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Green Synthesis and Catalysis 2024年第1期5卷 31-34页

作者： Zhen Tang chao Pi Yangjie Wu Xiuling Cui henan Key Laboratory of Chemical Biology and Organic Chemistry Key Laboratory of Applied Chemistry of Henan UniversitiesGreen Catalysis CenterCollege of ChemistryZhengzhou UniversityZhengzhou450052China

A visible-light-promoted formal[2+2+1]cyclization of N-aryl glycines with quinoxalin-2(1h)-ones to synthesize tetrahydroimidazo[1,5-a]quinoxalin-4(5h)-ones have been *** protocol features operational simplicity,mild reaction conditions with blue LED light employing Ru(bpy)3Cl2.6h2O as a photoredox catalyst,a combination of O2 from air and Cu(OAc)2 as the oxidant and broad substrate applicability.

关键词： Cyclization Decarboxylation Visible-light-promoted Quinoxalin-2(1h)-ones Mild conditions

Geochemistry and origins of hydrogen-containing natural gases in deep Songliao Basin,China:Insights from continental scientific drilling

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Petroleum Science 2024年第2期21卷 741-751页

作者： Shuang-Biao han chao-han Xiang Xin Du Lin-Feng Xie Jie huang Cheng-Shan Wang College of Geoscience and Surveying Engineering China University of Mining and TechnologyBeijing100083China State Key Laboratory of Biogeology and Environmental Geology China University of GeosciencesBeijing100083China

The different reservoirs in deep Songliao Basin have non-homogeneous lithologies and include multiple layers with a high content of hydrogen *** gas composition and stable isotope characteristics vary significantly,but the origin analysis of different gas types has previously been *** on the geochemical parameters of gas samples from different depths and the analysis of geological settings,this research covers the diverse origins of natural gas in different *** gas components are mainly methane with a small amount of C_(2+),and non-hydrocarbon gases,including nitrogen(N_(2)),hydrogen(h_(2)),carbon dioxide(CO_(2)),and helium(he).At greater depth,the carbon isotope of methane becomes heavier,and the hydrogen isotope points to a lacustrine sedimentary *** increasing depth,the origins of N_(2)and CO_(2)change gradually from a mixture of organic and inorganic to *** origins of hydrogen gas are complex and include organic sources,water radiolysis,water-rock(Fe^(2+)-containing minerals)reactions,and *** shales of Denglouku and Shahezi Formations,as source rocks,provide the premise for generation and occurrence of organic ***,the deep faults and fluid activities in Basement Formation control the generation and migration of mantle-derived *** discovery of a high content of h_(2)in study area not only reveals the organic and inorganic association of natural-gas generation,but also provides a scientific basis for the exploration of deep hydrogen-rich gas.

关键词： Gas compositions Stable isotopes Gas origins hydrogen gas Songliao Basin

Rationally construction of atomic-precise interfacial charge transfer channel and strong build-in electric field in nanocluster-based Zscheme heterojunctions with enhanced photocatalytic hydrogen production

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Nano Research 2024年第6期17卷 5002-5010页

作者： Qingtao Zhu honglei Shen chao han Liu huang Yanting Zhou Yuanxin Du Xi Kang Manzhou Zhu Department of Materials Science and Engineering Centre for Atomic Engineering of Advanced MaterialsKey Laboratory of Structure and Functional Regulation of Hybrid Materials of Ministry of EducationKey Laboratory of Functional Inorganic Material Chemistry of Anhui ProvinceAnhui UniversityHefei 230601China

The lack of effective charge transfer driving force and channel limits the electron directional migration in nanoclusters(NC)-based heterostructures,resulting in poor photocatalytic ***,a Z-scheme NC-based heterojunction(Pt1Ag28-BTT/CoP,BTT=1,3,5-benzenetrithiol)with strong internal electric field is constructed via interfacial Co-S bond,which exhibits an absolutely superiority in photocatalytic performance with 24.89 mmol·h^(−1)·g−1 h_(2)production rate,25.77%apparent quantum yield at 420 nm,and~100%activity retention in stability,compared with Pt1Ag28-BDT/CoP(BDT=1,3-benzenedithiol),Ag29-BDT/CoP,and *** enhanced catalytic performance is contributed by the dual modulation strategy of inner core and outer shell of NC,wherein,the center Pt single atom doping regulates the band structure of NC to match well with CoP,builds internal electric field,and then drives photogenerated electrons steering;the accurate surface S modification promotes the formation of Co-S atomic-precise interface channel for further high-efficient Z-scheme charge directional *** work opens a new avenue for designing NC-based heterojunction with matchable band structure and valid interfacial charge transfer.

关键词： atomically precise metal nanocluster Z-scheme heterojunction interfacial charge transfer build-in electric field photocatalytic hydrogen production

Chemoselective and Living/Controlled Polymerization of Alkenyl Methacrylates by the Phosphonium Ylide/Organoaluminum Lewis Pairs

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Chinese Journal of Polymer Science 2024年第2期42卷 159-167,I0005页

作者： Zhi-Kang Chen Wu-chao Zhao Yi-Ling Zhao Cong-Lei Liu Liu-Yin Jiang Yue-Tao Zhang hong-Ping Zhu State Key Laboratory of Physical Chemistry of Solid Surfaces College of Chemistry and Chemical EngineeringXiamen UniversityXiamen361005China State Key Laboratory of Supramolecular Structure and Materials College of ChemistryJilin UniversityChangchun130012China

Chemoselective,living/controlled polymerizations of allyl methacrylate(AMA) and vinyl methacrylate(VMA) with/without methyl methacrylate(MMA) by using the phosphonium ylide/organoaluminum based Lewis pairs(LPs) have been *** P-ylide-2/AIMe(BhT)_(2)(Pylide-2=Ph_(3)P=ChMe and BhT=2,6-iBu_(2)-4-MeC_(6)h_(2)O) was demonstrated to be superior by which homopolymers PAMAs(M_(n)=27.6-111.5kg/mol and ■=1.14-1.25) and PVMAs(M_(n)=28.4-78.4 kg/mol and ■=1.12-1.18) and block copolymers PMMA-b-PAMA,PAMA-b-PVMA,PAMA-bPMMA,PMMA-b-PAMA-b-PMMA,PAMA-b-PMMA-b-PAMA,and PAMA-b-PVMA-b-PAMA were *** the polymerizations,all of the monomers were reacted by the conjugated ester vinyl groups leaving intactly the nonconjugated acryloxy *** pendant acryloxy groups attached to the main chain enable further to post-functionalization by the AIBN-induced radical "thiol-ene" reaction using PhCh_(2)*** thiolether side group-containing polymers PAMA-SCh_(2)Ph and PAMA-SCh_(2)Ph-b-PMMA-b-PAMA-SCh_(2)Ph were thus prepared.

关键词： Phosphonium ylide Alkenyl methacrylate Chemoselectivity Living/controlled polymerization Post-functionalization

Recent advances in vacancy engineering for reliable lithiumsulfur batteries

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Rare Metals 2024年第2期43卷 455-477页

作者： Wen-Dong Liu Xiao Tang Jun-An Feng chao-Yue Zhang hao Liu Chuan Shi Xiao-Xian Zhao Jian-Jun Song College of Physics School of Chemistry and Chemical EngineeringQingdao UniversityQingdao266071China Faculty of Science Centre for Clean Energy TechnologySchool of Mathematical and Physical SciencesUniversity of Technology SydneySydneyNSW2007Australia Department of Chemistry College of ScienceHebei Agricultural UniversityBaoding071001China

The high-energy-density and low-cost features endow lithium-sulfur batteries with broad application ***,many drawbacks,especially the detrimental shuttle effect,have hindered the further development of *** response,a lot of new structures have been applied to suppress the shuttle effect and promote the development of ***,vacancy engineering has gained the attention of researchers due to its unique electronic *** review aims to analyze the application of vacancy engineering in ***,the electrochemistry of LSBs has been systematically discussed and the existing challenges as well as improvement tactics of LSBs have also been ***,the preparation methods and characterization technologies of various vacancies are summarized,including oxygen vacancies,sulfur vacancies,selenium vacancies,other anion vacancies,cation vacancies,*** latest applications of vacancy engineering in LSBs are also summarized in this ***,some prospects and insights for further investigation and practical application of vacancy engineering in LSBs are put forward.

关键词： Lithium-sulfur batteries(LSBs) Defects Vacancy engineering Electronic structure Shuttle effect

homochirality in Ferroelectrochemistry

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Chinese Journal of Chemistry 2024年第10期42卷 1133-1144页

作者： hang Peng Jun-chao Qi Yu-Si Liu Jia-Mei Zhang Wei-Qiang Liao Ren-Gen Xiong Ordered Matter Science Research Center Nanchang UniversityNanchangJiangxi 330031China

What is the most favorite and original chemistry developed in your research group?We originally proposed the design principle for molecular ferroelectrics:ferroelectrochemistry,including quasi-spherical theory,the introduction of homochirality,and h/F *** changed the blind search for molecular ferroelectrics into targeted chemical design,which will develop into a new discipline.

关键词： Molecular ferroelectrics homochirality Ferroelectricity Chemical design Point groups

Xuebijing improves intestinal microcirculation dysfunction in septic rats by regulating the VEGF-A/PI3K/Akt signaling pathway

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World Journal of Emergency Medicine 2024年第3期15卷 206-213页

作者： A-ling Tang Yan Li Li-chao Sun Xiao-yu Liu Nan Gao Sheng-tao Yan Guo-qiang Zhang Department of Emergency China-Japan Friendship HospitalBeijing 100029China Graduate School Beijing University of Chinese MedicineBeijing 100105China

BACKGROUND:This study aims to explore whether Xuebijing(XBJ) can improve intestinal microcirculation dysfunction in sepsis and its ***:A rat model of sepsis was established by cecal ligation and puncture(CLP).A total of 30 male SD rats were divided into four groups:sham group,CLP group,XBJ + axitinib group,and XBJ *** was intraperitoneally injected 2 h before *** data(blood pressure and heart rate) were *** intestinal microcirculation data of the rats were analyzed via microcirculation ***-linked immunosorbent assay(ELISA) kits were used to detect the serum levels of interleukin-6(IL-6),C-reactive protein(CRP),and tumor necrosis factor-α(TNF-α) in the *** analysis and transmission electron microscopy were used to analyze the injury of small intestinal microvascular endothelial cells and small intestinal mucosa in *** expression of vascular endothelial growth factor A(VEGF-A),phosphoinositide 3-kinase(PI3K),phosphorylated PI3K(p-PI3K),protein kinase B(Akt),and phosphorylated Akt(p-Akt) in the small intestine was analyzed via Western ***:XBJ improved intestinal microcirculation dysfunction in septic rats,alleviated the injury of small intestinal microvascular endothelial cells and small intestinal mucosa,and reduced the systemic inflammatory ***,XBJ upregulated the expression of VEGF-A,p-PI3K/total PI3K,and p-Akt/total Akt in the rat small ***:XBJ may improve intestinal microcirculation dysfunction in septic rats possibly through the VEGF-A/PI3K/Akt signaling pathway.

关键词： Sepsis Xuebijing Vascular endothelial growth factor A Microcirculation Rat Phosphoinositide 3-kinase Protein kinase B

Correlation between carbon emissions， fuel consumption of vehicles and speed limit on expressway

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Journal of Traffic and Transportation Engineering(English Edition) 2024年

作者： chao Gao Jinliang Xu Miao Jia Zhenhua Sun School of highway Chang'an University Shaoxing Communications Investment Group Co. Ltd.

This paper aimed to investigate the correlation between carbon emissions， fuel consumption， and speed limit. A theoretical model was derived based on the energy conservation law， which expresses the relationship between vehicle’s fuel consumption and speed. Subsequently， a total of 40 sets of fuel consumption data were collected through field tests to verify the accuracy of the theoretical model at different speeds and different road longitudinal slope combinations. The fuel consumption was then converted to carbon emissions according to the carbon emission factors specified by IPCC. In the field experiment， two types of cars and trucks， which are most common on the expressways in China， were selected. Finally， the travel speed under different posted speed limits was obtained through the previously established model， and the carbon emission changes of different vehicle types at different limited speeds are calculated. The results show that the speed limit has a significant impact on fuel consumption and carbon emissions. When the speed limit increased from 80 to 120km/h， average vehicle speeds increased about 21% to 27%， and fuel consumption and carbon emissions increased from approximately 33% to 38%. Another interesting result was that the vehicle’s fuel consumption and carbon emissions are only affected by speed. The results of the study explore the effect of speed limits on carbon emissions and provide evidence for road managers to set reasonable speed limits.

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Sandwich-type composited solid polymer electrolytes to strengthen the interfacial ionic transportation and bulk conductivity for all-solid-state lithium batteries from room temperature to 120℃

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Journal of Energy Chemistry 2024年第8期95卷 288-295,I0007页

作者： Jiewen Tan Zhen Wang Jiawu Cui Zhanhui Jia Wensheng Tian chao Wu Chengxin Peng Chengyong Shu Kang Yang Wei Tang School of Chemical Engineering and Technology Xi'an Jiaotong UniversityXi'an 710049ShaanxiChina Center for Advancing Materials Performance from the Nanoscale(CAMP-Nano) State Key Laboratory for Mechanical Behavior of MaterialsXi'an Jiaotong UniversityXi'an 710049ShaanxiChina State Key Laboratory of Space Power-sources Technology Shanghai Institute of Space Power-SourcesShanghai 200245China School of Materials Science and Engineering University of Shanghai for Science and TechnologyShanghai 200093China Top-Energy Digital Manufacturing Technologies(Xi'an)Co. Ltd.Xi'an 710100ShaanxiChina

The insurmountable charge transfer impedance at the Li metal/solid polymer electrolytes(SPEs)interface at room temperature as well as the ascending risk of short circuits at the operating temperature higher than the melting point,dominantly limits their applications in solid-state batteries(SSBs).Although the inorganic filler such as CeO_(2)nanoparticle content of composite solid polymer electrolytes(CSPEs)can significantly reduce the enormous charge transfer impedance at the Li metal/SPEs interface,we found that the required content of CeO_(2)nanoparticles in SPEs varies for achieving a decent interfacial charge transfer impedance and the bulk ionic conductivity in *** this regard,a sandwich-type composited solid polymer electrolyte with a 10%CeO_(2)CSPEs interlayer sandwiched between two 50%CeO_(2)CSPEs thin layers(sandwiched CSPEs)is constructed to simultaneously achieve low charge transfer impedance and superior ionic conductivity at 30℃.The sandwiched CSPEs allow for stable cycling of Li plating and stripping for 1000 h with 129 mV polarized voltage at 0.1 mA cm^(-2)and 30℃.In addition,the LiFePO_(4)/Sandwiched CSPEs/Li cell also exhibits exceptional cycle performance at 30℃and even elevated120℃without short *** multi-layered CSPEs with optimized contents of the inorganic fillers can be an efficient method for developing all solid-state PEO-based batteries with high performance at a wide range of temperatures.

关键词： PEO-based solid electrolytes CeO_(2)nanoparticles Charge transfer impedance Sandwich-type composite electrolytes All-solid-state Li metal batteries

Structural evolution and high-temperature sensing performance of polymer-derived SiAlBCN ceramics

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Journal of Advanced Ceramics 2024年第4期13卷 478-485页

作者： chao Ma Kun Liu Pengfei Shao Daoyang han Kang Wang Mengmeng Yang Rui Zhao hailong Wang Rui Zhang Gang Shao School of Materials Science and Engineering Zhengzhou UniversityZhengzhou 450001China Zhongyuan Critical Metal Laboratory Zhengzhou UniversityZhengzhou 450001China State Key Laboratory of Structural Analysis Optimization and CAE Software for Industrial EquipmentZhengzhou UniversityZhengzhou 450002China

In situ temperature monitoring has become extremely imperative in high-temperature harsh environments and polymer-derived ceramics(PDCs)as sensing materials have attracted great ***,the stability and oxidation/corrosion resistance of PDCs cannot be simultaneously achieved at the moment,limiting their practical ***,polymer-derived SiAlBCN ceramics were synthesized via polymer conversion method under different pyrolysis *** microstructure evolution,high temperature sensing properties,and stability were investigated in *** results show that the amorphous SiAlBCN phase grows more orderly and the size of the free carbon phase enlarges with the increasing *** defect concentration displays a decreasing ***,the SiAlBCN ceramics as sensing materials exhibit a good temperature-resistance property from roo temperature to 1100℃.The fabricated SiAlBCN temperature sensor possesses excellent stability,repeatability,and ***,SiAlBCN ceramics exhibit distinguished oxidation/corrosion resistance after 100 h treatment at 1200℃in a water/oxygen environment,which is attributed to their low corrosive rate constant(0.57 mg/(cm^(2)·h))and oxidative rate constant(3.43 mg^(2)/(cm^(4)·h)).Therefore,polymer-derived SiAlBCN ceramics as sensing materials,which possess outstanding stability and oxidation/corrosion resistance,have great potential for in-situ monitoring of extreme environmental temperatures in the future.

关键词： polymer-derived SiAlBCN ceramics temperature sensor harsh environments oxidation and corrosion resistance