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Structural,electrical and magnetic properties of cobalt ferrite with Nd^(3+) doping

Rare Metals 2022年第1期41卷 240-245页

作者： Regaty Anitha Reddy Kattepogu Rama Rao Bitra Rajesh Babu guthikonda kiran kumar Cherukupalli Rajesh Anindita Chatterjee Nadella Krishna Jyothi Department of Physics Koneru Lakshmaiah Education FoundationVaddeswaramGunturAndhra Pradesh 522502India Department of Physics Andhra UniversityVisakhapatnamAndhra Pradesh 530003India Department of Physics G.V.P.College of Engineering for WomenVisakhapatnamAndhra Pradesh 530048India Department of Physics Raghu College of Engineering(A)BheemunipatnamVisakhapatnamAndhra Pradesh 531162India Department of Physics Gayatri Vidya Parishad College of Engineering(Autonomous)VisakhapatnamAndhra Pradesh 530048India Department of Chemistry Raghu College of Engineering(A)BheemunipatnamVisakhapatnamAndhra Pradesh 531162India

A systematic study on the influence of Nd^(3+) substitution on structural,magnetic and electrical properties of cobalt ferrite nanopowders obtained by sol–gel auto-combustion routewas *** formation of spinel phasewas confirmed by X-ray diffraction(XRD)data,and percolation limit ofNd3?into the spinel lattice was also *** transform infrared spectroscopy(FTIR)bands observed ≈580 and ≈390 cm^(-1 ) support the presence of Fe^(3+) at A andBsites in the spinel *** variation in microstructure was investigated by scanning electronmicroscopy(SEM),and the average grain size varies from 5.3 to 3.3 *** substitution of Nd^(3+) significantly affects the formation of pores and grain size of cobalt ***-temperature saturation magnetization and coercivity decrease from 60 to 30 mA·m^(2)·g^(-1) and 19.9–17.8 mT,respectively,with Nd^(3+) substitution *** decreases in magnetic properties are explained based on the presence of non-magnetic nature of Nd^(3+) concentration and the dilution of super-exchange interaction in the spinel *** room-temperature direct-current electrical resistivity increases with Nd^(3+) concentration increasing,which is due to the unavailability of Fe^(2+) at octahedral B sites.

关键词： Co-Nd ferrite Saturation magnetization DC resistivity

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