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激光跟踪仪几何结构误差标定及修正

光学精密工程 2024年第11期32卷 1639-1652页

作者：王珊张滋黎董登峰周维虎纪荣祎潘映伶王国名崔成君中国科学院微电子研究所北京100029 中国科学院大学北京100049

为了提高激光跟踪仪坐标测量精度,分析了跟踪仪的几何结构误差,研究了横竖轴平移误差、横竖轴倾斜误差、激光平移误差和激光倾斜误差的标定和修正方法。利用几何分析法建立了几何结构误差模型,基于投影图像测量仪和检棒、PSD搭建了几何... 详细信息

为了提高激光跟踪仪坐标测量精度,分析了跟踪仪的几何结构误差,研究了横竖轴平移误差、横竖轴倾斜误差、激光平移误差和激光倾斜误差的标定和修正方法。利用几何分析法建立了几何结构误差模型,基于投影图像测量仪和检棒、PSD搭建了几何误差参数的标定装置,实现对几何误差的快速自动高精度标定及补偿。最后,利用误差标定实验测量出的几何误差代入误差补偿模型,与标尺的长度进行比对分析。实验结果表明:经几何误差修正后的跟踪仪坐标测量误差从13μm/m减小到4μm/m以内,测量精度约提升了9μm/m,验证了几何误差标定和修正方法的正确性,该方法可以提高激光跟踪仪的坐标测量精度。

关键词：激光跟踪仪几何结构误差误差标定误差修正最小二乘法

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Single molecule magnetic behavior and photo-enhanced proton conductivity in a series of photochromic complexes

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Chinese Chemical Letters 2022年第3期33卷 1417-1421页

作者： Qian Zhang Jixiang Hu Qi Li Dongxue Feng Zhenni Gao guoming wang College of Chemistry and Chemical Engineering Qingdao UniversityQingdao 266071China

Molecules with multifunctional properties are of immense interest in hybrid materials, while challenges still existed because of the limited compatibility of multiple functionalities in a single system. In this work, a series of metal-organic complexes were synthesized and characterized under the assembly of electron donor phosphonate, electron acceptor polypyridine ligand and spin carrier rare earth ions. All the compounds exhibited remarkable and reversible responses with photochromism and photomodulated fluorescence, originated from photogenerated radicals via electron transfer from phosphonates to polypyridine ligands. For the Dy analog, slow magnetic relaxation was observed at cryogenic temperature, indicating the single-molecule magnetic behavior. Furthermore, photogenerated radicals could enhance the proton conductive behavior, with about 2 times larger in magnitude after light irradiation for Dy and Y compounds. The introduction of photoluminescence, magnetism and proton conduction into metallic phosphonates can provide potential applications for photochromic materials.

关键词： Multifunctional Electron transfer Photochromism Single molecule magnetic behavior Proton conductivity

Ligand-regulated unusual nickel clusters: A centrosymmetric dicubane Ni_(8) and a tetrahedral Ni_(10) cluster

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Chinese Chemical Letters 2023年第3期34卷 522-525页

作者： Ying Zou Qiang Gao Na Sun Songde Han Xiaoyu Li guoming wang College of Chemistry and Chemical Engineering Qingdao UniversityQingdao 266071China School of Environmental and Chemical Engineering Jiangsu University of Science and TechnologyZhenjiang 212003China The Key Laboratory of Inorganic Molecule-Based Chemistry of Liaoning Province Shenyang University of Chemical TechnologyShenyang 110142China

Based on the reported Fe clusters constructed by using N-tris(hydroxymethyl)methylglycine (H_5thmmg),herein,we explored the use of H_5 thmmg for Ni ***,an octanuclear Ni cluster,Ni_(8)O(H_(3)thmmg)_6·2NO_(3)(Ni_(8)) was acquired under solvothermal *** metallic core is comprised of two centrosymmetric cubanes Ni_(4)(μ_(3)-O)_(3)(μ_6-O) linked by sharing an O^(2-)ion and six H_(3)thmmg^(2-) ligands are attached to the ***,the 2-mercapto-5-amino-1,3,4-thiadiazole (Hmat) ligand with both N and S donor atoms was introduced into the synthesis of Ni_(8) cluster,a disparate decanuclear nickel cluster,Ni_(10)O(OH)_(2)(H_(3)thmmg)_(4)(mat)_(8)(Ni_(10)) is assembled by H_(3)thmmg^(2-) and mat^(-) mixed *** metal core of Ni_(10)cluster is a pudgy tetrahedron,whose four vertexes are four Ni^(2+)ions and the remanent six Ni^(2+) ions are located in the tetrahedral *** H_(3)thmmg^(2-) ligands are located at the four vertices of the tetrahedron and 8 mat^(-) ligands are all on the six sides of the *** different synthetic conditions contribute to the different *** studies indicate that both complexes Ni_(8) and Ni_(10) display antiferromagnetic interactions.

关键词： Polymetallic Nickel clusters Ligand-regulated Synthesis Magnetic properties

黄芪发酵物通过调节Fas信号通路影响碘缺乏大鼠海马结构和学习记忆功能

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兰州大学学报（医学版） 2024年第5期50卷 26-33,40页

作者：李超杨伟伟杨晓晖王雪王国明沧州医学高等专科学校药理教研室河北沧州061001 沧州医学高等专科学校科技实验中心河北沧州061001 沧州市中医药康复保健产品技术创新中心河北沧州061001 沧州市甲状腺疾病工程技术研究中心河北沧州061001 沧州市中心医院妇二科河北沧州061001

目的探讨黄芪发酵物通过调节脂肪酸合成酶(Fas)信号通路对碘缺乏大鼠海马损伤和学习记忆功能的影响,以期选出药效最佳的黄芪制剂。方法60只Wistar大鼠随机分为对照组、模型组、黄芪发酵提取液4.00、2.00、1.00 g·kg^(-1)组和阳性药(左... 详细信息

目的探讨黄芪发酵物通过调节脂肪酸合成酶(Fas)信号通路对碘缺乏大鼠海马损伤和学习记忆功能的影响,以期选出药效最佳的黄芪制剂。方法60只Wistar大鼠随机分为对照组、模型组、黄芪发酵提取液4.00、2.00、1.00 g·kg^(-1)组和阳性药(左甲状腺素钠9×10^(-3)mg·L^(-1))组。除对照组外,各组大鼠喂养碘缺乏饲料(碘含量为20μg·kg^(-1))90 d构建甲状腺肿大鼠模型。检测各组大鼠血清中游离三碘甲腺原氨酸、游离甲状腺素、促甲状腺激素水平显示造模成功。跳台实验、Morris水迷宫实验检测各组大鼠的学习和记忆水平;酶联免疫吸附试验检测血清乙酰胆碱转移酶、乙酰胆碱酯酶、过氧化氢酶活性和乙酰胆碱、丙二醛含量;观察断头缺氧后存活时间和脑指数;苏木精-伊红染色、末端脱氧核苷酸转移酶介导的dUTP缺口末端标记染色观察海马组织病理学变化;同时,定量逆转录聚合酶链式反应检测Fas、半胱氨酸天冬氨酸蛋白酶-3(Caspase-3)、B淋巴细胞瘤-2基因(Bcl-2)、Bcl-2相关X蛋白(Bax)mRNA的相对表达;最后,蛋白质印迹法检测、Caspase-3、Bax、Bcl-2蛋白的表达。结果与对照组比较,模型组大鼠学习记忆能力明显下降,脑组织中乙酰胆碱水平、抗氧化活力降低,海马组织出现不同程度损伤和细胞凋亡,神经细胞排列紊乱、Fas、Caspase-3、Bax基因及蛋白表达增加,Bcl-2表达降低。与模型组相比,黄芪发酵物和阳性药组大鼠跳台潜伏期、错误次数和Morris水迷宫实验逃避潜伏期均明显减少,目标象限停留时间百分率和平台穿越次数均增加;血清乙酰胆碱转移酶、过氧化氢酶活性和乙酰胆碱含量升高,乙酰胆碱酯酶活性和丙二醛含量降低;缺氧后存活时间延长,脑指数增加;海马组织病理损伤得到明显改善;Fas、Caspase-3、Bax mRNA相对表达量减少,Bcl-2表达量增加,Bax/Bcl-2降低;蛋白质印迹法显示,Fas、Caspase-3、Bax蛋白表达量显著减少,Bcl-2蛋白表达增加,具有剂量依赖性。结论黄芪发酵物能够提高碘缺乏大鼠学习记忆水平,可能与抑制Fas信号通路及调节乙酰胆碱代谢、改善能量代谢、减轻氧化应激损伤和抑制凋亡效应有关。

关键词：黄芪发酵物碘缺乏脂肪酸合成酶海马学习记忆凋亡

Achieving an electron transfer photochromic complex for switchable white-light emission

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Chinese Chemical Letters 2022年第6期33卷 3203-3206页

作者： Qi Li Wuji Wei Zhenzhen Xue Ying Mu Jie Pan Jixiang Hu guoming wang College of Chemistry and Chemical Engineering Qingdao UniversityQingdao 266071China

Tuning white-light emission via free radicals is still a challenge in molecular-based functional ***, a new photoactive Zn^(2+) oxalate-based chain containing a polypyridine ligand was designed and synthesized with remarkably bifunctional photochromism and photo-actuated greenish white-light emission after UV, sunlight or Xe lamp light irradiation at room temperature. The photo-actuated coloration process was induced by the photogeneration of stable radicals originated from intermolecular electron transfers from oxalate components to the protonated polypyridine units, as demonstrated by UV–vis, IR,electron spin resonance and X-ray photoelectron spectra and magnetic measurements. Importantly, the on/off greenish white light emission(WLE) could be reversibly switched by generation and elimination of radicals via light irradiation and heat treatment, providing a feasible strategy for designing photoswitchable light emission diodes materials.

关键词： Charge separation Electron transfer Photochromism Photogenerated radicals White-light emission

Insulation Design Rule for a Spacer in SF_(6)/N_(2)-filled DC Gas Insulated Apparatus

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CSEE Journal of Power and Energy Systems 2024年第2期10卷 727-735页

作者： Hongyang Zhou guoming Ma Meng Zhang Cong wang Youping Tu Chengrong Li State Key Laboratory of Alternate Electrical Power System with Renewable Energy Sources and the Beijing Key Laboratory of High Voltage and EMC North China Electric Power UniversityBeijing 102206China

A recurring challenge of a DC SF_(6)/N_(2)-filled GIS/GIL apparatus is the charge accumulation at DC *** conventional design rules and knowledge of AC spacers may not be applicable for this new type of apparatus.A novel design rule is proposed considering the effect of accumulated charge on the threshold of electric field strength being resistant to the superposed voltage.A surface charge accumulation simulation model is introduced,and the key parameters in the simulation model are *** addition,an experimental platform for a 100 kV spacer flashover test is *** flashover tests under superimposed voltage with opposing polarities are carried out,and the withstanding voltage of the spacer is ***,based on the proposed model,the threshold of the surface electric field strength(tangential component)on the DC spacer in SF_(6)/N_(2) mixed gases is *** a reliable insulation design of a DC GIS/GIL apparatus filled with 0.7 MPa SF_(6)/N_(2),the threshold of surface electric field strength on the DC spacer is 12 kV/*** insulation design rule can be referenced in the design of a high-voltage DC SF_(6)/N_(2)-filled GIS/GIL apparatus.

关键词： Charge accumulation DC spacer flashover voltage SF_(6)/N_(2) threshold of surface electric field strength

Local field potentials,spiking activity,and receptive fields in human visual cortex

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Science China(Life Sciences) 2024年第3期67卷 543-554页

作者： Lu Luo Xiongfei wang Junshi Lu Guanpeng Chen guoming Luan Wu Li Qian wang Fang Fang School of Psychological and Cognitive Sciences and Beijing Key Laboratory of Behavior and Mental Health Peking UniversityBeijing 100871China School of Psychology Beijing Sport UniversityBeijing 100084China Department of Neurosurgery Sanbo Brain HospitalCapital Medical UniversityBeijing 100093China Beijing Key Laboratory of Epilepsy Epilepsy CenterSanbo Brain HospitalCapital Medical UniversityBeijing 100093China IDG/McGovern Institute for Brain Research Peking UniversityBeijing 100871China Peking-Tsinghua Center for Life Sciences Peking UniversityBeijing 100871China Beijing Institute for Brain Disorders Beijing 100069China State Key Laboratory of Cognitive Neuroscience and Learning and IDG/McGovern Institute for Brain Research Beijing Normal UniversityBeijing 100875China

The concept of receptive field(RF) is central to sensory neuroscience. Neuronal RF properties have been substantially studied in animals,while those in humans remain nearly unexplored. Here, we measured neuronal RFs with intracranial local field potentials(LFPs) and spiking activity in human visual cortex(V1/V2/V3). We recorded LFPs via macro-contacts and discovered that RF sizes estimated from lowfrequency activity(LFA, 0.5–30 Hz) were larger than those estimated from low-gamma activity(LGA, 30–60 Hz) and high-gamma activity(HGA, 60–150 Hz). We then took a rare opportunity to record LFPs and spiking activity via microwires in V1 simultaneously. We found that RF sizes and temporal profiles measured from LGA and HGA closely matched those from spiking activity. In sum, this study reveals that spiking activity of neurons in human visual cortex could be well approximated by LGA and HGA in RF estimation and temporal profile measurement, implying the pivotal functions of LGA and HGA in early visual information processing.

关键词： human visual cortex receptive field intracranial EEG local field potential spiking activity

基于层次分析法的城镇建设适宜性评价——以京津冀为例

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华北地质 2024年第1期47卷 94-103页

作者：白耀楠王国明刘宏伟李状韩博苗晋杰徐丹虹中国地质调查局天津地质调查中心(华北地质科技创新中心) 天津300170 中国地质调查局雄安城市地质研究中心天津300170

【研究目的】京津冀是工业化、城镇化高度聚集的世界级城市群。长期以来,京津冀地区人地关系矛盾突出,国土空间开发格局与资源环境空间布局匹配程度相对较低,需要科学全面的评价城镇建设适宜性和识别未来适宜城镇建设的潜力空间,以期为... 详细信息

【研究目的】京津冀是工业化、城镇化高度聚集的世界级城市群。长期以来,京津冀地区人地关系矛盾突出,国土空间开发格局与资源环境空间布局匹配程度相对较低,需要科学全面的评价城镇建设适宜性和识别未来适宜城镇建设的潜力空间,以期为城镇开发边界划定、城镇用地集约节约高效利用提供科学依据和决策支持。【研究方法】本文基于“双评价”指南建立京津冀地区城镇建设适宜性评价指标体系,利用层次分析-加权平均综合指数法对该地区的城镇建设适宜性进行了评价。在此基础上,结合土地“三调”数据,按照优先生态保护、稳定耕地数量的原则,依次从城镇建设适宜区中扣除生态保护极重要区,自然保护地,现状湿地、城镇和基础设施建设用地、特殊用地等,识别未来适宜城镇建设的潜力空间。【研究结果】京津冀城镇建设适宜区面积123027.2 km^(2),占全区陆地面积的56.98%,一般适宜区面积45773.43 km^(2),占21.20%,不适宜区面积4850.16 km^(2),占2.25%,城镇建设适宜区潜力规模为4676.30 km^(2),河北张家口市和承德市城镇建设用地建设潜力较大,其次为保定市、唐山市和秦皇岛市。【结论】北京东部、天津西部、保定东南部、沧州南部-衡水东、邯郸东部地下水严重超采且存在地面沉降问题,建议结合地下水禁(限)采,有条件时适度优化调整土地利用方式。活动断裂带通过地段可能直接影响城市、交通等重大工程规划建设及运行安全,建议加强活动断裂带调查评价,采取避让活动断层或提高相应抗震设防等级等措施。

关键词：京津冀城镇建设适宜性评价建设潜力

气相色谱-串联质谱法同时测定人参中33种农药残留量的不确定度评定

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数理医药学杂志 2024年第5期37卷 323-333页

作者：宋莹莹李健豪郭畅冰谢丽娟王国明徐芳菲吉林人参研究院植物化学研究室长春130031

目的探究影响气相色谱-串联质谱法测定人参中33种农药残留量时测量不确定度的主要因素。方法采用气相色谱-串联质谱法对人参中33种农药残留量进行测定,根据JJF 1059.1-2012《测量不确定度评定与表示》和JJF 1135-2005《化学分析测量不... 详细信息

目的探究影响气相色谱-串联质谱法测定人参中33种农药残留量时测量不确定度的主要因素。方法采用气相色谱-串联质谱法对人参中33种农药残留量进行测定,根据JJF 1059.1-2012《测量不确定度评定与表示》和JJF 1135-2005《化学分析测量不确定度评定》要求,建立不确定度评定的数学模型,分析在测定过程中的主要不确定度来源,即从样品的称量、标准溶液的稀释、样品的前处理和仪器测定的重复性等方面对各个分量进行评估。结果测量不确定度主要来源于回收率实验,样品平均回收率为79.61%~116.70%,33种农药残留在0.010~0.20 mg·kg^(-1)范围测量结果的扩展不确定度为±0.000718~±0.0252 mg·kg^(-1)。结论本评定方法为气相色谱-串联质谱法同时测定人参中33种农药残留量在临界点附近的结果判定提供了理论依据。

关键词：气相色谱-串联质谱法人参农药残留量同时测定不确定度评定

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