinement and LPSO phase strengthening were the major strengthening mechanisms for the MFSP *** particularly,the strength of IZ was comparable to that of PZ because the strength contribution of the 14H LPSO phase offsets the lack of grain refinement strengthening in *** result opposes the widely accepted notion that IZ is a weak region in MFSP-prepared large-scale fine-grained plate.

关键词： Friction stir processing Multi-pass Mg-Gd-Y-Zn-Zr alloy LPSO phase transformation Mechanical properties

Sedimentary Characteristics,Ages,and Environmental Significance of Gravel Deposits and Loess in Shandong,Eastern China:Regional Response to Global Change Since the Last Glacial Period

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Acta Geologica Sinica(English Edition) 2024年第2期98卷 491-504页

作者： WANG Min KONG Fanbiao KONG Xianglun CHEN Haitao WANG Jiawei MIAO Xiaodong JIA Guangju han Mei XU Shujian Department of Geography and Tourism Qilu Normal UniversityJinan 250014China School of Geography and Environment Shandong Normal UniversityJinan 250014China Shandong Provincial Key Laboratory of Water and Soil Conservation and Environmental Protection Linyi UniversitySchool of Resources and EnvironmentLinyiShandong 276005China College of Earth Science and Engineering Shandong University of Science and TechnologyQingdaoShandong 266590China

Investigation of rarely studied gravel layers found in the loess in Shandong Province,eastern China,reveals the fabric characteristics of two gravel layers(G1,G2)and the sedimentary characteristics of loess at the typical and well-preserved Heiyu section(HY),where,to determine the paleoclimatic changes during Marine Isotope Stage *** stimulated luminescence dates of the HY formation range from 0.26±0.02 ka to 39.00±2.00 *** addition,the ages of G1 and G2 were estimated using the Bayesian model to be 39.60-40.50 and 29.00-29.50 ka.G1 and G2 are mainly composed of fine and medium gravel,both of which were subangular to subrounded limestone,with gravel directions to NE and *** average flow velocity,average depth,and flood peak flow of G1 are 1.10 m/s,0.49 m,and 37.04 m^(3)/s,respectively,calculated using the flow energy method,whereas those of G2 are 0.98 m/s,0.38 m,and 18.38 m^(3)/s,*** of climate proxy indices show that the sedimentary environment of the gravel and loess in HY might be a regional response to global change.

关键词： paleoenvironment geochronology gravel layer sedimentology Pleistocene Shandong Province

Supramolecular complex glycoconjugate vaccine generates self-enhancement effects for carbohydrate antigen delivery

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Chinese Chemical Letters 2024年第2期35卷 317-322页

作者： han Lin Yanchun Li Kun Zhou Dan Li hangyan Yu Jie Zhao Haofei Hong Zhifang Zhou Zhimeng Wu Key Laboratory of Carbohydrate Chemistry & Biotechnology Ministry of EducationSchool of BiotechnologyJiangnan UniversityWuxi 214122China

Targeting delivery of tumor-associated carbohydrate antigen(TACA)-based vaccine to antigen-presenting cells(APCs)mediated by endogenous antibodies can improve the immunogenicity of ***,an essential requirement of this approach is to generate high titers of endogenous antibodies in vivo through pre-immunization,which complicates the immunization procedure and may cause side ***,we report a new generation of APC-targeting TACA-based supramolecular complex vaccine,assembled by sialyl Thomsen-nouveau-bovine serum albumin-adamantine(sTn-BSA-Ada)and heptavalent rhamnose(Rha)-modifiedβ-cyclodextrin(β-CD)via host-guest *** complex vaccine retained anti-Rha antibodies recruiting capability and facilitated the APCs uptake of the vaccine via the interaction of the Fc-domain with the Fc receptors on *** demonstrate that direct immunization of complex vaccine elicited anti-Rha and anti-sTn specific immune response synchronously,generating a novel self-enhancement effect that can improve the antigen delivery to APCs in high *** structure-activity relationship(SAR)study proved that complex vaccine 4 with polyethylene glycol 6(PEG 6)linker in host molecule provoked a robust and specific sTn immune response comparable to the pre-immunization *** antisera induced by complex vaccine,either through direct immunization or pre-immunization,exhibited equal potency of cytotoxicity against the sTn expression cancer *** study provides a general platform for TACA-based vaccines with self-enhancement effects without the need for pre-immunization.

关键词： Glycoconjugate vaccine Endogenous antibody APC-targeting Supramolecular complex sTn antigen

Enhancing Photovoltaic Performance of Nonfused-Ring Electron Acceptors via Asymmetric End-Group Engineering and Noncovalently Conformational Locks

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Chinese Journal of Chemistry 2024年第5期42卷 485-490页

作者： Bo Liu Congqi Li Xiaobin Gu Yinghui han Zhixiang Wei Yunhao Cai Xin Zhang Hui Huang Yanping Huo School of Chemical Engineering and Light Industry Guangdong University of TechnologyGuangzhouGuangdong510006 China College of Materials Science and Opto-Electronic Technology & Center of Materials Science and Optoelectronics Engineering & CAS Center for Excellence in Topological Quantum Computation & CAS Key Laboratory of Vacuum Physics University of Chinese Academy of SciencesBeijing100049 China College Resources and Environment University of Chinese Academy of SciencesBeijing100049 China Center for Excellence in Nanoscience (CAS) & Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS) National Center for Nanoscience and TechnologyBeijing100190 China

By employing the asymmetric end-group engineering,an asymmetric nonfused-ring electron acceptor(NFREA)was designed and *** with the symmetric analogs(NoCA-17 and NoCA-18),NoCA-19 possesses broader light absorption range,more coplanarπ-conjugated backbone,and appropriate crystallinity according to the experimental and theoretical *** organic solar cells based on J52:NoCA-19 exhibited a power conversion efficiency as high as 12.26%,which is much higher than those of J52:NoCA-17(9.50%)and J52:NoCA-18(11.77%),mainly due to more efficient exciton dissociation,better and balanced charge mobility,suppressed recombination loss,shorter charge extraction time,longer charge carrier lifetimes,and more favorable blend film *** findings demonstrate the great potential of asymmetric end-group engineering in exploring low-cost and high-performance NFREAs.

关键词： Organic solar cells Nonfused-ring electron acceptors Asymmetric end-group engineering Noncovalently conformational locks Low-cost acceptors

Bioceramic scaffolds with two-step internal/external modification of copper-containing polydopamine enhance antibacterial and alveolar bone regeneration capability

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Journal of Zhejiang University-Science B(Biomedicine & Biotechnology) 2024年第1期25卷 65-82页

作者： Xiaojian JIANG Lihong LEI Weilian SUN Yingming WEI Jiayin han Shuaiqi ZHONG Xianyan YANG Zhongru GOU Lili CHEN Department of Oral Medicine the Second Affiliated HospitalZhejiang University School of MedicineHangzhou310009China Bio-nanomaterials and Regenerative Medicine Research Division Zhejiang–California International Nanosystem InstituteZhejiang UniversityHangzhou310058China

Magnesium-doped calcium silicate(CS)bioceramic scaffolds have unique advantages in mandibular defect repair;however,they lack antibacterial properties to cope with the complex oral ***,for the first time,the CS scaffold was functionally modified with a novel copper-containing polydopamine(PDA(Cu^(2+)))rapid deposition method,to construct internally modified(*P),externally modified(@PDA),and dually modified(*P@PDA)*** morphology,degradation behavior,and mechanical properties of the obtained scaffolds were evaluated in *** results showed that the CS*P@PDA had a unique micro-/nano-structural surface and appreciable mechanical *** the prolonged immersion stage,the release of copper ions from the CS*P@PDA scaffolds was rapid in the early stage and exhibited long-term sustained *** in vitro evaluation revealed that the release behavior of copper ions ascribed an excellent antibacterial effect to the CS*P@PDA,while the scaffolds retained good cytocompatibility with improved osteogenesis and angiogenesis ***,the PDA(Cu^(2+))-modified scaffolds showed effective early bone regeneration in a critical-size rabbit mandibular defect ***,it was indicated that considerable antibacterial property along with the enhancement of alveolar bone regeneration can be imparted to the scaffold by the two-step PDA(Cu^(2+))modification,and the convenience and wide applicability of this technique make it a promising strategy to avoid bacterial infections on implants.

关键词： Copper-containing polydopamine Modification Antibacterial property Bone regeneration Angiogenesis Bioceramic scaffold