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Chinese Chemical Letters 2024年第5期35卷 392-396页

作者： guorong li Yijing Wu Chao Zhong Yixin Yang Zian lin Ministry of Education Key Laboratory of Analytical Science for Food Safety and Biology Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food SafetyCollege of ChemistryFuzhou UniversityFuzhou 350108China

Targeted construction of new covalent organic frameworks(COFs)with specific purposes and rationalities to build colorimetric assay platform for environmental pollutant monitoring have attracted increasing interest.However,it is still challenging due to lack of available coordination sites inside COFs pores and only a slight bonding ability for anchoring metal.In this work,a two-dimensional(2D)COFs(termed as Tz-COF)with high crystallinity,excellent chemical stability,and abundant sulfur coordination in its skeletons was synthesized and used for the confined growth of Au NPs.It was found that the Au NPs showed significant dispersibility for the support of Tz-COF.The proposed Tz-COF@Au NPs possessed outstanding Hg^(2+)-activated peroxidase-like activity benefited from physicochemical properties of gold amalgam and synergistic effect between COFs and Au NPs to oxidize chromogenic substrate.Based on highly efficient activity and distinctive color evolution,the strategy for detecting Hg^(2+)was developed and successfully applied to determine the content of Hg^(2+)in real environmental samples.This work manifests that a potential strategy to establish a colorimetric assay platform for environmental pollutant monitoring based on the targeted manufacturing of novel COFs with specific functions.

关键词： Covalent organic frameworks Thiazole Sulfur coordination Au nanoparticles Hg^(2+)-activated peroxidase-like activity

Shear resistance characteristics and influencing factors of root-soil composite on an alpine metal mine dump slope with different recovery periods

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Journal of Mountain Science 2024年第3期21卷 835-849页

作者： PANG Jinghao liANG Shen liU Yabin li Shengwei WANG Shu ZHU Haili li guorong HU Xiasong Department of Geological Engineering Qinghai UniversityXining 810016China Key Laboratory of Genozoic Resource&Environment in North Margin of the Tibetan Plateau Xining 810016China

Artificial vegetation restoration is the main measure for vegetation restoration and soil and water conservation in alpine mine dumps on the Qinghai-Tibet Plateau,China.However,there are few reports on the dynamic changes and the influencing factors of the soil reinforcement effect of plant species after artificial vegetation restoration under different recovery periods.We selected dump areas of the Delni Copper Mine in Qinghai Province,China to study the relationship between the shear strength and the peak displacement of the root-soil composite on the slope during the recovery period,and the influence of the root traits and soil physical properties on the shear resistance characteristics of the root-soil composite via in situ direct shear tests.The results indicate that the shear strength and peak displacement of the rooted soil initially decreased and then increased with the increase of the recovery period.The shear strength of the rooted soil and the recovery period exhibited a quadratic function relationship.There is no significant function relationship between the peak displacement and the recovery period.Significant positive correlations(Plinear correlations(P0.05)between the shear strength of the root-soil composite and the root length density,and the root volume ratio of the coarse roots to the fine roots.A significant negative linear correlation(P0.05)with the root traits,other soil physical property indices(the moisture content and dry density of the soil),and slope gradient.The coarse-grain content is the main factor controlling the peak displacement of the rooted soil.

关键词： Alpine mine dump Artificial vegetation restoration period Rooted soil Shear resistance characteristics Root traits Soil physical properties

Translationally controlled tumor protein: the mediator promoting cancer invasion and migration and its potential clinical prospects

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Journal of Zhejiang University-Science B(Biomedicine & Biotechnology) 2022年第8期23卷 642-654页

作者： Junying GAO Yan MA Guiwen YANG guorong li Shandong Provincial Key Laboratory of Animal Resistant School of Life SciencesShandong Normal UniversityJinan 250014China

Translationally controlled tumor protein(TCTP) is a highly conserved multifunctional protein localized in the cytoplasm and nucleus of eukaryotic cells. It is secreted through exosomes and its degradation is associated with the ubiquitin-proteasome system(UPS), heat shock protein 27(Hsp27), and chaperone-mediated autophagy(CMA). Its structure contains three α-helices and eleven β-strands, and features a helical hairpin as its hallmark. TCTP shows a remarkable similarity to the methionine-R-sulfoxide reductase B(Msr B) and mammalian suppressor of Sec4(Mss4/Dss4) protein families, which exerts guanine nucleotide exchange factor(GEF) activity on small guanosine triphosphatase(GTPase) proteins, suggesting that some functions of TCTP may at least depend on its GEF action. Indeed, TCTP exerts GEF activity on Ras homolog enriched in brain(Rheb) to boost the growth and proliferation of Drosophila cells. TCTP also enhances the expression of cell division control protein 42 homolog(Cdc42) to promote cancer cell invasion and migration. Moreover, TCTP regulates cytoskeleton organization by interacting with actin microfilament(MF) and microtubule(MT) proteins and inducing the epithelial-mesenchymal transition(EMT) process. In essence, TCTP promotes cancer cell movement. It is usually highly expressed in cancerous tissues and thus reduces patient survival;meanwhile, drugs can target TCTP to reduce this effect. In this review, we summarize the mechanisms of TCTP in promoting cancer invasion and migration, and describe the current inhibitory strategy to target TCTP in cancerous diseases.

关键词： Translationally controlled tumor protein(TCTP) Invasion Migration Cancer Clinical drugs

High efficiently harvesting visible light and vibration energy in(1−x)AgNbO_(3)-xliTaO_(3) solid solution around antiferroelectric-ferroelectric phase boundary for dye degradation

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Journal of Advanced Ceramics 2022年第10期11卷 1641-1653页

作者： Tufeng HE Zhenzhu CAO guorong li Yanmin JIA Biaolin PENG College of Chemical Engineering Inner Mongolia University of TechnologyHohhot 010051China Key Laboratory of Inorganic Function Material and Device Shanghai Institute of CeramicsChinese Academy of SciencesShanghai 200050China School of Science Xi’an University of Posts&TelecommunicationsXi’an 710121China School of Advanced Materials and Nanotechnology Xidian UniversityXi’an 710126China

Simultaneously employing light and vibration energy by piezoelectric material to realize environmental remediation is an advanced oxidation method.Silver niobate(AgNbO_(3))is a visible light driven photocatalyst for the removal of organic pollutants.However,the high recombination rate of photo-generated electrons and holes suppresses its photocatalytic activity.Piezoelectric potential excited by vibration can facilitate the separation of light induced charges.Unfortunately,AgNbO_(3) is an antiferroelectric.In this work,distinct photo-/vibration-bi-catalysis has been achieved in ferroelectric(1−x)AgNbO_(3)-xliTaO_(3) solid solution.The results show that ~96% Rhodamine B(RhB)can be decomposed under the bi-excitation of ultrasound and visible light within 120 min with 0.95AgNbO_(3)-0.05liTaO_(3) catalyst.The synergy effect from efficient visible light excitation and enhanced separation of the photo-induced charges from the electric field by the mechanical strain results in the distinct decomposition performance of catalysts.

关键词： piezoelectric effect photocatalysis visible light decomposition

Characterization of alpine meadow surface crack and its correlation with root-soil properties

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Journal of Arid Land 2024年第6期16卷 834-851页

作者： WU Yuechen ZHU Haili ZHANG Yu ZHANG Hailong liU Guosong liU Yabin li guorong HU Xiasong School of Geological Engineering Qinghai UniversityXining 810016China Key Laboratory of the Cenozoic Resources and Environment on the North Rim of the Qinghai-Tibet Plateau Xining 810016China Qinghai Provincial Transportation Planning and Design Research Institute Co.Ltd. Xining 810002China

Quantifying surface cracks in alpine meadows is a prerequisite and a key aspect in the study of grassland crack development.Crack characterization indices are crucial for the quantitative characterization of complex cracks,serving as vital factors in assessing the degree of cracking and the development morphology.So far,research on evaluating the degree of grassland degradation through crack characterization indices is rare,especially the quantitative analysis of the development of surface cracks in alpine meadows is relatively scarce.Therefore,based on the phenomenon of surface cracking during the degradation of alpine meadows in some regions of the Qinghai-Tibet Plateau,we selected the alpine meadow in the Huangcheng Mongolian Township,Menyuan Hui Autonomous County,Qinghai Province,China as the study area,used unmanned aerial vehicle(UAV)sensing technology to acquire low-altitude images of alpine meadow surface cracks at different degrees of degradation(light,medium,and heavy degradation),and analyzed the representative metrics characterizing the degree of crack development by interpreting the crack length,length density,branch angle,and burrow(rat hole)distribution density and combining them with in situ crack width and depth measurements.Finally,the correlations between the crack characterization indices and the soil and root parameters of sample plots at different degrees of degradation in the study area were analyzed using the grey relation analysis.The results revealed that with the increase of degradation,the physical and chemical properties of soil and the mechanical properties of root-soil composite changed significantly,the vegetation coverage reduced,and the root system aggregated in the surface layer of alpine meadow.As the degree of degradation increased,the fracture morphology developed from"linear"to"dendritic",and eventually to a complex and irregular"polygonal"pattern.The crack length,width,depth,and length density were identified as the crack characterization indices via analysis of variance.Th

关键词： alpine meadow grassland degradation grassland cracks crack characterization index crack morphology root length density grey relation analysis

Unusual local electric field concentration in multilayer ceramic capacitors

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Journal of Materiomics 2023年第2期9卷 403-409页

作者： Wentong Du Huarong Zeng Weiwei Yang Kunyu Zhao Faqiang Zhang guorong li Yongxiang li Zhifu liu CAS Key Laboratory of Inorganic Functional Materials and Devices Shanghai Institute of CeramicsChinese Academy of SciencesShanghai201899China Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of SciencesBeijing100049China School of Engineering RMIT UniversityMelbourneVIC3000Australia

Local electric-field around multitype pores(dielectric pore,interface pore,electrode pore)in multilayer ceramic capacitors(MLCCs)was investigated using Kelvin probe force microscopy combined with the finite element simulation to understand the effect of pores on the electric reliability of MLCCs.Electricfield is found to be concentrated significantly in the vicinity of these pores and the strength of the local electric-field is 1.5e5.0 times of the nominal strength.Unexpectedly,the concentration degree of the pores in the inner electrode is much higher than that in the dielectrics and dielectric-electrode interfaces.Meanwhile,geometry orientations are found to have a remarkable influence on the local electric field strength.The pores act as an insulation degradation precursor via local electric,thermal center,and oxygen vacancies accumulation center.Such unusual local electric field concentration of multitype pores can provide new insights into the understanding of insulation degradation evolution,processing tailoring and design optimization for MLCCs.

关键词： Multilayer ceramic capacitors(MLCCs) Kelvin probe force microscopy Pore Local electric field concentration

Synergy of lead vacancies and morphotropic phase boundary to promote high piezoelectricity and temperature stability of PBZTN ceramics

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Journal of Materials Science & Technology 2023年第6期137卷 1-7页

作者： Wenbin liu Ting Zheng Xuezheng Ruan Zhenyong Man Haoyue Xue Laiming Jiang Fuping Zhang guorong li Jiagang Wu Department of Materials Science Sichuan UniversityChengdu 610065China Shanghai Institute of Ceramics Chinese Academy of SciencesShanghai 201800China Institute of Fluid Physics China Academy of Engineering PhysicsMianyang 621900China

The flourishing development of emerging electromechanical applications has stimulated an urgent demand for ferroelectric ceramics with high piezoelectric properties and broad temperature usage range.However,it remains a challenge to simultaneously obtain good piezoelectricity and reliable temperature stability in lead zirconate titanate(PZT)-based piezoelectric ceramics.To solve this issue,a synergetic strategy was proposed to introduce lead vacancies through niobium doping and construct morphotropic phase boundary(MPB).In this work,Pb_(0.905)Ba_(0.085)(V Pb″)_(0.01)[(Zr_(x)Ti_(1-x))_(0.98)Nb_(0.02)]O_(3)(PBZTN-x)material system was designed.Good comprehensive properties(d_(33)=864 pC/N,k_(p)=84%,T_(C)=201℃)and excellent temperature stability(less than 10%variation of electrical properties from 20℃ to 160℃)were obtained in PBZTN-0.540 ceramics.Good piezoelectricity can be attributed to high extrinsic contribution(domain wall motion)induced by Pb^(2+)vacancies and the existence of nano-domains emerged at MPB,while excellent temperature stability is mainly attributed to the minimized local stress in the lattice and the stable domain structure.

关键词： Piezoelectricity Lead vacancies Morphotropic phase boundary Temperature stability

Thiophene-based covalent organic frameworks for highly efficient iodine capture

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Chinese Chemical Letters 2023年第1期34卷 550-554页

作者： Xi Yan Yixin Yang guorong li Jianhua Zhang Yu He Ran Wang Zian lin Zongwei Cai Ministry of Education Key Laboratory of Analytical Science for Food Safety and Biology Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food SafetyCollege of ChemistryFuzhou UniversityFuzhou 350108China State Key Laboratory of Environmental and Biological Analysis Department of ChemistryHong Kong Baptist UniversityHong KongChina Radiation Environment Supervision Station of Fujian Province Fuzhou 350001China

Development of adsorbent materials for highly efficient iodine capture is high demand from the perspective of ecological environment and human health. Herein, the two kinds of thiophene-based covalent organic frameworks(COFs) with different morphologies were synthesized by solvothermal reaction using thieno[3,2-b]thiophene-2,5-dicarbaldehyde(TT) as the aldehyde monomer and tri(4-aminophenyl)benzene(PB) or tris(4-aminophenyl)amine(PA) as the amino monomer(denoted as PB-TT COF and PA-TT COF) and the as-prepared two heteroatoms-rich COFs possessed many excellent properties,including high thermal stability and abundant binding sites. Among them, PB-TT COF exhibited ultra-high iodine uptake up to 5.97 g/g in vapor, surpassing most of adsorbents previously reported, which was ascribed to its high specific surface(1305.3 m2/g). Interestingly, PA-TT COF with low specific surface(48.6m2/g) showed good adsorption ability for iodine in cyclohexane solution with uptake value of 750 mg/g,which was 2.38 times higher than that obtained with PB-TT COF due to its unique sheet-like morphology.Besides, the two COFs possessed good reusability, high selectivity and iodine retention ability. Based on experimental results, the adsorption mechanisms of both COFs were studied, revealing that iodine was captured by the physical-chemical adsorption. Furthermore, the both COFs showed excellent adsorption ability in real radioactive seawater treated safely, demonstrating their great potential in real environment.

关键词： Thiophene-based covalent organic frameworks Iodine Morphology Adsorption mechanisms Radioactive seawater

Copper(Ⅱ) ions-immobilized virus-like hollow covalent organic frameworks for highly efficient capture and sensitive analysis of amyloid beta-peptide 1–42 by MALDI-MS

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Chinese Chemical Letters 2022年第12期33卷 5174-5179页

作者： Wende Ma Chao Zhong Juan lin Zhuling Chen guorong li Wei Tong Yijing Wu Lan Zhang Zian lin Ministry of Education Key Laboratory of Analytical Science for Food Safety and Biology Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food SafetyCollege of ChemistryFuzhou UniversityFuzhou 350108China Department of Cardiology Fujian Provincial Governmental HospitalFuzhou 350003China

Amyloid beta-peptide 1-42(Aβ1-42)is one of the biomarkers of Alzheimer's disease,and its selective capture and quantitative detection are important for diagnosis and treatment of Alzheimer's disease.Herein,copper(Ⅱ)ions-immobilized virus-like hollow covalent organic frameworks(V-HCOFs@Cu^(2+))were synthesized by a facile approach.The as-prepared V-HCOFs@Cu^(2+)showed unique morphology,ultra-high specific surface(2552 m^(2)/g),uniform mesoporous structure(3.2 nm),superior chemical stability and abundant binding sites.Based on these excellent properties,the V-HCOFs@Cu^(2+)could be adopted as an ideal enrichment probe for highly efficient capture of Aβ1-42,exhibiting high adsorption capacity(320 mg/g),and fast adsorption equilibration time(3 min).In addition,an attractive approach of the V-HCOFs@Cu^(2+)-based matrix-assisted laser desorption/ionization mass spectrometry(MALDI-MS)was developed for the rapid screening and quantitative analysis of Aβ1-42 in human serum by using C-peptide as an internal standard,which exhibited low limit of detection(LOD,0.2 fmol/μL),and satisfactory recovery.This work provides an alternative solution for enrichment of biomarkers and also offers the potential applications of COFs in clinical analysis.

关键词： Virus-like hollow covalent organic frameworks Metal ion immobilization Amyloidβ-peptide 1–42 Capture Matrix-assisted laser desorption ionization mass spectrometry

Metal-organic framework nanofilm enhances serum metabolic profiles for diagnosis and subtype of cardiovascular disease

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Chinese Chemical Letters 2023年第6期34卷 273-277页

作者： Dan Ouyang Zhihua Fu guorong li Chao Zhong Jiahao Yuan Huan Huang Juan lin Gang Xu Zian lin Ministry of Education Key Laboratory of Analytical Science for Food Safety and Biology Fujian Provincial Key Laboratory of Analysis and Detection Technology for Food SafetyCollege of ChemistryFuzhou UniversityFuzhou 350108China State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of Sciences(CAS)Fuzhou 350002China Department of Cardiology Fujian Provincial Governmental HospitalFuzhou 350003China

Cardiovascular disease(CVD)is a global health problem and is thought to be responsible for almost half of all deaths in the world.Nevertheless,currently available diagnostic methods for CVD are strongly depended on clinical observation and monitoring,which commonly result in false diagnosis.Herein,an attractive strategy of a metal-organic framework(MOF)nanofilm-based laser desorption/ionization mass spectrometry(LDI-MS)was developed for enhancing serum metabolic profiling,which could provide precise diagnosis and molecular subtyping of CVD.The porous MOF nanofilm fabricated on indium-tin oxide(ITO)glass possessed enhanced ionization efficiency and size-exclusion effect,which endowed it as substrate with high sensitivity and selectivity for serum metabolites.Furthermore,the MOF nanofilm with uniform surface and high orientation provided high-quality and high-reproducibility serum metabolic profiles(SMPs)without any tedious pretreatment.Further analysis of extracted serum metabolic fingerprints could successfully distinguish patients with CVD from healthy controls and also differentiate two major subtypes of CVD.This work not only extends the application of MOF nanofilm as an attractive MS probe,but also provide an alternative way for precise diagnosis of CVD in molecular level.

关键词： Cardiovascular disease Mass spectrometry Metal-organic framework nanofilm Metabolites Precise diagnosis