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lithiophilic li-Si alloy-solid electrolyte interface enabled by high-concentration dual salt-reinforced quasi-solid-state electrolyte

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Journal of Energy Chemistry 2024年第8期95卷 216-230页

作者： Yuanxing zhang ling zhang Zhiguang Zhao Yuxiang zhang Jingwen Cui Chengcai liu Daobin Mu Yuefeng Su Borong Wu Feng Wu School of Materials Science and Engineering Beijing Institute of Technology Chongqing Innovation Center Beijing Institute of Technology Collaborative Innovation Center of Electric Vehicles in Beijing

Solid polymer electrolytes（SPEs） are urgently required to achieve practical solid-state lithium metal batteries（lMBs） and lithium-ion batteries（lIBs）,herein,we proposed a mechanism for modulating interfacial conduction and anode interfaces in high-concentration SPEs by liDFBOP.Optimized electrolyte exhibits superior ionic conductivity and remarkable interface compatibility with salt-rich clusters:（1）polymer-plastic crystal electrolyte（P-PCE,TPU-SN matrix） dissociates ion pairs to facilitate li+transport in the electrolyte and regulates li+diffusion in the SEI.The crosslinking structure of the matrix compensates for the loss of mechanical strength at high-salt concentrations;（2） dual-anion TFSI-_n-DFBOP-min the li+solvation sheath facilitates facile li+desolvation and formation of salt-rich clusters and is conducive to the formation of li conductive segments of TPU-SN matrix;（3） theoretical calculations indicate that the decomposition products of liDFBOP form SEI with lower binding energy with liF in the SN system,thereby enhancing the interfacial electrochemical redox kinetics of SPE and creating a solid interface SEI layer rich in liF.As a result,the optimized electrolyte exhibits an excellent ionic conductivity of9.31 × 10-4S cm-1at 30℃ and a broadened electrochemical stability up to 4.73 V.The designed electrolyte effectively prevents the formation of li dendrites in li symmetric cells for over 6500 h at0.1 mA cm-2.The specific li-Si alloy-solid state half-cell capacity shows 711.6 mAh g-1after 60 cycles at 0.3 A g-1. Excellent rate performance and cycling stability are achieved for these solid-state batteries with li-Si alloy anodes and NCM 811 cathodes.NCM 811‖ Prelithiated silicon-based anode solid-state cell delivers a discharge capacity of 195.55 mAh g-1and a capacity retention of 97.8% after 120 cycles.NCM 811‖li solid-state cell also delivers capacity retention of 84.2% after 450 cycles.

关键词： li-Si alloy anode Prelithiation SEI layer Solid-state electrolyte

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Compatibility evaluation between waterborne epoxy resin and SBR latex modified asphalt emulsion

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Journal of Traffic and Transportation Engineering(English Edition) 2024年第1期11卷 160-171页

作者： Jianhua Yang Zhengqi zhang Ying Fang Key laboratory for Special Area highway Engineering of Ministry of Education Chang'an UniversityXi'an 710064China

Good compatibility between waterborne epoxy resin(WER)modifier and styrene-butadiene rubber(SBR)latex modified asphalt emulsion(SBRE)is an essential premise for good pavement performance of WER and SBR latex compositely modified asphalt emulsion(WSAE).This study aims to explore the compatibility between WER modifier and SBRE.To achieve the goal,several WER modifiers produced by two methods were first selected to modify SBRE,thus the WSAEs were prepared.Next,storage stability and workability of the WSAEs themselves,and high-temperature performance,rheological behavior and temperature sensitivity of their evaporated residues were compared and evaluated via performing a series of experiments,respectively,thus the WER modifier possessing an optimal modification effect was recommended.Results show that the storage stability of WSAEs is sensitive to the amount of WERs.The incorporation of 1%WERs by the mass of SBRE improves the storage stability of SBRE,while WERs that exceed 1%weaken its storage stability.When the WERs reach 3%and 4%,the 5 d storage stability of prepared WSAEs will be beyond the limitation of specification.Incorporating WERs into SBRE negatively affects the workability of SBRE,and the workability of WSAEs is adversely influenced by the WERs content and the storage time.To ensure the construction,the WSAEs with 3%and 4%WERs should not be stored for more than 36 h and 48 h,respectively.The WERs effectively improve the high-temperature performance of SBRE residue,especially the 3%WERs.Besides,the WERs notably enhance the rheological property and thermal stability of SBRE residue.In contrast,the WER modifier produced by chemically modified method has a smaller adverse impact on the storage stability and workability of WSAE,and a larger enhancement on the high-temperature performance,rheological property and thermal stability of SBRE residue,which is thus recommended to modify SBRE.

关键词： Waterborne epoxy resin SBR modified asphalt emulsion Workability Rheological property Temperature sensitivity Compatibility evaluation

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h_(∞)/Passive Synchronization of Semi-Markov Jump Neural Networks Subject to hybrid Attacks via an Activation Function Division Approach

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Journal of Systems Science & Complexity 2024年第3期37卷 1023-1036页

作者： zhang Ziwei ShEN hao SU lei School of Electrical and Information Engineering Anhui University of TechnologyMa'anshan 243002China Anhui Province Key laboratory of Special heavy load Robot and School of Electrical and Information Engineering Anhui University of TechnologyMa'anshan243002China

In this work,an h_(∞)/passive-based secure synchronization control problem is investigated for continuous-time semi-Markov neural networks subject to hybrid attacks,in which hybrid attacks are the combinations of denial-of-service attacks and deception attacks,and they are described by two groups of independent Bernoulli distributions.On this foundation,via the lyapunov stability theory and linear matrix inequality technology,the h_(∞)/passive-based performance criteria for semi-Markov jump neural networks are obtained.Additionally,an activation function division approach for neural networks is adopted to further reduce the conservatism of the criteria.Finally,a simulation example is provided to verify the validity and feasibility of the proposed method.

关键词： Activation function division approach deception attacks denial-of-service attacks h_(∞)/passive synchronization semi-Markov jump neural networks

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Asynchronous gain-scheduled control of deepwater drilling riser system with hybrid event-triggered sampling and unreliable communication

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Frontiers of Information Technology & Electronic Engineering 2024年第2期25卷 272-285页

作者： Na PANG Dawei zhang Shuqian ZhU School of Mathematics Shandong UniversityJinan250100China

This paper investigates the recoil control of the deepwater drilling riser system with nonlinear tension force and energy-bounded friction force under the circumstances of limited network resources and unreliable communication.Different from the existing linearization modeling method,a triangle-based polytope modeling method is applied to the nonlinear riser system.Based on the polytope model,to improve resource utilization and accommodate random data loss and communication delay,an asynchronous gain-scheduled control strategy under a hybrid event-triggered scheme is proposed.An asynchronous linear parameter-varying system that blends input delay and impulsive update equation is presented to model the nonlinear networked recoil control system,where the asynchronous deviation bounds of scheduling parameters are calculated.Resorting to the lyapunov-Krasovskii functional method,some solvable conditions of disturbance attenuation analysis and recoil control design are derived such that the resulting networked system is exponentially mean-square stable with prescribed h∞performance.The obtained numerical results verified that the proposed nonlinear networked control method can achieve a better recoil response of the riser system with less transmission data compared with the linear control method.

关键词： Riser system Recoil control Asynchronous gain-scheduled control Data loss Event-triggered scheme

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Phosphorylation Promotes the Accumulation of PERIOD Protein Foci

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Research 2024年第1期2023卷 59-69页

作者： Mengna li Shujing li luoying zhang Key laboratory of Molecular Biophysics of Ministry of Education College of Life Science and TechnologyHuazhong University of Science and TechnologyWuhanHubei 430074China Department of life Sciences Bengbu Medical CollegeBengbuAnhui 233030China hubei Province Key laboratory of Oral and Maxillofacial Development and Regeneration WuhanHubei 430022China

Circadian clock drives the 24-h rhythm in our behavior and physiology.The molecular clock consists of a series of transcriptional/translational feedback loops operated by a number of clock genes.A very recent study reported that the clock protein PERIOD(PER)is organized into discrete foci at the nuclear envelope in fly circadian neurons,which is believed to be important for controlling the subcellular localization of clock genes.loss of inner nuclear membrane protein lamin B receptor(lBR)leads to disruption of these foci,but how they are regulated is yet unknown.here,we found that PER foci are likely phase-separated condensates,the formation of which is mediated by intrinsically disordered region in PER.Phosphorylation promotes the accumulation of these foci.Protein phosphatase 2A,which is known to dephosphorylate PER,hampers the accumulation of the foci.On the other hand,the circadian kinase DOUBlETIME(DBT)which phosphorylates PER enhances the accumulation of the foci.lBR likely facilitates PER foci accumulation by destabilizing the catalytic subunit of protein phosphatase 2A,MICROTUBUlE STAR(MTS).In conclusion,here,we demonstrate a key role for phosphorylation in promoting the accumulation of PER foci,while lBR modulates this process by impinging on the circadian phosphatase MTS.

关键词： conclusion separated translational

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Progression from ductal carcinoma in situ to invasive breast cancer:molecular features and clinical significance

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Signal Transduction and Targeted Therapy 2024年第5期9卷 1841-1868页

作者： Jing Wang Baizhou li Meng luo Jia huang Kun zhang Shu Zheng Suzhan zhang Jiaojiao Zhou The Key laboratory of Cancer Prevention and Intervention China National Ministry of Educationthe Second Affiliated HospitalZhejiang University School of MedicineHangzhouChina Department of Breast Surgery and Oncology the Second Affiliated HospitalZhejiang University School of MedicineHangzhouChina Zhejiang Provincial Clinical Research Center for Cancer HangzhouChina Department of Pathology the Fourth Affiliated HospitalZhejiang University School of MedicineYiwuChina Department of Plastic Surgery the Second Affiliated HospitalZhejiang University School of MedicineHangzhouChina Cancer Center Zhejiang UniversityHangzhouChina

Ductal carcinoma in situ(DCIS)represents pre-invasive breast carcinoma.In untreated cases,25-60%DCIS progress to invasive ductal carcinoma(IDC).The challenge lies in distinguishing between non-progressive and progressive DCIS,often resulting in over-or under-treatment in many cases.With increasing screen-detected DCIS in these years,the nature of DCIS has aroused worldwide attention.A deeper understanding of the biological nature of DCIS and the molecular journey of the DCIS-IDC transition is crucial for more effective clinical management.here,we reviewed the key signaling pathways in breast cancer that may contribute to DCIS initiation and progression.We also explored the molecular features of DCIS and IDC,shedding light on the progression of DCIS through both inherent changes within tumor cells and alterations in the tumor microenvironment.In addition,valuable research tools utilized in studying DCIS including preclinical models and newer advanced technologies such as single-cell sequencing,spatial transcriptomics and artificial intelligence,have been systematically summarized.Further,we thoroughly discussed the clinical advancements in DCIS and IDC,including prognostic biomarkers and clinical managements,with the aim of facilitating more personalized treatment strategies in the future.Research on DCIS has already yielded significant insights into breast carcinogenesis and will continue to pave the way for practical clinical applications.

关键词： clinical breast alterations

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Identification and validation of novel prognostic fatty acid metabolic gene signatures in colon adenocarcinoma through systematic approaches

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Oncology Research 2024年第2期32卷 297-308页

作者： hENG zhang WENJING ChENG hAIBO ZhAO WEIDONG ChEN QIUJIE zhang QING-QING YU Department of laboratory Shandong Daizhuang HospitalJining272051China Jining No.1 People’s hospital Shandong First Medical UniversityJining272000China

Colorectal cancer(CRC)belongs to the class of significantly malignant tumors found in humans.Recently,dysregulated fatty acid metabolism(FAM)has been a topic of attention due to its modulation in cancer,specifically CRC.however,the regulatory FAM pathways in CRC require comprehensive elucidation.Methods:The clinical and gene expression data of 175 fatty acid metabolic genes(FAMGs)linked with colon adenocarcinoma(COAD)and normal cornerstone genes were gathered through The Cancer Genome Atlas(TCGA)-COAD corroborating with the Molecular Signature Database v7.2(MSigDB).Initially,crucial prognostic genes were selected by uni-and multi-variate Cox proportional regression analyses;then,depending upon these identified signature genes and clinical variables,a nomogram was generated.lastly,to assess tumor immune characteristics,concomitant evaluation of tumor immune evasion/risk scoring were elucidated.Results:A 8-gene signature,including ACBD4,ACOX1,CD36,CPT2,ElOVl3,ElOVl6,ENO3,and SUClG2,was generated,and depending upon this,CRC patients were categorized within high-risk(h-R)and low-risk(l-R)cohorts.Furthermore,risk and age-based nomograms indicated moderate discrimination and good calibration.The data confirmed that the 8-gene model efficiently predicted CRC patients’prognosis.Moreover,according to the conjoint analysis of tumor immune evasion and the risk scorings,the h-R cohort had an immunosuppressive tumor microenvironment,which caused a substandard prognosis.Conclusion:This investigation established a FAMGs-based prognostic model with substantially high predictive value,providing the possibility for improved individualized treatment for CRC individuals.

关键词： Fatty acid metabolism Colorectal cancer Gene signatures Machine learning

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Unlock the full potential of carbon cloth-based scaffolds towards magnesium metal storage via regulation on magnesiophilicity and surface geometric structure

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Journal of Energy Chemistry 2024年第3期90卷 423-434,I0010页

作者： Jing liu Min Wang Zhonghua zhang Jinlei zhang Yitao he Zhenfang Zhou Guicun li College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042ShandongChina Department of Pharmacy Jining Medical UniversityRizhao 276826ShandongChina Department of Energy and Power Engineering School of Energy and EnvironmentAnhui University of TechnologyMa’anshan 243000AnhuiChina

The development of rechargeable magnesium(Mg) batteries is of practical significance to upgrade the electric energy storage devices due to exceptional capacity and abundant resources of Mg-metal anode.however,the reversible Mg electrochemistry suffers from unsatisfied rate capability and lifespan,mainly caused by non-uniform distribution of electrodeposits.In this work,a fresh design concept of threedimensional carbon cloths scaffolds is proposed to overcome the uncontrollable Mg growth via homogenizing electric field and improving magnesiophilicity.A microscopic smooth and nitrogen-containing defective carbonaceous layer is constructed through a facile pyrolysis of ZIF8 on carbon cloths.As revealed by finite element simulation and DFT calculation results,the smooth surface endows with uniform electric field distribution and simultaneously the nitrogen-doping species enable good magnesiophilicity of scaffolds.The fine and uniform Mg nucleus as well as the inner electrodeposit behavior are also disclosed.As a result,an exceptional cycle life of 500 cycles at 4.0 mA cm^(-2) and 4.0 mA h cm^(-2) is firstly realized to our best knowledge.Besides,the functional scaffolds can be cycled for over 2200 h at 2.0 mA cm^(-2) under a normalized capacity of 5.0 mA h cm^(-2),far exceeding previous results.This work offers an effective approach to enable the full potential of carbon cloths-based scaffolds towards metal storage for next generation battery applications.

关键词： Magnesium metal anodes Electrodeposition heterogeneous nucleation

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A healable, mechanically robust and ultrastretchable ionic conductive elastomer for durably wearable sensor

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Nano Research 2024年第4期17卷 3369-3378页

作者： Guoxian zhang Chunmei li JiaoJun Tan Mingqi Wang Yafeng Ren Feijie Ge Qiuyu zhang Key laboratory of Special Functional and Smart Polymer Materials of Ministry of Industry and Information Technology School of Chemistry and Chemical EngineeringNorthwestern Polytechnical UniversityXi'an 710072China College of Bioresources Chemical and Materials Engineering National Demonstration Center for Experimental Light Chemistry Engineering EducationShaanxi University of Science&TechnologyXi’an 710021China

The ionic conductive elastomers show great promise in multifunctional wearable electronics,but they currently suffer from liquid leakage/evaporation or mechanical compliance.Developing ionic conductive elastomers integrating non-volatility,mechanical robustness,superior ionic conductivity,and ultra-stretchability remains urgent and challenging.here,we developed a healable,robust,and conductive elastomer via impregnating free ionic liquids(Ils)into the Ils-multigrafted poly(urethane-urea)(PUU)elastomer networks.A crucial strategy in the molecular design is that imidazolium cations are largely introduced by double-modification of PUU and centipede-like structures are obtained,which can lock the impregnated Ils through strong ionic interactions.In this system,the PUU matrix contributes outstanding mechanical properties,while the hydrogen bonds and ionic interactions endow the elastomer with self-healing ability,conductivity,as well as non-volatility and transparency.The fabricated ionic conductive elastomers show good conductivity(3.8×10^(-6) S·cm^(-1)),high mechanical properties,including tensile stress(4.64 MPa),elongation(1470%),and excellent healing ability(repairing efficiency of 90%after healing at room temperature for 12 h).Significantly,the conductive elastomers have excellent antifatigue properties,and demonstrate a highly reproducible response after 1000 uninterrupted extension-release cycles.This work provides a promising strategy to prepare ionic conductive elastomers with excellent mechanical properties and stable sensing capacity,and further promote the development of mechanically adaptable intelligent sensors.

关键词： ionic conductive elastomers poly(urethane-urea)(PUU) ionic interactions centipede-like self-healing

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Selective nickel-electrocatalyzed benzylic C-h oxygenation of functionalized alkyl arenes

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Chinese Chemical letters 2024年第2期35卷 396-401页

作者： Shunyao Tang Siyi Wang Dongmei zhang Xinxing zhang Guang Yang Yanwei Wang Youai Qiu State Key laboratory of Elemento-Organic Chemistry Frontiers Science Center for New Organic MatterCollege of ChemistryNankai UniversityTianjin 300071China College of Chemistry Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education)Renewable Energy Conversion and Storage Center (RECAST)Frontiers Science Center for New Organic MatterNankai UniversityTianjin 300071China

herein, a site-selective paired electrochemical C–h oxidation of functionalized alkyl arenes promoted by nickel catalyst is disclosed. A Ni(Ⅱ)-dioxygen species formed in situ efficiently enable the oxidation process under mild conditions with a broad substrate scope with excellent functional group compatibilities,such as free carboxylic acid, aldehyde, halogen(including aryl iodide), amide and amino acid. The use of the nickel catalyst in combination with water provides a safe, green and economical method for oxidation of a range of molecules varying in complexity and drug derivatives, demonstrating its potential application in organic synthesis and the pharmaceutical industry. Reaction outcomes and mechanistic studies revealed the key role of the in situ Ni(Ⅱ)-dioxygen species for the subsequent oxidation of C(sp^(3))–h bonds,and short-lived reactive intermediates(aryl radical cation) was rapidly captured by the combination of a bipolar ultramicroelectrode(BUME) with nano-electrospray ionization mass spectrometry.

关键词： Electrochemical C-h oxidation Functionalized alkyl arenes Paired nickel-electrocatalysis h_(2)O oxidation Ketones

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