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heterostructured nickel-cobalt metal alloy and metal oxide nanoparticles as a polysulfide mediator for stable lithium-sulfur full batteries with lean electrolyte

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Carbon Energy 2024年第7期6卷 163-177页

作者： hyeona Park Suyeong Lee hyerim kim hyunyoung Park hun kim Jongsoon kim Marco Agostini Yang-Kook Sun Jang-Yeon hwang department of Energy Engineering Hanyang UniversitySeoulRepublic of Korea LG Energy Solution LtdCTOLG Science ParkSeoulRepublic of Korea department of Energy Science Sungkyunkwan UniversitySuwonRepublic of Korea SKKU Institute of Energy Science and Technology(SIEST) Sungkyunkwan UniversitySuwonRepublic of Korea dipartimento di Chimica e Tecnologia del Farmaco Universitàdi Roma La SapienzaRomaItaly department of Battery Engineering Hanyang UniversitySeoulRepublic of Korea

Batteries that utilize low-cost elemental sulfur and light metallic lithium as electrodes have great potential in achieving high energy ***,building a lithium-sulfur(Li-S)full battery by controlling the electrolyte volume generally produces low practical energy because of the limited electrochemical Li-S ***,the high energy/high performance of a Li-S full battery with practical sulfur loading and minimum electrolyte volume is reported.A unique hybrid architecture configured with Ni-Co metal alloy(NiCo)and metal oxide(NiCoO_(2))nanoparticles heterogeneously anchored in carbon nanotube-embedded selfstanding carbon matrix is fabricated as a host for *** work demonstrates the considerable improvement that the hybrid structure's high conductivity and satisfactory porosity promote the transport of electrons and lithium ions in Li-S *** experimental and theoretical validations,the function of NiCo and NiCoO_(2) nanoparticles as an efficient polysulfide mediator is *** particles afford polysulfide anchoring and catalytic sites for Li-S redox reaction,thus improving the redox conversion *** at high sulfur loading,the nanostructured Ni-Co metal alloy and metal oxide enable to have stable cycling performance under lean electrolyte conditions both in half-cell and full-cell batteries using a graphite anode.

关键词： full cell high energy lean electrolyte Li-S batteries polysulfide mediator

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Analysis of the Oscillatory Flows of Multiple Shock Waves in a Constant Area duct

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Journal of Thermal Science 2024年第3期33卷 794-806页

作者： K JAMES Jintu kim heuy dong department of Mechanical Engineering Andong National UniversityAndong36729Republic of Korea CAd-IT Korea Co. Ltd.Seoul08591Republic of Korea

The oscillatory response of multiple shock waves to downstream perturbations in a supersonic flow is studied numerically in a rectangular *** shock waves are formed inside the duct at a shock Mach number of *** duct has an exit height of h,and the effect of duct resonance on multiple shock oscillations is investigated by attaching exit ducts of lengths 0h,50h,and *** downstream disturbance frequency varied from 10 hz to 200 hz to explore the oscillation characteristics of the multiple shock *** oscillatory response of shock waves under self-excited and forced oscillation conditions are analyzed in terms of wall static pressure,shock train leading-edge location,shock train length,and the size of the separation *** extent of the initial shock location increases with an increase in exit duct length for the self-excited oscillation *** analysis of the shock train leading edge and the spectral analysis of wall static pressure variations are *** variation in the shock train length is analyzed using the pressure ratio method for self-excited as well as forced *** RMS amplitude of the normalized shock train length(ζ_(ST))increases with an increase in the exit duct length for the self-excited oscillation *** the downstream perturbation frequency is increased,ζ_(ST)is decreased for exit duct *** all exit duct designs and downstream forcing frequencies,the size of the separation bubble grows and shrinks during the shock oscillations,demonstrating the dependence on duct resonance and forced oscillations.

关键词： shock train downstream disturbance supersonic flow shock wave boundary layer interaction duct resonance flow separation

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Malware detection Using dual Siamese Network Model

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Computer Modeling in Engineering & Sciences 2024年第10期141卷 563-584页

作者： ByeongYeol An Jeahyuk Yang Seoyeon kim Taeguen kim department of Software Convergence Soonchunhyang UniversityAsan31538Republic of Korea department of Mobility Convergence Security Soonchunhyang UniversityAsan31538Republic of Korea department of Information Security Engineering Soonchunhyang UniversityAsan31538Republic of Korea

This paper proposes a new approach to counter cyberattacks using the increasingly diverse malware in cyber *** signature detection methods that utilize static and dynamic features face limitations due to the continuous evolution and diversity of new ***,machine learning-based malware detection techniques,such as Convolutional Neural Networks(CNN)and Recurrent Neural Networks(RNN),have gained *** these methods demonstrate high performance by leveraging static and dynamic features,they are limited in detecting new malware or variants because they learn based on the characteristics of existing *** overcome these limitations,malware detection techniques employing One-Shot Learning and Few-Shot Learning have been *** on this,the Siamese Network,which can effectively learn from a small number of samples and perform predictions based on similarity rather than learning the characteristics of the input data,enables the detection of new malware or *** propose a dual Siamese network-based detection framework that utilizes byte images converted frommalware binary data to grayscale,and opcode frequency-based images generated after extracting opcodes and converting them into *** proposed framework integrates two independent Siamese network models,one learning from byte images and the other from opcode frequency-based *** detection models trained on the different kinds of images generated separately apply the L1 distancemeasure to the output vectors themodels generate,calculate the similarity,and then apply different weights to each *** proposed framework achieved a malware detection accuracy of 95.9%and 99.83%in the experimentsusingdifferentmalware *** experimental resultsdemonstrate that ourmalware detection model can effectively detect malware by utilizing two different types of features and employing the dual Siamese network-based model.

关键词： Siamese network malware detection few-shot learning

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Flexible thermocouple using a thermoelectric graphene fiber with a seamless junction

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Journal of Materials Science & Technology 2024年第5期172卷 15-22页

作者： Seungwon kim Soomook Lim Myeong hee Jeong Wonjoon kim Seunghyun Baik Ji Won Suk School of Mechanical Engineering Sungkyunkwan UniversitySuwonGyeonggi-do 16419Republic of Korea department of Smart Fab.Technology Sungkyunkwan UniversitySuwonGyeonggi-do 16419Republic of Korea SKKU Advanced Institute of Nanotechnology(SAINT) Sungkyunkwan UniversitySuwonGyeonggi-do 16419Republic of Korea

Temperature is an important physical variable that indicates the condition of the human body and artificial *** wearable applications require the development of temperature sensors with different form *** this study,a fiber-shaped thermoelectric temperature sensor is fabricated using a continuous graphene fiber whose two halves possess different reduction states.A seamless junction is formed by partially reducing a wet-spun graphene oxide fiber with hydroiodic acid(hI)solutions of different ***-half of the fiber is mildly reduced with 0.97 wt%hI,while the other half is highly reduced with 30.6 wt%*** different reduction states of the graphene composite fiber result in different Seebeck coefficients,allowing for the fabrication of a fiber-shaped graphene thermocou-ple without any laborious *** flexible graphene thermocouple exhibits high sensitivity with a thermopower of 12.5μV K^(-1)in the temperature range of room temperature to∼70℃.Furthermore,it exhibits high linearity with a correlation coefficient exceeding 0.995 and fast response with a time constant of 0.24 *** to its mechanical robustness and flexibility,the stand-alone graphene ther-mocouple can be knitted into a cotton fabric glove,which presents a fast response to environmental changes without any external power *** work offers a unique fabrication method for producing a high-performance,flexible thermocouple that features a seamless and clear junction without the use of additional *** alternative method eliminates the complicated assembly processes typically required for conventional thermocouples.

关键词： Graphene fiber Thermocouple Reduced graphene oxide Flexible temperature sensor Seebeck coefficient

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Liquid crystal-integrated metasurfaces for an active photonic platform

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Opto-Electronic Advances 2024年第6期7卷 5-29页

作者： dohyun Kang hyeonsu heo Younghwan Yang Junhwa Seong hongyoon kim Joohoon kim Junsuk Rho department of Mechanical Engineering Pohang University of Science and Technology(POSTECH)Pohang 37673Republic of Korea department of Chemical Engineering Pohang University of Science and Technology(POSTECH)Pohang 37673Republic of Korea department of Electrical Engineering Pohang University of Science and Technology(POSTECH)Pohang 36763Republic of Korea POSCOPOSTECh-RIST Convergence Research Center for Flat Optics and Metaphotonics Pohang 37673Republic of Korea National Institute of Nanomaterials Technology(NINT) Pohang 37673Republic of Korea

Metasurfaces have opened the door to next-generation optical devices due to their ability to dramatically modulate electromagnetic waves at will using periodically arranged ***,metasurfaces typically have static optical responses with fixed geometries of nanostructures,which poses challenges for implementing transition to technology by replacing conventional optical *** solve this problem,liquid crystals(LCs)have been actively employed for designing tunable metasurfaces using their adjustable birefringent in real ***,we review recent studies on LCpowered tunable metasurfaces,which are categorized as wavefront tuning and spectral *** to numerous reviews on tunable metasurfaces,this review intensively explores recent development of LC-integrated *** the end of this review,we briefly introduce the latest research trends on LC-powered metasurfaces and suggest further directions for improving *** hope that this review will accelerate the development of new and innovative LC-powered devices.

关键词： tunable metasurface liquid crystal active metasurface electrically tunable optical system

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Boosting the catalytic activity toward oxygen reduction via a heterostructure of porous iron oxide-decorated 2d NiO/NG nanosheets

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Journal of Energy Chemistry 2024年第6期93卷 669-681,I0016页

作者： Kakali Maiti Matthew T.Curnan hyung Jun kim Kyeounghak kim Jeong Woo han department of Chemical Engineering Pohang University of Science and Technology(POSTECH)PohangGyeongbuk 37673Republic of Korea department of Materials Science and Engineering Research Institute of Advanced MaterialsSeoul National UniversitySeoul 08826Republic of Korea department of Chemical Engineering Clean-Energy Research InstituteHanyang UniversitySeoul 04763Republic of Korea CSIR-Institute of Minerals and Materials Technology RRL CampusAcharya ViharBhubaneswarOdisha 751013India

As a noble metal substitute,two-dimensional(2d)hierarchical nano-frame structures have attracted great interest as candidate catalysts due to their remarkable advantages-high intrinsic activity,high electron mobility,and straightforward surface ***,they may replace Pt-based catalysts in oxygen reduction reaction(ORR)***,a simple method is developed to design hierarchical nano-frame structures assembled via 2d NiO and N-doped graphene(NG)*** procedure can yield nanostructures that satisfy the criteria correlated with improved electrocatalytic performance,such as large surface area,numerous undercoordinated atoms,and high defect ***,porous NG nanosheet architectures,featuring NiO nanosheets densely coordinated with accessible holey Fe_(2)O_(3) moieties,can enhance mesoporosity and balance *** improvements can facilitate charge transport and expose formerly inaccessible reaction sites,maximizing active site density *** functional theory(dFT)calculations reveal favored O_(2) adsorption and dissociation on Fe_(2)O_(3) hybrid structures when supported by 2d NiO and NG nanomaterials,given 2d materials donated charge to Fe_(2)O_(3) active *** systematic studies reveal that synergistic contributions are responsible for enriching the catalytic activity of Fe_(2)O_(3)@NiO/NG in alkaline media-encompassing internal voids and pores,unique hierarchical support structures,and concentrated N-dopant and bimetallic atomic ***,this work expands the toolbox for designing and synthesizing highly efficient 2d/2d shelled functional nanomaterials with transition metals,endeavoring to benefit energy conversion and related ORR applications.

关键词： N-doped graphene holey Fe_(2)O_(3)nanocrystals NiO nanosheets high catalytic performance ORR

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hydrangea serrata extract exerts tumor inhibitory activity against hepatocellular carcinoma hepG2 cells via inducing p27/CdK2-mediated cell cycle arrest and apoptosis

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Asian Pacific Journal of Tropical Biomedicine 2024年第2期14卷 65-72,I0002-I0005页

作者： Ye-eun kim Jeonghye hwang Ki-Young kim Graduate School of Biotechnology Kyung Hee UniversitySeocheonGiheungYonginGyeonggi-do 446-701Republic of Korea department of Genetics and Biotechnology College of Life SciencesKyung Hee UniversitySeocheonGiheungYonginGyeonggi-do 446-701Republic of Korea

Objective:To examine the inhibitory effect of hydrangea serrata extract against hepatocellular carcinoma hepG2 cells and its underlying ***:The effects of hydrangea serrata extract on growth inhibition of tumor cells and spheroids were assessed using MTT and 3d culture *** real-time PCR and Western blot analyses were employed to investigate the changes in mRNA and protein expression levels of molecules related to cell cycle and ***:hydrangea serrata extract effectively inhibited the growth of both tumor cells and *** extract also significantly upregulated p27 mRNA expression and downregulated CdK2 mRNA expression,leading to cell cycle ***,increased BAX/Bcl-2 ratio as well as caspase-9 and-3 were observed after treatment with hydrangea serrata extract,indicating the induction of tumor cell ***:hydrangea serrata extract has the potential to alleviate tumors by effectively modulating cell-cycle-related gene expressions and inducing apoptosis,thereby inhibiting tumor growth.

关键词： hydrangea serrata hepatocellular carcinoma Liver cancer Anticancer Cell cycle arrest Apoptosis

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Factors affecting length of stay according to bronchopulmonary dysplasia severity:a nationwide cohort study in Korea

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World Journal of Pediatrics 2024年第5期20卷 470-480页

作者： hye Mi Lee Jeongmin Shin Sae Yun kim So Young kim department of Pediatrics College of MedicineThe Catholic University of KoreaSeoulRepublic of Korea department of Pediatrics Yeouido St.Mary’s HospitalCollege of MedicineThe Catholic University of Korea1063-roYeongdeungpo-guSeoul07345Republic of Korea

Background Longer hospitalizations for preterm infants with bronchopulmonary dysplasia(BPd)delay developmental outcomes,increase the risk for hospital-acquired complications,and exert a substantial socioeconomic *** study aimed to identify factors associated with an extended length of stay(LOS)at different levels of severity of *** A cohort study was conducted using the Korean Neonatal Network registry of very low birth weight infants with BPd between 2013 and 2017 through retrospective *** A total of 4263 infants were diagnosed with *** mild BPd,infants requiring surgical treatment for patent ductus arteriosus needed a longer LOS[eadjustedβcoefficients(adjβ)1.041;95%confidence interval(CI):0.01–0.08]and hydrocephalus(eadjβ1.094;95%CI 0.01–0.17).In moderate BPd,infants administered steroids or with intraventricular hemorrhage required a longer LOS(eadjβ1.041;95%CI 0.00–0.07 and eadjβ1.271;95%CI 0.11–0.38,respectively).In severe BPd,infants with comorbidities required a longer LOS:pulmonary hypertension(eadjβ1.174;95%CI 0.09–0.23),administrated steroid for BPd(eadjβ1.116;95%CI 0.07–0.14),sepsis(eadjβ1.062;95%CI 0.01–0.11),patent ductus arteriosus requiring surgical ligation(eadjβ1.041;95%CI 0.00–0.08),and intraventricular hemorrhage(eadjβ1.016;95%CI 0.05–0.26).Additionally,the higher the clinical risk index score,the longer the LOS needed for infants in all *** The factors affecting LOS differed according to the severity of *** approaches to reducing LOS may be devised using knowledge of the various risk factors affecting LOS by BPd severity.

关键词： Bronchopulmonary dysplasia Length of stay Very low birth weight

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Restoration of the JPEG Maximum Lossy Compressed Face Images with hourglass Block-GAN

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Computers, Materials & Continua 2024年第3期78卷 2893-2908页

作者： Jongwook Si Sungyoung kim department of Computer AI Convergence Engineering Kumoh National Institute of TechnologyGumi39177Korea department of Computer Engineering Kumoh National Institute of TechnologyGumi39177Korea

In the context of high compression rates applied to Joint Photographic Experts Group(JPEG)images through lossy compression techniques,image-blocking artifacts may *** necessitates the restoration of the image to its original *** challenge lies in regenerating significantly compressed images into a state in which these become ***,this study focuses on the restoration of JPEG images subjected to substantial degradation caused by maximum lossy compression using Generative Adversarial Networks(GAN).The generator in this network is based on theU-Net *** features a newhourglass structure that preserves the characteristics of the deep *** addition,the network incorporates two loss functions to generate natural and high-quality images:Low Frequency(LF)loss and high Frequency(hF)*** loss uses a pretrained VGG-16 network and is configured using a specific layer that best represents *** can enhance the performance in the high-frequency *** contrast,LF loss is used to handle the low-frequency *** two loss functions facilitate the generation of images by the generator,which can mislead the discriminator while accurately generating high-and low-frequency ***,by removing the blocking effects frommaximum lossy compressed images,images inwhich identities could be recognized are *** study represents a significant improvement over previous research in terms of the image resolution performance.

关键词： JPEG lossy compression restoration image generation GAN

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Efficient Route Planning for Real-Time demand-Responsive Transit

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Computers, Materials & Continua 2024年第4期79卷 473-492页

作者： hongle Li SeongKi kim development department Changseol Build SystemDaegu42601South Korea division of Software Convergence Sangmyung UniversitySeoul03016South Korea

demand Responsive Transit (dRT) responds to the dynamic users’ requests without any fixed routes and timetablesand determines the stop and the start according to the demands. This study explores the optimization of dynamicvehicle scheduling and real-time route planning in urban public transportation systems, with a focus on busservices. It addresses the limitations of current shared mobility routing algorithms, which are primarily designedfor simpler, single origin/destination scenarios, and do not meet the complex demands of bus transit systems. Theresearch introduces an route planning algorithm designed to dynamically accommodate passenger travel needsand enable real-time route modifications. Unlike traditional methods, this algorithm leverages a queue-based,multi-objective heuristic A∗ approach, offering a solution to the inflexibility and limited coverage of suburbanbus routes. Also, this study conducts a comparative analysis of the proposed algorithm with solutions based onGenetic Algorithm (GA) and Ant Colony Optimization Algorithm (ACO), focusing on calculation time, routelength, passenger waiting time, boarding time, and detour rate. The findings demonstrate that the proposedalgorithmsignificantly enhances route planning speed, achieving an 80–100-fold increase in efficiency over existingmodels, thereby supporting the real-time demands of demand-Responsive Transportation (dRT) systems. Thestudy concludes that this algorithm not only optimizes route planning in bus transit but also presents a scalablesolution for improving urban mobility.

关键词： Autonomous bus route planning real-time dynamic route planning path finding dRT bus route optimization sustainable public transport

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