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Novel synthesis of stabilized Bi1-x-yGdxDyyO1.5 solid electrolytes with enhanced conductivity for intermediate temperature solid oxide fuel cells（SOFCs）

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Journal of Rare Earths 2024年第10期42卷 1903-1911页

作者： Ahmed h.ibrahim Yehia M.Abbas h.A.Ayoub Marwa h.Ali Mustafa Aldoori Materials Science Laboratory Physics DepartmentFaculty of ScienceSuez Canal University Ministry of higher Education and Scientific Research Aliraqia University

herein,we report the synthesis of a Dy-Gd co-doped cubic phase-stabilized Bi2O3solid electrolyte system via solid-state processing under atmospheric *** with Dy3+and Gd3+has been observed to significantly enhance the densification process during sintering for stabilization purposes,thereby improving the electrical properties of δ-Bi2O3-type *** synthesized ceramics were characterized using X-ray diffraction（XRD）,field emission scanning electron microscopy-energy dispersive X-ray spectroscopy（FESEM-EDX）,thermal gravimetry/differential thermal analysis（TG/DTA）,and the four-point probe technique（4PPT）.XRD analysis reveals that the samples Bi1-x-yGdxDyyO1.5（y=0.05/x=0.05,0.10,0,15,and 0.20,and x=0.05/y=0.10,0.15,and 0.20） exhibit a stable face-centered cubic δ-phase and a mixed-phase crystallographic *** XRD analysis of the stabilized δ-phase suggests that the prepared oxides show a face-centered cubic（FCC） structure with a space group of *** micrographs reveal that the composition Bi0.90Gd0.05Dy0.05O1.5has no significant ***,an evident increase in the pore formation is observed as the amount of Gd2O3increases until it reaches 20%.This finding suggests that dense pellets are formed during the sintering process at 900-1000℃.The DTA analyses were performed to verify the phase stability,which agrees with the XRD *** electrochemical performance of the synthesized Dy-Gd co-doped Bi2O3solid electrolyte system was evaluated and analyzed in detail by using the electrochemical impedance spectroscopy（EiS） technique,Based on EiS and conductivity measurements,Bi0.75Gd0.20Dy0.05O1.5exhibits the lowest activation energy of 0.519 eV and the highest conductivity value of 0.398 S/cm at 627℃compared to the other samples;this composition can be used as a solid electrolyte for intermediatetemperature solid oxide fuel cells（SOFCs）.

关键词： Electrochemical impedance spectroscopy (EiS) Fast Fourier transform (FFT) Rare earths Rietveld Solid oxide fuel cells (SOFCs) Solid-state processing

Sequence Stratigraphy and Rudist Facies Development of the Upper Barremian-Lower Cenomanian Platform, Northern Sinai, Egypt

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Acta Geologica Sinica(English Edition) 2018年第1期92卷 286-310页

作者： Yasser SALAMA Michael GRAMMER Shaban SABER Soheir EL-ShAZLY Gouda abdel-gawad Beni-Suef University Faculty of SciencesGeology Department Boone Pickens School of Geology Oklahoma State University

The Lower Cretaceous sections in northern Sinai are composed of the Risan Aneiza(upper Barremian-middle Albian) and the halal(middle Albian-lower Cenomanian) formations. The facies reflect subtle paleobathymetry from inner to outer ramp facies. The inner ramp facies are peritidal, protected to open marine lagoons, shoals and rudist biostrome facies. The inner ramp facies grade northward into outer ramp deposits. The upper Barremian-lower Cenomanian succession is subdivided into nine depositional sequences correlated with those recognized in the neighbouring Tethyan areas. These sequences are subdivided into 19 medium-scale sequences based on the facies evolution, the recorded hardgrounds and flooding surfaces, interpreted as the result of eustatic sea level changes and local tectonic activities of the early Syrian Arc rifting stage. Each sequence contains a lower retrogradational parasequence set that constituted the transgressive systems tracts and an upper progradational parasequence set that formed the highstand systems tracts. Nine rudist levels are recorded in the upper Barremian through lower Cenomanian succession at Gabal Raghawi. At Gabal Yelleg two rudist levels are found in the Albian. The rudist levels are associated with the highstand systems tract deposits because of the suitability of the trophic conditions in the rudist-dominated ramp.

关键词： Cretaceous sequence stratigraphy rudists Sinai Egypt

high-temperature tribological performance of functionally graded Stellite 6/WC metal matrix composite coatings manufactured by laser-directed energy deposition

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Friction 2024年第3期12卷 522-538页

作者： Marta OSTOLAZA Alaitz ZABALA Jon inaki ARRiZUBiETA iñigo LLAVORi Nagore OTEGi Aitzol LAMiKiZ Department of Mechanical Engineering University of the Basque Country UPV/EHUPlaza Torres Quevedo 1Bilbo 48013Spain Faculty of Engineering Mechanics and Industrial ProductionMondragon UnibertsitateaLoramendi 4Mondragon 20500Spain

Wear-driven tool failure is one of the main hurdles in the *** issue can be addressed through surface coating with ceramic-reinforced metal matrix ***,the maximum ceramic content is limited by *** this work,the tribological behaviour of the functionally graded WC-ceramic-particlereinforced Stellite 6 coatings is *** that end,the wear resistance at room temperature and 400°C is ***,the tribological analysis is supported by crack sensitivity and hardness evaluation,which is of utmost importance in the processing of composite materials with *** indicate that functionally graded materials can be employed to increase the maximum admissible WC content,hence improving the tribological behaviour,most notably at high ***,a shift from abrasive to oxidative wear is observed in high-temperature wear testing.

关键词： friction coating metal matrix composite functionally graded materials high temperature laserdirected energy deposition

用于提升全水解性能的超低含量Ru掺杂NiMoO_(4)@Ni_(3)(PO_(4))_(2)核壳纳米结构

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Chinese Journal of Catalysis 2024年第5期60卷 360-375页

作者： Adel Al-Salihy 梁策 Abdulwahab Salah abdel-Basit Al-Odayni 卢子昂陈孟新刘倩倩徐平哈尔滨工业大学化工与化学学院新能源转化与存储关键材料工业和信息化部重点实验室黑龙江哈尔滨150001 东北师范大学化学学院动力电池国家地方联合工程实验室吉林长春130024 沙特国王大学牙科学院修复性牙科科学系沙特阿拉伯利雅得

随着全球能源危机和环境污染日益加剧,开发可持续的绿色能源技术已经成为当务之急.其中,水分解制氢作为一种清洁能源的生产方式,因其零排放和高能量密度的特点,而受到广泛的研究和关注.析氢反应(hER)和析氧反应(OER)是水分解过程的关键... 详细信息

随着全球能源危机和环境污染日益加剧,开发可持续的绿色能源技术已经成为当务之急.其中,水分解制氢作为一种清洁能源的生产方式,因其零排放和高能量密度的特点,而受到广泛的研究和关注.析氢反应(hER)和析氧反应(OER)是水分解过程的关键步骤,它们的反应效率直接影响整个制氢过程的能量转换效率.因此,开发高效的双功能电催化剂对于推动水分解技术的发展具有重要意义.本文制备了一种超低Ru掺杂的新型核壳纳米结构电催化剂,该催化剂生长在泡沫镍(NF)上,简称Ru-NiMoO_(4)@Ni_(3)(PO_(4))_(2)/NF.首先,通过水热法在NF上均匀生长了水合NiMoO_(4)纳米柱,并通过共价相互作用,确保其在垂直方向上有序排列.随后,采用超低浓度的RuCl_(3)对NiMoO_(4)纳米柱进行蚀刻,并通过磷酸化反应引入(PO_(4))^(3+)离子形成了Ni_(3)(PO_(4))_(2)壳层.这种设计克服了以往Ru易团聚的难题,保障了Ru的均匀分布,从而合成Ru-NiMoO_(4)@Ni_(3)(PO_(4))_(2)/NF催化剂.通过X-射线衍射、X-射线光电子能谱及透射电子显微镜等对催化剂的化学组分和微观结构进行了分析,证实其成功制备.元素分析结果表明,催化剂中Ru的含量仅为1.94 wt%,显著降低了其制备成本.电化学测试结果表明,该催化剂在hER和OER中均表现出较好的催化活性.在10和100 mA cm^(−2)电流密度下,hER的过电位分别为−14.8和−57.1 mV,Tafel斜率为35.8 mV dec^(-1),优于商业Pt/C催化剂;在100 mA cm^(−2)电流密度下,OER过电位为259.7 mV,Tafel斜率为21.6 mV dec^(−1),优于商业RuO_(2)催化剂.在全水解测试中,该催化剂在10和100 mA cm^(−2)时所需的电池电压分别为1.43和1.68 V,与其他自支撑材料相比表现出良好的性能.此外,该催化剂在150 h性能测试过程中表现出较好的稳定性.采用密度泛函理论计算研究了催化剂具有较好活性的内在机制.结果表明,其具有低水离解能垒(ΔGb=0.46 eV),接近零的hER自由吸附能(∆G*h=0.02 eV),低的OER自由吸附能量(ΔG*OOh−ΔG*Oh=2.74 eV)和接近费米能级的高密度态.这些特性共同促进了电解水反应的高效进行.综上,本文研究开发的Ru-NiMoO_(4)@Ni_(3)(PO_(4))_(2)/NF双功能催化剂具有较好的催化活性、低电位需求和长期稳定性,为氢气生产开辟了新途径,也为优化双功能水分解催化剂提供了新视角,并为未来可持续能源应用发展提供一定的参考.

关键词：电催化核壳结构掺杂密度泛函理论析氢反应析氧反应分解水

The Adsorption Properties of TEMPO Oxidized Cellulose against the Mixture of Methylene Blue and Rhemazol Yellow FG

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Journal of Renewable Materials 2024年第8期12卷 1369-1382页

作者： i.Putu Mahendra Kartika Dinita Program Studi Kimia Fakultas SainsInsitut Teknologi SumateraJalan Terusan RyacuduWay HuwiJati AgungLampung Selatan35365Indonesia

TEMPO/NaOCl/NaBr treatment significantly increased the number of negative charges on the cellulose *** concentrations of NaOCl,5 and 30 mmol/g of cellulose,were used in this *** number of carboxyl groups in the two cellulosic samples oxidized using TEMPO/NaOCl/NaBr was 0.5160 and 1.8461 mmol/g of cellulose,*** oxidized cellulose samples treated with 5 and 30 mmol/g NaOCl exhibited higher crystallinity,at 81.15%and 80.14%,respectively,compared to untreated cellulose,which had a crystallinity of 75.95%.The ph effect indicated that the highest adsorption capacity for methylene blue was achieved under alkaline conditions(ph 9),while the highest adsorption capacity for rhemazol yellow FG was achieved under acidic *** kinetic model of TEMPO-oxidized cellulose for methylene blue and rhemazol yellow FG conformed to the pseudo-second-order *** initial concentration parameter revealed that the isotherm model for the adsorption of methylene blue and rhemazol yellow FG by TEMPO-oxidized cellulose conformed to the Langmuir *** dye removal efficiencies for methylene blue and rhemazol yellow FG using TEMPOoxidized cellulose(30 mmol/g)were approximately 80.17%and 59.52%,*** results demonstrate that TEMPO/NaOCl/NaBr-oxidized samples can effectively separate cationic and anionic dye ***,the use of TEMPO-oxidized cellulose showed good regeneration capability,maintaining more than 95%of its adsorption capacity after 8 cycles.

关键词： Cellulose TEMPO oxidation cationic and anionic dyes dye separation

Convexification of hybrid AC-DC Optimal Power Flow with Line-Commutated Converters

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CSEE Journal of Power and Energy Systems 2024年第2期10卷 617-628页

作者： hongyuan Liang Zhigang Li J.h.Zheng Q.h.Wu School of Electric Power Engineering South China University of TechnologyGuangzhou 510641China

Line-commutated converter (LCC)-based high-voltage DC (hVDC) systems have been integrated with bulk AC power grids for interregional transmission of renewable power. The nonlinear LCC model brings additional nonconvexity to optimal power flow (OPF) of hybrid AC-DC power grids. A convexification method for the LCC station model could address such nonconvexity but has rarely been discussed. We devise an equivalent reformulation for classical LCC station models that facilitates second-order cone convex relaxation for the OPF of LCC-based AC-DC power grids. We also propose sufficient conditions for exactness of convex relaxation with its proof. Equivalence of the proposed LCC station models and properties, exactness, and effectiveness of convex relaxation are verified using four numerical simulations. Simulation results demonstrate a globally optimal solution of the original OPF can be efficiently obtained from relaxed model.

关键词： AC-DC power system convex relaxation linecommutated converter optimal power flow second-order cone programming

Shell-model representations of the microscopic version of the Bohr-Mottelson collective model

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Communications in Theoretical Physics 2024年第8期76卷 79-90页

作者： h G Ganev Joint institute for Nuclear Research DubnaRussia institute of Mechanics Bulgarian Academy of SciencesSofiaBulgaria

The structure of the irreducible collective spaces of the group Sp(12,R),which many-particle nuclear states are classified according to the chain Sp(12,R)⊃U(6)⊃SO(6)⊃SU_(pn)(3)⊗SO(2)⊃SO(3)of the proton-neutron symplectic model(PNSM),is considered in *** chain of the PNSM was recently shown to correspond to a microscopic shell-model version of the Bohr-Mottelson collective *** construction of the relevant shell-model representations of the Sp(12,R)group along this chain is considered for three nuclei with varying collective properties and from different mass *** is shown that the SU_(pn)(3)basis states of the Sp(12,R)representations belonging to the SO(6)irreps with seniorityυ≥υ0,withυ0 denoting the maximal seniority SO(6)irrep contained in the Sp(12,R)bandhead,are always Pauli allowed,but organized in a different way into different SO(6)*** is in contrast to the case of filling the levels of the standard three-dimensional harmonic oscillator and using the plethysm *** the SU_(pn)(3)multiplets withinυi forbidden,it is safe to discard *** results obtained in the present work are important for the practical application of the microscopic version of the Bohr-Mottelson collective model.

关键词： microscopic shell-model version of the Bohr-Mottelson model proton-neutron symplectic model Sp(12,R)dynamical algebra shell-model representations

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Are population cycles recovering?

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integrative Zoology 2024年第3期19卷 538-547页

作者： Vasily D.YAKUShOV Boris i.ShEFTEL A.N.Severtsov institute of Ecology and Evolution of the Russian Academy of Sciences MoscowRussia

The dynamics of populations of small mammals of Central Siberia was *** studies were carried out at the Yenisei ecological station“Mirnoye”of the *** institute of Ecology and Evolution,Russian Academy of *** time series analysis was performed by the wavelet transform using the statistical data processing language *** the 20th century,the dynamics of the population of the community and some of its constituent species(Sorex araneus;***;***;***;***;Craseomys rufocanus;Clethrionomys rutilus;Microtus oeconomus;***)were characterized by a 4-year *** type of dynamics changed to noncyclic by the nineties,but by 2022,four species(***,***,***,and ***)and the community as a whole showed a tendency toward recovery of population *** remaining species were characterized by consistently low numbers with irregular low amplitude fluctuations.

关键词： population cycles small mammals time-series analysis wavelet transform

Oncologic outcomes with and without amniotic membranes in robotic-assisted radical prostatectomy:A propensity score matched analysis

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Asian Journal of Urology 2024年第1期11卷 19-25页

作者： Jonathan Noël Daniel Stirt Marcio Covas Moschovas Sunil Reddy abdel Rahman Jaber Marco Sandri Seetharam Bhat Travis Rogers Subuhee Ahmed Anya Mascarenhas Ela Patel Vipul Patel Advent health Global Robotics institute CelebrationFLUSA University of Central Florida College of Medicine OrlandoFLUSA Big and Open Data innovation Laboratory University of BresciaItaly SUNY Upstate Medical University SyracuseNYUSA Kansas City University College of Medicine Kansas CityMOUSA harvard University CambridgeMAUSA

Objective:Placement of human placenta derived grafts during robotic-assisted radical prostatectomy(RARP)hastens the return of continence and *** long-term impact on the oncologic outcomes remains to be *** objective was to determine the oncologic outcomes of patients with dehydrated human amnion chorion membrane(dhACM)at RARP compared to a matched ***:in a referral centre,from August 2013 to October 2019,599 patients used dhACM in bilateral nerve-sparing *** excluded patients with less than 12 months follow-up,simple prostatectomy,and unilateral *** with dhACM(amnio group)were 529,and were propensity score matched 1:1 to 2465 patients without dhACM(non-amnio group)and a minimum follow-up of 36 *** the time of RARP,dhACM was placed around the neurovascular bundle in the amnio *** and categorical variables in matched groups was tested by two-sample Kolmogorov-Smirnov test and Fisher's exact test *** measured were biochemical recurrence(BCR),adjuvant and salvage therapy ***:Propensity score matching resulted in two groups of 444 *** incidence functions for BCR did not show a difference between the groups(p=0.3).Patients in the non-amnio group required salvage therapy more frequently than the amnio group,particularly after partial nerve-sparing RARP(6.3%vs.2.3%,p=0.001).Limitations are the absence of prospective ***:The data suggest that using dhACM does not have a negative impact on BCR in *** of cancer specific and overall survival will require follow-up study to increase our understanding of these grafts’impact on prostate cancer biology.

关键词： Prostatectomy Prostatecancer Robotic Oncology Outcome Allograft Biomaterial Dehydrated human amnionchorion membrane