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An in-vitro Investigation of Iron-Containing hydroxyapatite/Titanium Composites

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Journal of Materials Science & Technology 2011年第6期27卷 546-552页

作者： q. Chang h.q. Ru D.L. Chen X.Y. Yue L. Yu C.P. Zhang Key Laboratory for Anisotropy and Texture of Materials (Ministry of Education) Northeastern University Shenyang 110004 China Department of Mechanical and Industrial Engineering Ryerson University 350 Victoria Street Toronto Ontario M5B 2K3 Canada

The in-vitro biological behavior of a newly-developed iron-containing hydroxyapatite/titanium（hA/Ti） composite was investigated by immersing the composites in the simulated body fluid（SBF） for up to 5 *** addition of iron was observed to have a significant influence on the in-vitro biological behavior of the *** obtained results revealed that the stability of the composites in the physiological solution was markedly *** solubility decreased in the order of pure hA,hA/5（Ti-33Fe）,and hA/15（Ti33Fe）.Precipitation occurred on the surface of hA/5（Ti-33Fe） composite,showing a good combination of physiostability with bioactivity,while hA/15（Ti-33Fe） composite exhibited superior physiostability since there was no obvious change on the surface of hA/15（Ti-33Fe）.

关键词： hydroxyapatite composite Iron Titanium Simulated body fluid Biological behavior

Molecule‑Level Multiscale Design of Nonflammable Gel Polymer Electrolyte to Build Stable SEI/CEI for Lithium Metal Battery

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Nano-Micro Letters 2025年第1期17卷 404-423页

作者： qiqi Sun Zelong Gong Tao Zhang Jiafeng Li Xianli zhu Ruixiao zhu Lingxu Wang Leyuan Ma Xuehui Li Miaofa Yuan Zhiwei Zhang Luyuan Zhang Zhao qian Longwei Yin Rajeev Ahuja Chengxiang Wang Key Laboratory for Liquid‑Solid Structural Evolution and Processing of Materials(Ministry of Education) School of Materials Science and EngineeringShandong UniversityJinan 250061People’s Republic of China Condensed Matter Theory Department of Physics and AstronomyUppsala UniversityUppsala 75120Sweden

The risk of flammability is an unavoidable issue for gel polymer electrolytes(GPEs).Usually,flameretardant solvents are necessary to be used,but most of them would react with anode/cathode easily and cause serious interfacial instability,which is a big challenge for design and application of nonflammable ***,a nonflammable GPE(SGPE)is developed by in situ polymerizing trifluoroethyl methacrylate(TFMA)monomers with flame-retardant triethyl phosphate(TEP)solvents and LiTFSI–LiDFOB dual lithium *** is strongly anchored to PTFMA matrix via polarity interaction between-P=O and-Ch_(2)CF_(3).It reduces free TEP molecules,which obviously mitigates interfacial reactions,and enhances flame-retardant performance of TEP *** TEP molecules are also inhibited in solvation of Li^(+),leading to anion-dominated solvation sheath,which creates inorganic-rich solid electrolyte interface/cathode electrolyte interface *** coordination structure changes Li^(+)transport from sluggish vehicular to fast structural transport,raising ionic conductivity to 1.03 mS cm^(-1) and transfer number to 0.41 at 30℃.The Li|SGPE|Li cell presents highly reversible Li stripping/plating performance for over 1000 h at 0.1 mA cm^(−2),and 4.2 V LiCoO_(2)|SGPE|Li battery delivers high average specific capacity>120 mAh g^(−1) over 200 *** study paves a new way to make nonflammable GPE that is compatible with Li metal anode.

关键词： Anchoring effect Nonflammable gel electrolyte In situ cross-linked Electrode-electrolyte interface Li metal battery

Constructing Donor–Acceptor‑Linked COFs Electrolytes to Regulate Electron Density and Accelerate the Li^(+)Migration in quasi‑Solid‑State Battery

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Nano-Micro Letters 2025年第1期17卷 456-471页

作者： Genfu Zhao hang Ma Conghui Zhang Yongxin Yang Shuyuan Yu haiye zhu Yongjiang Sun hong Guo School of Materials and Energy International Joint Research Center for Advanced Energy Materials of Yunnan ProvinceYunnan UniversityKunming 650091People’s Republic of China Yunnan Yuntianhua Co. LtdR&D CenterKunming 650228People’s Republic of China Southwest United Graduate School Kunming 650091People’s Republic of China

Regulation the electronic density of solid-state electrolyte by donor–acceptor(D–A)system can achieve highly-selective Li^(+)transportation and conduction in solid-state Li metal *** study reports a high-performance solid-state electrolyte thorough D–A-linked covalent organic frameworks(COFs)based on intramolecular charge transfer *** other reported COFbased solid-state electrolyte,the developed concept with D–A-linked COFs not only achieves electronic modulation to promote highly-selective Li^(+)migration and inhibit Li dendrite,but also offers a crucial opportunity to understand the role of electronic density in solid-state Li metal *** introduced strong electronegativity F-based ligand in COF electrolyte results in highlyselective Li^(+)(transference number 0.83),high ionic conductivity(6.7×10^(-4)S cm^(−1)),excellent cyclic ability(1000 h)in Li metal symmetric cell and high-capacity retention in Li/LiFePO_(4)cell(90.8%for 300 cycles at 5C)than substituted C-and N-based *** is ascribed to outstanding D–A interaction between donor porphyrin and acceptor F atoms,which effectively expedites electron transferring from porphyrin to F-based ligand and enhances Li^(+)***,we anticipate that this work creates insight into the strategy for accelerating Li^(+)conduction in high-performance solid-state Li metal batteries through D–A system.

关键词： Electronic modulation engineering Donor-acceptor-linked covalent organic frameworks quasi-solid-state Li metal battery

Low-cost and fluoride-free synthesis of MFI zeolite nanosheets with enhanced stability for benzene alkylation with ethanol

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Journal of Energy Chemistry 2025年第1期100卷 458-468页

作者： Peng zhu Cun Liu Yiren Yu Guoshu Gao Yumeng Zhao Xiongfu Zhang Guodong Liu Guohui Yang State Key Laboratory of Fine Chemicals School of Chemical Engineering Dalian University of Technology State Key Laboratory of Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences

Zeolite nanosheets with a short b-axis thickness are highly desirable in lots of catalytic reactions due to their reduced diffusion resistance. Nevertheless, conventional synthesis methods usually require expensive structure-directing agents(SDAs), pricey raw materials, and eco-unfriendly fluorine-containing additives. here, we contributed a cost-effective and fluoride-free synthesis method for synthesizing high.q.ality MFI zeolite nanosheets through a Silicalite-1(Sil-1) seed suspension and urea cooperative strategy, only with inexpensive colloidal silica as the Si source. Our approach was effective for synthesizing both Sil-1 and aluminum-containing ZSM-5 nanosheets. By optimizing key synthesis parameters,including seed aging time, seed quantity, and urea concentration, we achieved precise control over the crystal face aspect ratio and b-axis thickness. We also revealed a non-classical oriented nanosheet growth mechanism, where Sil-1 seeds induced the formation of quasi-ordered precursor particles, and the(010)crystal planes of these particles facilitated urea adsorption, thereby promoting c-axis-oriented *** obtained ZSM-5 nanosheets exhibited exceptional catalytic performance in the benzene alkylation with ethanol, maintaining stability for over 500 h, which is 5 times longer than traditional ZSM-5 catalysts. Furthermore, large-scale production of ZSM-5 nanosheets was successfully carried out in a 3 L highpressure autoclave, yielding samples consistent with those from laboratory-scale synthesis. This work marks a significant step forward in the sustainable and efficient production of MFI nanosheets using inexpensive and environmentally friendly raw materials, offering the broad applicability in catalysis.

关键词： Aspect ratio

Comparing Ordinary Kriging and Regression Kriging for Soil Properties in Contrasting Landscapes

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Pedosphere 2010年第5期20卷 594-606页

作者： q.zhu h.S.LIN Department of Crop and Soil Sciences 116 ASI BuildingThe Pennsylvania State UniversityUniversity ParkPA 16802(USA)

The accuracy between ordinary kriging and regression kriging was compared based on the combined consideration of sample size,spatial structure,and auxiliary variables(terrain indices and electromagnetic induction surveys) for a variety of soil properties in two contrasting landscapes(agricultural ***).When spatial structure could not be well captured by point-based observations(e.g.,when the ratio of sample spacing over correlation range was > 0.5),or when a strong relationship existed between target soil properties and auxiliary variables(e.g.,their R2 was > 0.6),regression kriging(RK) was more accurate for interpolating soil properties in both landscapes ***,ordinary kriging(OK) was *** depth and wetness condition did not appear to affect the selection of kriging for soil moisture interpolation,because they did not significantly change the ratio of sample spacing over correlation range and the relationship with the auxiliary *** of a smaller ratio of elevation change over total study area(E/A = 1.2) and multiple parent materials in the agricultural land,OK was generally more accurate in that *** contrast,a larger E/A ratio of 6.8 and a single parent material led to RK being preferable in the steep-sloped forested *** results from this study can be useful for selecting kriging for various soil properties and landscapes.

关键词： geostatistics soil moisture spatial interpolation spatial structure

Effect of Silver Content on Microstructure and Properties of Brass/steel Induction Brazing Joint Using Ag-Cu-Zn-Sn Filler Metal

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Journal of Materials Science & Technology 2011年第4期27卷 377-381页

作者： J. Cao L.X. Zhang h.q. Wang L.Z. Wu J.C. Feng State KeyLab of AdvanCed Welding Production Technology Harbin Instituteof Technology Harbin 150001 China Center for Composite Materials and Structures Harbin Institute of Technology Harbin 150001 China

The induction brazing of brass to steel using Ag-Cu-Zn-Sn filler metal was investigated in this study. The influence of A8 content on the microstructure and properties were analyzed by means of optical microscopy, scanning electron microscopy and electron probe microanalysis. Defect free joint was achieved using Ag- Cu-Zn-Sn filler metal. The microstructure of the joint was mainly composed of Ag-based solid solution and Cu-based solid solution. The increase of A8 content and the cooling rate both led to the increase of the needle like eutectic structure. The tensile strength decreased with the increase of Ag content. The tensile strength at room temperature using Ag25CuZnSn filler metal reached 445 MPa. All fractures using Ag-Cu-Zn-Sn filler metal presented ductile characteristic.

关键词： Induction brazing Brass Steel Microstructure Tensile strength

Interference Suppression and Jitter Elimination Ability-Based Adaption Tracking Guidance for Robotic Fishes

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IEEE/CAA Journal of Automatica Sinica 2025年第1期 126-137页

作者： Dongfang Li Jie huang Rob Law Xin Xu Limin zhu Edmond q.Wu IEEE the School of Electrical Engineering and Automation Fuzhou University the Key Laboratory of System Control and Information Processing Ministry of Education the School of Electrical Engineering and Automation Fuzhou University 5G+Industrial Internet Institute Fuzhou University the University of Macau the College of Mechatronics and Automation National University of Defense Technology the School of Mechanical Engineering Shanghai Jiao Tong University the Department of Computer Science and Engineering Shanghai Jiao Tong University

This work presents an adaptive tracking guidance method for robotic fishes. The scheme enables robots to suppress external interference and eliminate motion jitter. An adaptive integral surge line-of-sight guidance rule is designed to eliminate dynamics interference and sideslip issues. Limited-time yaw and surge speed observers are reported to fit disturbance variables in the model. The approximation values can compensate for the system's control input and improve the robots' tracking ***, this work develops a terminal sliding mode controller and third-order differential processor to determine the rotational torque and reduce the robots' run jitter. Then, Lyapunov's theory proves the uniform ultimate boundedness of the proposed method. Simulation and physical experiments confirm that the technology improves the tracking error convergence speed and stability of robotic fishes.

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SUBCONVERGENCE OF FINITE ELEMENTS AND A SELF-ADAPTIVE ALGORIThM

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Journal of Computational Mathematics 1996年第4期14卷 336-344页

作者： zhu, qD Lin, q SOUThEAST UNIV DEPT MECH & MATHNANJINGPEOPLES R CHINA ChINESE ACAD SCI INST SYST SCIBEIJINGPEOPLES R CHINA

Mapping Sea Level Rise Behavior in an Estuarine Delta System：A Case Study along the Shanghai Coast

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Engineering 2018年第1期4卷 156-163页

作者： h.q. Cheng J.Y. Chen Z.J. Chen R.L. Ruan G.q. Xu G. Zeng J.R. zhu Z.J. Dai X.Y. Chen S.h. Gu X.L. Zhang h.M. Wang State Key Laboratory of Estuarine and Coastal Research East China Normal University Shanghai 200062 China Shanghai Water Planning Design and Research Institute Shanghai 200232 China Shanghai Water Authority Shanghai 200050 China School of Urban and Regional Science East China Normal University Shanghai 200062 China School of Ecological and Environmental Sciences East China Normal University Shanghai 200062 China Shanghai hydrological Station Shanghai 200232 China Shanghai Municipal Bureau of Urban Planning and Land Resources Shanghai 200003 China Shanghai Institute of Geological Survey Shanghai 200072 China

Sea level rise （SLR） is a major projected threat of climate change that is expected to affect developing coastal cities located in estuarine delta regions, Shanghai is one such city, being located in the Yangtze River Delta （YRD）, It is difficult, however, for decision-makers to implement adaptation due to the uncer- tain causes, magnitudes, and timings of SLR behaviors, This paper attempts to map the causes and mag- nitudes of SLR behaviors on a decadal scale, We analyze the tidal level records from 11 tidal gauge stations and the corresponding bathymetry measurements around these stations since 1921, We identify three new SLR behaviors along the Shanghai coast due to anthropogenic geomorphologic changes （AGCs）, besides the well-known eustatic sea level rise （ESLR）, tectonic subsidence （TS）, and urban land subsidence （ULS）, The first new behavior is regional sea level rise （RSLR）, which occurs as a result of land reclamation and deep waterway regulation, The second is regional sea level fall （RSLF）, which occurs because the channel bed is eroded due to sediment supply decline in the river catchment, The last SLR behavior is local tidal datum rise （LTDR）. Thus, we project that the magnitude of SLR for the Shanghai coast ranges from 10 cm to 16 cm from 2011 to 2030, Clarifying SLR behaviors is important to aid local decision- makers in planning structural and non-structural measures to combat escalating flood damage costs in an estuarine delta system; this field is full of future challenges,

关键词： Sea level rise behavior Anthropogenic geomorphologic change Local tidal datum Flood management Adaptation