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Silk-based nerve guidance conduits with macroscopic holes modulate the vascularization of regenerating rat sciatic nerve

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neural Regeneration Research 2025年第6期20卷 1789-1800页

作者： Carina hromada Patrick heimel Markus Kerbl lászlóGál Sylvia nürnberger Barbara Schaedl james Ferguson nicole Swiadek Xavier Monforte johannes C.heinzel Antal nógrádi Andreas h.Teuschl-Woller David hercher Department life Science Engineering University of Applied Sciences Technikum WienViennaAustria Austrian Cluster for Tissue Regeneration ViennaAustria ludwig Boltzmann Institute for Traumatology The Research Center in Cooperation with AUVAViennaAustria University Clinic of Dentistry Medical University of ViennaViennaAustria Department of Plastic Reconstructive and Aesthetic SurgeryLandesklinikum Wiener Neustadt2700 Wiener NeustadtAustria Department of Anatomy Histology and EmbryologyAlbert Szent-Györgyi Medical SchoolUniversity of SzegedSzegedHungary Medical University of Vienna Department of Orthopedics and Trauma SurgeryDevision of Trauma SurgeryViennaAustria Department of hand- PlasticReconstructive and Burn SurgeryBG Unfallklinik TuebingenUniversity of TuebingenTuebingenGermany

Peripheral nerve injuries induce a severe motor and sensory deficit. Since the availability of autologous nerve transplants for nerve repair is very limited, alternative treatment strategies are sought, including the use of tubular nerve guidance conduits(tnGCs). however, the use of tnGCs results in poor functional recovery and central necrosis of the regenerating tissue, which limits their application to short nerve lesion defects(typically shorter than 3 cm). Given the importance of vascularization in nerve regeneration, we hypothesized that enabling the growth of blood vessels from the surrounding tissue into the regenerating nerve within the tnGC would help eliminate necrotic processes and lead to improved regeneration. In this study, we reported the application of macroscopic holes into the tubular walls of silk-based tnGCs and compared the various features of these improved silk^(+) tnGCs with the tubes without holes(silk^(–) tnGCs) and autologous nerve transplants in an 8-mm sciatic nerve defect in rats. Using a combination of micro-computed tomography and histological analyses, we were able to prove that the use of silk^(+) tnGCs induced the growth of blood vessels from the adjacent tissue to the intraluminal neovascular formation. A significantly higher number of blood vessels in the silk^(+) group was found compared with autologous nerve transplants and silk^(–), accompanied by improved axon regeneration at the distal coaptation point compared with the silk^(–) tnGCs at 7 weeks postoperatively. In the 15-mm(critical size) sciatic nerve defect model, we again observed a distinct ingrowth of blood vessels through the tubular walls of silk^(+) tnGCs, but without improved functional recovery at 12 weeks postoperatively. Our data proves that macroporous tnGCs increase the vascular supply of regenerating nerves and facilitate improved axonal regeneration in a short-defect model but not in a critical-size defect model. This study suggests that further optimizatio

关键词： axon regeneration blood vessel functional recovery macroporous nerve lesion peripheral nerve repair sciatic nerve silk-based nerve guidance conduit vascularization

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nUMERICAl SIMUlATIOn STUDY On DEFORMATIOn UnIFORMITY OF EQUAl CROSS SECTIOn lATERAl EXTRUSIOn

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Acta Metallurgica Sinica(English letters) 2004年第1期17卷 61-63页

作者： Z.l.Chang j.l.Song n.h.hao Department of Materials Engineering Taiyuan Heavy Machinery Institute Taiyuan 030024 ChinaDepartment of Materials Engineering Taiyuan Heavy Machinery Institute Taiyuan 030024 ChinaDepartment of Materials Engineering Taiyuan Heavy Machinery Institute Taiyuan 030024 China

Equal cross section lateral extrusion (ECSlE) is an effective method realizing pure shear deformation. The influence of friction factor on the deformation uniformity of ECSlE was investigated with rigid plastic finite element method. The result shows that the non-uniform deformation in extrusion is caused mainly by the friction between workpiece and die. The higher the friction factor is, the more uneven plastic deformation resulted in extruded workpiece. The relation curve of deformation uniformity vs. friction factor was drawn based on the analysis result. The curve can be used as a basis of ECSlE process design.

关键词： equal cross section lateral extrusion strain finite element method

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Synthesis and Crystal Structure of (CO) 5ReSnMe 2Re(CO) 5

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Chinese journal of Structural Chemistry 1999年第2期18卷 39-43页

作者： li, j liu, h Song, XQ Kai, l Yin, n nankai Univ State Key Lab Elementoorgan Chem Tianjin 300071 Peoples R China nankai Univ Inst Elementoorgan Chem Tianjin 300071 Peoples R China

The crystal structure of the title complex (CO) 5ReSnMe 2Re(CO) 5, (C 12 h 6O 10 Re 2Sn, M r =801.27), has been determined by single crystal X ray diffraction. The crystal is monoclinic with space group P2 1/n (nO.14), a=10.587(2), b=12.392(2), c = 14.594(3) , β = 100.59(3)°, V = 1882(1) 3, D x = 2.828 g·cm -3 , F(000)=1432, μ =14.3759mm -1 , Z =4, and final R =0 0440 and R w =0 0483 for 1954 reflections ( I≥3σ(I )). In the complex the Sn atom is connected to two methyl groups and two Re atoms which are in slightly distorted tetrahedral arrangement. The Re atom is coordinated by five carbonyl ligands and one Sn atom, forming an octahedral structure.

关键词： metal carbonyl cluster Re complex synthesis crystal structure

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Atomic-scale roles of Zn element in age-hardened AlMgSiZn alloys

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journal of Materials Science & Technology 2021年第11期70卷 105-112页

作者： n.n.jiao Y.X.lai S.l.Chen P.Gao j.h.Chen Center for high-Resolution Electron Microscopy College of Materials Science&EngineeringHunan UniversityChangsha410082China Electron Microscopy laboratory and International Center for Quantum Materials School of PhysicsPeking UniversityBeijing100871China

Adding alloying elements to improve the performances or the manufacturing processes of Al-Mg-Si alloys has long been a serious issue in developing advanced automotive aluminum *** Zn element,among those promising ones,has demonstrated positive alloying effects on Al-Mg-Si ***,the atomic-scale roles of Zn in an age-hardened Al-Mg-Si-Zn alloy have not been adequately *** atomic-resolution electron microscopy,here we report the precise locations of Zn elements in all hardening precipitates involved and their alloying mechanism at the atomic scale when alloying the *** results show that Zn atoms enter all the major hardening phases to occupy specific featured atomic sites of the original elements,*** Si1 and Mg2 sites in theβ’-2 phase,and modify their crystal structures,interfacial structures and morphologies in characteristic *** is revealed that for theβ’-phase,Zn atoms occupy unique atomic sites,whereas for other phases,they demonstrate similar behaviors as other additive alloying elements such as Ag and Cu do.

关键词： Al-Mg-Si alloy Zn addition Precipitate Electron microscopy

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Unexpected creep behavior in a rejuvenated metallic glass

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journal of Materials Science & Technology 2023年第32期163卷 140-149页

作者： j.P.Wu Y.lin F.h.Duan Q.Chen h.T.Wang n.li j.l.Wen j.Pan l.liu Shenyang national laboratory for Materials Science Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China School of Materials Science and Engineering University of Science and Technology of ChinaHefei 230026China State Key laboratory of Material Processing and Die&Mould Technology and School of Materials Science and Engineering Huazhong University of Science and TechnologyWuhan 430074China laboratory of nanomaterials&nanomechanics Department of Mechanical EngineeringCity University of Hong KongHong KongChina Wuhan national high Magnetic Field Center Huazhong University of Science and TechnologyWuhan 430074China Shenzhen Polytechnic Shenzhen 518055China

Rejuvenation,bringing metallic glasses(MGs)to the younger and higher energy states,provides an alternative avenue to explore the interplay between the property and microstructures of *** this study,the creep behavior of the Zr_(69.5)Cu_(12)ni_(11)Al_(7.5)MGs was experimentally examined by controlling the energy state in terms of structural rejuvenation and thermal *** is found that compared to the as-cast counterpart,the annealed MG at a lower energy state exhibits a higher hardness,a smaller displacement,and a lower creep rate due to the decreased free volume and the inhibited activation of the shear transformation ***,the rejuvenated MG at a high energy state displays lower hardness and increased free volume content,yet it demonstrates superior creep resistance compared to its as-cast counterpart,which deviates from conventional *** unexpected phenomenon occurs as the initial high-content free volume annihilates during creep,and strain hardening takes precedence over strain softening as the prevailing process during creep deformation,leading to a superior creep performance in extremely rejuvenated MGs.

关键词： Metallic glass Energy state Rejuvenation Creep Strain-hardening

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nonlinear stability of advanced sandwich cylindrical shells comprising porous functionally graded material and carbon nanotube reinforced composite layers under elevated temperature

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Applied Mathematics and Mechanics(English Edition) 2021年第9期42卷 1327-1348页

作者： h.V.TUnG l.T.n.TRAnG Faculty of Civil Engineering Hanoi Architectural UniversityHa Noi 10000Viet Nam Faculty of Civil Engineering University of Transport TechnologyHa Noi 10000Viet Nam

The nonlinear stability of sandwich cylindrical shells comprising porous functionally graded material(FGM) and carbon nanotube reinforced composite(CnTRC)layers subjected to uniform temperature rise is investigated. Two sandwich models corresponding to CnTRC and FGM face sheets are proposed. Carbon nanotubes(CnTs) in the CnTRC layer are embedded into a matrix according to functionally graded distributions. The effects of porosity in the FGM and the temperature dependence of properties of all constituent materials are considered. The effective properties of the porous FGM and CnTRC are determined by using the modified and extended versions of a linear mixture rule, respectively. The basic equations governing the stability problem of thin sandwich cylindrical shells are established within the framework of the Donnell shell theory including the von K’arm’an-Donnell nonlinearity. These equations are solved by using the multi-term analytical solutions and the Galerkin method for simply supported *** critical buckling temperatures and postbuckling paths are determined through an iteration procedure. The study reveals that the sandwich shell model with a CnTRC core layer and relatively thin porous FGM face sheets can have the best capacity of thermal load carrying. In addition, unlike the cases of mechanical loads, porosities have beneficial effects on the nonlinear stability of sandwich shells under the thermal load. It is suggested that an appropriate combination of advantages of FGM and CnTRC can result in optimal efficiency for advanced sandwich structures.

关键词： carbon nanotube reinforced composite(CnTRC) porous functionally graded material(FGM) thermal instability cylindrical shell advanced sandwich model

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Effects of Shannon entropy and electric field on polaron in RbCl triangular quantum dot

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Chinese Physics B 2016年第4期25卷 432-435页

作者： M Tiotsop A j Fotue S C Kenfack n Issofa h Fotsin l C Fai Mesoscopic and Multilayers Structures laboratory Department of Physics Faculty of Science University of Dschang laboratory of Electronics and Signal Processing Department of Physics Faculty of Science University of Dschang

In this paper, the time evolution of the quantum mechanical state of a polaron is examined using the Pekar type variational method on the condition of the electric-lO-phonon strong-coupling and polar angle in RbC1 triangular quantum dot. We obtain the eigenenergies, and the eigenfunctions of the ground state, and the first excited state respectively. This system in a quantum dot can be treated as a two-level quantum system qubit and the numerical calculations are performed. The effects of Shannon entropy and electric field on the polaron in the RbC1 triangular quantum dot are also studied.

关键词： Shannon entropy polaron electric field triangular quantum dot

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Effect of cold-working on corrosion induced damage in lug joints

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Defence Technology（防务技术） 2024年第6期36卷 175-182页

作者： Ramanath M.n Chikmath l. Murthy h. Department of Aerospace Engineering Indian Institute of Technology-MadrasChennai 600036India Department of Aeronautical Engineering KLS Gogte Institute of TechnologyBelagavi 590008India

lug joints are preferred joineries for transferring heavy loads to parent components in aerospace *** experience corrosion due to environmental conditions,improper surface finishes and rubbing displacement between the pin and *** causes damage of different sizes and shapes near the *** degradation due to corrosion-induced damage is modelled as a through-pit at one of the identified critical locations through stress *** effect of this pit on fatigue crack initiation life is ***-hole is pre-stressed by cold-working and the benefits of inducing plastic wake on the intended performance of the lug joint during the damages due to corrosion are brought out and compared with non-cold-worked *** analysis is performed on this lug joint with *** results obtained highlight the benefits of cold-working and the methodology can be extended to damage growth and analyse the effect of surface treatments for better structural integrity of components of aerospace vehicles.

关键词： lug joint Corrosion Crack initiation Cold-working Structural integrity

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Decorating crystalline YFe_(2-x)Al_(x) on the Mg_(60)la_(10)ni_(20)Cu_(10) amorphous alloy as “hydrogen pump” to realize fast de/hydrogenation

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journal of Materials Science & Technology 2024年第6期173卷 72-79页

作者： l.j.huang h.Wang l.Z.Ouyang M.Zhu h.j.l.n School of Materials Science and Engineering Key Laboratory of Advanced Energy Storage Materials of Guangdong ProvinceSouth China University of TechnologyGuangzhou 510641China Institute of Advanced Wear&Corrosion Resistance and Functional Materials Jinan UniversityGuangzhou 510632China

Mg-based amorphous alloys are one of the potential hydrogen storage materials but suffer from sluggish dehydrogenation/hydrogenation(de/hydrogenation)*** this work,as a new strategy,a hydrogen pump is built on the surface of amorphous alloys to solve this *** milling crystalline YFe_(2-x)Al_(x) hydrogen storage alloy with Mg_(60)la_(10)ni_(20)Cu_(10) amorphous alloy,fine crystalline particles were seeded on amorphous alloy powder to form a“strawberry”*** to the TEM observation,a metallurgical bonding boundary formed between the Mg-based amorphous matrix and the Y-Fe-Al crystalline *** microstructure and de/hydrogenation kinetics investigation,the“hydrogen pump”effect of the seeded crystalline alloy was confirmed,which makes it much easier for the hydrogen to dissociate on and diffuse through the surface of the Mg-based amorphous *** such effect,the h absorption rate of Mg_(60)la_(10)ni_(20)Cu_(10) amorphous alloy became almost eight times faster and it absorbs ~2.8 wt.% in 1 h at 130℃ under 4.5 MPa-h_(2).Further,fast hydrogenation can even achieve at 70℃ and the low-temperature dehydrogenation kinetics of the amorphous hydride can be also greatly *** present work proves that surface modification is of great importance for obtaining Mg-based amorphous alloy with ideal hydrogen storage performance.

关键词： hydrogen storage Mg-based amorphous alloy hydrogen pump Composite structure

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A comparison study of Ce/la and Ca microalloying on the bio-corrosion behaviors of extruded Mg-Zn alloys

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journal of Magnesium and Alloys 2020年第4期8卷 1269-1280页

作者： j.h.Chu l.B.Tong Z.h.jiang D.n.Zou Q.j.Wang S.F.liu h.j.Zhang School of Metallurgical Engineering Xi'an University of Architecture and TechnologyXi'an 710055China State Key laboratory of Rare Earth Resources Utilization Changchun Institute of Applied ChemistryChinese Academy of SciencesChangchun 130022China Key lab of Automobile Materials College of Materials Science and EngineeringJilin UniversityNanling CampusChangchun 130025China

The influences of Ca and Ce/la microalloying on the microstructure evolution and bio-corrosion resistances of extruded Mg-Zn alloys have been systematically investigated in the current *** with single Ca or Ce/la addition,the Ca-Ce/la cooperative microalloying results in an outstanding grain refinement,because the fine secondary phase particles effectively hinder the recrystallized grain *** coarse Ca2Mg6Zn3 phases promote the formation of Ca3(PO4)2 or hydroxyapatite particles during the immersion process and accelerate the dissolution of the corrosion product film,which destroys its integrity and results in the deterioration of anti-corrosive *** Ce/la elements can be dispersed within the conventional Mg7Zn3 phases,which reduce the internal galvanic corrosion between Mg matrix and the secondary phases,leading to an obvious improvement of corrosion ***,the Ca-Ce/la cooperative microalloying achieves a homogenous fine-grained microstructure and improves the protective ability of surface film,which will pave a new avenue for the design of biomedical Mg alloys in the coming future.

关键词： Extruded Mg-Zn alloy Ca and Ce/la microalloying Microstructure evolution Bio-corrosion behaviors

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