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Nano Research 2024年第6期17卷 4961-4970页

作者： Yongpan Gu Yike Li haoqiang feng Yanan han Zhongjun Li College of Chemistry Zhengzhou UniversityZhengzhou 450001China

S-scheme possesses superior redox capabilities compared with the II-scheme,providing an effective method to solve the innate defects of g-C_(3)N_(4)(CN).In this study,S-doped g-C_(3)N_(4)/g-C_(3)N_(4)(SCN-tm/CN)S-scheme homojunction was constructed by rationally integrating morphology control with interfacial engineering to enhance the photocatalytic hydrogen evolution ***-situ Kelvin probe force microscopy(KPFM)confirms the transport of photo-generated electrons from CN to *** functional theory(DFT)calculations reveal that the generation of a built-in electric field between SCN and CN enables the carrier separation to be more efficient and *** transient absorption spectrum(fs-TAS)indicates prolonged lifetimes of SCN-tm/CN_(3)(τ1:9.7,τ2:110,andτ3:1343.5 ps)in comparison to those of CN(τ1:4.86,τ2:55.2,andτ3:927 ps),signifying that the construction of homojunction promotes the separation and transport of electron hole pairs,thus favoring the photocatalytic *** visible light irradiation,the optimized SCN-tm/CN_(3)exhibits excellent photocatalytic activity with the hydrogen evolution rate of 5407.3μmol·g^(−1)·h^(−1),which is 20.4 times higher than that of CN(265.7μmol·g^(−1)·h^(−1)).Moreover,the homojunction also displays an apparent quantum efficiency of 26.8%at 435 nm as well as ultra-long and ultra-stable cycle *** work offers a new strategy to construct highly efficient photocatalysts based on the metal-free conjugated polymeric CN for realizing solar energy conversion.

关键词： homojunction built-in electric field morphology control interfacial engineering carrier separation

Modifying effects and mechanisms of superfine stainless wires on microstructures and mechanical properties of ultra-high performance seawater sea-sand concrete

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Science China Technological Sciences 2024年第10期67卷 3205-3220页

作者： YU feng DONG SuFen AShOUR Ashraf DING SiQi hAN BaoGuo School of Infrastructure Engineering Dalian University of Technology Faculty of Engineering & Informatics University of Bradford Department of Civil and Environmental Engineering The Hong Kong Polytechnic University

Ultra-high-performance seawater sea-sand concrete（UhPSSC） presents a prospective solution to address the natural resource shortage in marine infrastructure construction. To eliminate the corrosion risk of steel fibers and broaden the applicability of UhPSSC, this study investigates the mechanical properties and free chloride ion content as well as microstructures of UhPSSC reinforced with superfine stainless wires（SSWs） under natural curing. The results indicate that 1.5% SSWs can remarkably improve the flexural strength and toughness of UhPSSC by 127% and 1724%, respectively, and mitigate the long-term strength degradation of UhPSSC. The strong interfacial bond between SSW and UhPSSC improves the compactness of UhPSSC, thus reducing the growth space for Ca（Oh）2crystals and swelling hydration products generated by sulfate and magnesium ions. This can be supported by the observed reduction in the Ca/Si ratio of C–S–h gels, Ch crystal orientation index, and ***, through mechanisms such as pull-out, rupture, overlapping network, and internal anchor interface, SSWs effectively prevent microcrack growth and propagation, transforming single long-connected microcracks into multiple-emission microcracks centered on SSW. Additionally, the free chloride ion content of the composites at 28 and 180 d meets the ACI 318-19 standard requirements for concrete exposed to seawater. This compliance is attributed to the chloride immobilization facilitated by Friedel's salt and C–S–h gels within the interfaces around SSWs and sea-sand. Consequently, SSWs-reinforced UhPSSC exhibits considerable potential for applications in sustainable marine infrastructures, demanding long-term mechanical properties and high durability.

关键词： ultra-high performance seawater sea-sand concrete superfine stainless wire mechanical properties chloride ion content microstructure

Atomistic Investigation of Shock-Induced Amorphization within Micro-shear Bands in hexagonal Close-Packed Titanium

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Acta Metallurgica Sinica(English Letters) 2024年第9期37卷 1590-1600页

作者： Z.C.Meng K.G.Wang T.Ali D.Li C.G.Bai D.S.xu S.J.Li A.h.feng G.J.Cao J.h.Yao Q.B.Fan h.Wang R.Yang Institute of Metal Research Chinese Academy of SciencesShenyang 110016China School of Materials Science and Engineering University of Science and Technology of ChinaShenyang 110016China Interdisciplinary Centre for Additive Manufacturing(ICAM) School of Materials and ChemistryUniversity of Shanghai for Science and TechnologyShanghai 200093China School of Materials Science and Engineering Tongji UniversityShanghai 201804China Key Laboratory for Light-Weight Materials Nanjing Tech UniversityNanjing 210009China National Key Laboratory of Science and Technology on Materials Under Shock and Impact School of Materials Science and EngineeringBeijing Institute of TechnologyBeijing 100081China Beijing Institute of Technology Chongqing Innovation Center Chongqing 401135China

The mechanical response of a single crystal titanium sample against(0001)α surface impact was investigated using molecular dynamics ***,non-uniform plastic deformation was observed in the *** high strain rates,amorphization occurred near the edge of the contact region where severe shear strain induced a large number of stacking faults(SFs)and *** contrast,the central part of the contact region underwent less deformation with significantly fewer ***,instead of amorphization by consuming SFs and dislocations,there was a gradual increase in the density of dislocations and SFs during the process of *** local amorphous regions eventually grew into shear bands.

关键词： Shock compression Amorphization Shear band Titanium Molecular dynamics

Desialylated Platelet Clearance in the Liver is a Novel Mechanism of Systemic Immunosuppression

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Research 2024年第3期2023卷 35-50页

作者： June Li Danielle Karakas feng xue Yingyu Chen Guangheng Zhu Yeni h.Yucel Sonya A.MacParland haibo Zhang John W.Semple John Freedman Qizhen Shi heyu Ni Department of Laboratory Medicine and Pathobiology University of TorontoTorontoONCanada Toronto Platelet Immunobiology Group TorontoONCanada Keenan Research Centre for Biomedical Science of St.Michael's hospital TorontoONCanada Canadian Blood Services Centre for Innovation TorontoONCanada Departments of Pediatrics Medical College of WisconsinMilwaukeeWIUSA Blood Research Institute Versiti WisconsinMilwaukeeWIUSA Departments of Ophthalmology and Vision Sciences Medicine University of TorontoTorontoONCanada Faculty of Engineering and Architectural Science Ryerson UniversityTorontoONCanada Multi-Organ Transplant Program Toronto General Hospital Research InstituteTorontoONCanada Department of Immunology University of TorontoTorontoONCanada Critical Care Medicine Department ofAnesthesiology and PainUniversity of TorontoTorontoONCanada Department of Physiology University of TorontoTorontoONCanada Department of Pharmacology University of TorontoTorontoONCanada. Division of hematology and Transfusion Medicine Lund UniversityLundSweden clinical Immunology and Transfusion Medicine Ofice of Medical ServicesRegion SkaneLundSweden Department of Medicine University of TorontoTorontoONCanada Children's Research Institute Children's WisconsinWauwatosaWIUSA Midwest Athletes Against Childhood Cancer Fund Research Center MilwaukeeWIUSA.

Platelets are small, versatile blood cells that are critical for hemostasis/thrombosis. Local platelet accumulation is a known contributor to proinflammation in various disease states. however, the anti-inflammatory/immunosuppressive potential of platelets has been poorly explored. here, we uncovered, unexpectedly, desialylated platelets (dPLTs) down-regulated immune responses against both platelet-associated and -independent antigen challenges. Utilizing multispectral photoacoustic tomography, we tracked dPLT trafficking to gut vasculature and an exclusive Kupffer cell-mediated dPLT clearance in the liver, a process that we identified to be synergistically dependent on platelet glycoprotein Ibα and hepatic Ashwell–Morell receptor. Mechanistically, Kupffer cell clearance of dPLT potentiated a systemic immunosuppressive state with increased anti-inflammatory cytokines and circulating CD4+ regulatory T cells, abolishable by Kupffer cell depletion. Last, in a clinically relevant model of hemophilia A, presensitization with dPLT attenuated anti-factor VIII antibody production after factor VIII ( infusion. As platelet desialylation commonly occurs in daily-aged and activated platelets, these findings open new avenues toward understanding immune homeostasis and potentiate the therapeutic potential of dPLT and engineered dPLT transfusions in controlling autoimmune and alloimmune diseases.

关键词： Platelet transfusion homeostasis

Cr-catalyzed allylic C(sp^(3))–h addition to aldehydes enabled by photoinduced ligand-to-metal charge transfer

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Science China Chemistry 2024年第5期67卷 1589-1595页

作者： xianrong Zeng feng-hua Zhang Runchen Lai xiaoyu Lin Zhaobin Wang Key Laboratory of Precise Synthesis of Functional Molecules of Zhejiang Province Department of ChemistrySchool of Science and Research Center for Industries of the FutureWestlake UniversityHangzhou 310030China Institute of Natural Sciences Westlake Institute for Advanced StudyHangzhou 310024China Key Laboratory of Precise Synthesis of Functional Molecules of Zhejiang Province Instrumentation and Service Center for Molecular SciencesWestlake UniversityHangzhou 310024China

Photoinduced ligand-to-metal charge transfer(LMCT) has emerged as an effective strategy for synthesizing organic molecules in a sustainable manner. however, the majority of existing reports on selective C(sp^(3))–h bond functionalization via photoinduced LMCT focus on the use of late transition metals or rare-earth metals for radical additions or cross-couplings. In contrast, the utilization of photoinduced LMCT with 3d early transition metals poses a significant challenge. herein, we describe an unprecedented approach to allylic C(sp^(3))–h addition to aldehydes, employing chromium(Cr) complexes as catalysts through visible-light-induced LMCT. By investigating the reaction pathway through various mechanistic studies, including radical trapping, kinetic isotope effect(KIE) analysis, and transient absorption spectroscopy, valuable insights have been gained. The proposed mechanism suggests the intermediacy of bromine radicals through homolysis of the Cr–Br bond. Notably, this protocol expands our understanding of the photochemical properties of earth-abundant Cr complexes.

关键词： Cr catalysis photoinduced ligand-to-metal charge transfer hydrogen-atom transfer carbonyl addition

Tracing the sources of nutrients through the Tsushima/Korea Strait

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Acta Oceanologica Sinica 2024年第6期43卷 142-152页

作者： Jing Zhang xinyu Guo Lei Zhu Jianlong feng Liang Zhao Key Laboratory of Marine Resource Chemistry and Food Technology Ministry of EducationTianjin 300457China College of Marine and Environmental Science Tianjin University of Science and TechnologyTianjin 300457China Center for Marine Environmental Studies Ehime UniversityMatsuyama 790-8577Japan

The nutrients from the East China Sea(ECS) through the Tsushima/Korea Strait(TS) strongly impact the eco system of the Japan Sea(JS).The complex origins of the Tsushima Warm Current and the various nutrient sources in the ECS result in complex spatial-temporal variations in nutrients in the *** a physical-biological model with a tracking technique,we studied the effects of nutrient sources from the ECS on the *** all the nutrient sources,the Kuroshio has the highest nutrient concentrations in the *** maximum concentration occurs at the bottom,while those of rivers and atmospheric depo sition occur at the surface,and that of the Taiwan Strait occurs in the middle *** nutrient transport through the TS exhibits similar seasonal variations,as does the volume *** transport of nutrients from the Kuroshio accounts for more than 85% of the *** transport of nutrients from the Taiwan Strait is greater during autumn and *** transport of dissolved inorganic nitrogen(DIN) from both rivers and atmospheric deposition through the TS peak in *** transport cannot be equated with volume *** DIN in the less saline zone originates not only from rivers but also from atmospheric deposition and the *** transport of nutrients from the Taiwan Strait is not as significant as its volume transport in the TS.

关键词： dissolved inorganic nitrogen dissolved inorganic phosphate East China Sea Japan Sea nutrient transport

Role of Crystal Seed in Aluminum hydroxide Crystallization from Ammonia System with Added Nh_(4)Al(SO_(4))_(2)·12h_(2)O

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Journal of Wuhan University of Technology(Materials Science) 2024年第4期39卷 945-953页

作者：王俊凯李来时 LIU feng WANG Yuzheng 吴玉胜 School of Material Science and Engineering Shenyang University of TechnologyShenyang 110870China

A method to promote aluminum hydroxide crystal growth through pickling Al(Oh)_(3)as seed in the ammonia system was proposed to overcome these *** experimental results show that,under the conditions of pickling time of 15 min,the acid concentration of 10%,the addition of 70 g/L pickling-Al(Oh)_(3)seed,and the coarse granular Al(Oh)_(3)products(d0.5=85.667)can be *** characterization results show that the phase of the product is gibbsite,consistent with the ***,the steps and ledges can be formed on pickling Al(Oh)_(3)seed surface under the ammonia system,effectively promoting crystal *** crystal growth,the roughness of the crystal surface was first increased and then decreased,and the lamellar structure was deposited on the crystal seed *** final particles are approximately round,the surface is compact and *** growth of the product is surface reaction *** addition,the content of the AlO_(6)unit is increased and contributed to Al(Oh)_(3)crystal growth.

关键词： reactive crystallization coarse-grained Al(Oh)_(3) crystal seed crystal growth process

Pre-reduction of WO_(3)-Co_(3)O_(4)by h_(2)-C_(2)h_4 in a fluidized bed

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Chinese Journal of Chemical Engineering 2024年第2期66卷 273-284页

作者： huijun Shang hengli Li Weijun Li feng Pan Zhan Du State Key Laboratory of Multiphase Complex Systems Institute of Process EngineeringChinese Academy of Sciences(CAS)Beijing 100190China College of Chemical Engineering Nanjing Technology UniversityNanjing 211816China School of Chemistry and Chemical Engineering Shihezi UniversityShihezi 832003China College of Chemical Engineering University of Chinese Academy of SciencesBeijing 100049China Chinalco Environmental Protection and Energy Conservation Group Co. Ltd.Xiong’an 071700China

In order to avoid the formation ofηphase(W_(6)Co_(6)C or W_(3)Co_(3)C)that adversely affects the sintering process and its products in the preparation process of ultra-fine WC-Co powder,a technical route of prereduction of WO_(3)-Co_(3)O_(4)to WO_(2)-Co and then deep reduction carbonization to WC-Co powder has been *** study mainly investigates the influence of gas partial pressure on the pre-reduction process of WO_(3)-Co_(3)O_(4)under a mixed atmosphere of h_(2)-C_(2)h_(4)-Ar at 600℃and establishes the kinetic equations of pre-reduction and carbon *** results indicate that increasing the partial pressure of hydrogen is conducive to the rapid and complete conversion of WO_(3) to WO_(2).high carbon content can be generated by the deposition of C_(2)h_(4),and it hinders the diffusion of the reducing gas;WO_(3)still cannot be completely reduced to WO_(2)as the partial pressure of C_(2)h_(4) increases to 60%.For the carbon evolution of C_(2)h_(4),the carbon amount is positively related to the h_(2)partial pressure,but it shows the highest amount and evolution rate when the ethylene partial pressure is 20%.Based on the reduction rate curves of WO_(3) and carbon evolution rate curves of C_(2)h_(4),the rate equations of pre-reduction and carbon evolution of WO_(3)-Co_(3)O_(4)system at 600℃are *** pre-reduction reaction belongs to the first-order reaction,and its equation is expressed as follows:r=-(dw_(WO_(3)))/dt=(9±0.15)×10^(-2)×P_(h_(2))^(0.44)P_(C_(2)h_(4))&(0.57)The carbon deposition rate equation of C_(2)h_(4) can be expressed as follows:r=-(dc_C)/dt=r_f-r_b≌7.35×10^(-2)×P_(C_(2)h_(4))^(0.31)

关键词： Fluidization WO_(3)-Co_(3)O_(4) Reduction Carbon deposition Rate equation

Enhancement and Removal of PM_(2.5)by Cold and Warm Air Masses Accompanying Certain Synoptic Weather Systems across hangzhou,China during 2014-2020

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Journal of Meteorological Research 2024年第3期38卷 620-634页

作者： Bu YU feng ChEN hanqing KANG Bin ZhU hongnian LIU hangzhou Meteorological Bureau Hangzhou310051China hangzhou International Urbanology Research Center for Urban Governance Studies Hangzhou311121China Zhejiang Institute of Meteorological Sciences Hangzhou310008China Key Laboratory for Aerosol-Cloud-Precipitation of China Meteorological Administration Nanjing University of Information Science&TechnologyNanjing210044China School of Atmospheric Sciences Nanjing UniversityNanjing210023China

Local air pollution is strongly affected by synoptic weather systems,such as fronts,troughs,low-altitude vortices,or high-altitude ***,few studies have analyzed the meteorological properties of cold or warm air masses associated to these systems and their impact on local air *** this study,hourly observations of fine particulate matter(diameter of up to 2.5µm,i.e.,PM_(2.5)),wind(V),temperature(T),pressure(P),and precipitation(R),acquired in hangzhou in 2014-2020,were *** this analysis,weather patterns were categorized into 27 types;89 and 94 cases illustrating the passage of warm and cold air masses over hangzhou were identified,respectively;the influence of air mass temperature,wind speed,and wind direction on PM_(2.5) concentrations and local accumulation or removal was *** main results are as follows.(1)Pollution events occurred more frequently for cold than for warm air masses,but average pollutant concentration was lower for cold air masses;(2)48%of the cold air mass cases corresponded to PM_(2.5) decreases and 52%to PM_(2.5) increases,with strong cold air masses(ΔT_(24h)>4°C;∣V∣_(average)>4 m s^(−1))markedly reducing local pollution,but weak cold air masses(ΔT24hhe cases,respectively:warm air masses(ΔT24h>4°C)reduced the PM_(2.5) concentration whereas weaker winds(∣V∣_(average)harply within 4 h after the passage of strong cold air masses,but more gradually within 14 h after the passage of strong warm air *** results considerably improve the current understanding of the influence of cold and warm air masses on local pollution patterns.

关键词： weather type air mass enhancement removal meteorological condition

Achieving high-efficient photocatalytic persulfate-activated degradation of tetracycline via carbon dots modified MIL-101(Fe)octahedrons

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Chinese Journal of Chemical Engineering 2024年第2期66卷 298-309页

作者： hao Yuan xinhai Sun Shuai Zhang Weilong Shi feng Guo School of Material Science and Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang 212003China

The synergistic reaction of photocatalysis and advanced oxidation is a valid strategy for the degradation of harmful antibiotic ***,carbon dots(CDs)modified MIL-101(Fe)octahedrons to form CDs/MIL-101(Fe)composite photocatalyst was synthesized for visible light-driven photocatalytic/persulfate(PS)-activated tetracycline(TC)*** electron spin resonance(ESR)spectra,scavenging experiment and electrochemical analysis were carried out to reveal that the high visible light-driven photocatalytic degradation activity of TC over CDs/MIL-101(Fe)photocatalysts is not only ascribed to the production of free active radicals in the CDs/MIL-101(Fe)/PS system(·Oh,·SO_(4-),^(1)O_(2),h^(+)and·O_(2)^(-))but also attributed to the consumption of electrons caused by the PS,which can suppress the recombination of photo-generated carriers as well as strong light scattering and electron trapping effects of ***,the possible degradation pathways were proposed by analyzing intermediates via liquid chromatography-mass spectrometry *** research presents a rational design conception to construct a CDs/PS-based photocatalysis/advanced oxidation technology with high-efficient degradation activity for the remediation of organic antibiotic pollutant wastewater and for the improvement of carrier transport kinetics of photocatalysts.

关键词： Carbon dots MIL-101(Fe) Photocatalytic Persulfate activation Tetracycline degradation