检索结果-南通市图书馆

ATOMIC STATES AND BRITTLENESS OF hcp Ti_3Al-ORDERED-TYPE ALLOYS

在线全文

学校读者我要写书评

暂无评论

Acta Metallurgica Sinica(English Letters) 2007年第4期20卷 270-276页

作者： h.j. Peng Y.Q. Xie College of Chemistry and Chemical Engineering Central South University Changsha 410083 China College of Materials Science and Engineering Central South University Changsha 410083 China

On the basis of the framework of systematic science of alloys （SSA）, the basic information such as states, volumes, and potential energies of characteristic atoms in hcp Ti-Al system have been determined. The average atomic state of the hcp Ti3Al compound consisting of ψ4^Ti and ψ0^Al atoms is 0.75[Ar] （3dn）^0.573 （3dc）^2.1685 （4sc）^0.972 （4sf）^0.3093 ＋ 0.25[Ne] （3sc）^1.32 （3pc）^1.19 （3sf ＋ 3pf）^0.49. The brittleness of the ordered hcp Ti3Al compound has been discussed considering the fundamental factors, which are atomic states, bond networks, potential energy wave planes, and the ratio xTi/xAl. The existence of more pc and more dc directional electrons in the hcp Ti3Al compound lead to considerable brittleness; From bond networks and potential energy wave planes, the hcp Ti3Al compound has poorer ductility than the pure hcp Ti metal and the pure fcc Al metal; The Al-rich hcp Ti3Al ordered type alloys have poorer ductility than the Ti-rich hcp Ti3Al ordered type alloys.

关键词： Ti3Al alloy atomic state brittleness

Design of a cationic accelerator enabling ultrafast ion diffusion kinetics in aqueous zinc-ion batteries

在线全文

学校读者我要写书评

暂无评论

journal of Energy Chemistry 2025年第1期100卷 377-384页

作者： Yawei Xiao Qianqian Gu haoyu Li Mengyao Li Yude wang National Center for International Research on Photoelectric and Energy Materials School of Materials and Energy Yunnan University Key Laboratory of Ministry of Education for Advanced Materials in Tropical Island Resources School of Chemistry and Chemical Engineering Hainan University College of Chemical Engineering Fuzhou University Yunnan Key Laboratory of Carbon Neutrality and Green Low-carbon Technologies Yunnan University

Aqueous zinc-ion batteries are highly favored for grid-level energy storage owing to their low cost and high safety,but their practical application is limited by slow ion *** address this,a strategy has been developed to create a cation-accelerating electric field on the surface of the cathode to achieve ultrafast Zn2+diffusion *** employing electrodeposition to coat MoS2on the surface of BaV6O16·3h2O nanowires,the directional built-in electric field generated at the heterointerface acts as a cation accelerator,continuously accelerating Zn2+diffusion into the active *** optimized Zn2+diffusion coefficient in CC@BaV-6O16·3h2O@MoS2(7.5×10～8cm2s-1) surpasses that of most reported V-based ***,MoS2serving as a cathodic armor extends the cycling life of the Zn-CC@BaV6O16·3h2O@MoS2full batteries to over 10000 *** work provides valuable insights into optimizing ion diffusion kinetics for high-performance energy storage devices.

关键词： Zinc alloys

Electrocatalytic nitrite reduction to ammonia on isolated bismuth alloyed ruthenium

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

journal of Energy Chemistry 2025年第1期100卷 369-376页

作者： Shiyao Shang Fuzhou wang Zeyi Sun Chaofan Qiang Ke Chu School of Materials Science and Engineering Lanzhou Jiaotong University

Electrochemical reduction of NO2-to Nh3（NO2-RR） is recognized as an appealing approach for achieving renewable Nh3synthesis and waste ***,we report isolated Bi alloyed Ru （Bi1Ru） as an efficient NO2-RR *** calculations and in situ electrochemical measurements reveal the creation of Bi1-Ru dual sites which can remarkably promote NO2-activation and suppress proton adsorption,while accelerating the NO2-RR protonation energetics to render a high NO2--to-Nh3conversion ***,Bi1Ru assembled in a flow cell delivers an Nh3yield rate of 1901.4μmol h-1cm-2and an Nh3-Faradaic efficiency of 94.3%at an industrial-level current density of 324.3 mA *** study offers new perspectives for designing and constructing p-block single-atom alloys as robust and high-current-density NO2-RR catalysts toward the ammonia electrosynthesis.

关键词： Ammonia

A surface engineering strategy for the stabilization of zinc metal anodes with montmorillonite layers toward long-life rechargeable aqueous zinc ion batteries

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

journal of Energy Chemistry 2025年第1期100卷 94-105页

作者： Wenbo wang Ruifeng Xu Xu Zhang Peiyu wang Bao Yang Bingjun Yang juan Yang Kailimai Su Pengjun Ma Yanan Deng Xianfeng Fan Wanjun Chen Key Laboratory for Electronic Materials College of Electrical Engineering Northwest Minzu University Resource Chemistry and Energy Materials Research Center State Key Laboratory of Solid Lubrication Lanzhou Institute of Chemical Physics Chinese Academy of Sciences University of Chinese Academy of Sciences Institute for Materials and Processes School of Engineering University of Edinburgh

Rechargeable aqueous zinc-ion batteries （AZIBs） exhibit appreciable potential in the domain of electrochemical energy ***,there are serious challenges for AZIBs,for instance zinc dendrite growth,hydrogen evolution reaction （hER）,and corrosion side ***,we propose a surface engineering modification strategy for coating the montmorillonite （MMT） layer onto the surface of the Zn anode to tackle these issues,thereby achieving high cycling stability for rechargeable *** results reveal that the MMT layer on the surface of the Zn anode is able to provide ordered zincophilic channels for zinc ions migration,facilitating the reaction kinetics of zinc *** functional theory（DFT） calculations and water contact angle （CA） tests prove that MMT@Zn anode exhibits superior adsorption capacity for Zn2+and better hydrophobicity than the bare Zn anode,thereby achieving excellent cycling ***,the MMT@Zn||MMT@Zn symmetric cell holds the stable cycling over 5600 h at 0.5 mA cm-2and 0.125 m A h cm-2,even exceeding 1800 h long cycling under harsh conditions of 5 m A cm-2and 1.25 m A h *** MMT@Zn||V2O5full cell reaches over 3000 cycles at 2 A g-1with excellent rate ***,this surface engineering modification strategy for enhancing the electrochemical performance of AZIBs represents a promising application.

关键词： hydrogen evolution reaction

Cyclic behavior of reinforced sand under principal stress rotation

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

journal of Rock Mechanics and Geotechnical Engineering 2017年第4期9卷 585-598页

作者： Alaa h.j. Al-rkaby A. Chegenizadeh h.R. Nikraz Department of Civil Engineering School of Civil and Mechanical Engineering Curtin University Perth Australia

Although the cyclic rotation of the principal stress direction is important,its effect on the deformation behavior and dynamic properties of the reinforced soil has not been reported to *** carried out on large-scale hollow cylinder samples reveal that the cyclic rotation of the principal stress direction results in significant variations of strain components(ε,ε,εand γ) with periodic characteristics despite the deviatoric stress being constant during *** oscillation can be related to the corresponding variations in the stress components and the anisotropic fabric that rotate continuously along the principal stress *** under rotation appears to develop a plastic *** trends are observed for reinforced sand,but the shear interaction,the interlocking between particles and reinforcement layer,and the confinement result in significant reductions in the induced strains and associated irrecoverable plastic *** of the strains occur in the first cycle,and as the number of cycles increases,the presence of strains becomes very small,which is almost *** indicates that the soil has reached anisotropic critical state(ACS),where a stable structure is formed after continuous orientation,realignment and rearrangement of the particles accompanied with increasing cyclic *** in the range of 60°-135° produces more induced strains even in the presence of the reinforcement,when compared with other *** relates to the extension mode of the test in this range in which σ>σand to the relative approach between the mobilized plane and the weakest horizontal *** results in an increase in shear modulus while it appears to have no effect on the damping *** cycles of rotation result in an increase in shear modulus and lower damping ratio due to the densification that causes a decrease in shear strain and less dissipation of energy.

关键词： Cyclic rotation Principal stress direction Reinforced sand Strain components Damping ratio Shear modulus

Boosting high-performance in Zr-rich side protonic solid oxide electrolysis cells by optimizing functional interlayer

在线全文

学校读者我要写书评

暂无评论

Green Energy & Environment 2025年第1期10卷 150-160页

作者： Chunmei Tang Ning wang Sho Kitano hiroki habazaki Yoshitaka Aoki Siyu Ye huangpu hydrogen Energy Innovation Center School of Chemistry and Chemical EngineeringGuangzhou UniversityNo.230 Wai Huan Xi RoadGuangzhou510006China Graduate School of Chemical Sciences and Engineering Hokkaido UniversityN13W8Kita-kuSapporo060-8628Japan Faculty of Engineering Hokkaido UniversityN13W8Kita-kuSapporo060-8628Japan

Protonic solid oxide electrolysis cells(P-SOECs)are a promising technology for water electrolysis to produce green ***,there are still challenges related key materials and anode/electrolyte interface.P-SOECs with Zr-rich electrolyte,called Zr-rich side P-SOECs,possess high thermodynamically stability under high steam concentrations but the large reaction resistances and the current leakage,thus the inferior *** this study,an efficient functional interlayer Ba_(0.95)La_(0.05)Fe_(0.8)Zn_(0.2)O_(3-δ)(BLFZ)in-between the anode and the electrolyte is *** electrochemical performances of P-SOECs are greatly enhanced because the BLFZ can greatly increase the interface contact,boost anode reaction kinetics,and increase proton injection into *** a result,the P-SOEC yields high current density of 0.83 A cm^(-2) at 600℃ in 1.3 Vamong all the reported Zr-rich side *** work not only offers an efficient functional interlayer for P-SOECs but also holds the potential to achieve P-SOECs with high performances and long-term stability.

关键词： Functional interlayer Zr-rich side electrolyte Protonic solid oxide electrolysis cells Current density Faradaic efficiency

Oximes： Unrecognized Chameleons in Genera and Specialized Plant Metabolism

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Molecular Plant 2018年第1期11卷 95-117页

作者： Mette S rensen Elizabeth h.j. Neilson Birger Lindberg Moiler Plant Biochemistry Laboratory Department of Plant and Environmental Sciences University of Copenhagen Thorvaldsensvej 40 Frederiksberg C Copenhagen Denmark VILLUM Center for Plant Plasticity University of Copenhagen Thorvaldsensvej 40 Frederiksberg C Copenhagen Denmark Center for Synthetic Biology University of Copenhagen Thorvaldsensvej 40 Frederiksberg C Copenhagen Denmark

Oximes （R1R2C=NOh） are nitrogen-containing chemical constituents that are formed in species representing all kingdoms of life. In plants, oximes are positioned at important metabolic bifurcation points between general and specialized metabolism. The majority of plant oximes are amino acid-derived metabolites formed by the action of a cytochrome P450 from the CYP79 family. Auxin, cyanogenic glucosides, glucosinolates, and a number of other bioactive specialized metabolites including volatiles are produced from oximes. Oximes with the E configuration have high biological activity compared with Z-oximes. Oximes or their derivatives have been demonstrated or proposed to play roles in growth regulation, plant defense, pollinator attraction, and plant communication with the surrounding environment. In addition, oxime-derived products may serve as quenchers of reactive oxygen species and storage compounds for reduced nitrogen that may be released on demand by the activation of endogenous turnover pathways. As highly bioactive molecules, chemically synthesized oximes have found versatile uses in many sectors of society, especially in the agro- and medical sectors. This review provides an update on the structural diversity, occurrence, and biosynthesis of oximes in plants and discusses their role as key players in plant general and specialized metabolism.

关键词： structural diversity CYP79 auxin cyanogenic glucosides volatile organic compounds E-oxime Z-oxime

Enhanced post-combustion CO2 capture and direct air capture by plasma surface functionalization of graphene adsorbent

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

journal of Energy Chemistry 2025年第1期100卷 653-664页

作者： Rahul Navik Eryu wang Xiao Ding huang Yunyi Yiyu Liu jia Li Guangdong-hong Kong joint Laboratory for Carbon Neutrality Jiangmen Laboratory of Carbon and Science and Technology Guangzhou hKUST Fok Ying Tung Research Institute The hong Kong University of Science and Technology (Guangzhou) Carbon Neutrality and Climate Change Thrust Society Hub The Hong Kong University of Science and Technology (Guangzhou) Stoddart Institute of Molecular Science Department of Chemistry Zhejiang University

Graphene has enormous potential to capture CO2due to its unique properties and ***,graphene-based adsorbents have drawbacks of lower CO2adsorption capacity and poor *** work demonstrates a one-step rapid and sustainable N2/h2plasma treatment process to prepare graphene-based sorbent material with enhanced CO2adsorption *** treatment directly enriches amine species,increases surface area,and improves textural *** CO2adsorption capacity increases from 1.6 to 3.3 mmol/g for capturing flue gas,and from 0.14 to 1.3 mmol/g for direct air capture （DAC）.Importantly,the electrothermal property of the plasma-modified aerogels has been significantly improved,resulting in faster heating rates and significantly reducing energy consumption compared to conventional external heating for regeneration of *** aerogels display improved selectivity of 42 and 87 after plasma modification for 5 and 10 min,*** plasma-treated aerogels display minimal loss between 17%and 19% in capacity after 40 adsorption/desorption cycles,rendering excellent *** N2/h2plasma treatment of adsorbent materials would lower energy expenses and prevent negative effects on the global economy caused by climate change.

关键词： Carbon neutrality CO 2 capture Climate change Plasma treatment Graphene aerogel

A STUDY OF TEMPERATURE-DEPENDENT VALENCE BOND STRUCTURE OF TITANIUM

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Acta Metallurgica Sinica(English Letters) 2007年第1期20卷 27-34页

作者： X.B. Li Y.Q. Xie Y.Z. Nie h.j. Peng h.j. Tao F.X. Yu College of Materials Science and Engineering Central South University Changsha 410083 China

On the basis of energy and shape method for the determination of the valence bond （ VB ） structures of crystal, the valence bond structure of titanium is redetermined at room temperature and calculated in the whole temperature range of 0-1943K. The outer shell electronic distribution of Ti is ec^29907. （sc^0.4980 ＋ dc^2.4927） ef^1.0098 in crystal. The temperature dependences of the VB structures of hcp and bcc phases are the same. The VB structures of hcp and bcc phases monotonically increase or decrease with the increase in temperature, but show discontinuous changes at the phase-transformation temperature 1155K.

关键词： valence bond structure temperature titanium